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Wyniki wyszukiwania dla: UV-VIS spectroscopy
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Koncepcja autonomicznego układu do dezynfekcji wody
PublikacjaW artykule poruszono temat pozyskania energii z nietypowych źródeł. Przedstawiono wyniki prac nad prototypem układu wykorzystującego przepływ strumienia wody jako źródło energii. Zakładano pozyskanie strumienia zarówno z naturalnych cieków wodnych jak i z domowych instalacji wodnych. W pracy sprawdzano koncepcję zastosowania odzyskanej energii do zasilania diod UV – C mających na celu zmniejszenie zagrożenia mikrobiologicznego...
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Balance of pesticides mass in gas, liquid and solid phase after their chemical degradation.
PublikacjaOpisano metodę usuwania pestycydów z wody przy zastosowaniu fotodegradacji (UV) i katalizatora (TiO2). Efektywność procesu usuwania pestycydów była kontrolowana przy zastosowaniu chromatografu gazowego z detektorem wychwytu elektronów. Oznaczano zawartość pestycydów w wodzie, a także zaadsorbowanych na powierzchni stałej, oraz w fazie gazowej. Największa zawartość pestycydów znajdowała się na fazie stałej, następnie w cieczy i...
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Factors causing degradation of sulfadimetoxine
PublikacjaSulfadimetoxine is a representative of sulfonamide drugs which presence inhibits growth of activated sludge bacteria, rhat is necessary for the effective mineralization of organic and inorganic contaminants. Therefore factors which con prevent this situation are searched. Aim of this study is selection of conditions causing efficien degradation of the drug- sulfadimetoxine. The impact of such aspects as : the type of oxidizing...
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Ocena możliwości dezynfekcji biologicznie oczyszczonych ścieków na przykładzie Grupowej Oczyszczalni Ścieków "Dębogórze" w Gdyni
PublikacjaPraca przedstawia wyniki badań dezynfekcji biologicznie oczyszczonych ścieków z Grupowej Oczyszczalni Ścieków "Dębogórze w Gdyni. Badania przeprowadzono z wykorzystaniem trzech technologii dezynfekcji: ozonowania, promieniowania UV oraz mikrofiltracji. Wszystkie z metod wykazały się wysoką skuteczność dezynfekcji ścieków. O konkretnym wyborze powinny decydować względy ekonomiczne. Podkreślono jednocześnie rolę badań kontrolnych,...
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Sources and fate of microplastics in marine and beach sediments of the Southern Baltic Sea—a preliminary study
PublikacjaMicroplastics’ sources and fate in marine bottom and beach sediments of strongly polluted Baltic Sea have been investigated.Microplastics were extracted using sodium chloride. Their qualitative identification was conducted using micro-Fourier-transform infrared spectroscopy (μFT-IR).
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Corrosivity of environment and the current state of the steel elements at the former Auschwitz concentration camp
PublikacjaThe objective of this study was to assess corrosivity of the atmospheric environment in the former Auschwitz I and Auschwitz II-Birkenau concentration and extermination camp, and to identify the protective properties of existing corrosion products in order to estimate the actual corrosion rate of original steel elements located there. The current atmospheric corrosivity of the former Auschwitz camp, specified during one year of exposure...
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Dielectric Properties of BiNbO<sub>4</sub>-Based Ceramic-Polymer Composites with 0-3 Connectivity
PublikacjaIn the present study two-phase BiNbO4//PVDF composites with 0-3 connectivity were studied by impedance spectroscopy within the frequency range Δν=100Hz-1MHz at room temperature. Polyvinylidene fluoride (PVDF) acted as a matrix whereas bismuth niobate (BiNbO4) powder acted as a dispersed phase. The volume fraction of the ceramic phase was cV=2, 4, 6, 8, 10, 16 and 20vol%. Analysis of the impedance data registered for composites...
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The influence of magnetic particle incorporation on bisphenol A removal by β-cyclodextrin-derived sorbent
PublikacjaA novel, biomass-derived hybrid sorbent Ban-CD-EPI-Fe was successfully synthesized in a coprecipitation method, in which β-cyclodextrin copolymerized with banana peel extract and epichlorohydrin was grafted onto an iron oxide surface. The composition, presence of functional groups, morphology, thermal stability, and magnetic properties of the obtained material were characterized by Powder X-Ray Diffraction (XRD), X-Ray Photoelectron...
