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Search results for: TADESZ SENDZIMIR
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Reactions of Lithium Salts of Triphosphanes tBu2P-PLi-PtBu2 and tBu2P-PLi-P(NEt2)2 with Metal Complexes [(R3P)2MCl2] (M = Ni, Pd, Pt, R3P = Et3P, pTol3P, Ph2EtP, iPr3P)
PublicationtBu2P-PLi-PtBu2·2THF reacts with [(R3P)2MCl2] (M = Pt, Pd, Ni; R3P = Et3P, pTol3P, Ph2EtP, iPr3P) to yield isomers of [(1,2-η-tBu2P=P-PtBu2)M(PR3)Cl], in which the tBu2P-P-PtBu2 ligand adopts the arrangement of a side-on bonded 1,1-di-tert-butyl-2-(di-tert-butylphosphanyl)diphosphenium cation. tBu2P-PLi-P(NEt2)2·2THF reacts with [(R3P)2MCl2] but does not form complexes with a tBu2P-P-P(NEt2)2 moiety, however, splitting...
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Nonlinear Influence of Sound on the Vibrational Energy of Molecules in a Relaxing Gas
PublicationDynamics of a weakly nonlinear and weakly dispersive flow of a gas where molecular vibrational relaxation takes place is studied. Variations in the vibrational energy in the field of intense sound is considered. These variations are caused by a nonlinear transfer of the acoustic energy into energy of vibrational degrees of freedom in a relaxing gas. The final dynamic equation which describes this is instantaneous, it includes a...
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A spice equivalent circuit for modeling the performance of dual frequency echo-sounder
PublicationThe paper presents novel network equivalent circuit of piezoceramic circular disc transducers that takes into account thickness and radial mode of vibrations. The starting point of the analysis is 4-port description of circular disc element representing the solution of wave equation set in radial and thickness directions. The approximate solution for harmonic case is represented in the form of 4x4 matrix, which is synthesised and...
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Quality negotiation mechanism for e-learning platforms
PublicationZarządzanie jakością w aplikacjach działających w środowiskach sieci WEB opiera się na zadaniach związanych z wykrywaniem jakości połączenia klient - serwer oraz na optymalnym przydziale zasobów wedle jakości takowego połączenia. Optymalne zarządzanie jakością zależy od wypracowanego kompromisu pomiędzy jakością łącza a jakości transportowanego łączem zasobu. Artykuł opisuje możliwy do implementacji mechanizm odpowiedzialny za...
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Determining QoS in the Video Telephony Service in an IP Environment
PublicationIP networks are indispensable nowadays. They are among the most efficient platforms. The constantly growing number of users and new services in these networks - the largest being the Internet - requires a good quality of any application used.Determining the QoS in real-time services is particularly important. This work is dedicated to exactly this aspect of the real-time service Video Telephony over IP (VToIP). First, the ITU-T...
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TRANSPORT POSSIBILITY FOR MPEG-4/AVC- AND MPEG-2-ENCODED VIDEO DATA IN IPTV: A COMPARISON STUDY
PublicationIPTV (Television over IP) is a modern service with a great potential to expand. It uses the IP transport platform, that is already in worldwide operation. At the time of writing, two techniques are used to transport the video and audio data of IPTV: MPEG-2 TS and Native RTP. The two techniques quite definitely have an influence on both quality of service (QoS) and quality of experience (QoE). This paper sets out to demonstrate...
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Ocena wpływu wirtualizacji na jakość usługi telekonferencji w systemie VoIP
PublicationZastosowanie wirtualizacji w systemach informatycznych jest dzisiaj bardzo powszechne. Pod względem ekonomicznym wirtualizacja umożliwia efektywniejsze wykorzystanie zasobów. Dodatkowo w aspekcie technicznym oddzielenie fizycznych zasobów od logicznych instancji pozwala na poprawę niezawodności i dostępności systemu. Separacja między poszczególnymi wirtualnymi maszynami pozwala na zapewnienie większego poziomu bezpieczeństwa. W...
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Influence of the jitter buffer on the quality of service VoIP.
