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Wyniki wyszukiwania dla: POLYMER DERIVED CERAMICS
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Simultaneous determination of Na+, K+, Ca2+, Mg2+ and Cl- in unstimulated and stimulated human saliva using all solid state multisensor platform
PublikacjaHuman saliva is one of the body fluids which collection method is relatively simple and non-invasive. The article is dedicated to assess concentration (activity) of Na+, K+, Ca2+, Mg2+ and Cl- in fresh, unstimulated or stimulated human saliva samples using single solid contact ion-selective electrodes with conventional reference electrode and self-made multisensor platform (MP) equipped with ion-selective membranes for Na+, K+,...
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Molecular dynamics simulations of the growth of poly (chloro-para-xylylene) films.
PublikacjaParylene C, poly(chloro-para-xylylene) is the most widely used member of the parylene family due to its excellent chemical and physical properties. In this work we analyzed the formation of the parylene C film using molecular mechanics and molecular dynamics methods. A five unit chain is necessary to create a stable hydrophobic cluster and to adhere to a covered surface. Two scenarios were deemed to take place. The obtained results...
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Studying of spin-coated oxad-Si properties
PublikacjaPurpose: The major aim of this paper was describing technical conditions of polymer thin film deposition byspin-coating techniques.Design/methodology/approach: Thin films of about nanometres thickness were prepared by spin-coatingand their properties were studied. As a material for preparing polymer thin films oxad-Si was used. The thinfilms were deposited with various spinning velocity from solution of different concentration....
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Degradibility in vitro of polyurethanes based on synthetic atactic poly[)R,S)-3-hydroxybutyrate
PublikacjaThe aim of the paper was to determine the degradibility of aliphatic polyurethanes in hydrolytic and oxidative solutions. DSC, GPC, density, polymer surface morphology were studied.
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Stanowisko do pomiaru termicznej stałej czasowej bolometrów
PublikacjaPrzedstawiono stanowisko umożliwiające pomiar termicznej stałej czasowej bolometrów. Stanowisko to składa się z dwóch układów pomiarowych połączonych z cyfrowym analizatorem sygnału i umożliwia pomiar stałej czasowej w zakresie od pojedynczych milisekund do kilku sekund. Omówiono budowę i działanie opracowanych układów i zaprezentowano wyniki pomiarów stałej czasowej bolometrów z niestechiometrycznych tlenków lantanowo-strontowo-żelazowych...
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Beneficial effects and potential risks of tomato consumption for human health: An overview
PublikacjaTomato and its derived products have a very interesting nutritional value in addition to prominent antioxidant,anti-inflammatory, and anticancer activities. In terms of tomatoes are generally quite safe to eat. However,overall consumption varies from individual to individual. Indeed, either beneficial or harmful effects of plantsor their derived products are closely related to quality, including the presence of biologically active...
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Underwater Wet Repair Welding of API 5L X65M Pipeline Steel
PublikacjaThis paper presents results of the research of effect of polymer insulation of pipeline made of API 5L X65M steel as well as underwater wet welding parameters on properties of joints made by covered electrodes. Effect of heat input on structure and hardness of joints during repair of underwater pipeline was analyzed. Welding defects like microcracks, micro-lacks of fusion, slag inclusions, as well as HAZ hardness increase over...
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Highly Dissipative Materials for Damage Protection against Earthquake-Induced Structural Pounding
PublikacjaIt is a common situation that seismic excitations may lead to collisions between adjacent civil engineering structures. This phenomenon, called earthquake-induced structural pounding, may result in serious damage or even the total collapse of the colliding structures. Filling the gap between two buildings erected close to one another by using visco-elastic materials can be considered to be one of the most effective methods to avoid...
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The Input of Nanoclays to the Synergistic Flammability Reduction in Flexible Foamed Polyurethane/Ground Tire Rubber Composites
PublikacjaCurrently, postulated trends and law regulations tend to direct polymer technology toward sustainability and environmentally friendly solutions. These approaches are expressed by keeping materials in a loop aimed at the circular economy and by reducing the environmental burdens related to the production and use of polymers and polymer-based materials. The application of recycled or waste-based materials often deals efficiently...
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The experimental research on the axially compressed CFFT columns
PublikacjaThe research objectives is to test the behaviour of the axially compressed glass fiber reinforced polymer tubes CFFT (concrete-filled FRP tube) withe the R-C core.
