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Ion Chromatography with Pulsed Amperometric Detection for Determining Cyanide in Urine and Meconium Samples
PublicationThe parents’ addictions and eating habits have a significant influence on the child’s growth. The first stool of a newborn baby provides a large amount of information about xenobiotics transmitted by the mother’s body. The analytical technique used in the study is ion chromatography with pulsed amperometric detection (IC-PAD). The biological samples, which were obtained from women staying in a maternity ward and their partners,...
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Quenching effects in organic electroluminescence
PublicationWe examine various electronic processes that underlie the quenching of the emission from highly efficient phosphorescent and electrophosphorescent organic solid-state molecular systems. As an example, we study the luminescent efficiencies from the phosphorescent iridium (III) complex, fac tris (2-phenylpyridine) iridium [(Ir (ppy)3] doped into a diamine derivative doped polycarbonate hole-transporting matrix and in the form...
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Gaseous products from scrap tires pyrolisis
PublicationIn European Union 75% of used tires should be recycled. The most common method of used tires disposal, is burning in cement kilns, which does not solve the problem. Pyrolysis process can be an alternative way of utilization of tires. The aim of the researches was to check the influence of pyrolysis products (gas and oil fractions) on environment. Samples from pyrolysis process, like light oil fractions or pyrolysis gases were analyzed...
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Kreowanie nowej ścieżki rozwoju dzięki poprawie modelu procesów innowacji na Pomorzu
PublicationCreating of New Development Path Due to Upgrading the Innovation Process- es Model in Pomeranian Region. The study presents a change in the innovation model and a change of development path towards new industries and modernization of traditional indus- tries in the Pomeranian Voivodship. The characteristics of the region and the characteristics of the regional innovation system based on statistical data, existing research, analysis...
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Taking decisions in the diagnostic intelligent systems on the basis information from an artificial neural network
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Reinforcing and plasticizing effects of reclaimed rubber on the vulcanization and properties of natural rubber
PublicationThe production of high-added value reclaimed rubber (RR) is of great signifi-cance for the sustainability of rubber industries. To green recycle waste rub-bers and broaden the application of RR, a RR material with potentialreinforcing and plasticizing effects on nature rubber (NR) composites are pre-pared by a thermo-oxidative reclamation process. The reclamation degree ofRR is controlled by adjusting the content of soybean oil....
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Vegetable derived-oil facilitating carbon black migration from waste tire rubbers and its reinforcement effect
PublicationThree dimensional chemically cross-linked polymer networks present a great challenge for recycling and reutilization of waste tire rubber. In this work, the covalently cross-linked networks of ground tire rubber (GTR) were degraded heterogeneously under 150 °C due to the synergistic effects of the soybean oil and controlled oxidation. The degradation mechanism was discussed using Horikx theory and Fourier transformation infrared...
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Novel chalcone-derived pyrazoles as potential therapeutic agents for the treatment of non-small cell lung cancer
PublicationLung cancer is considered to account for approximately one-fifth of all malignant tumor-related deaths worldwide and is therefore one of the most lethal malignancies. Pyrazole scaffold possesses a wide range of biological and pharmacological activities, which play important roles in medicinal chemistry. The present study reports the synthesis and in vitro biological characterization of nine pyrazoles derived from chalcones as potential...
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Silicon oxycarbide-tin nanocomposite derived from a UV crosslinked single source preceramic precursor as high-performance anode materials for Li-ion batteries
PublicationIn this work, we report an innovative and facile UV light-assisted synthesis of a nanocomposite based on silicon oxycarbide (SiOC) and tin nanoparticles. SiOC ceramic matrix, containing a conductive free carbon phase, participates in lithium-ion storage, and buffers the volume changes of Li-alloying/de-alloying material. The reported synthesis procedure through a polymer-derived ceramic route involves the preparation of a single-source...
