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Search results for: temperatura ekwiwalentna
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Structural changes of a simple peptide—Trpzip-1—in aqueous solutions and the corresponding hydration phenomena under the influence of temperature
PublicationTrpzip-1, a simple β-hairpin, is a rare example of peptide with stable secondary structure and can be a convenient model to study temperature-related processes that potential prion or amyloid proteins undergo. Although its sequence is simple, the exact processes which the peptide undergoes in aqueous solutions are quite complex and not well understood. The selection of well-established experimental (DSC, FTIR) and theoretical methods...
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Temperature, velocity and mean turbulence structure in strongly heated internal gas flows. Comparison of numerical predictions with data
PublicationW pracy przedstawiono symulacje numeryczne przy użyciu szeregu modeli turbulencji celem analizy silnie ogrzewanego przepływu powietrza w pionowych rurach. Obliczenia porównano z danymi eksperymentalnymi. Analizowano modyfikacje pola prędkości, temperatury i turbulencji. W rozpatrywanych warunkach odnotowano silną wrażliwość obliczeń na silnie zmieniające się pole temperatury. Stwierdzono, że analizowane przypadki najlepiej odzwierciedla...
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Influence of temperature and anion type on thermophysical properties of aqueous solutions of morpholine based amino acid ionic liquids
PublicationDensities and sound velocities of aqueous solutions of N-butyl-N-methylmorpholine based amino acid ionic liquids (AAILs), including N-acetyl-L-alanine, N-acetyl-Lvalinate, N-acetyl-L-leucinate, and N-acetyl-L-izoleucinate anions were measured at a temperature from 293.15 to 313.15 K at 5 K intervals and atmospheric pressure. These data were used to calculate the apparent molar volumes and the apparent molar compressibilities in...
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Metallurgical characterization and high-temperature tensile failure of Inconel 617 alloy welded by GTAW and SMAW—a comparative study
PublicationTwo types of the weld joint of Inconel 617 alloy were produced using gas tungsten arc welding (GTAW) and shielded metal arc welding (SMAW) processes with ERNiCrCoMo-1 filler metal and ENiCrCoMo-1 electrode, respectively. The weld metal showed the segregation of the principle alloying elements like Mo and Cr along the inter-dendritic spaces, triggering the formation of secondary phases. The microstructure characterization of the...
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Experimental and theoretical study on high-temperature creep of VT6 titanium alloy under multi-axial loading conditions
PublicationIn the framework of damage mechanics, we discuss a new mathematical model that describes the kinetics of the stress–strain state and damage accumulation during material degradation by the mechanism of long-term strength under complex multiaxial stress state. An experimental and theoretical technique is proposed for determination of material parameters and scalar constitutive functions for damaged media based on specially set experiments...
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Warunki krystalizacji cienkich warstw V2O5 i V2O3 wytwarzanych metodą zol-żel
PublicationPraca ta przedstawia wyniki badań struktury cienkich warstw tlenku wanadu otrzymanych metodą zol - żel. Cienkie warstwy osadzano metodą spin - coating na podłożach wykonanych ze szkła kwarcowego oraz krzemowych. Tak przygotowane próbki wygrzewano w zakresie temperatur od 200 °C do 1200 °C. Zakres temperatur dobrano w taki sposób, aby można było zarówno określić optymalną temperaturę krystalizacji nanoprętów V2O5 jak i otrzymać...
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Michał Ryms dr inż.
PeopleMichał Ryms, PhD, Eng. is the physicist, graduate of the Gdańsk University of Technology. PhD thesis defended at the Chemical Faculty. Since 2011 an employee at the Department of Chemical Apparatus and Theory of Machines, Chemical Faculty, Gdansk University of Technology, POLAND – now as an assistant professor. His research interests includes: improvement of energy efficiency and possibilities of new application of phase change...
