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Wyniki wyszukiwania dla: ORGANIC SYNTHESIS AND TECHNOLOGY
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Application of gaze tracking technology to quality of experience domain
PublikacjaA new methodological approach to study subjective assessment results employing gaze tracking technology is shown. Notions of Human-Computer Interaction (HCI) and Quality of Experience (QoE) are shortly introduced in the context of their common application. Then, the gaze tracking system developed at the Multimedia Systems Department (MSD) of Gdansk University of Technology (GUT) is presented. A series of audio-visual subjective...
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Optimization of Graphene Oxide Synthesis and Its Reduction
PublikacjaIn this article, we present the review of the chemical methods of synthesis of graphene oxide and its reduction in order to obtain the so-called reduced graphene oxide (rGO) whose properties are similar to those of pure graphene. We also present our experiments and the results in this field and the comparison of the efficiency of different methods of synthesis as well as the reduction of graphene oxide. To characterize the obtained...
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Catalytic Asymmetric Synthesis of Isochroman Derivatives
PublikacjaThe isochroman scaffold constitutes an important structural unit, which is present in various bioactive natural products and synthetic pharmaceutical compounds exhibiting wide arrays of biological properties. Hence the synthesis of this class of heterocyclic compounds in a stereoselective fashion is highly significant and desirable. In the last decade, a substantial advancement has been witnessed ln the catalytic asymmetric...
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Holistic approach to control Melolontha spp. in organic strawberry plantations
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Modifications of total synthesis of mycophenolic acid
PublikacjaThe total synthesis of mycophenolic acid (MPA), a potent immunosuppressant, was modified. The obtained mycophenolic acid was suitable for further preparation of new prospective immunosuppressants with improved therapeutic properties.
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Model of management of knowledge bases in the information technology evaluation environment
PublikacjaThe paper presents the model of management of knowledge bases in multi-agent system for evaluation of information technologies (IT_MAS). Such system is being developed in Gdansk Uni-versity of Technology by Information Technology Management Team. Multi-agent system is supposed to support manager level specialists during decision processes when there is identified need to buy or change any information technology. The main goal of...
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Influence of dissolved organic nitrogen on surface waters
PublikacjaThe aim of this study was to determine the susceptibility of dissolved organic nitrogen (DON) contained in biologically treated wastewater disposed from municipal wastewater treatment plants (WWTPs) to biodegradability and bioavailability in a water environment. Additionally an evaluation was performed of the participation of this organic nitrogen fraction, including bioavailable DON (bDON), in the nitrogen balance for the Baltic...
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Speech synthesis controlled by eye gazing
PublikacjaA method of communication based on eye gaze controlling is presented. Investigations of using gaze tracking have been carried out in various context applications. The solution proposed in the paper could be referred to as ''talking by eyes'' providing an innovative approach in the domain of speech synthesis. The application proposed is dedicated to disabled people, especially to persons in a so-called locked-in syndrome who cannot...
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Functionalization of graphene: does the organic chemistry matter?
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Potential applicability of ontologies for the evaluation of information technology
PublikacjaIn this article we present the possibilities of using ontologies as a part of a multi-agent system (MAS) designed for the evaluation of information technologies. This is a part of a broader idea devel-oped by the team of researchers at Gdańsk University of Technology. The article deals with defining ontologies, presenting main technologies for their design and implementation and proposes, initially, domains of the ontologies' interest...
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The role of organic and mineral constituents on kerogen transformation ratio
PublikacjaThe main aim of this dissertation is to determine the role of mineral and organic matter constituents in kerogen transformation ratio. Practical aspects of the work include application of the results in the assessment of hydrocarbon production potential; to make process of hydrocarbon recovery more predictable consistent and efficient. The work used shale from the Vaca Muerta formation from the Nequen basin in Argentina. The formation...
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Organic Supercritical Thermodynamic Cycles with Isothermal Turbine
PublikacjaOrganic Rankine cycles (ORC) are quite popular, but the overall efficiencies of these plants are rather very low. Numerous studies have been conducted in many scientific centers and research centers to improve the efficiency of such cycles. The research concerns both the modification of the cycle and the increase in the parameters of the medium at the inlet to the turbine. However, the efficiency of even these modified cycles rarely...