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Locally sculptured modification of the electrochemical response of conductive poly(lactic acid) 3D prints by femtosecond laser processing
PublikacjaThis manuscript presents an approach to sculpture high electrochemical activity of the 3D printed electrodes with poly(lactic acid) (PLA) matrix and carbon black (CB) filler by femtosecond laser (FSL) ablation. CB-PLA utility for electrochemical applications depends on a surface modification aiming to remove the PLA and uncover the conductive CB. We have discussed how laser pulse energy is critical for such an activation process....
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Spectroscopic studies of Nb-doped tricalcium phosphate glass-ceramics prepared by sol-gel method
PublikacjaCalcium-phosphate based glasses and glass-ceramics play a crucial role in the tissue engineering development. Apart from their high biocompatibility and excellent ability to undergo varying degrees of resorbability1, they exhibit relatively high bioactivity and due to that they are commonly used as bone and dental implants. A substantial research effort is devoted to improve calcium-phosphate materials physico-chemical properties...
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Structural and electrical properties of titanium-doped yttrium niobate
PublikacjaIn this work, the influence of the substitution of niobium by titanium in Y3Nb1-xTixO7-δ on the structural and electrical properties is reported. Several experimental techniques, i.e. X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), X-Ray Photoelectron Spectroscopy (XPS) and Electrochemical Impedance Spectroscopy (EIS), were applied to investigate the system Y3Nb1-xTixO7-δ. Titanium in Y3Nb1-xTixO7-δ is an acceptor-type...
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Influence of Sn and Pb Ions Substitutions on Dielectric Properties of Barium Titanate
PublikacjaThe results of the microstructural and dielectric measurements of (Ba1-xPbx)(Ti1-xSnx)O3 (BPTSx) (x = 0, 0.05, 0.10, 0.30) polycrystalline samples are presented. The samples were obtained by means of a high temperature synthesis and their expected stoichiometry was confirmed by energy dispersive spectroscopy (EDS) measurements. The dielectric properties of BPTSx were studied with the use of broadband dielectric spectroscopy. The...
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Optical method supported by machine learning for dynamics of C‐reactive protein concentrations changes detection in biological matrix samples
PublikacjaIn this article we present the novel spectroscopy method supported with machine learning for real-time detection of infectious agents in wastewater. In the case of infectious diseases, wastewater monitoring can be used to detect the presence of inflammation biomarkers, such as the proposed C-reactive protein, for monitoring inflammatory conditions and mass screening during epidemics for early detection in communities of concern,...
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The Influence of Nanometals, Dispersed in the Electrophoretic Nanohydroxyapatite Coatings on the Ti13Zr13Nb Alloy, on Their Morphology and Mechanical Properties
PublikacjaIn this work, nanohydroxyapatite coatings with nanosilver and nanocopper have been fabricated and studied. The presented results concern coatings with a chemical composition that has never been proposed before. The present research aims to characterize the effects of nanosilver and nanocopper, dispersed in nanohydroxyapatite coatings and deposited on a new, non-toxic Ti13Zr13Nb alloy, on the physical and mechanical properties of...
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Novel application of dynamic electrochemical impedance monitoring to a cataphoretic coating process
PublikacjaThe paper presents a novel method of on-line impedance monitoring of cataphoretic coating application process. Utilization of dynamic electrochemical impedance spectroscopy (DEIS) overcame the fundamental problem connected with non-stationarity of the aforementioned coating deposition process, which eliminates classical impedance spectroscopy technique from a real-time description of cataphoresis. The paper illustrates selected examples...
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An examination of an Antarctic soil metagenomic-derivate putative methylthioadenosine phosphorylase gene as a novel reporter gene for promoter trapping
PublikacjaThe rsfp gene was discovered during examination ofan Antarctic soil-derived metagenome library and encodesa bacterial methylthioadenosine phosphorylase (GenBank accession number GQ202582). In a previous study, we found that E. coli colonies expressing the rsfp gene reveal strong pink fluorescence after exposure to UV light when grown on culture medium supplemented with rhodamine B (Cieśliński et al., 2009). In contrast to that,...