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Auto adaptation of mobile device characteristics to various acoustic conditions
PublicationThe proposed methodology of auto adaptation of the mobile device characteristics to various acoustic conditions is presented in the paper. The first goal of this study was to determine the parameters of the acoustic path of the mobile device, for both transmitting (speaker) and receiver (microphone). Results of the measurement of characteristics of mobile devices were presented. Information about characteristics of individual parts...
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Elektro- i magnetomodulacja dysocjacji ekscytonów w organicznych układach jednoskładnikowych i dwuskładnikowych typu donor elektronu - akceptor elektronu
PublicationW ramach rozprawy doktorskiej przeprowadzono badania procesu dysocjacji stanów wzbudzenia elektronowego w układach molekularnych jedno- i dwuskładnikowych typu donor elektronu - akceptor elektronu. Do tego celu wykorzystano technikę spektroskopii elektro- i magnetomodulacyjnej wykonując pomiary zarówno fotoprądu, jak i elektromodulowanej fotoluminescencji. Spektroskopia magnetomodulacyjna okazała się skutecznym narzędziem do opisu...
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Sprawiedliwość agrarna
Publicationprawiedliwość agrarna została napisana z intencją zreformowania stosunków społeczno-politycznych. Tekst opiera się na założeniu wywodzącym się z tradycji prawnonaturalnej, które brzmi, iż pierwotnie każdy był współwłaścicielem powierzchni Ziemi. Powstanie prywatnej własności ziemskiej (czyli, eo ipso, wywłaszczenie większości ludzi) należy zakwalifikować jako akt bezprawia, kumulujący się w historycznie nawarstwionych nierównościach...
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A new approach to determination of the two-mass model parameters of railway current collector
PublicationThe paper presents two mathematical models of railway current collectors both with two degrees of freedom. The first one, hereinafter Pantograph Articulated Model (PAM), has one degree of freedom in rotational motion and the second degree of freedom in translational motion. The second model, called henceforth as Pantograph Reference Model (PRM), has both degrees of freedom in translational motion. Differential equations of the...
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A new approach to determination of the two-mass model parameters of railway current collector
PublicationThe paper presents two mathematical models of railway current collectors both with two degrees of freedom. The first one, hereinafter Pantograph Articulated Model (PAM), has one degree of freedom in rotational motion and the second degree of freedom in translational motion. The second model, called henceforth as Pantograph Reference Model (PRM), has both degrees of freedom in translational motion. Differential equations of the...
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Application of ion chromatography with pulsed amperometric detection for the determination of trace cyanide in biological samples, including breast milk
PublicationCyanide (CN) is the biomarker of exposure to the components of tobacco smoke, although its presence in biological samples is also due to the consumption of products containing cyanogenic glycosides. In this work, we determine the concentration of the free cyanide in urine, saliva and breast milk matrices, using ion chromatography with pulsed amperometric detection (IC-PAD). IC-PAD is an emerging method, with only few documented...
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Performance of LSP preemption methods in different MPLS networks
PublicationPreemption in Multiprotocol Label Switching (MPLS) is an optional traffic engineering technique used to create a new path of high priority when there is not enough bandwidth available. In such case the path is admitted by removing one or more previously allocated paths of lower priority. As there are usually many possible sets of low priority paths which can be selected, a preemption algorithm is being started to select the best...
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Simulation of large thrust-bearing performance at transient states, warm and cold start-up
PublicationThe start-up of a large hydrodynamic thrust bearing of a vertical hydrogenerator is one of the most critical situations during the lifetime of a bearing. Hydrodynamic load capacity is low due to low speed and higher thermal deformations of the pad. A new approach to the simulation of a hydrodynamic bearing is shown in this article. A combination of finite elements method and computational fluid dynamics is used to perform the transient...
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Prospects of Decreasing Power Losses in a Hydrostatic Thrust Bearing
PublicationIn numerous machines, axial load is carried by tilting pad thrust bearings known since the beginning of 20th century. These bearings are commonly bath lubricated, which is simple, does not require any additional pumps, and, due to this, such systems are highly reliable. In a contemporary technology, however, minimization of friction losses became an important goal of machinery improvement. Calculations based on elementary rules...