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Tip-Based Nanofabrication as a Rapid Prototyping Tool for Quantum Science and Technology
PublikacjaTip-Based Nanofabication as a Rapid Prototyping Tool for Quantum Science and Technology discusses the development of cantilevered nanotips techniques of quantum devices prototyping and how they evolved from scanning probe microscopy. Also covered are the advantages and future prospects of atomic resolution capability and how to use this enabling technology as a rapid prototyping tool for quantum science and technology.
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A Review on Metal–Organic Framework as a Promising Catalyst for Biodiesel Production ENERGY & FUELS
PublikacjaThe rapid depletion of fossil-derived fuels along with rising environmental pollution have motivated academics and manufacturers to pursue more environmentally friendly and sustainable energy options in today’s globe. Biodiesel has developed as an ecologically favorable alternative. However, the mass manufacturing of biodiesel on an industrial scale confronts substantial cost and pricing challenges. To address this issue, high-efficiency...
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Synthesis of coupled lossy resonator filters.
PublikacjaA technique for fast synthesis of coupling matrix low-pass prototypes of generalized. Chebyshev bandpass filters with lossy resonators is presented in this letter. The coupling matrix is found by solving a nonlinear least squares problem based on zeros and poles of filter's transfer functions.
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Technology transfer centers as an instrument for the development of technological capabilities
PublikacjaPurpose of the article is to show how technology transfer centers (TTCs) can affect the development of technological capabilities as a result of cooperation between the science and business sectors on the example of Polish experiences in this field. Scientific aims: The first scientific aim was to present the role of TTCs in the development of technological capabilities. The second scientific aim was to discuss the research results...
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Global Digital Technology Convergence: Driving Diffusion via Network Effects
PublikacjaSince the 1970s, we have witnessed unprecedented diffusion of digital technologies in both speed and geographic coverage. These technologies are pervasive and disruptive, and lead to profound shifts and transformations in societies and economies. Many claim that emerging network externalities are the principal phenomenon driving the process of technology diffusion and determining its in-time dynamics. This book analyses the unique...
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Influence of passive house technology on time and cost of construction investment
PublikacjaDue to the changes in the energy standards for housing in Poland there are many concerns. Is the standard required by the regulation achievable and if it is, then at what cost? There are many solutions to construct a building in line with the requirements of passive house technology. They are differentiated by price and time required for implementation. This study is based on the solution proposed by one of Polish companies, offering...
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Sano-Tachiya-Noolandi-Hong, Onsager and Braun models vs Monte Carlo simulation of charge photogeneration in organic solids
PublikacjaThe Sano-Tachiya-Noolandi-Hong (STNH), Onsager, and Braun models as well as Monte Carlo (MC) simulations of charge recombination/separation have been applied for the first time to reproduce the results of the electromodulated photoluminescence measurements in vacuum-evaporated films of fluorescent materials commonly used in optoelectronic devices. The values of the electron-hole pair final recombination speed in the monomer emitters:...
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USE OF LANGMUIR PROBE IN DIESEL ENGINE DIAGNOSTIC RESEARCH Part I MEASUREMENT TECHNOLOGY. - Part 1 : MEASUREMENT TECHNOLOGY
PublikacjaIn the paper, the basic assumptions of diesel engine cylinder system's diagnosing method, based on observation of emerging and moving electric charges of ionized gas in the combustion workspaces, using Langmuir's probe. In the first part of the paper, only the technology of the measurement and results of the preliminary diagnostic tests of laboratory engine Farymann Diesel D10 were presented. The primary purpose of the research...
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Influence of Holes Manufacture Technology on Perforated Plate Aerodynamics
PublikacjaTranspiration flow is a very important and still open subject in many technical applications. Perforated walls are useful for the purpose of “flow control”, as well as for the cooling of walls and blades (effusive cooling) in gas turbines. We are still not able to include large numbers of holes in the numerical calculations and therefore we need physical models. Problems are related also to the quality of the holes in perforated...