PublicationVoIP (Voice over IP) is a modern service with enormous potential for yet further growth. It uses the already available and universally implemented IP transport platform. One significant problem, however, is ensuring the Quality of Service, abbreviated QoS. This paper addresses exactly that issue. In an extensive investigation the influence of jitter buffers on QoS is being examined in depth. Two implementations, namely a passive...
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eLearning im Wandel der Zeit am Beispiel der TU Gdansk und der FH Flensburg
PublicationW referacie omówiono zmiany systemów eLearning na przykładzie ich rozwoju na Politechnice Gdańskiej i w Wyższej Szkole Zawodowej we Flensburgu. Dokonano analizy pierwszych rozwiązań, w tym własnych systemów i narzędzi, jak również dokonanego na obu uczelniach zwrotu w kierunku otwartych systemów LMS. Podkreślono rolę oceny jakości(QoS) systemów zdalnego nauczania.
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Core loss resistance impact on sensorless speed control of an induction motor using hybrid adaptive sliding mode observer
PublicationInduction motors (IMs) experience power losses when a portion of the input power is converted to heat instead of driving the load. The combined effect of copper losses, core losses, and mechanical losses results in IM power losses. Unfortunately, the core losses in the motor, which have a considerable impact on its energy efficiency, are not taken into account by the generally employed dynamic model in the majority of the studies. Due...
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Multiscalar Control Based Airgap Flux Optimization of Induction Motor for Loss Minimization
PublicationBased on the induction motor model, considering the core loss resistance that accounts for magnetic characteristic saturation, a speed control approach is devised with an adaptive full-order (AFO) speed observer. The induction motor model analysis is done sincerely in a stationary reference frame. The control approach incorporates a flux reference generator designed to meet optimal operational circumstances and a nonlinear speed...
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New approach for determining the QoS of MP3-coded voice signals in IP networks
PublicationPresent-day IP transport platforms being what they are, it will never be possible to rule out conflicts between the available services. The logical consequence of this assertion is the inevitable conclusion that the quality of service (QoS) must always be quantifiable no matter what. This paper focuses on one method to determine QoS. It defines an innovative, simple model that can evaluate the QoS of MP3-coded voice data transported...
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New Tool for Examining QoS in the VToIP Service
PublicationThis paper is dedicated to the subject of measuring QoS in the Video Telephony over IP (VToIP) service. QoS measurement models in general and then models designed specifically for measuring QoS in the VToIP service are presented. A new numerical tool for examining the quality of VToIP video streams VToIP is described. The tool’s functionality is then put to the test in a number of analysis scenarios. The results and insights gained...
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Opposite pressure impact on electron-phonon coupling in Eu2+ and Ce3+ doped AlN
Open Research DataThis data analyzes the influence of pressure on electron–lattice interactions in the 5d excited states of Ce3+ and Eu2+ in the AlN host based on pressure-dependent photoluminescence and photoluminescence excitation spectra. High-pressure measurements on AlN samples doped with Eu2+ and Ce3+ ions reveal that the Stokes shift increases with pressure for...
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The luminescence study of Ga1.98–xAlxO3:0.02Cr3+ coumpounds.
Open Research DataA chemical and mechanical pressure-induced photoluminescence tuning method was developed through structural evolution and hydrostatic pressure involving phase transition. A series of Ga1.98−xAlxO3:0.02Cr3+ phosphors were synthesized by collaborators from National Taiwan University. Structural evolution reveals a crystal phase change with the incorporation...
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The luminescence study of Ca14Zn6Ga10−xMnxO35 coumpounds.
Open Research DataManganese in the pentavalent state (Mn 5+) is both rare and central in materials exhibiting narrow-band near-infrared (NIR) emission and is highly sought after for phosphor-converted light-emitting diodes as promising candidates for future miniature solid-state NIR light source. We develop the Ca 14 Zn 6 Ga 10−x Mn x O 35 (x = 0.3, 0.5, 1.0, 1.25, 1.5,...