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Analiza lepkosprężysta konstrukcji nawierzchni drogowych z zastosowaniem modelu Burgersa
PublicationMieszanki mineralno-asfaltowe wykorzystywane w warstwach asfaltowych nawierzchni charakteryzują się właściwościami sprężystymi i lepkimi. Zależą one istotnie od temperatury. Im jest ona wyższa, tym bardziej znaczące są właściwości lepkie mma, które są przyczyną powstawania trwałych deformacji (kolein). Przedmiotem badań było modelowanie zachowania się mma w konstrukcji nawierzchni w wysokich temperaturach przy wykorzystaniu modelu...
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Wpływ utleniania w wysokich temperaturach na struktury napawanych warstw na bazie kobaltu
PublicationPrzedmiotem badań są napawane plazmowo warstwy wykonane ze stopu kobaltu zawierające ok. 29% chromu, ok. 5% wolframu i ok. 2% niklu, nałożone powierzchnie przylgni grzybków zaworów wylotowych silnika dieslowskiego. Powierzchnia podlega zarówno oddziaływaniom temperatury i środowiska, jak i oddziaływaniom mechanicznym. Podczas badań warstwy poddano oddziaływaniu środowiska utleniającego i wysokich temperatur: 750°C- górna w normalnej...
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Metody określania zdatności zespołów i układów hydraulicznych uruchamianych w niskich temperaturach otoczenia
PublicationPrzedstawiono badania eksperymentalne zespołów hydraulicznych w warunkach szoku termicznego. W tych warunkach może dochodzić do nieprawidłowej ich pracy, szczególnie przy dużej różnicy temperatur oleju i zespołów w chwili początkowej. Zasadniczym czynnikiem konstrukcyjnym, decydującym o dopuszczalnych parametrach działania zespołów hydraulicznych w warunkach szoku termicznego, jest efektywny luz między współpracującymi elementami...
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Cold Start Emissions of Spark-Ignition Engines at Low Ambient Temperatures as an Air Quality Risk
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Excess Emissions and Fuel Consumption of Modern Spark Ignition Passenger Cars at Low Ambient Temperatures
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A comparative study on geopolymers synthesized by different classes of fly ash after exposure to elevated temperatures
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Tribological synergy between classical ZDDP and innovative MoS2 and MoO3 nanotube additives at elevated temperatures
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Deviations of treeline Norway spruce radial growth from summer temperatures in East-Central Europe
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The effects of Fe3O4 and Fe3O4/SiO2 nanoparticles on the mechanical properties of cement mortars exposed to elevated temperatures
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X-Ray Computer Tomography Study of Degradation of the Zircaloy-2 Tubes Oxidized at High Temperatures
PublicationThe investigations of high-temperature oxidation of zirconium alloys, applied for fuel pellets in nuclear power plants, are usually limited to oxidation kinetics, phase transformations and microstructural characterization. The purpose of this research was to characterize the degradation phenomena occurring within oxide layer and at the interface oxide/metal, on internal and external Zircaloy-2 tube...
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Long-Term Stability of Benzodiazepines and Z-Hypnotic Drugs in Blood Samples Stored at Varying Temperatures
PublicationBenzodiazepines (BZDs) and Z-drugs are among the most commonly prescribed pharmaceuticals in the world and are considered standard care for various mental illnesses and for treatment of sleeping and anxiety disorders, alcohol withdrawal, muscle spasms and epilepsy. Some BZDs are not allowed as pharmaceuticals in many countries, and they are used as "designer benzodiazepines" (DBZDs). All these compounds are typically screened in...
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Effect of long term service at elevated temperatures on mechanical properties of Manaurite XM reformer tubes
PublicationMicrostructure transformations occur in the Manaurite XM cast steel tubes during long-term operation in the reformer furnace were revealed and described. The rela tionship between mechanical properties, an increase of internal diameter of the tube and microstructure degradation is discussed. Static tensile test was performed on two types of samples with different shapes. It has been shown differences in the results of tests...
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Mechanizm nanokrystalizacji warstwy wierzchniej stopu Al-Si nadtapianego laserem w niskiej temperaturze.
