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Search results for: INJECTABLE HYDROGEL
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Photocatalytic hydrogen generation over alkaline-earth titanates in the presence of electron donors
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Conformers and hydrogen bond transformations in N-methylpiperidine betaine 2,4-dinitrophenolate crystals
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Self-ignition of hydrogen–nitrogen mixtures during high-pressure release into air
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Numerical Simulations of DDT Limits in Hydrogen-Air Mixtures in Obstacle Laden Channel
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Hydrogen-Containing Na3HTi1–xMnxF8 Narrow-Band Phosphor for Light-Emitting Diodes
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Alkyl Monolayers on Silicon Prepared from 1-Alkenes and Hydrogen-Terminated Silicon
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Descriptors to Predict Dye‐Sensitized Semiconductor Based Photocatalyst for Hydrogen Evolution Reaction
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The use of nitriding as a prevention method against hydrogen degradation of high-strength steels
PublicationPrzedstawiono badania wpływu warstw azotowanych jarzeniowo na stali 34CrAlNi7-10 na jej podatność na niszczenie wodorowe. Wytworzono warstwy azotowane w atmosferach technologicznych o różnym udziale wodoru. Próbki materiału rodzimego i z warstwami azotowanymi poddano próbie rozciągania z małą prędkością odkształcania w środowisku 0,01 N kwasu siarkowego przy polaryzcaji katodowej. Względny spadek plastyczności i charakter przełomu...
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Superconducting state in the atomic metallic hydrogen just above the pressure of the molecular dissociation
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Non-parametric application of Tsallis statistics to systems consisting of M hydrogen molecules
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Pd supported ordered mesoporous hollow carbon spheres (OMHCS) for hydrogen storage
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Municipal wastewater reclamation: Reclaimed water for hydrogen production by electrolysis – A case study
PublicationThis paper presents an analysis of a treatment system selection for municipal wastewater stream based on the DuPont Water Solutions WAVE software. The results obtained based on an analysis of 7 different processing cases studies (ultrafiltration and reverse osmosis) confirmed that the application of 2-pass membrane systems enables the reclamation of water from municipal wastewater that fulfills the requirements concerning the...
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DETERMINATION OF DIFFUSIBLE HYDROGEN CONTENT IN DEPOSITED METAL OF RUTILE ELECTRODES BY GLYCERIN METHOD
PublicationThe presence of diffusible hydrogen in welded joints is one of the causes of formation the welding imperfections. Improvement of weldability can be achieved by reducing the hydrogen amount in welded joints. This requires, among others, the finding of sources of hydrogen. For high hydrogen processes the commonly used method of determining the diffusible hydrogen amount is the glycerin method. This paper concerns issues related to...
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Superconducting lead granular layer prepared by reducting in hydrogen lead of germanate glass
PublicationCienka warstwa granul Pb została wytworzona poprzez wygrzewanie w wodorze, w wysokiej temperaturze. Struktura i nadprzewodzące właściwości warstwy ołowiu zależą od temperatury i czasu redukcji. Artykuł analizuje wpływ warunków redukcji na wytworzoną warstwę granul Pb.
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Effect of underwater wet welding conditions on the diffusible hydrogen content in deposited metal
PublicationIn the study mercury displacement method was used for determination of diffusible hydrogen amount in deposited metal obtained during underwater wet welding with covered electrodes in laboratory conditions according to a two-level full factorial design for three factors. The factors and their levels were chosen among conditions and parameters of welding in accordance with the results of own preliminary studies. A statistical analysis...
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Hydrogen migration in formation of NH(A3Π) radicals in photodissociations of isoxazole and pyridine molecules
PublicationIn the present study, the H atom migration was observed in the photodissociation processes of the isoxazole and pyridine molecules in the gas-phase, applying the photon-induced fluorescence spectroscopy (PIFS).
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Application of atmospheric pressure microwave plasma source for hydrogen production from ethanol
PublicationIn contrast to conventional technologies of hydrogen production like water electrolysis or coal gasification we propose a method based on the atmospheric pressure microwave plasma. In this paper we present results of the experimental investigations of the hydrogen production from ethanol in the atmospheric pressure plasma generated in waveguidesupplied cylindrical type nozzleless microwave (915 MHz and 2.45 GHz) plasma source (MPS)....