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Preparation and Properties of Thermoplastic Polyurethane Composites Filled with Powdered Buckwheat Husks
PublikacjaBio-based fillers for the polymer composites are still interesting from the scientific and industrial point of view, due to their low cost and renewable nature. In this work partially green composites were obtained by the mixing of thermoplastic poly(ester-urethane) with the unmodified and modified (by acetylation) grinded buckwheat husks. Obtained biocomposites were characterized in the terms of their chemical structure (FTIR),...
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Thermal Properties of PLA/TPS Blends
PublikacjaFour types of polymer compositions having different amount of potato starch, glycerin and poly(lactic acid) was obtained and characterized by DSC. Adding of TPS to PLA lowered Tg.
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CFGFRPT Piles with a Circular Cross-Section and their Application in Offshore Structures
PublikacjaThe possibilities of using concrete piles in a polymer composite reinforced with glass fibres in offshore facilities were shown. Laboratory tests of CFGFRPT type piles compressed axially and in eccentric compression for the analysis of CFGFRPT piles were used. Methods of analysis of dynamic systems for mathematical modelling of the displacement of the hammer in the pile driving process were applied. The possibilities of combining...
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Analysis of Ceramic Elements with Ring-Crack Defects in Lubricated Rolling Contact
PublikacjaThe properties of ceramics, specifically low density, high hardness, high temperature capability and low coefficient of thermal expansion are of most interest to rolling element manufacturers. Surface ring cracks on lubricating rolling contact fatigue failure has been studied using numerical fracture analysis. Such cracks are very often found on ceramic bearing balls and decrease fatigue life rapidly. The numerical calculations...
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On dynamics of origami-inspired rod
PublikacjaWe discuss the dynamics of a relatively simple origami-inspired structure considering discrete and continuum models. The latter was derived as a certain limit of the discrete model. Here we analyze small in-plane deformations and related equations of infinitesimal motions. For both models, dispersion relations were derived and compared. The comparison of the dispersion relations showed that the continuum model can capture the behavior...
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Carbon Nanomaterials From Metal-Organic Frameworks: A New Material Horizon for CO2 Reduction
PublikacjaThe rise of CO2 in the atmosphere, which results in severe climate change and temperature increase, is known as the major reason for greenhouse effect. Reducing CO2 to value-added products is an attractive solution to this severe problem, along with addressing the energy crisis, to which the catalysts being employed are of vital importance. Due to their high porosity and tunable compositions, Metal-Organic Frameworks (MOFs) show...
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Nano-particle doped hydroxyapatite material evaluation using Spectroscopic Polarization Sensitive Optical Coherence Tomography
PublikacjaBio-ceramics such as hydroxyapatite (HAp) are widely used materials in medical applications, especially as an interface between implants and living tissues. There are many ways of creating structures from HAp like electrochemical assisted deposition, biomimetic, electrophoresis, pulsed laser deposition or sol-gel processing. Our research is based on analyzing the parameters of the sol-gel method for creating thin layers of HAp....
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A review on hydrophobic electrospun nanofibers-based materials and membranes for water treatment: Challenges, outlook, and stability
PublikacjaMembrane technology is well recognized as a dependable means of supplementing the availability of potable water through processes such as water purification and desalination. Electrospun nanofiber membranes have garnered significant attention because of their advantageous features, including a greater specific surface area, increased porosity, reduced thickness, and popularity. Consequently, ENMs have emerged as an up-and-coming...
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Rotational molding of polylactide (PLA) composites filled with copper slag as a waste filler from metallurgical industry
PublikacjaThe research work carried out so far indicates the ever wider possibilities and demand for shaping composite products in the rotational molding technology. This trend was the main reason to use waste-based filler from the metallurgical process as a filler for manufacturing polylactide (PLA)-based remolded composites. Copper slag (CS) was introduced in the single-step processing method to PLA matrix at 5, 10, 20, and 35 wt%. The...