PublicationPrzedstawiono mechanizm nanokrystalizacji stopu aluminium nadtapianego laserowo po schłodzeniu do niskiej temperatury w powiązaniu z obserwacjami struktury warstwy wierzchniej.
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Amides as models to study the hydration of proteins and peptides — spectroscopic and theoretical approach on hydration in various temperatures
PublicationInteractions with water are one of the key factors which determine protein stability and activity in aqueous solutions. However, the protein hydration is still insufficiently understood. N-methylacetamide (NMA) is regarded as a minimal part of the peptide backbone and the relative simplicity of its structure makes it a good model for studies on protein–water interactions. In this paper, the influence of NMA and N,N-dimethylacetamide...
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Highly stable CsFAPbIBr perovskite solar cells with dominant bulk recombination at real operating temperatures
PublicationMixed-cation mixed-halide perovskite solar cells have been characterized in DC at different temperatures (from −20 °C up to 50 °C) and the time evolution of the device efficiency has been assessed using different degradation protocols (indoors and outdoors). The completely planar p–i–n structure is ITO/CuNiOx/PTAA/CsFAPbIBr/PCBM/PEI/Ag. Pristine current–voltage characteristics barely show hysteresis, at any temperature. Open circuit...
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EFFECT OF WATER ACTIVITY AND TEMPERATURE ON GROWTH AND LIPOLYTIC ACTIVITY OF PENICILLIUM CHRYSOGENUM STRAINS IN LIQUID CULTURE MEDIA WITH PLANT OILS
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Winter temperature and forest cover have shaped red deer distribution in Europe and the Ural Mountains since the Late Pleistocene
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Temperature-Caused Changes in Raman Pattern and Protein Profiles of Winter Triticale (x Triticosecale, Wittm.) Field-Grown Seedlings
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Monolithic polydimethylsiloxane-modified silica composites prepared by a low-temperature sol–gel micromolding technique for controlled drug release
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In-situ FTIR study of reaction mechanism and chemical kinetics of a Xundian lignite during non-isothermal low temperature pyrolysis
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Photoluminescence enhancement study in a Bi-doped Cs2AgInCl6 double perovskite by pressure and temperature-dependent self-trapped exciton emission
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Room temperature ionic liquid-based dispersive liquid–liquid microextraction of uranium in water samples before spectrophotometric determination
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Data normalisation for Lamb wave–based damage detection using cointegration: A case study with single- and multiple-temperature trends
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Spectral characteristic of high-dose high-temperature emission from LiF:Mg,Cu,P (MCP-N) TL detectors
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Effect of bitumen characteristics obtained according to EN and Superpave specifications on asphalt mixture performance in low-temperature laboratory tests
PublicationThe paper aims to identify those characteristics of bitumen which have the greatest impact on asphalt mixture low-temperature performance. It was observed that stiffness and m-value of bitumen from BBR test were moderately related to stiffness and m-value of asphalt mixture obtained from 3 PB test. Simultaneously those rheological properties significantly impact on cryogenic stresses induced during TSRST test. The multiple regression...
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Predicting enthalpy of vaporization for Persistent Organic Pollutants with Quantitative Structure–Property Relationship (QSPR) incorporating the influence of temperature on volatility
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Antioxidant properties of infusions from leaves of sweet potato (Ipomoea batatas L. Lam) depending on temperature and brewing time
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Low-temperature synthesis of zeolite from perlite waste — Part I: review of methods and phase compositions of resulting products
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POSZUKIWANIE RELACJI DIAGNOSTYCZNYCH POMIĘDZY USZKODZENIAMI W KANALE SPALIN WYLOTOWYCH SILNIKA O ZS A SZYBKOZMIENNĄ TEMPERATURĄ SPALIN
PublicationTemperatura spalin wylotowych tłokowego silnika spalinowego o zapłonie samoczynnym, mierzona w charakterystycznych przekrojach kontrolnych jego układu cieplno-przepływowego, może stanowić cenne źródło informacji diagnostycznej o stanie technicznym elementów ograniczających wydzielone w ten sposób przestrzenie robocze, wraz z układem turbodoładowania, ale także jego układu zasilania paliwem i wymiany czynnika roboczego. W standardowych...