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Procesy i efektywność usuwania zanieczyszczeń z odcieków ze składowisk odpadów komunalnych w oczyszczalniach hydrofitowych
PublicationOczyszczanie odcieków z SOK jest jednym z najbardziej istotnych problemów ekologicznych na świecie. Odprowadzenie odcieków do oczyszczalni ścieków komunalnych jest przeważnie niemożliwe, ze względu na ich zmienną ilość oraz skład, bardzo wysokie stężenia ChZT i azotu amonowego, a także obecność trwałych zanieczyszczeń organicznych (TZO) oraz metali ciężkich. Najlepszym rozwiązaniem jest oczyszczanie wód odciekowych na terenie składowiska....
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The evidence for the impact of policy on physical activity outcomes within the school setting: A systematic review
PublicationPurpose Despite the well-established health benefits of physical activity (PA) for young people (aged 4–19 years), most do not meet PA guidelines. Policies that support PA in schools may be promising, but their impact on PA behavior is poorly understood. The aim of this systematic review is to ascertain the level and type of evidence reported in the international scientific literature for policies within the school setting that...
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Emulsifying properties of surfactants and biosurfactants in the context of soil remediation
PublicationZbadano stabilność emulsji, w których fazę rozproszoną stanowił dodekan oraz bazowy olej syntetyczny typu polialfaolefin - PAO. Zbadano wpływ czasu i temperatury na stabilność emulsji zawierających różne stężenia surfaktantów (Triton X-100, biosurfaktant JBR 325) oraz różne zawartości fazy niepolarnej za pomocą aparatu Turbiscan Lab wykorzystując technikę wstecznego rozproszenia światła. We wszystkich próbkach stwierdzono niestabilności...
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Inteligentne hybrydowe systemy wyszukiwania informacji
PublicationIstnieje wiele metod wyszukiwania informacji. Artykuł przedstawia możliwości połączenia tych metod i skonstruowania uniwersalnego, hybrydowego systemu wyszukiwania. W artykule zaproponowana została architektura personalnego agenta wyszukiwania (PAW). Posiada on cechy systemu ekspertowego, wyszukiwarki oraz agenta komputerowego. PAW pozwala na pozyskiwanie informacji personalnych tj. numery telefonów osób znajomych. Ponadto umożliwia...
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Comparing some convolution-based methods for creation of surround sound. W: [CD-ROM] Collected papers. First Pan-American/Iberian Meeting on Acoustics. 144 Meeting of the Acoustical Society of America. III Iberoamerican Cong- ress of Acoustics. 9o Mexican Congress of Acoustics. Cancun, Q. R. Mxico, 2-6 Dec. 2002. [B.m.:ASA]**2002 paper 2pPP22, 7 s. 8 rys. 1 tab. bibliogr. 12 poz. system nagrań dźwięku dookólnego z wykorzystaniem splotu odpowiedzi impul- sowej sali.
PublicationW referacie przedstawiono eksperymenty związane z symulacją dźwięku dookól-nego w sali koncertowej. W tym celu wykorzystano splot odpowiedzi impulsowejz danego wnętrza (wielokanałowe nagrania odpowiedzi impulsowej) z nagraniamiz komory bezechowej. Uzyskany w ten sposób sygnał został następnie przypisa-ny do odpowiednich kanałów w systemie dookólnym. Uzyskane w ten sposób nag-rania były następnie porównywane w testach subiektywnych...
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Fading Modelling in Dynamic Off-Body Channels
PublicationThis paper presents an off-body fading channel model for Body Area Networks (BANs) in indoor environments. The proposed model, which is based on both simulations and measurements in a realistic environment, consists of three components: mean path loss, body shadowing, and multipath fading. Seven scenarios in an indoor environment (a medium-size room with furniture, mostly consisting of wooden tables and chairs) have been measured:...