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The effect of sunscreen 4‐methylbenzylidene camphor in different and reproductive models, its bioaccumulation and molecular effects on ligand‐receptor interaction, and protein expression
Publikacja4-Methylbenzylidene camphor (4-MBC) is a photo-absorbing UV filter prevalently used in cosmetics, which can be absorbed into circulation and cause systemic effects. 4-MBC is continued to be released in the environment despite the growing knowledge about its bioaccumulation and endocrine disrupting effects. Previous reviews have mentioned UV-filter together but this review considers 4-MBC alone, due to its prevalence and concerning...
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Degradation of tetracycline antibiotic utilizing light driven-activated oxone in the presence of g-C3N4/ZnFe LDH binary heterojunction nanocomposite
PublikacjaIn the present study, a binary heterojunction nanocomposite composed of graphitic carbon nitride (g-C3N4) and Zn/Fe-contained layered double hydroxide (ZnFe LDH) was employed as heterogeneous catalyst for the decomposition of tetracycline (TC) antibiotic utilizing Oxone and UV light irradiation. The sole use of g-C3N4/ZnFe LDH as adsorbent led to the negligible elimination of TC. In addition, the sole use of Oxone or UV (photolysis)...
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KTaO3-based nanocomposites for air treatment
PublikacjaThe advantage is that photocatalytic methods allow removing VOCs, NOx, SO2, deodorants, and microorganisms at the same system. The new third generation of photoactive materials activated by low powered and low cost irradiation sources (such as LEDs or black fluorescent UV lamps) can be used as photocatalysts in air purification systems. A series of single semiconductors and their nanocomposites combination were prepared using hydrothermal...
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Otrzymanie tłuszczu smażalniczego na drodze enzymatycznego przeestryfikowania oleju rzepakowego i łoju wołowego. Obtaining of frying fat by enzymatic interesterification of rapeseed oil and tallow.
PublikacjaTłuszcz strukturyzowany otrzymywano na drodze enzymatycznego przeestryfikowania mieszaniny oleju rzepakowego i łoju wołowego (4:6 w/w). Określano stabilność termooksydatywną triacylogliceroli wyizolowanych z poszczególnych surowców, z mieszaniny wyjściowej oraz z produktów enzymatycznego przeestryfikowania. Badano takie wyróżniki jak: okres indukcji -(met.DSC)-, zawartość frakcji polarnej -(met. chromatografii kolumnowej) i E%1cm...
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Wpływ cyklicznych naprężeń mechanicznych na trwałość organicznych powłok ochronnych
PublikacjaTematem pracy jest wpływ cyklicznych naprężeń mechanicznych na właściwości ochronne organicznych powłok przeciwkorozyjnych. Zbadano dynamikę procesu niszczenia zmęczeniowego powłok poddanych powtarzającym się napężeniom zginającym o różnych częstotliwościach. Odporność powłok nowych porównano z powłokami poddanymi procesom starzenia fizycznego (poprzez ekspozycję na promieniowanie UV lub na podwyższoną temperaturę). W pracy wykazano,...
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SILICA AEROGEL TOWARDS ANODES FOR LITHIUM-ION BATTERIES
PublikacjaAn increasing demand for electrochemical energy storage and conversion devices stimulates progress in research on electrode and electrolyte materials. In the field of electrodes materials, silicon is the one of the most promising anode materials for Li-ion batteries. However silicon has the drastic volume variation (around 3 times lower on extraction) during insertion and extraction of lithium ions. As an alternative, nanocomposites...
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Intense and stable room-temperature photoluminescence from nanoporous vanadium oxide formed by in-ambient degradation of VI3 crystals
PublikacjaVanadium oxides have attracted research interest because their optoelectronic properties make them optically active with room-temperature photoluminescence (PL) emission, which, however, is not sufficiently intense for real applications. For this reason, many nanostructured vanadium oxides are currently fabricated through several precursors and different treatments to improve the PL efficiency and enhance the PL intensity. Herein,...
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Emerging oxidized and defective phases in low-dimensional CrCl3
PublikacjaTwo-dimensional (2D) magnets such as chromium trihalides CrX3 (X ¼ I, Br, Cl) represent a frontier for spintronics applications and, in particular, CrCl3 has attracted research interest due its relative stability under ambient conditions without rapid degradation, as opposed to CrI3. Herein, mechanically exfoliated CrCl3 flakes are characterized at the atomic scale and the electronic structures of pristine, oxidized, and defective...
