Search results for: electroanalysis
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ELECTROANALYSIS
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Electrocatalysis
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Functionalized polypyrroles. New molecular materials for electrocatalysis and related applications
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Highly Porous Carbon Flakes Derived from Cellulose and Nickel Phosphide Heterostructure towards Efficient Electrocatalysis of Oxygen Evolution Reaction
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Optimizing Ni–Cr patterned boron-doped diamond band electrodes: Doping effects on electrochemical efficiency and posaconazole sensing performance
PublicationThere is growing interest in developing diamond electrodes with defined geometries such as, for example, micrometer-sized electrode arrays to acquire signals for electroanalysis. For electroanalytical sensing applications, it is essential to achieve precise conductive patterns on the insulating surface. This work provides a novel approach to boron-doped diamond patterning using nichrome masking for selective seeding on an oxidized...
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A prototype of electrochemical sensor for measurement of carbonyl compounds in air
PublicationThe paper presents the results of investigation on a prototype sensor for measurement of benzaldehyde and formaldehyde in air. Sensitivity, limit of quantification and coefficient of selectivity of the sensor have been determined as a function of membrane thickness and electrode type using square wave voltammetry (SWV) technique. The working and counter electrodes were made of platinum and gold. Ionic liquids 1-hexyl, 3-methylimidazolium...
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Lower Rim Substituted tert-Butyl Calix[4]arenes (Part IV). Calix[4]arene-Crown Ethers as Ionophores in Plasticized PVC-membrane electrodes.
PublicationPrzedstawiono syntezę i charakterystykę trzech p-tert-butylokaliks[4]aren-koron-4, -5, -6 (związki 2 - 4 o różnej długości łańcucha polyoksaetylenowego łączącego distalne grupy OH). Syntezowane związki wykazują wysoką selektywność na kationy sodu, potasu lub cezu. Badano zależność pomiędzy stereochemiczną strukturą tych ligandów, a wyznaczonymi potencjometrycznie współczynnikami selektywności oraz wyznaczonymi stałymi trwałości...
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Evaluation, Pitfalls and Recommendations for the “Water Layer Test” for Solid Contact Ion‐selective Electrodes
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Differences in Electrochemically Deposited PEDOT(PSS) Films on Au and Pt Substrate Electrodes: A Quartz Crystal Microbalance Study
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Lower Rim Substitutedp-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based onp-tert-Butyl-calix[4]arene Thioamides
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Melamine-modified boron-doped diamond towards enhanced detection of adenine, guanine and caffeine
PublicationThis work describes the electrochemical method of boron-doped diamond (BDD) modification by poly-melamine to obtain organic film. The detection of adenine, guanine and caffeine were carried out by differential pulse wave voltammetry. The poly-melamine modified B-NCD electrodes exhibit excellent activity towards the electrochemical oxidation of all examined analytes. The poly-melamine modified BDD electrodes in all measurements...
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Conventional and solid-contact lithium-selective electrodes based on tris(N,N-dicyclohexylamide) neutral ionophore
PublicationKonstruowano jonoselektywne elektrody litowe (Li-ISEs) z membraną polimerową i obojętnym jonoforem tris(N,N-dicycloheksyloamidem) jako: elektrodę konwencjonalną (z wodnym roztworem elektrolitu wewnętrznego) oraz ze stałym kontaktem (polianilina jako przekaźnik jonowo-elektronowy). Charakterystyki obu elektrod (nachylenie i zakres liniowy) są porównywalne. Badana elektroda ze stałym kontaktem wykazuje dobrą stabilność w czasie....
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Influence of aprotic solvent on selectivity of an amperometric sensor with nafion membrane
PublicationW publikacji przedstawiono rezultaty badań dotyczące selektywności amperometrycznego czujnika ditlenku siarki z membraną nafionową wobec tlenku węgla i dwutlenku azotu jako interferentów. Zostały porównane współczynniki selektywności dla czujników wypełnionych roztworami elektrolitów zawierających wodne roztwory kwasu siarkowego i różne ilości rozpuszczalnika aprotycznego - dimetylosulfotlenku.
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Impedance investigations of amperometric gas sensor containing aprotic solvent
PublicationSkonstruowany został amperometryczny czujnik gazowy w układzie trójelektrodowym ze złotą elektrodą roboczą bezpośrednio napyloną na membranę Nafionową. W publikacji przedstawiono wyniki badań charakterystyk czujnika do oznaczania ditlenku siarki wypełnionego elektrolitem zawierającym różne względne zawartości DMSO/H2O. Wyniki badań impedancyjnych zostały przeanalizowane w oparciu o zaproponowany elektryczny układ zastępczy.