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An Off-Body Channel Model for Body Area Networks in Indoor Environments
PublicationThis paper presents an off-body channel model for body area networks (BANs) in indoor environments. The proposed model, which is based on both simulations and measurements in a realistic environment, consists of three components: mean path loss, body shadowing, and multipath fading. Seven scenarios in a realistic indoor office environment containing typical scatterers have been measured: five were static (three standing and two...
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All-gather Algorithms Resilient to Imbalanced Process Arrival Patterns
PublicationTwo novel algorithms for the all-gather operation resilient to imbalanced process arrival patterns (PATs) are presented. The first one, Background Disseminated Ring (BDR), is based on the regular parallel ring algorithm often supplied in MPI implementations and exploits an auxiliary background thread for early data exchange from faster processes to accelerate the performed all-gather operation. The other algorithm, Background Sorted...
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Active Control of Highly Autocorrelated Machinery Noise in Multivariate Nonminimum Phase Systems
PublicationIn this paper, a novel multivariate active noise control scheme, designed to attenuate disturbances with high autocorrelation characteristics and preserve background signals, is proposed. The algorithm belongs to the class of feedback controllers and, unlike the popular feedforward FX-LMS approach, does not require availability of a reference signal. The proposed approach draws its inspiration from the iterative learning control...
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Competitiveness of the Visegrad Countries - Paths for Competitiveness Growth
PublicationThe article includes two objectives: 1) to determine competitiveness of V4 countries in terms of 12 pillars of competitiveness used by The Global Competitiveness Report of the WEF, 2) to propose taxonomic method to appoint a path of competitiveness growth of economies.
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Modelling of network schedule including priority of selected technical resources
PublicationThe paper presents a method of network planning CPM – Critical Path Method. The author compares models of optimal solutions to design deadlines for individual works, taking various leading technical resources such as is labor and a tower crane into account.
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Uczelnie są kuźnią rozwiązań inowacyjnych
PublicationUczelnie są kuźnią rozwiązań inowacyjnych, a także kuźnią kadr dla innych instytucji - dla PAN-u, dla instytutów branżowych. W stosunku do lat ubiegłych kilkakrotnie wzrosła liczba zgłoszeń patentowych.
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Electrochemical Characterization of Gelatine Derived Ceramics
PublicationNew materials obtained by pyrolysis of gelatine (G) and poly(1,2-dimethylsilazane) (PSN) (weight ratio: G/PSN 70/30) at temperatures 700 and 900 °C were characterized by SEM and Raman spectroscopy. The presence of ceramics influences on the cluster size of the materials. Electrochemical tests were performed by cyclic voltammetry and galvanostatic cyclic polarization. The capacity of G/PSN was 464 and 527 mAh/g for materials pyrolysed...
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Modelling of Mechanical Behaviour of High-Frequency Piezoelectric Actuators Using Bouc-Wen Model
PublicationThe paper presents the application of a modified, symmetrical Bouc-Wen model to simulate a mechanical behaviour of high-frequency piezoelectric actuators (PAs). In order to identify parameters of the model, a two-step algorithm was utilized. In the first stage, the mechanical parameters were identified by taking into account their bilinear variability and using a square input voltage waveform. In the second step, the hysteresis...
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HYDROSTATIC THRUST BEARING WITH REDUCED POWER LOSSES
PublicationIn many cases in rotating machinery, axial load is carried by tilting pad thrust bearings which have been developed since the beginning of 20th century. For high reliability and simplicity, most commonly the bearings are bath lubricated. In the times of sustainable development, however, minimization of friction losses becomes an important criterion for machinery assessment, and a strategic goal of their development. Performed calculations,...
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O zagospodarowaniu odpadów podczas II Bałtyckiego Festiwalu Nauki.