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Enhancement of self-trapped excitons and near-infrared emission in Bi3+/Er3+ co-doped Cs2Ag0.4Na0.6InCl6 double perovskite
Open Research DataErbium (Er) complexes are used as optical gain materials for signal generation in the telecom C-band at 1540 nm, but they need a sensitizer to enhance absorption. Na+ substitution for Ag+ and Bi3+ doping at the In3+ site is a possible strategy to enhance the broadband emission of Cs2AgInCl6, which could be used as a sensitizer for energy transfer to...
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Wear in siding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specim. sets #20-#21, #22-#23, #24-#25, #26-#27, #28-#29,#30 - #31. Run time: 4-8h.
Open Research DataWear in sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer.Running time: 4-8h.Specimen sets:Specim. sets (# [upper, rotating] - #[lower, non-rotating]):#20-#21, #22-#23, #24-#25, #26-#27,...
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Wear in siding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specim. sets #20-#21, #22-#23, #24-#25, #26-#27, #28-#29,#30 - #31. Run time: 0-4h.
Open Research DataWear in sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer.Running time: 0 - 4h.Specimen sets:Specim. sets (# [upper, rotating] - #[lower, non-rotating]):#20-#21, #22-#23, #24-#25, #26-#27,...
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The luminescence study ofNaK2Li[Li3SiO4]4:Ce coumpounds.
Open Research DataPhosphors with a rigid and symmetrical structure are urgently needed. The alkali lithosilicate family (A[Li3SiO4]) has been extensively studied with a narrow emission band due to its unique cuboid-coordinated environment and rigid structure. However, here we demonstrate for the first time Ce-doped NaK2Li[Li3SiO4]4 phosphors with a broad emission band,...
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Specimen running-in. Prep. to sliding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specimen set #30 - #31.
Open Research DataSpecimen running-in procedure. Preparation to sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. Specimen set #30 (upper, rotating), #31 (lower, non-rotating)CZ_PRZYS.MAT - accelerometerMOM_TAR.MAT...
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Wear in siding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specim. sets #20-#21, #22-#23, #24-#25, #26-#27, #28-#29,#30 - #31. Run time: 0-4h. High frequency burst recording.
Open Research DataWear in sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. High frequency burst recording.Running time: 0 - 4h.Specimen sets:Specim. sets (# [upper, rotating] - #[lower, non-rotating]):#20-#21,...
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Specimen running-in. Prep. to sliding friction tests. Ring-on-ring contact. Sintered alumina ceramics (98%). Paraffin oil lubrication. Specimen set #28 - #29.
Open Research DataSpecimen running-in procedure. Preparation to sliding friction tests in ring-on-ring contact. Sintered alumina ceramics (98%) in self-mated contact. Lubrication: paraffin oil. Sliding velocity: 0.2 m/s. Mean contact stress: 10 MPa. Test rig: PT-3 Tribometer. Specimen set #28 (upper, rotating), #29 (lower, non-rotating)CZ_PRZYS.MAT - accelerometerMOM_TAR.MAT...
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The luminescence study of Bi-doped Cs2AgInCl6 double perovskite.
Open Research DataHere, we report a halide precursor acid precipitation method to synthesize Cs2AgIn1−xBixCl6 (x = 0, 0.02, 0.04, 0.08, 0.16, 0.32, 0.64, and 1) microcrystals. Cs2AgInCl6 and Bi derivative double perovskites show broadband white light emission via self-trapped excitons (STEs) and have achieved the highest internal quantum efficiency of up to 52.4% at...
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An animal model of the procognitive properties of cysteine protease inhibitor and immunomodulatory peptides based on colostrum.