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Spectroelectroanalytical properties of antitumor agent C1311
PublicationZastosowano kilka metod woltamperometrycznych dla charakterystyki właściwości elektrochemicznych przeciwnowotworowej pochodnej imidazoakrydonu o symbolu C-1311. Wyniki wskazały, że możliwym będzie zastosowanie metod elektrochemicznych do badania oddziaływań badanego związku z DNA. Badania spektroelektrochemiczne ujawniły, że oscylacyjne zmiany absorbcji związku obserwowane po cyklicznej polaryzacji elektrody. Oscylacje te znikały...
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Composite Bioelectrodes Based on Lipidic Cubic Phase with Carbon Nanotube Network
PublicationElektrody z węgla szklistego modyfikowane fazą kubiczną z siecią nanorurek zastosowano do enzymatycznej redukcji tlenu katalizowanej przez lakazę. Zastosowanie nanorurek obniżyło nadpotencjał redukcji tlenu o 0,5 V. W celu zwiększenia gęstości prądu redukcji tlenu zastosowano znany mediator przeniesienia elektronów - ABTS. Mediator adsorbowano na nanorurkach lub wiązano kowalencyjnie z końcami nanorurek. Kowalencyjne związanie...
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Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based on p-tert-Butyl-calix[4]arene Thioamides.
PublicationTetra podstawione tioamidowe pochodne para-tert-butylokaliks[4]arenu (1-5) zostały zastosowane jako jonofory w membranowych elektrodach jonoselektywnych (EJS) selektywne na kationy Pb(II). Wyznaczono współczynniki selektywności. Czwartorzędowe kaliks[4]aren-tioamidy (1,2) wykazują nadzwyczaj dobrą selektywność na kationy Pb(II) w porównaniu z kaliks[4]aren-amidami. Membrany z tymi ligandami wykazują dużą trwałość, a charakterystyki...
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Influence of Analyte Flow Rate on Signal and Response Time of the Amperometric Gas Sensor with Nafion Membrane
PublicationW publikacji przedstawiono rezultaty badań nad wpływem zmian objętościowego natężenia przepływu gazu na sygnał i czas odpowiedzi prototypowego czujnika ditlenku siarki z membraną nafionową. Porównywano właściwości czujników różniących się materiałem elektrody pracującej oraz składem roztworu elektrolitu wewnętrznego. Zastosowano elektrody pracujące wykonane z napylonych próżniowo na powierzchnię membrany nafionowej złota i platyny....
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Interactions of dissolved dsDNA with intercalating drug by anodic voltammetry and spectroscopy. Influence of pH
PublicationOddziaływanie związku przeciwnowotworowego C-1305 z DNA było badane przy pomocy impulsowej voltametrii różnicowej oraz spektroskopii UV/Vis. Triazoloakrydon C-1305 oddziałuje z DNA na dwóch drogach: przez interkalacje pomiedzy pary zasad oraz przez wiązanie sie w małym rowku helisy. W fizjologicznym pH (7,4) stałe wiązania wynoszą: K1=3,36E+5 i K2=0,18E+5 [1/M] a wielkość miejsca wiązania: n1=2,5 i n2=4,0, odpowiednio dla pierwszego...
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Potentiometric Solid-Contact Multisensor System for Simultaneous Measurement of Several Ions
PublicationThe design and performance of potentiometric multisensor system made in solid-contact technology is described. Both, the measuring electrodes as well as the reference electrode are in a compact cell. The system allows for simultaneous measurement of various ions. The characteristics of the electrodes for Na+, K+ and Ca2+ ions were determined using the designed system and compared with ISEs of the same membrane composition in classical...
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Synergic Effect of Naphthylated Carbon Nanotubes and Gold Nanoparticles on Catalytic Performance of Hybrid Films Containing Bilirubin Oxidase for the Dioxygen Reduction
PublicationTo improve the direct electron transfer from a multicopper oxidase MvBOd to the glassy carbon electrode surface the naphthylated multiwall carbon nanotubes (Napht-MWCNTs) are ombined with gold nanoparticles (AuNPs) to form a conductive network at the electrode and to increase its working surface. Such approach allowed to eliminate the necessity of employing mediators to reach elevated current values. The enzyme stability was improved...