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Low temperature deposition of dense MnCo 2 O 4 protective coatings for steel interconnects of solid oxide cells
PublicationIn this work manganese cobalt spinel (MnCo2O4) coatings were deposited on steel substrates by spray pyrolysis at 390 °C. This is at much lower temperatures than previously reported (typically in excess of 900 °C). It was possible to produce coatings with well controlled thickness (2-5-10 μm). The as-deposited coatings were evaluated for their microstructural changes and electrical conductivity up to 800 °C. Results confirm the...
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Influence of Storage Time and Temperature on the Toxicity, Endocrine Potential, and Migration of Epoxy Resin Precursors in Extracts of Food Packaging Materials
PublicationThe aim of the present study was to establish a standard methodology for the extraction of epoxy resin precursors from several types of food packages (cans, multi-layered composite material, and cups) with selected simulation media (distilled water, 5% ethanol, 3% dimethyl sulfoxide, 5% acetic acid, artificial saliva) at different extraction times and temperatures (factors). Biological analyses were conducted to determine the acute...
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Exhaust gas temperature measurements in diagnostic examination of naval gas turbine engines. Part III. Diagnostic and operating tolerances
PublicationThe third part of the article presents a method for detecting failures of the automatic engine control system with the aid of an exhaust gas temperature setter, specially designed and machined for this purpose. It also presents a procedure of identifying the operating tolerances and determining the diagnostic tolerances for the exhaust gas temperature recorded in the naval turbine engine during the start-up and acceleration processes....
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Wpływ temperatury wody chłodzącej w skraplaczu na ilość produkowanej mocy elektrycznej w obiegu parowym 200MW
PublicationReferat przedstawia analizę techniczną wpływu zmian temperatury wody chłodzącej skraplacz na ilość produkowanej energii elektrycznej, jak również zmiany jednostkowego zużycia ciepła dla obiegu elektrowni Turów z turbiną 200MW. Analiza została przeprowadzona przy pomocy programu DIAGAR oraz jego preprocesora Projdiag w którym został stworzony wstępny graf obliczeniowy a także wygenerowane dane, dzięki którym możliwe było przeprowadzenie...
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Calculation of silicon cell temperature of loaded photovoltaic module based on thermal coefficients for different weather conditions of Northern Poland
PublicationWydajność obciążonego modułu fotowoltaicznego zależy silnie od natężenia promieniowania słonecznego, temperatury otoczenia, prędkości wiatru i temperatury wewnętrznej składowych ogniw fotowoltaicznych. Sprawność konwersji fotowoltaicznej spada istotnie wraz z e wzrostem temperatury złącza p-n. Pomiar tej temperatury jest niemożliwy i oblicza się ją w oparciu o mierzoną wartość temperatury przedniej lub tylnej powierzchni modułu...
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Photocatalytic activity of boron-modified TiO2 under visible light: The effect of boron content, calcination temperature and TiO2 matrix
PublicationPrzedstawiono wpływ temperatury kalcynacji (200, 300, 350, 400, 450 oraz 600oC) na fotoaktywność w świetle widzialnym (l> 400 nm) oraz właściwości powierzchniowe TiO2 modyfikowanego borem. B-TiO2 został przygotowany metodą impregnacji powierzchniowej. Jako prekursor bory wykorzystano ester trietylowy kwasu borowego (BATE). Charakterystyka otrzymywanych fotokatalizatorów obejmowała wyznaczenie powierzchni właściwej, właściwości...