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Efficacy and safety of B-cell receptor signaling pathway inhibitors in relapsed/refractory chronic lymphocytic leukemia: a systematic review and meta-analysis of randomized clinical trials
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Estimation of nitrogen leaching load from agricultural fields in the Puck Commune with an interactive calculator
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Thermal quenching of Ce3+luminescence in the cuspidine-type oxide nitride compounds Y4Si2−xAlxO7+xN2−x
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Ts2631 Endolysin from the Extremophilic Thermus scotoductus Bacteriophage vB_Tsc2631 as an Antimicrobial Agent against Gram-Negative Multidrug-Resistant Bacteria
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Damage Detection in Composite Materials Using Hyperspectral Imaging
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Condition monitoring and fault detection in wind turbines based on cointegration analysis of SCADA data
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An Experimental Study on the Effect of Temperature on Acoustic Emission Characteristics in Metallic Structures
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Psychopathological profile and antipsychotic treatment may be linked to internalised stigma in schizophrenia – a cross-sectional study
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Ts2631 Endolysin from the Extremophilic Thermus scotoductus Bacteriophage vB_Tsc2631 as an Antimicrobial Agent against Gram-Negative Multidrug-Resistant Bacteria
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Eveningness and its possibility of predicting burnout symptoms among physicians and nurses – preliminary results
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Blue-berried honeysuckle a promising cancer preventing fruit; Polish genotypes as a source of bioactive phytochemicals
PublicationFrom the ancient times, plants containing health-oriented compounds in their matrices are used in the treatment of different complaints and diseases. One of these groups are plant secondary metabolites (PSM), especially phenolic compounds, terpenes and terpenoids. A large number of PSM exhibit cytotoxicity against a variety of tumor cells, as well as cancer preventive and anticancer efficacy in preclinical animal models. For this...
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Simultaneous Determination of Indolic Compounds in Plant Extracts by Solid-Phase Extraction and High-Performance Liquid Chromatography with UV and Fluorescence Detection
PublicationA high-performance liquid chromatographic method with UV and fluorescence detection (HPLC-DAD-FLD) was developed for simultaneous determination of indolic compounds in plant material. Indole-3-carbinol (I3C), indole-3-acetic acid (I3AA), indole-3-acetonitrile (I3ACN), and 3,3′-diindolylmethane (DIM) were used as representative compounds that cover a wide spectrum of indole structures occurring in nature. For concentration and purification...
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Biofumigacja jako przyjazna środowisku technologia ochrony roślin
PublicationWobec rosnącej świadomości co do szkodliwości syntetycznych pestycydów, biofumigacja może stanowić alternatywną metodykę ochrony roślin. Proces ten polega na wykorzystaniu naturalnych związków antybiologicznych, zawartych m.in. w roślinach z rodziny kapustowatych, do zwalczania agrofagów. Do oceny skuteczności tej przyjaznej środowisku technologii ochrony roślin niezbędna jest znajomość metodyk oznaczania aktywności enzymatycznej...
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Structure and thermoelectric properties of Te/Ag/Ge/Sb (TAGS) materials obtained by reduction of melted oxide substrates
PublicationThe Ge0.77Ag0.1Sb0.13Te1alloy was fabricated by a novel two step route. For that purpose firstly the oxide reagents were melted at high temperature and quenched into pellets. After that pellets were milled to the powder and then reduced in hydrogen at various temperatures and for various periods of time. Energy dispersive X-ray analysis indicated the possibility of successful fabrication of stoichiometric thermoelectric materials...
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Awaryjne wczesne zarysowanie żelbetowego stropu hali widowiskowo-sportowej
PublicationW artykule przestawiono analizę przyczyn powstania wczesnego zarysowania stropu płaskiego w hali widowiskowo - sportowej. Przeprowadzono analizę nośności istniejącej konstrukcji oraz przedstawiono koncepcję jej wzmocnienia.
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Awaryjne zarysowanie oraz błędy projektowe stropu płaskiego hali widowiskowo-sportowej
Publicationw pracy przedstawiono analizę przyczyn spękania oraz błędy projektowe skutkujące niedostateczną nośnością stropu płaskiego na zginanie oraz przebicie w nowo budowanej hali widowiskowi-sportowej. w celu przeniesienia założonego przez projektanta obciążenia konieczne było wzmocnienie stropu.
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SEDIMENT DEPOSITION IN RESERVOIRS IN URBAN BASIN
PublicationIn recent years Gdańsk had sustained economic and social losses due to severe flash floods coming down from moraine hills. The first flood occurred in July 2001 and the second in July 2016. Both events were caused by intense and long rainfall characterized by different from each other rain intensity in time. Among other Gdansk’s streams the Oliwski Stream has the most extended flood protection system consist of 15 small retention...