PublicationOpisano II Bałtycki Festiwal Nauki, który jest imprezą popularno-naukową organizowaną przez wyższe uczelnie województwa pomorskiego, instytuty naukowe PAN-u, instytuty branżowe oraz inne instytucje związane z nauką.
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The importance of the bottom layer in double-layer porous asphalt for noise reduction
PublicationDouble-layer porous asphalt concrete (DPAC) surfaces are generally considered to be the acoustically most effective low noise road surfaces ready for implementation. While DPAC used on highways in warm climates may have an average life of around 8 years, in Scandinavia with severe winter climate DPAC usually survive only about 3 years; partly due to wear of studded tyres. An ongoing project in Sweden, applying DPAC and single-layer...
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O działalności Komitetu Metrologii i Aparatury Naukowej Polskiej Akademii Nauk w roku 2002
PublicationPrzedstawiono skład osobowy oraz struktury działalności Komitetu Metrologii Aparatury Naukowej PAN. Opisano bardziej szczegółowo działalność naukową i organizacyjną, aktywność konferencyjną krajową i międzynarodową oraz aktywność wydawniczą w roku 2002.
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Równolegle przebiegające procesy separacji pianowej jonów Al(III), Cu(II) i Zn(II) z roztworów ich mieszanin
PublicationMetody flotacji jonowej i precypitacyjnej należą do procesów separacji pianowej, wykorzystujących zdolność selektywnej adsorpcji niektórych składników roztworu na powierzchni międzyfazowej gaz – ciecz. Do zalet separacji pianowej zalicza się m.in. niewysokie koszty inwestycyjne i eksploatacyjne oraz wysoką skuteczność w obróbce roztworów rozcieńczonych. Celem pracy jest ocena wpływu kluczowych parametrów na wydajność i przebieg...
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Determination of API content in a pilot-scale blending by near-infrared spectroscopy as a first step method to process line implementation
PublicationNear infrared (NIR) spectroscopy was used for estimation of powder blend homogeneity and manufacturing control of a medicinal product powder mixture containing active pharmaceutical ingredient (API). Aiming at initiating a Process Analytical Technology (PAT) activity, the first step was a stationary mode atline evaluation. In this, the content of pharmaceutical active compound in the powder mixtures intended to the direct tabletting...
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Application of Peracetic Acid for Biological Foam Elimination in the SBR Bioreactor
PublicationPrzedstawiono wyniki wstępnych badań nad zastosowaniem kwasu nadoctowego (PAA) do likwidacji piany biologicznej, spowodowanej przez bakterię nitkowatą Microthrix parvicella. Wykazano, że okresowe zraszanie powierzchni piany małymi dawkami kwasu nadoctowego (rzędu kilkudziesięciu ml 1% roztworu PAA/na 1 m2 piany o grubości 1 cm) powoduje niemal natychmiastwy zanik piany, wytworzonej na powierzchni osadu czynnego w bioreaktorze...
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Fading Modelling in Dynamic Off-Body Channels
PublicationThis paper presents an off-body fading channel model for Body Area Networks. The proposed model, based on both simulations and measurements at 2.45 GHz in a realistic indoor environment, consists of three components: mean path loss, body shadowing, and multipath fading. The first is modelled as a log function of distance, the path loss exponent being in between 0.4 and 1.6. A statistical perspective is taken for the other two components,...
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HYDRODYNAMIC THRUST BEARINGS WITH POLYMER LINING
PublicationPolymeric linings of sliding surfaces of the hydrodynamic bearings have been used successfully for over 50 years. Despite of their long history of operation and research, they have not become wide spread in industrial applications. This fact may be surprising, considering th e conclusions that have been published concerning bearing operation and design. This paper summarizes the current...
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A system for acoustic field measurement employing cartesian robot
PublicationA system setup for measurements of acoustic field, together with the results of 3D visualisations of acoustic energy flow are presented in the paper. Spatial sampling of the field is performed by a Cartesian robot. Automatization of the measurement process is achieved with the use of a specialized control system. The method is based on measuring the sound pressure (scalar) and particle velocity (vector) quantities. The aim of the...