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Exhaust gas temperature measurements in diagnostic examination of naval gas turbine engines. Part I: Steady-state processes
PublicationThe article presents a possible method of detecting failures in the flow section and supply system of a naval gas turbine engine based on the exhaust gas temperature measured behind the gas generator. This temperature is a basic diagnostic parameter use for evaluating the technical state of the turbine engine in operation, and is monitored during engine start-ups, accelerations and decelerations of rotor units, and steady-load...
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Variable-temperature X-ray diffraction study of structural parameters of NH---S hydrogen bonds in triethylammonium and pyridinium silanethiolates
PublicationHydrogen bonds in triethylammonium and pyridinium silanethiolate salts have been characterized by X-ray, FT–IR and NMR spectroscopies. DFT calculations reveal strongly asymmetric double-well minima at the potential energy curves of the studied compounds
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Comparative analysis of thermodynamic cycles of selected nuclear ship power plants with high-temperature helium-cooled nuclear reactor
PublicationThis paper presents a comparative analysis of thermodynamic cycles of two ship power plant systems with a high-temperature helium- cooled nuclear reactor. The first of them is a gas system with recuperator , in which classical gas chamber is substituted for a HTGR reactor (High Temperature Gas-cooled Reactor) . The second of the considered cycles is a combined gas-steam system where working medium flux from gas turbine outlet...
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CPLFD-GDPT5: High-resolution gridded daily precipitation and temperature data set for two largest Polish river basins
PublicationThe CHASE-PL (Climate change impact assessment for selected sectors in Poland) Forcing Data–Gridded Daily Precipitation & Temperature Dataset–5 km (CPLFD-GDPT5) consists of 1951–2013 daily minimum and maximum air temperatures and precipitation totals interpolated onto a 5 km grid based on daily meteorological observations from the Institute of Meteorology and Water Management (IMGW-PIB; Polish stations), Deutscher Wetterdienst...
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Preparation of methanation catalysts for high temperature SOEC by β-cyclodextrin-assisted impregnation of nano-CeO2 with transition metal oxides
PublicationThe aim of this work was to prepare and examine the catalytic activity of nanometric CeO2 decorated with transition metal oxides – Ni, Co, Cu, Fe and Mn – towards a high-temperature methanation process under SOEC CO2/H2O simulated co-electrolysis conditions. Samples were prepared using the wet impregnation method via the conventional process and with the addition of native cyclodextrin. The influence of β-cyclodextrin (βCD) onto...
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Non-Coaxially Rotating Motion in Casson Martial along with Temperature and Concentration Gradients via First-Order Chemical Reaction
PublicationThe effect of non-coaxial rotation on the transport of mass subjected to first-order chemical reaction is studied analytically. The effects of thermal radiation, buoyancy, constructive and destructive chemical reactions along with Casson fluid in rotating frame are discussed. Time evolution of primary and secondary velocities, energy and solute particles are analyzed. The behavior of flow under the variation of intensity of magnetic...
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Morphology changes in Fe-Cr porous alloys upon high-temperature oxidation quantified by X-ray tomographic microscopy
PublicationThe effect of high-temperature oxidation at 850 C (10 h, 30 h, 100 h) and 900 C (10 h) on porous (30 % porosity) ferritic stainless steel (Fe22Cr) has been investigated using synchrotron tomographic microscopy, which allowed for visualisation, separation and quantitative analysis of the metallic core, closed pores, open pores and oxide scale phase. The same regions within the samples were investigated before and after oxidation...
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High-temperature Corrosion of ~ 30 Pct Porous FeCr Stainless Steels in Air: Long-Term Evaluation Up to Breakaway
PublicationIn this work, a long-term (up to 6000 hours) corrosion evaluation of three porous (~ 30 pct of initial porosity) ferritic iron-chromium alloys with different Cr contents (20, 22, and 27 wt pct of Cr) was carried out at 600 C, 700 C, 800 C, and 900 C in air. Mass gain measurements and SEM analyses revealed that at temperatures above 600 C, all alloys exhibit breakaway corrosion, whereas at 600 C, none of the alloys were heavily...