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Analytical methods for exhaustive characterization of Brassica plants and dietary products based on them
PublicationGlucosinolates (GLs), and particularly two classes of their degradation products - isothiocyanates (ITC) and indoles - released upon myrosinase catalyzed hydrolysis, belong to the most promising chemopreventive dietary components. Despite their wide use in plant research, studies on chemopreventive mechanisms and industrial utilization in the production of e.g. dietary supplements, the methods of reliable characterization of myrosinase-GLs...
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Structure and thermoelectric properties of Cs-Bi-Te alloys fabricated by different routes of reduction of oxide reagents
PublicationCesium-bismuth-telluride polycrystalline materials were fabricated using a cost-effective method based on a reduction of oxide reagents, leading to a production of a material with good thermoelectric properties. Several samples with various initial stoichiometry were prepared by melting of oxide powders at 1050 °C, quenching, milling to powders and then reducing in pure hydrogen at 400 °C. Another concept was to obtain the CsBi4Te6...
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Influence of the Spectral Quality of Light on Daytime Alertness Levels in Humans
PublicationExposure to light is very important for human health. However, the characteristics of the light stimulus and the appropriate timing of such exposure are essential. Studies that have used monochromatic light exposure have shown no systematic patterns for the effects of blue light compared to longer wavelengths. Previous studies have shown that red light exposure increases objective and subjective measures of alertness at night without...
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The influence of cultivation conditions on the myrosinase activity and glucosinolate content in white cabbage
PublicationIn the process of biofumigation typically natural compounds present in Brassicaceae family are used to combat pests and protect crops. Glucosinolates, sulfur-containing secondary metabolites found in Brassica plants, are hydrolized by the enzyme myrosinase (β-thioglucosidase, EC 3.2.3.1) with the liberation of degradation products such as isothiocyanates, nitriles, thiocyanates and epithionitriles. Isothiocyanates are the most...
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Autonomiczne hybrydowe systemy fotowoltaiczne wspomagane ogniwami paliwowymi
PublicationW większości krajów świata promieniowanie słoneczne charakteryzuje się dużą zmiennością zarówno w cyklu dobowym, miesięcznym jak i rocznym.Fakt ten zmusza projektantów autonomicznych systemów fotowoltaicznych do zwiększania ilości modułów, zwiększania mocy regulatorów oraz pojemności akumulatorów, a co za tym idzie do wzrostu ceny instalacji PV.Aby rozwiązać te problemy stosuje się fotowoltaiczne systemy hybrydowe, w których generatory...
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Thioamides and selenoamides with chirality solely due to hindered rotation about the C-N bond: enantioselective complexation with optically active hosts
PublicationBariera rotacji wokół wiązania C-N w tioamidach jest średnio o 3-5 kcal/mol wyższa niż w odpowiednich amidach, a w analogicznych selenoamidach wzrasta jeszcze o 1 kcal/mol. Dzięki temu związki te występują w dwu enancjomerycznych formach, których wzajemna przemiana zachodzi w wyniku rotacji wokół wiązań C-N. Bariera rotacji jest wystarczająco wysoka, aby można było podjąć próbę ich rozdziału na enancjomery w temperaturze pokojowej....
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The influence of synthesis method on the microstructure and catalytic performance of Y 0.07 Sr 0.93 Ti 0.8 Fe 0.2 O 3-δ in synthetic biogas operated solid oxide fuel cells
PublicationThe Y0.07Sr0.93Ti0.8Fe0.2O3-δ (YSTF) material was fabricated using three different synthesis methods: modified polymer precursor method (MPP), Pechini method and a solid state reaction method. It was applied as an anode catalytic material for biogas reforming in solid oxide fuel cells. Clear differences in the microstructure of fabricated catalytic layers were found, mainly with respect to a grain size and distribution of grains....
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Changes on the Surface of the SiO2/C Composite, Leading to the Formation of Conductive Carbon Structures with Complex Nature of DC Conductivity
PublicationSol–gel layers have been the subject of many studies in recent decades. However, very little information exists about layers in which carbon structures are developed in situ. Using the spin-coating method, we obtained thin iron-doped SiO2/C composite films. The results of Raman spectroscopy showed that our samples consisted of graphitic forms and polymers. The latter’s contribution decreases with rising temperature. FTIR and EDS...