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Simultaneous determination of Na+, K+, Ca2+, Mg2+ and Cl- in unstimulated and stimulated human saliva using all solid state multisensor platform
PublicationHuman saliva is one of the body fluids which collection method is relatively simple and non-invasive. The article is dedicated to assess concentration (activity) of Na+, K+, Ca2+, Mg2+ and Cl- in fresh, unstimulated or stimulated human saliva samples using single solid contact ion-selective electrodes with conventional reference electrode and self-made multisensor platform (MP) equipped with ion-selective membranes for Na+, K+,...
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Study on Combined Optical and Electrochemical Analysis Using Indium-tin-oxide-coated Optical Fiber Sensor
PublicationThe growing needs for fast and reliable sensing devices stimulate development of new technological solutions. In this work a new multi-domain sensing method is demonstrated where optical sensing device has been applied to enhance amount of data received during electrochemical analysis. Thin, optically transparent, high-refractive-index, and electrically conductive indium tin oxide (ITO) film was deposited using magnetron sputtering...
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Comparison of Cadmium Cd2+ and Lead Pb2+ Binding by Fe2O3@SiO2‐EDTA Nanoparticles – Binding Stability and Kinetic Studies
PublicationThis study describes the synthesis and characterization of ethylenediaminetetraacetic acid (EDTA) functionalized magnetic nanoparticles of 20 nm in size – Fe3O4@SiO2‐EDTA – which were used as a novel magnetic adsorbent for Cd(II) and Pb(II) binding in aqueous medium. These nanoparticles were obtained in two‐stage synthesis: covering by tetraethyl orthosilicate and functionalization with EDTA derivatives. Nanoparticles were characterized...
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A Flexible Nafion Coated Enzyme‐free Glucose Sensor Based on Au‐dimpled Ti Structures
PublicationThe detection of glucose at low concentrations using electrochemical sensors is of great importance due to the possibility of using different human body fluids than blood, such as e.g. urine, saliva, sweat or tears. The interest behind those biofluids is related to their utility in non-invasive sugar determination. In this work, we present flexible, fully biocompatible electrode material based on Au nanoparticles immobilized onto...
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An electrochemical biosensor for the determination of hormone Human Chorionic Gonadotropin (hCG) in human serum
PublicationThis work describes the modification of a gold electrode to create an electrochemical biosensor capable of detecting human chorionic gonadotropin (hCG). The biosensor was obtained by modifying the gold electrode with cysteamine and oligopeptide (PPLRINRHILTR). The modification steps of the gold electrode were confirmed by cyclic voltammetry (CV) and impedance electrochemical spectroscopy (EIS) measurements. The conducted EIS experiments...
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Impedance and cyclic voltammetry studies of GPLA electrodes after laser ablation
Open Research DataThe 3D printed GPLA electrodes present a brand new opportunity for electrode material for electrochemical biosensors. In order for the electrodes to be considered viable for electroanalysis studies, the pretreatment procedure must be applied in order to etch PLA matrix and reveal graphene filler. The following dataset presents an approach towards such...
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Impedance Measurement and Selection of Electrochemical Equivalent Circuit of a Working PEM Fuel Cell Cathode
PublicationThe dynamic impedance analysis of direct methanolfuel cell (DMFC) cathode supplied with pure oxygen is pre-sented. Presented results were obtained during dynamic chang-es of the current density in working fuel cell. Investigation ofthe occurring processes at cathode was carried with dynamicelectrochemical impedance spectroscopy (DEIS). A discussionwas conducted based on the determined correlation parameterχ2. It was shown that...
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Photoinduced K+ Intercalation into MoO3/FTO Photoanode—the Impact on the Photoelectrochemical Performance
PublicationIn this work, thin layers of MoO3 were tested as potential photoanodes for water splitting. The influence of photointercalation of alkali metal cation (K+) into the MoO3 structure on the photoelectrochemical properties of the molybdenum trioxide films was investigated for the first time. MoO3 thin films were synthesized via thermal annealing of thin, metallic Mo films deposited onto the FTO substrate using a magnetron sputtering...