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Comprehensive study on graphene hydrogels and aerogels synthesis and their ability of gold nanoparticles adsorption
PublicationGraphene hydrogels were prepared by ascorbic acid-assisted gelation of graphene oxide (GO) aqueous suspensions both in acidic and basic conditions. Different mass ratio of ascorbic acid (AA) to GO was used (namely 20:1 and 10:1). In order to eliminate the influence of AA on the final structure of hydrogels, samples without AA were prepared by a hydrothermal gelation of GO in an autoclave. An in-depth structural characterization...
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Bioconversion of waste materials to hydrogen via dark fermentation using Enterobacter aerogenes
PublicationHydrogen can be obtained via dark fermentation with the use of anaerobic Enterobacter aerogenes. The efficiency of hydrogen production by fermentation techniques is strongly dependent on the con-ditions used i.e. the pH range, temperature, composition of fermentation broths, oxygen content, or even the presence of substances with potentially inhibitory effects on the microbiological culture [1-4]. The paper describes the study...
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Neutral Dissociation of Pyridine Evoked by Irradiation of Ionized Atomic and Molecular Hydrogen Beams
PublicationThe interactions of ions with molecules and the determination of their dissociation patterns are challenging endeavors of fundamental importance for theoretical and experimental science. In particular, the investigations on bond-breaking and new bond-forming processes triggered by the ionic impact may shed light on the stellar wind interaction with interstellar media, ionic beam irradiations of the living cells, ion-track nanotechnology,...
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Shape-controllable synthesis of GdVO4 photocatalysts and their tunable properties in photocatalytic hydrogen generation
PublicationNovel visible light responsive materials for water splitting are essential for the efficient conversion of solar energy into hydrogen bond energy. Among other semiconductors, gadolinium orthovanadate has appropriate conduction and valence band edges positioned to split water molecules and a narrow band gap that allows the use of visible light for hydrogen generation. Thus, we present here that hydrogen evolution under visible light...
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Intermolecular Hydrogen Bonding Directed by Aryl–Perfluoroaryl π–π Stacking Interactions
PublicationThe crystal structures of five compounds capable of forming self-complementary hydrogen bonds but crystallizing as catemers or creating more complex crystal structures were compared with their complexes prepared by cocrystallization with perfluoroaryl compounds. The results of X-ray diffraction revealed that in all the cases the π–π stacking interactions caused reorganization of hydrogen bonds and induced creation of the expected...
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Techno-economic assessment of cooperation of hybrid renewable energy sources with hydrogen storage
PublicationThe paper presents a technical and economic analysis of the power supply for a model industrial facility with the use of the most promising renewable energy sources (RES), supported by a hydrogen energy storage. This scenario was compared with the variants of supplying the facility directly from the grid and from RES without energy storage. A strategy was proposed for powering the plant aimed at maximising self-consumption of self-generated...
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Recent advances in hydrogen production from biomass waste with a focus on pyrolysis and gasification
PublicationThis paper presents the results research on the optimal fuel compositions and the control parameters of the spark ignition engine fueled with syngas-biogas-hydrogen for the purpose of setting up a flexible electronic control unit for the engine working in a solar-biomass hybrid renewable energy system. In syngas-biogas-hydrogen mixture, the optimal content of hydrogen and biogas is 20% and 30%, respectively. Exceeding these thresholds,...
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Bi-based halide perovskites: Stability and opportunities in the photocatalytic approach for hydrogen evolution
PublicationIn this study, we successfully prepared Bi-based single perovskites of the A3Bi2I9 type (A = Cs, Rb, MA, FA), and, for the first time, attempted to experimentally obtain double perovskites Cs2B’BiI6 type (B′ = Ag, Au, In, Cu). Despite the premises available in theoretical studies, our research has proven the impossibility of the existence of double perovskites of this type. Nevertheless, both types of obtained materials were subjected...
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Bismuth-based nanomaterials-assisted photocatalytic water splitting for sustainable hydrogen production
PublicationThe rapidly increase in the world's population has resulted in a corresponding increase in the energy demand. This demand is largely being met by fossil fuels for power generation, industrial fuel and transportation. However, due to the limited availability of fossil fuels and their negative effects on the environment. The use of fossil fuels results in by-products such as carbon, nitrogen and sulfur oxides which have negative...