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Evaluating experimental molecular physics studies of radiation damage in DNA*
PublikacjaThe field of Atomic and Molecular Physics (AMP) is a mature field exploring the spectroscopy, excitation, ionisation of atoms and molecules in all three phases. Understanding of the spectroscopy and collisional dynamics of AMP has been fundamental to the development and application of quantum mechanics and is applied across a broad range of disparate disciplines including atmospheric sciences, astrochemistry, combustion and environmental...
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Zirconia ceramics with additions of Alumina for advanced tribological and biomedical applications
PublikacjaThe results of an investigation on slip cast and sintered Y2O3 (3 wt%)- stabilized ZrO2 with additions of 5, 10, 15 wt% Al2O3 are reported. The surface roughness, porosity and density of the samples were measured. The hardness HRc and Hv, fracture toughness K1C, and friction coefficients were also measured using standard methods. The structural properties of the samples were observed by Scanning Electron Microscopy (SEM). The surface...
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Sodium nitrite as a corrosion inhibitor of copper in simulated cooling water
PublikacjaThe corrosion inhibition behavior of sodium nitrite (NaNO2) towards pure copper (99.95%) in simulated cooling water (SCW) was investigated by means of electrochemical impedance spectroscopy (EIS) and dynamic electrochemical impedance spectroscopy (DEIS). NaNO2 interferes with metal dissolution and reduce the corrosion rate through the formation or maintenance of inhibitive film on the metal surface. Surface morphologies illustrated...
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Structure and magnetic properties of BeO-Fe2O3-Al2O3-TeO2 glass-ceramic composites
PublikacjaIn this work, glass-ceramics in the xBeO–20Fe2O3–(80-x)TeO2 system with x = 0–25 mol% were synthesized by the traditional melt quenching route and studied by inductively coupled plasma optical emission spectroscopy, X-ray diffraction, confocal microscopy, infrared and Raman spectroscopy. BeO addition was found to support the crystallization process of Fe2O3 during melting, and an increased BeO content was associated with an increased...
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Reactions in nanofilms of trifluoroacetic acid (CF3COOH) driven by low energy electrons
PublikacjaBadano modyfikacje chemiczne indukowane przez niskoenergetyczne elektrony (0-20eV) w cienkich warstwach skondensowanych molekuł CF3COOH. Do badań zastosowano dwie metody: desorpcję jonów w wyniku bombardowania elektronami (ESD - Electron Stimulated Desorption) oraz termiczną desorpcję jonów (TDS - Thermal Desorption Spectroscopy).
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Electro-photoluminescence in organics
PublikacjaElektro-fotoluminescencję zaobserwowano w układzie ITO(+)/emiter/Ca(-), gdzie emiter wzbudzany światłem UV (350nm) zawierał dendrymer aminowy m-MTDATA, pochodną fenantroliny BPT i organiczny kompleks platyny PtL2Cl. Widmo fotoluminescencji pochodzi od singletowych ekscypleksów m-MTDATA:BPT i trypletowych ekscypleksów m-MTDATA:PtL2Cl. Ze wzrostem pola elektrycznego następuje wygaszanie ekscypleksów na skutek ich dysocjacji na nośniki...
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A new phosphonium calix[4]arene for selective anion recognition: synthesis and studies in solution and in ion selective electrodes
PublikacjaZaprezentowana została synteza i charakteryzacja tetra (trifenylofosfoniowego) p-tert-butylkaliks[4]arenu 2. Oddziaływania z anionami były badane z użyciem (1)H oraz (31)P NMR i spektrofotometrii absorpcyjnej UV. Badania wykazały oddziaływania z anionami: CLO4-, I-, oraz SCN-. Selektywność jonoforu 2 badano również w membranowych elektrodach jonoselektywnych (ISE) PCV/o-NPOE. Elektroda zawierająca związek 2 generuje odpowiedź potencjometryczną...
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Oznaczanie wybranych związków z grupy jonowych surfaktantów w próbkach środowiskowych z wykorzystaniem techniki chromatografii jonowej
PublikacjaCelem przeprowadzonych badań było opracowanie metodyki oznaczania wybranych związków z grupy kationowych i anionowych surfaktantów w ciekłych i stałych próbkach środowiskowych. W trakcie badań dobrano odpowiednie warunki prowadzenia etapu oznaczenia końcowego z wykorzystaniem techniki chromatografii jonowej z detekcją konduktometryczna bądź spektrofotometryczną (UV). We wcześniejszych badaniach porównano efektywność procesu ekstrakcji...