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State of the art electronic nose technology and future trends
PublikacjaThis chapter briefly reviews the progress in field of artificial olfaction and demonstrates future trends in electronic nose technology. The discussion about e-nose concern also a big challenge for the pattern recognition (PARC) systems due to several particular problems they involve. Finally, the application of e-nose in different areas of life is given.
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Chiral-based optical and electrochemical biosensors: Synthesis, classification, mechanisms, nanostructures, and applications
PublikacjaThis review seeks to collect, summarize, classify and discuss the latest advances in chiral-based optical biosensors. Starting from the identification of chiral molecules, photoluminescence, and electrochemical sensors, applications of chiral structures in biosensing molecules are reviewed. Then, biosensors working on the basis of chirality are classified, followed by summarizing the outcomes of research works on design, synthesis,...
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Modelling Evolution of Knowledge-Based Information Technology Organization: The Concept and Perspective
PublikacjaIncreasing pressure on improving the efficiency of companies' operations leads to transformation of their Information Technology (IT) organizations from technology-oriented to service-oriented, based on the Information Technology Infrastructure Library (ITIL) model. The evolution of these IT organizations can be supported by the knowledge-based systems centered on the rules determined through agregation and refinement of existing...
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A Green Chemistry "environmentally friendly" approach to the synthesis of chloro-intermediates of ephedrine/pseudoephedrine
PublikacjaMethylamphetamine is an addictive stimulant drug that strongly activates certain systems in the brain. It is closely related chemically to amphetamine, but the central nervous system effects of methamphetamine are greater. There is much interest in methylamphetamine among scientists and therefore the synthesizes of methylamphetamine and its metabolites are carried out on a large scale in chemical laboratories. Globally, ephedrine...
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Methods of ZnO nanoparticles synthesis
PublikacjaZinc oxide nanostructures are interesting nanomaterials with a wide range of applications. Since the physical and chemical properties of ZnO nanoparticles are influenced both by their shape and size, a control of morphology of ZnO structures is needed for their commercial usage. Different chemical, physical, and biological methods used to produce ZnO nanostructures can be found in the literature. The production of ZnO nanoparticles...
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Correlations between organic pollution indicators in municipal wastewater
PublikacjaThe paper presents the results of a study of parameters used for determining the amount of organic pollutants in wastewater flowing into a collective wastewater treatment plant with a population equivalent of about 120 000 PE. The plant constituted part of a sewage system. Assays were performed for biochemical oxygen demand (BOD5), chemical oxygen demand (CODCr), permanganete index (CODMn) and total organic carbon (TOC). In addition,...
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Adaption of Open Science Paradigm at Gdańsk University of Technology
PublikacjaThe paper describes the basic principles standing behind Open Access and will try to dispel the doubts behind them. Further the solution adapted by the Gdańsk University of Technology is presented. Later on the systems that the University uses and means of their integration into a complex Open Science platform are described. Finally the procedures needed to publish a document in the repository alongside the University's policy...
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Enhanced trap-assisted recombination in organic semiconductors
PublikacjaAn analytical model to describe the interaction of excitons and charge transfer states with deep traps is formulated for the case of molecular materials. Here, we have considered the influence of a trap-assisted recombination on this phenomenon. The final expression for the effective recombination rate has been derived from the Shockley–Read–Hall theory and kinetic equations which characterize different photophysical processes....
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Ion Chromatography in Environmental Analysis of Selected Organic Acids
PublikacjaLow molecular mass carboxylic acids (LCAs) occur in many environmental compartments dueto natural processes and human activity. When volatile and nonvolatile acids are to be monitored then liquidchromatography, including ion chromatography seems a method of choice. At high pH the acids are inionized form and can be separated as carboxylats by means of anion exchange chromatography. LCAs canalso be separated at low pH by ion exclusion...
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Application of the near-infrared spectroscopy in the pharmaceutical technology
PublikacjaNear-infrared (NIR) spectroscopy is currently the fastest-growing and the most versatile analytical method not only in the pharmaceutical sciences but also in the industry. This review focuses on recent NIR applications in the pharmaceutical technology. This article covers monitoring, by NIR, of many manufacturing processes, such as granulation, mixing or drying, in order to determine the end-point of these processes. In this...