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Structure and thermoelectric properties of nickel-doped copper selenide synthesised in a hydrogen atmosphere
PublicationNickel-doped copper selenide—Cu2-xNixSe (x = 0; 0.01; 0.02; 0.03)—materials with high thermoelectric properties were synthesised through reduction of reagents in hydrogen. The impact of the nickel content on both the microstructure and thermoelectric properties was examined. The nickel-doped samples’ microstructure differed significantly from pristine copper selenide. Besides Cu2Se, copper precipitations were present in the materials....
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In vivo evaluation of the antipsoriatic effect of hydrogel with lavandin essential oil and its main components after topical application
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Estimation–identification problem for diffusive transport in porous materials based on single reservoir test: Results for silica hydrogel
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Expermental investigation on adsorption of methylene blue dye from waste water using corncob cellulose-based hydrogel
PublicationHydrogel from corncob cellulose was synthesized in this investigation. The synthesized Hydrogel was characterized by SEM, XRD, and FTIR instruments. As the results indicate the synthesized hydrogel has required and important features, these suggest the suitability of hydrogel for the adsorption of methylene blue dye (MBD). Three important process variables (dosage, contact time, and initial concentration) with three levels were...
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Hydrogel Delivery System Containing Calendulae flos Lyophilized Extract with Chitosan as a Supporting Strategy for Wound Healing Applications
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DEVELOPMENT OF HYDROGEL CAPSULES FOR USE IN DUAL-PHASE TOPICAL PREPARATIONS CONTAINING DIHYDROXYACETONE AND AMINO ACIDS – PRELIMINARY RESULTS
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The influence of chitosan hydrogel cross-linking by agarose on coating physico-chemical properties
Open Research DataThis dataset contains various physicochemical analyses showing the effect of different concentration of chitosan and the cross-linking agent agarose. Each sample is labeled by C and A representing chitosan and agarose concentrations, respectively, while the exact amounts are depicted in the attached table. Fourier-transform infrared (FT-IR) spectroscopy...
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Effect of NaCl and KCl solutions on deformation of PVA hydroge- chemo-mechanical coupling
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Novel non-metallic carbon-nitrogen photocatalysts deposited in cold plasma for hydrogen production
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Identification of diffusive transport properties of poly(vinyl alcohol) hydrogels from reservoir test
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Influence of conductive carbon and MnCo2O4 on morphological and electrical properties of hydrogels for electrochemical energy conversion
PublicationIn this work, a strategy for one-stage synthesis of polymer composites based on PNIPAAm hydrogel was presented. Both conductive particles in the form of conductive carbon black (cCB) and MnCo2O4 (MCO) spinel particles were suspended in the three-dimensional structure of the hydrogel. The MCO particles in the resulting hydrogel composite acted as an electrocatalyst in the oxygen evolution reaction. Morphological studies confirmed...
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Bismuth-Doped Nano Zerovalent Iron: A Novel Catalyst for Chloramphenicol Degradation and Hydrogen Production
PublicationIn this study, we showed that doping bismuth (Bi) at the surface of Fe0 (Bi/Fe0, bimetallic iron system)—synthesized by a simple borohydride reduction method—can considerably accelerate the reductive degradation of chloramphenicol (CHP). At a reaction time of 12 min, 62, 68, 74, 95, and 82% degradation of CHP was achieved with Fe0, Bi/Fe0-1 [1% (w/w) of Bi], Bi/Fe0-3 [3% (w/w) of Bi], Bi/Fe0-5 [5% (w/w) of Bi], and Bi/Fe0-8 [8%...
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Laboratory bioreactor with pH control system for investigations of hydrogen production in the dark fermentation process
PublicationThe work presents the construction of a low-cost research bioreactor equipped with a pH control sys-tem. The developed bioreactor was applied for hydrogen production in the dark fermentation process using Enterobacter aerogenes ATCC 13048. Presented paper compares the results obtained during the process without and with pH regulation for different feed materials: glucose, energetic poplar hydro-lysates, acid whey and glycerol....
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High temperature air/steam gasification of biomass in view of hydrogen rich gas production.
PublicationArtykuł przedstawia opis nowej i zaawansowanej metody konwersji termochemicznej biomasy i miejskich odpadów stałych w paliwo gazowe, bogate w wodór. W porównaniu z tradycyjnym procesem gazyfikacji, w metodzie tej wykorzystuje się powietrze/parę wodną przegrzane do wysokiej temperatury (powyżej 1300 st. C). Przegrzanie powietrza lub pary wodnej odbywa się z zastosowaniem ceramicznego przegrzewacza wysokotemperaturowego. W celu...