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Impedance Spectra of RC Model as a Result of Testing Pulse Excitation Measurement Method Dataset
PublikacjaThe dataset titled Impedance spectra of RC model as a result of testing pulse excitation measurement method contains the impedance spectrum of an exemplary test RC model obtained using pulse excitation. The dataset allows presentation of the accuracy of the impedance spectroscopy measuring instrument, which uses the pulse excitation method to shorten the time of the whole spectrum acquisition.
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Spectroscopic investigations into degradation of polymer membranes for fuel cells applications
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Spectroscopic evaluation on pseudopolymorphs of sodium naproxen
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The effect of a miniature argon flow rate on the spectral characteristics of a direct current atmospheric pressure glow micro-discharge between an argon microjet and a small sized flowing liquid cathode
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Ultrasonic nebulization atmospheric pressure glow discharge — Preliminary study
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Adsorption of (Phe-h5)/(Phe-d5)-substituted peptides from neurotensin family on the nanostructured surfaces of Ag and Cu: SERS studies
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A DFT/TD DFT study of the structure and spectroscopic properties of 5-methyl-2-(8-quinolinyl)benzoxazole and its complexes with Zn(II) ion
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Smartphone-based digital image colorimetry for the determination of total capsaicinoid content in chili pepper extracts
PublikacjaA simple smartphone-based digital image colorimetry was proposed for the determination of total capsaicinoid content and the assessment of chili pepper pungency. The biobased solvent D-limonene was used for the first time to isolate analytes. Capsaicinoids were efficiently separated from chili pepper by solid-liquid extraction with D-limonene followed by partitioning of the analytes into the ammonium hydroxide solution to eliminate...
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Vibrational spectroscopic studies of N,N'-dimethylpropyleneurea-water system: Affected solvent spectra and factor analysis
PublikacjaZmierzono widma FT-IR układu N,N'-dimetylopropylenomocznik (DMPU) - woda w całym zakresie składów w zakresie 4000-500 cm-1 przy użyciu techniki całkowitego wewnętrznego odbicia (ATR). Hydratacja DMPU została dodatkowo zbadana przy pomocy transmisyjnej spektroskopii FT-IR izotopowo rozcieńczonej HDO w H2O. Widma zanalizowano przy użyciu ilościowej wersji metody widm różnicowych, prowadzącej do wyizolowania widma rozpuszczalnika...
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Box-Behnken design optimization of pipette tip solid phase extraction for methyl orange and acid red determination by spectrophotometry in seawater samples using graphite based magnetic NiFe2O4 decorated exfoliated as sorbent
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Comparison of two novel in-syringe dispersive liquid–liquid microextraction techniques for the determination of iodide in water samples using spectrophotometry
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Application of Micro-cloud point extraction for spectrophotometric determination of Malachite green, Crystal violet and Rhodamine B in aqueous samples
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Synthesis of UiO-66-OH zirconium metal-organic framework and its application for selective extraction and trace determination of thorium in water samples by spectrophotometry
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Application of Taguchi L16 design method for comparative study of ability of 3A zeolite in removal of Rhodamine B and Malachite green from environmental water samples
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Application of a smartphone based spectrophotometer for rapid in-field determination of nitrite and chlorine in environmental water samples
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Different molecular organization of two carotenoids, lutein and zeaxanthin, in human colon epithelial cells and colon adenocarcinoma cells
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Designing efficient A-D-A1-D-A type fullerene free acceptor molecules with enhanced power conversion efficiency for solar cell applications
PublikacjaThe achievement of highly efficient power conversion efficiency (PCE) is a big concern for non-fullerene organic solar cells (NF-OSCs) because PCE can depend on numerous variables. Here, new five novel acceptor molecules without fullerenes were developed and investigated using DFT (density functional theory) and TD-DFT (time dependent-density functional theory). Compared to the recently synthesized molecule (PZ-dIDTC6), the developed...
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Simple colorimetric copper(II) sensor – spectral characterization and possible applications
PublikacjaNew o-hydroxyazocompound L bearing pyrrole residue was obtained in the simple synthetic protocol. The structure of L was confirmed and analyzed by X-ray diffraction. It was found that new chemosensor can be successfully used as copper(II) selective spectrophotometric regent in solution and can be also applied for the preparation of sensing materials generating selective color signal upon interaction with copper(II). Selective colorimetric...