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New devices to capture the temperature effect under dynamic compression and impact perforation of polymers, application to PMMA
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Impact of environmental conditions on silicone pressure-sensitive adhesives
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Use of pyrolysis and gas chromatography for the determination of acrylic acid concentration in acrylic copolymers containing carboxylic groups
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Nanostructured polyethersulfone nanocomposite membranes for dual protein and dye separation: Lower antifouling with lanthanum (III) vanadate nanosheets as a novel nanofiller
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Machinability investigation in electric discharge machining of carbon fiber reinforced composites for aerospace applications
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Nanostructured polyethersulfone membranes for dye and protein separation: Exploring antifouling role of holmium (III) molybdate nanosheets
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In situ optical studies of thermal stability of iodine-doped polyazomethine thin films
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Phase diagram of P3HT:PC70BM thin films based on variable-temperature spectroscopic ellipsometry
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In situ thermo-optical studies of polymer:fullerene blend films
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Synergistic effect of nickel formate on the thermal and flame-retardant properties of polypropylene
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Modified titanate nanotubes for the production of novel aliphatic polyurethane nanocomposites
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Aging of silicone pressure-sensitive adhesives
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Modification of microporous polyurethane elastomers with different types of ash—morphological, mechanical, and thermal studies
PublikacjaIncorporation of wood ash particles from wood gasification into microporous polyurethane elastomers has been investigated and compared to addition of commercially available microspheres resulting from coal burning. Samples were modified with 3 and 6 wt% of fillers. Structure, mechanical, and thermal properties of obtained elastomers were investigated. Incorporation of both types of ash particles decreased the density of polyurethanes...
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Study of the effect of thermally reduced graphene oxide on the physical and mechanical properties of flexible polyurethane foams
PublikacjaFlexible polyurethane foams were obtained from a two-component system via the one-step method. The foams were modified with thermally reduced graphene oxide added in the amount equal to 0.25, 0.5 and 0.75 wt%. The morphology, static and dynamic properties, and thermal stability of modified foams were determined. The application of carbon filler resulted in the visible increase in the cell size, apparent density and rigidity of...
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Progress in non-isocyanate polyurethanes synthesized from cyclic carbonate intermediates and di- or polyamines in the context of structure–properties relationship and from an environmental point of view
PublikacjaCommercially, polyurethanes are produced by the reaction of diisocyanates, polyols (polyester or polyether) and low molecular weight chain extender. Toxicity, moisture sensitivity and phosgene-based synthesis of diisocyanates resulted in investigations focused on obtaining the non-isocyanate polyurethanes (NIPUs). This work presents the review of synthesis and structure–properties relationship of non-isocyanate polyurethanes obtained...
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Preparation and characterization of 3D collagen materials with magnetic properties
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Low-temperature air plasma modification of chitosan-coated PEEK biomaterials
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Shape memory thin films of Polyurethane: Does graphene content affect the recovery behavior of Polyurethane nanocomposites?
PublikacjaThin nanocomposite films of polyurethane have received remarkable attention due to their shape memory properties. As most of the reports focus on the beneficial aspects of the presence of nanofillers such as graphene nanoplatelets (GNPs) introduced into shape memory polymers, some research results reveal the opposite trend. The polyether/polyester-based polyurethane was synthesized through a condensation polymerization and the...
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Fabrication of exfoliated graphite reinforced silicone rubber composites - Mechanical, tribological and dielectric properties
PublikacjaThe effect of exfoliated graphite (EG) on the mechanical, tribological and dielectric properties of the silicone rubber (QM) composites has been systematically investigated and analysed. Morphological analysis of the composites helps to understand the interfacial interaction between the filler and the rubber matrix as well as wear mechanism respectively. An enhancement in the mechanical, tribological and dielectric properties was...
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Influence of chemical structure on physicochemical properties and thermal decomposition of the fully bio-based poly(propylene succinate-co-butylene succinate)s
PublikacjaIn this work, two polyesters and four copolyesters were studied. All materials were synthesized to obtain the monomers dedicated for thermoplastic polyurethane elastomers. For this type of PUR, the monomers should characterize by appropriate selected physicochemical properties and macromolecular structure distribution, which depends on synthesis conditions. The study of chemical structure with extensive and knowledgeable analysis...
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Fabrication of exfoliated graphite reinforced silicone rubber composites - Mechanical, tribological and dielectric properties
PublikacjaThe effect of exfoliated graphite (EG) on the mechanical, tribological and dielectric properties of the silicone rubber (QM) composites has been systematically investigated and analysed. Morphological analysis of the composites helps to understand the interfacial interaction between the filler and the rubber matrix as well as wear mechanism respectively. An enhancement in the mechanical, tribological and dielectric properties was...
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Bacterial cellulose in the field of wound healing and regenerative medicine of skin: recent trends and future prospectives
PublikacjaIn this overview, we focused on the bacterial cellulose (BC) applications, described in recently published scientific papers, in the field of skin regenerative medicine and wound care industry. Bacterial cellulose was proven to be biocompatible with living tissues. Moreover, its mechanical properties and porous structure are considered to be suitable for biomedical applications. It is due to the fact that porous structure of bacterial...