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Nano Tin/Tin Oxide Attached onto Graphene Oxide Skeleton as a Fluorine Free Anode Material for Lithium-Ion Batteries
PublicationHerein, we show a composite formation method of tin/tin oxide nanoparticles with graphene oxide and CMC based on laser ablation technique as an electrode material for energy storage devices. The material exhibited a three-dimensional conducting graphene oxide network decorated with tin or tin oxide nanoparticles. The structure, homogeneous distribution of nanoparticles, and direct contact between inorganic and organic parts were...
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Fading Characteristics for Dynamic Body-to-Body Channels in Indoor and Outdoor Environments
PublicationThis paper presents an analysis of the fading characteristics in dynamic body-to-body channels, based on measurements performed at 2.45 GHz in indoor and outdoor environments. The statistical analysis of the small- and large-scale fading shows that the Nakagami Distribution is the best model for the former and the Log-Normal one for the latter. An important influence of body shadowing...
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Characteristics of Propagation Conditions in the Container Terminal Environment
PublicationIn the paper a characteristics of propagation conditions in the container terminal environment is presented. The investigated environment is characterized on the example of Gdansk Deepwater Container Terminal in Poland. An empirical propagation model for path loss calculation in mobile radio links in a container terminal environment is presented.
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From phosphanylphosphaalkenes to coordination copper and silver polymers containing P–P bonds
PublicationThis study was focused on the activation of the C[double bond, length as m-dash]P bond via reactions of Ph2C[double bond, length as m-dash]P-PtBu2 (1) with 1,6-hexanediol and selected dithiols (1,4-butanedithiol, 1,4-benzenedithiol and 1,4-benzenedimethanethiol). These reactions proceed according to a 1,2-addition mechanism, providing new compounds with formulas {(Ph)2(H)C-P-PtBu2}{μ2-(O-(CH2)6-O)}{tBu2P-P-C(H)(Ph)2} (2), {(Ph)2(H)C-P-PtBu2}{μ2-(S-(CH2)4-S)}{tBu2P-P-C(H)(Ph)2}...
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The Workshop on Multi-Phase Flows
PublicationPrzedstawiono ideę warsztatów ''Modelowanie przepływów wielofazowych w układach termochemicznych'' - organizowanych corocznie - od 2000 roku, przez Podsekcję Przepływów Wielofazowych Komitetu Mechaniki PAN. Omówiono tematykę VI Warsztatów, które były poświęcone głównie metodom eksperymentalnym.
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Gasochromic effect in nanocrystalline TiO2 thin films doped with Ta and Pd
Publicationw pracy zebrano wyniki badań cienkich warstw domieszkowanego tlenku tytanu. w szczególności zaprezentowano zmianę przezroczystości pod wpływem działania par alkoholu etylowego. badane warstwy zostały naniesione na szklane podłoże metodą rozpylania magnetronowego.
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Modelowanie przepływów i procesów technologicznych w urządzeniach i systemach wodociągowych i kanalizacyjnych
PublicationRozdział w pracy zbiorowej, przygotowanej przez Sekcję Inżynierii Sanitarnej KILiW PAN, stanowiącej ekspertyzę poświęconą stanowi obecnemu i kierunkom rozwoju przedmiotowej dyscypliny nauk technicznych. Rozdział dotyczy problematyki modelowania przepływów i procesów technologicznych.
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Modélisation d'ordre non entier des machines synchrones. Modèle fréquentiel non linéaire, identification des paramètres, calcul de la réponse temporelle.
PublicationDans les réseaux d'énergie électrique contemporains, on assiste à une diversification considérable des différentes sources d'énergie. L'énergie produite est transformée par une grande quantité de dispositifs électriques pour être finalement acheminée à diverses installations électriques. Il devient donc primordial d'améliorer les modèles des différents composants électriques afin de pouvoir prévoir les interactions entre eux et...