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CONSTRUCTION TECHNOLOGY OF TIMBER-FRAME HOUSES RESISTANT TO DYNAMIC LOADS – STUDY ON MODELS OF EXTERIOR WALLS
PublikacjaThe aim of this paper is to show the numeric representation of experimental studies concerning the behaviour of exterior wall models of a timber-frame house under harmonic loading. A single wall model according to traditional technology of timberframe house walls (filling with mineral wool) was tested. The analysis was conducted for the following frequencies: 0.5 Hz, 1.0 Hz, 2.0 Hz and 5.0 Hz for various values of the specified...
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The Use of Organic Coagulants in the Primary Precipitation Process at Wastewater Treatment Plants
PublikacjaMeasurements for determining the effect of chemically enhanced primary treatment (CEPT) on the efficiency of pollutant removal from wastewater were carried out using conventional inorganic coagulants PIX113 with polymer A110 (Kemipol, Police, Poland) and unconventional cationic organic coagulants Cofloc (Attana, Coalville, UK) C29510 (Kemipol, Police, Poland) and Sedifloc 575 (3F Chimica, Sandrigo, Italy). The average removal efficiency...
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Utilization of molten salt synthesis route in ceramics production
PublikacjaThe molten salt synthesis method is widely used to prepare ceramic powders for various applications e.g. piezoelectric devices or electrolytes for solid oxide fuel cells. The usage of this method workdwide is quite common especially in piezoelectric powder synthesis. In this work several application of the method is presented and the advantages of this route are numbered.
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Mineral and Organic Matter Constituents in Weak Interfaces in Shales
PublikacjaThis paper identifies formation interfaces that would appear to be "weak interfaces", in the Jurassic, Early- Cretaceous Vaca Muerta formation, in the Neuquén Basin, Argentina. Significant distribution of the weak interfaces was observed including contacts between volcanic ash layers of varying thicknesses, calcite-filled veins, and contacts between lithology changes, such as between argillaceous mudstone and mottled carbonates....
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Concept for Perfecting the Marketing of New Technologies at Gdańsk University of Technology
PublikacjaThe chapter discusses the problem of improving the use of modern marketing achievements in the development and offering of new technologies, based on the experience of the Gdansk University of Technology (PG). Were discussed the concept, features, benefits and conditions of modern marketing, as well as the essence of the new technologies and ways of transferring them from scientific research units to the economy. Presented past...
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Catalysts for advanced oxidation processes: Deep eutectic solvents-assisted synthesis – A review
PublikacjaNew catalyst synthesis techniques, including green materials, are extensively studied for heterogeneous photocatalytic advanced oxidation processes (AOPs) on spotlight of sustainable development. Deep eutectic solvents (DESs) started to be used in this field as environmentally friendly alternative to ionic liquids (ILs). During the catalyst synthesis, DESs can act as stabilizers, capping agents, structure directing agents, templates,...
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Subcritical Thermodynamic Cycles with Organic Medium and Isothermal Expansion
PublikacjaThe efffciencies of the Organic Rankine Cycle (ORC) are not very high and only very seldom do they exceed 20%. The increase and optimization of initial parameters and certain modifications of the thermodynamic cycle make it possible to overcome these drawbacks. A new modified cycle has been described and analyzed in detail in the paper. Similarly to the Ericsson cycle for gas turbines, isothermal expansion in the turbine is suggested...
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Spatial distribution of pharmaceuticals in conventional wastewater treatment plant with Sludge Treatment Reed Beds technology
PublikacjaPharmaceutical residues are an emerging environmental problem. It is strongly confirmed that pharmaceuticals are present in soils and environmental waters (surface, marine and even groundwater), and that wastewater treatment plant (WWTP) effluents are the main source of pharmaceuticals in the watershed. The aim of this studywas to recognize the spatial distribution and seasonal changes of selected pharmaceuticals in conventional WWTP...
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Quenching effects in organic electroluminescence
PublikacjaWe examine various electronic processes that underlie the quenching of the emission from highly efficient phosphorescent and electrophosphorescent organic solid-state molecular systems. As an example, we study the luminescent efficiencies from the phosphorescent iridium (III) complex, fac tris (2-phenylpyridine) iridium [(Ir (ppy)3] doped into a diamine derivative doped polycarbonate hole-transporting matrix and in the form...