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Interfacially modified LDPE/GTR composites with non-polar elastomers: From microstructure to macro-behavior
PublikacjaThis paper provides some new insights into the mechanism of interaction and modifications in thermoplastic composites based on low density polyethylene (LDPE), ground tire rubber (GTR) and non-polar elastomer. The composites were prepared using a co-rotating twin-screw extruder at variable LDPE/GTR ratio and constant elastomer content. Two types of commercial elastomer were applied: styrene-butadiene-styrene (SBS) block copolymers (Kraton®)...
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Assessment of the impact of bacteria Pseudomonas denitrificans, Pseudomonas fluorescens, Bacillus subtilis and yeast Yarrowia lipolytica on commercial poly(ether urethanes)
PublikacjaThe assessment of the impact of the bacteria Pseudomonas denitrificans, Pseudomonas fluorescens, Bacillus subtilis and yeast Yarrowia lipolytica on commercial poly(ether urethanes) Tecoflex® and Tecothane® is presented. The polyurethane samples were incubated with pure cultures of the microorganisms at 30 °C for five months. The changes in the chemical structure of the polymers were evaluated using loss of weight and contact angle...
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Structural, mechanical and thermal behavior assessments of PCL/PHB blends reactively compatibilized with organic peroxides
PublikacjaThe efficiency of two commercially available organic peroxides, dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB), during reactive processing of poly (ε-caprolactone)/poly (3-hydroxybutyrate) (PCL/PHB) blends was investigated. The changes in chemical structure of PCL/PHB blends, as a function of organic peroxide type (DCP/BIB) and content (in range: 0–1.0 parts by weight - pbw), were characterized by Fourier...
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Evaluation and rationale of the performance of several elastomeric composites incorporating devulcanized EPDM
Publikacjathylene Propylene Diene rubber (EPDM), is present in many applications. However, its crosslinked structure makes difficult its recycling. The use of devulcanized EPDM, (dEPDM) as a component of elastomeric composites, is a real possibility to reuse EPDM scraps. In this study, three matrices (natural rubber (NR), styrene butadiene rubber (SBR) and EPDM rubber) have been tested including devulcanized EPDM as a recycled component....
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Biomechanical testing of bioactive bone cements – a comparison of the impact of modifiers: antibiotics and nanometals
PublikacjaApart from its bone filler and fracture stabilizing function, bone cement can be used as a carrier of bioactive substances, and such modified bone cement can protect the implant against microorganisms, treat local infections and combat bacteria introduced during the surgical procedure. In this paper, the effects of modifying antibiotics and nanosilver on the biomechanical properties of bone cement were examined. The following tests...
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The influence of different glycerine purities on chemical recycling process of polyurethane waste and resulting semi‐products
PublikacjaChemical recycling is the most favourable recycling method due to the possibility of polyol recovery. This work is dedicatedto the utilisation of crude glycerine and polyurethane waste. It aims at determining the impact of the use of glycerine fromthe production of biodiesel with various degrees of purity as a cleavage agent on the decomposition process of polyurethanefoam. The influence of glycerine purit y on the chemical structure...
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Towards understanding the role of peroxide initiators on compatibilization efficiency of thermoplastic elastomers highly filled with reclaimed GTR
PublikacjaThermoplastic elastomers based on recycled high density polyethylene (rHDPE) and styrene-butadiene-styrene (SBS) block copolymer were highly filled with reclaimed ground tire rubber (RR). The impact of various organic peroxides (dicumyl peroxide (DCP), benzoyl peroxide (BP) and di-tert-butyl peroxide (DB)), applied as free-radical initiators, on the processing, structure and performance properties of rHDPE/SBS/RR blends was investigated....
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Tuning of microstructure in engineered poly (trimethylene terephthalate) based blends with nano inclusion as multifunctional additive
PublikacjaImmiscible blends and their composites are heterogeneous and have variable morphology due to variation in mesophase regions. Tuning, i.e. controlling the phase dimension is important, thereof we report a “super-combo” effect of multiwalled carbon nanotubes (MWCNTs) in poly (trimethylene terephthalate)/polypropylene (PTT/ PP) blend system. MWCNTs act as a good reinforcing agent and compatibilizer in the otherwise immiscible PTT/...
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Transport of paracetamol in swellable and relaxing polyurethane nanocomposite hydrogels
PublikacjaPolyurethane hydrogels are potentially attractive materials for biomedical applications. They are able to absorb large amount of water, biological fluids or active substances, and thus, they have potential to be used as absorbents or wound-healing dressings. They are also used for the controlled release of therapeutics because of their capacity to embed biologically active agents in their water-swollen network. The presence of...