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Hydrogen rich gas production from high temperature air/steam gasification of biomass
PublicationW pracy przedstawiono nowoczesną technikę konwersji biomasy oraz stałych odpadów komunalnych w celu produkcji paliwa gazowego bogatego w wodór. Opisany proces gazyfikacji przebiega w wysokiej temperaturze przy obniżonej koncentracji tlenu i udziale pary wodnej. Dzięki temu możliwa jest produkcja gazów palnych, w szczególności H2, który można wykorzystać do produkcji energii elektrycznej i cieplnej.
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Hydrogen-enhanced stress corrosion cracking and corrosion fatigue of HSLA steels in sea-water
PublicationPrzedstawiono ocenę podatności stali o wysokiej wytrzymałości na naprężeniowe pękanie korozyjne i zmęczenie korozyjne wspomagane przez wodór. Wykonano próby powolnego rozciągania i zmęczenia niskoczęstotliwościowego na stalach 17HMBVA i 14HNMBCu oraz ich złączach spawanych, w środowisku wody morskiej, przy polaryzacji katodowej. Zamieszczono wyniki badań elektrochemicznych oraz przełomów na skaningowym mikroskopie elektronowym.
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Molybdenum sulfide modified with nickel or platinum nanoparticles as an effective catalyst for hydrogen evolution reaction
PublicationIn this study, we investigate the catalytic performance of molybdenum sulfide (MoS2) modified with either nickel (Ni) or platinum (Pt) nanoparticles as catalysts for the hydrogen evolution reaction (HER). The MoS2 was prepared on the TiO2 nanotube substrates via a facile hydrothermal method, followed by the deposition by magnetron sputtering of Ni or Pt nanoparticles on the MoS2 surface. Structural and morphological characterization...
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Niszczenie wodorowe stali o podwyższonej wytrzymałości = Hydrogen degradation of high-strength steels.
PublicationW artykule przedstawiono niszczenie wodorowe stali 18G2A i jej symulowanej strefy wpływu ciepła (SWC). Jako parametry niszczenia wodorowego wybrano względne wartości energii zniszczenia, czasu do pęknięcia, wydłużenia, przewężenia i wytrzymałości na rozciąganie. Parametry te wyznaczono w próbie odkształcania z małą prędkością na próbkach gładkich, okrągłych. Stwierdzono, że stal 18G2A w środowisku kwaśnym (0,1 N H2SO4) podczas...
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Diffusible hydrogen management in underwater wet self-shielded flux cored arc welding
PublicationThis article reports the effect of underwater wet welding parameters and conditions on the diffusible hydrogen content in deposited metal for welding with a self-shielded flux cored wire. The diffusible hydrogen content in deposited metal was determined using the glycerin method according to the Plackett-Burman design determining the significance of the effect of the stick out length, welding current, arc voltage, travel speed...
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Conversion of Biomass and Municipal Wastes into Syngas and Hydrogen using Highly Preheated Agent (HTAG)
PublicationGasification is considered to be one of the most promising energy recovery technologies for the widespread utilization of biomass and wastes. During this process raw feedstock is converted into a combustible gas, which can then be burnt to produce thermal energy, or to run engines for mechanical or electrical power. The studies of biomass gasification demonstrate it as a friendly alternative to fossil fuels as one of renewable...
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Hydrogen Production from Energy Poplar Preceded by MEA Pre-Treatment and Enzymatic Hydrolysis
PublicationThe need to pre-treat lignocellulosic biomass prior to dark fermentation results primarily from the composition of lignocellulose because lignin hinders the processing of hard wood towards useful products. Hence, in this work a two-step approach for the pre-treatment of energy poplar, including alkaline pre-treatment and enzymatic saccharification followed by fermentation has been studied. Monoethanolamine (MEA) was used as the...
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Effect of Pd loading on hydrogen storage properties of disordered mesoporous hollow carbon spheres
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PANI/NaTaO3 composite photocatalyst for enhanced hydrogen generation under UV light irradiation
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Oxidized SWCNT and MWCNT as co-catalysts of polymeric carbon nitride for photocatalytic hydrogen evolution
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