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Enhanced Photoelectrocatalytical Performance of Inorganic-Inorganic Hybrid Consisting BiVO4, V2O5, and Cobalt Hexacyanocobaltate as a Perspective Photoanode for Water Splitting
PublicationThin layers of BiVO4/V2O5 were prepared on FTO substrates using pulsed laser deposition technique. The method of cobalt hexacyanocobaltate (Cohcc) synthesis on the BiVO4/V2O5 photoanodes consists of cobalt deposition followed by electrochemical oxidation of metallic Co in K3[Co(CN)6] aqueous electrolyte. The modified electrodes were tested as photoanodes for water oxidation under simulated sunlight irradiation. Deposited films...
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The microstructure of aluminium alloys AA1050 and AA7075 subjected to anodic polarization at 8V in KOH electrolyte
Open Research DataThe dataset contains SEM pictures of the microstructure of aluminum alloy AA1050 and AA7075 exposed in aqueous KOH in the pH range between 14–11. Two sets of samples are presented, revealing the topography of the alloys when exposed to aggressive media under open circuit potential conditions as well as when subjected potentiodynamic polarization ranging...
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Current advances in membrane processing of wines: A comprehensive review
PublicationBackground Membrane-based operations, especially pressure-driven membrane operations, are today well-established procedures for various applications in the wine industry thanks to their intrinsic properties and undoubted advantages over traditional methods. Emerging membrane processes, such as pervaporation, electrodialysis and osmotic distillation, forward osmosis, membrane contactors, offer new and interesting perspectives to...
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The electrochemical studies of thin boron-doped diamond films deposited at conductive poly(lactic acid) 3D prints
Open Research DataThe dataset contains the electrochemical characteristics of the electrodes composed of thin boron-doped diamond films coated on commercially available graphene-doped polylactide acid. The boron doping level expressed as the [B]/[C] ratio in the gas phase for these studies was 500 and 10,000 ppm.
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Diamondized carbon nanoarchitectures as electrocatalytic material for sulfate-based oxidizing species electrogeneration
PublicationThe introduction of nanotechnology seems to be an imperative factor to intensify the synergic effects of electrocatalytic materials to produce strong oxidant species or to increase the active sites on their surfaces as well as to enhance the conversion yield in a fuel cell, high-added value products, electrolytic treatment for environmental protection or the detection limit in electroanalysis. Recently, a new type of 3D-diamond...
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The effect of Fe on chemical stability and oxygen evolution performance of high surface area SrTix-1FexO3-δ mixed ionic-electronic conductors in alkaline media
PublicationDevelopment of environmentally friendly, high performing oxygen evolution reaction (OER) catalysts is an important research challenge. In this work, iron doped strontium titanates with a general formula SrTi1-xFexO3-δ (x = 0.35, 0.50, 0.70, 0.90, and 1.00) denoted as STFx, were synthesized via a solid state reaction technique and characterized in terms of oxygen evolution reaction electrocatalysis in an alkaline electrolyte (0.1...
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Highly Occupied Surface States at Deuterium-Grown Boron-Doped Diamond Interfaces for Efficient Photoelectrochemistry
PublicationPolycrystalline boron-doped diamond is a promising material for high-power aqueous electrochemical applications in bioanalytics, catalysis, and energy storage. The chemical vapor deposition (CVD) process of diamond forma-tion and doping is totally diversified by using high kinetic energies of deu-terium substituting habitually applied hydrogen. The high concentration of deuterium in plasma induces atomic arrangements and steric...
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Tailoring diamondised nanocarbon-loaded poly(lactic acid) composites for highly electroactive surfaces: extrusion and characterisation of filaments for improved 3D-printed surfaces
PublicationA new 3D-printable composite has been developed dedicated to electroanalytical applications. Two types of diamondised nanocarbons - detonation nanodiamonds (DNDs) and boron-doped carbon nanowalls (BCNWs) - were added as fillers in poly(lactic acid) (PLA)-based composites to extrude 3D filaments. Carbon black served as a primary filler to reach high composite conductivity at low diamondised nanocarbon concentrations (0.01 to 0.2...
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Cathodic activation of synthesized highly defective monoclinic hydroxyl‐functionalized ZrO2 nanoparticles for efficient electrochemical production of hydrogen in alkaline media
PublicationThe high electrochemical stability of Zirconia (ZrO2) at high potentials strongly suggested it as an alternative to carbon supports, which experience reduced efficiency due to some corrosion problems particularly during prolonged electrocatalysis activity. However, the use of ZrO2 was limited by its low electrical conductivity and surface area. In this work, we developed a methodology for synthesizing monoclinic ZrO2 NPs with increased...