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Organic matter removal efficiency in treatment wetlands simulation by COD fractions
PublikacjaThe objective of this paper was to investigate the organic fraction (colloidal, particulate, and dissolved) in sewage treatment in treatment wetland. Performance of TWs was simulated well with a simple first order model k – C* based on monitoring data. In this investigation background or residual concentration (C*) was assumed to be equal concentration of input influent organic matter in particulate (CODp). Calculated reaction...
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Synthesis of Bis(ethylenedithio)dithiadiazafulvalenes (BEDT-DTDAF) and Generation of Charge Transfer Complexes with Tetracyanoquinodimetane
PublikacjaW artykule opisana została synteza Bis(etylenoditio)ditiadiazafulwalenów (BEDT-DTDAF) wykorzystująca jako kluczowe związki przejściowe 4,5-(etylenoditio)tiazol oraz sole 3-aliklo-4,5-(etylenoditio)tiazoliowe oraz generowanie przewodzących kompleksów z przeniesieniem ładunku usyskanych z Bis(etylenoditio)ditiadiazafulwalenów oraz tetracyjanochinodimetanu.
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Synthesis and structural investigation of N-acyl selenophosphoramides
PublikacjaN-acylowane amidy kwasu O,O-neopentylidenomonoselenofosforowego, w zależności od podstawnika na atomie azotu, krystalizują jako konformery zawierające selen w pozycji ekwatorialnej bądź aksjalnej. Wyniki tych eksperymentów wyjaśniono działaniem efektu anomerycznego.
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Effect of environmental temperature variations on protective properties of organic coatings
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Local properties of organic coatings close to glass transition temperature
PublikacjaAcrylic coating applied on copper substrate has been investigated at different temperatures starting from the ambient one up to the level above the glass transition temperature. Its local topographic and electric properties have been examined with the atomic force microscopy (AFM) based approach including dc current mapping and local impedance spectroscopy. The local findings have been compared with the information from global...
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Effect of environmental temperature variations on protective properties of organic coatings
PublikacjaW oparciu o model rozwoju naprężeń oraz niszczenia kumulatywnego przedyskutowano wpływ zmiennych temperatur środowiska na mechaniczną spójność i własności ochronne systemów powłokowych. Badano wpływ cykli temperaturowych pomiędzy 20 i 55 st. C oraz między -20 i 20 st. C na trwałość różnych powłokowych systemów malarskich na stali. Stosując technikę spektroskopii impedancyjnej monitorowano zmiany parametrów powłok poddanych cyklom...
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Laser technology 2012
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Transformations of descriptive geometry education for architecture students at Gdańsk University of Technology, Poland
PublikacjaIn this article, the authors analyse the evolution of teaching descriptive geometry for architecture students at Gdańsk University of Technology (Gdańsk Tech), Poland. The study traces changes in the curriculum in terms of teaching hours, considering also practices at Politechnika Lwowska (Lwów Polytechnic) and the Technische Hochschule Danzig (Technical University of Gdańsk), before World War II....
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Evaluation of a Novel Approach to Virtual Bass Synthesis Strategy
PublikacjaThe aim of this paper is to present a novel approach to the Virtual Bass Synthesis (VBS) strategy applied to portable computers. The developed algorithms involve intelligent, rule-based settings of bass synthesis parameters with regard to music genre of an audio excerpt and the type of a portable device in use. The Smart VBS algorithm performs the synthesis based on a nonlinear device (NLD) with artificial controlling synthesis...
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Organic Rankine cycle as bottoming cycle to a combined Brayton and Clausius - Rankine cycle
PublikacjaA preliminary evaluation has been made of a possibility of bottoming of a conventional Brayton cycle cooperating with the CHP power plant with the organic Rankine cycle installation. Such solution contributes to the possibility of annual operation of that power plant, except of operation only in periods when there is a demand for the heat. Additional benefit would be the fact that an optimized backpressure steam cycle has the advantage...