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Stimulation of Heavy Metal Adsorption Process by Using a Strong Magnetic Field
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The Diagnostic Value of Trace Metal Concentrations in Hair in Carotid Artery Disease
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Pylenie metalu w środowisku rafineryjnym = Metal dusting in refinery environment
PublikacjaPrzedstawiono niektóre wyniki pierwszego etapu pracy zaprojektowanej w celu określenia mechanizmu pylenia stali 9Cr-1Mo w środowisku pieców Platformingu CCR oraz wpływu dodatku siarki w środowisku na degradację mikrostruktury stali w zaawansowanym etapie pylenia.
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Emulsion cleaning of metal surfaces contaminated with fresh and oxidized printing ink.
PublikacjaWykonano badania usuwania farby drukarskiej, stosowanej do druku offsetowego za pomocą emulsji terpentyny i hexanu w wodzie.
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Detection of stray current field interference on metal constructions using STFT
PublikacjaZaprezentowano metodę detekcji pola prądów błądzących wykorzystującą krótkoczasową transformatę Fouriera STFT. Ten sposób analizy umożliwia wyznaczenie zmian spektralnej gęstości mocy sygnału (np. potencjału konstrukcji) w funkcji czasu. Przedstawiono rezultaty analizy zmian potencjału w polu prądów błądzących generowanych przez trakcję tramwajową. Spektrogramy są kompozycją prążków w łącznej dziedzinie czasu i częstotliwości....
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A time-frequency method for detection of electromagnetic field interference on metal constructions.
PublikacjaPrzedstawiono metodę detekcji oddziaływania pola elektromagnetycznego na metalowe konstrukcje podziemne. Polega ona na czasowo-częstotliwościowej analizie rejestrów zmian potencjału źródła pola (np. prądów błądzących) oraz potencjału konstrukcji podziemnej, z wykorzystaniem krótkoczasowej transformaty Fouriera STFT. Wnioski o oddziaływaniu pola na konstrukcję metalową wyciąga się na podstawie analizy uzyskanych widm.
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Metal enhanced fluorescence of flavin mononucleotide using new plasmonic platform
PublikacjaNew plasmonic platform was successfully obtained to investigate the increase of fluorescence intensity of a fluorophore in the presence of silver nanoparticles. A flavin mononucleotide, was selected by us as a fluorophore for this study as a very important biological compound playing a key role in many biochemical process. Plasmonic platforms were characterized by means of luminescence spectroscopy. Flavin mononucleotide deposited...
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The effect of laser on metal surfaces for multidisciplinary usage in material and thermal engineering
PublikacjaThe subject of heat transfer and cooling systems is still a matter of contention in many different fields of science and industry. Infrigidation is much more difficult than warming, and so, much more needed in more and more different devices, starting from massive industrial machinery and air conditioning in commercial buildings, up to micro and nano-surgery tools. In fact, the size of many cooling systems is still a problem. It...
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Aspects of the biomonitoring studies using mosses and lichens as indicatorsof metal pollution.
PublikacjaWykazano, wbrew wszelkim ograniczeniom, że mchy i porosty są dobrymi narzędziami służącymi do monitorowania zanieczyszczenia powietrza. Najlepsze rezultaty przynoszą badania w których stosuje się zarówno mchy jak i porosty łącznie, ponieważ rośliny te różnią się retencją i przyswajalnością metali.W pracy przedstawiono pasywną oraz aktywną formę monitoringu z wykorzystaniem biowskaźników i omówiono zalety oraz ograniczenia...
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Microstructure degradation and creep failure study of the dissimilar metal welded joint of heat-resistant steel and Inconel 617 alloy tested at 650 °C and applied stress range of 100–150 MPa
PublikacjaThe advanced ultra-supercritical (A-USC) power plant system is anticipated to become India's next-generation base-load power station. To adopt AUSC technology, dissimilar welded joints (DWJs) between heat-resistant steels and the nickel-based alloys, using the nickel-based fillers, will need to be implemented. However, failure of dissimilar welded joints from P92 steel base metal or the heat affected zone (HAZ) has been commonly...
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Broadband/Dual-band Metal-Mountable UHF RFID Tag Antennas: A Systematic Review. Taxonomy Analysis, Standards of Seamless RFID System Operation, Supporting IoT implementations, Recommendations and Future Directions
PublikacjaThe employment of broadband/dual-band ultra-high frequency (UHF) radio frequency identification (RFID) tag antennas contributes to the growth of RFID technology, with many potential implications, such as the increase of international trade, and reducing costs thereof. This study presents all reported articles on RFID tags for metal objects that can work seamlessly across different countries. Moreover, it addresses all available...
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Cation homeostasis and transport related gene markers are differentially expressed in porcine buccal pouch mucosal cells during long-term cells primary culture in vitro
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Uptake, accumulation, and translocation of Zn, Cu, Pb, Cd, Ni, and Cr by P. australis seedlings in an urban dredged sediment mesocosm: impact of seedling origin and initial trace metal content
PublikacjaThe study presents results from 6 months of phytoremediation of sediments dredged from three urban retention tanks carried out in a mesocosm setup with the use of P. australis. Two kinds of P. australis seedlings were considered: seedlings originating from natural (uncontaminated - Suncont) and anthropogenically changed environments (contaminated – Scont); this distinction was reflected in the baseline concentrations of trace metals...
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Reactions of Lithium Salts of Triphosphanes tBu2P-PLi-PtBu2 and tBu2P-PLi-P(NEt2)2 with Metal Complexes [(R3P)2MCl2] (M = Ni, Pd, Pt, R3P = Et3P, pTol3P, Ph2EtP, iPr3P)
PublikacjatBu2P-PLi-PtBu2·2THF reacts with [(R3P)2MCl2] (M = Pt, Pd, Ni; R3P = Et3P, pTol3P, Ph2EtP, iPr3P) to yield isomers of [(1,2-η-tBu2P=P-PtBu2)M(PR3)Cl], in which the tBu2P-P-PtBu2 ligand adopts the arrangement of a side-on bonded 1,1-di-tert-butyl-2-(di-tert-butylphosphanyl)diphosphenium cation. tBu2P-PLi-P(NEt2)2·2THF reacts with [(R3P)2MCl2] but does not form complexes with a tBu2P-P-P(NEt2)2 moiety, however, splitting...
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Valorization of waste plastics to a novel metal-organic framework derived cobalt/carbon nanocatalyst as peroxymonosulfate activator for antibiotics degradation
PublikacjaMetal-organic frameworks (MOFs), with excellent structural properties, exhibit unique advantages as promising catalysts in the degradation of emerging organic contaminants (EOCs) by PS-AOPs. Herein, Co-MOF-71 was prepared by hydrothermal method using terephthalic acid (TPA) obtained from the hydrolysis of waste PET plastics as an organic ligand, and the derived cobalt/carbon composite (PETC) was prepared by carbonizing Co-MOF-71...
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Atmospheric heavy metal deposition accumulated in rural forest soils of southern Scandinavia
PublikacjaPrzeprowadzono obliczenia zakumulowanej ( w okresie 50 lat) atmosferycznej depozycji metali ciężkich na glebach leśnych na obszarach wiejskich. Podstawę do obliczeń stanowiły:- pomiary zawartości metali ciężkich w opadach atmosferycznych (przeprowadzone przez okres 33 lat) na terenie Danii,- europejska baza danych o emisji zanieczyszczeń.Oznaczano zawartość metali ciężkich (Pb, Cd, Cu, Zn, V, Ni, As) w próbkach opadów atmosferycznych...
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Cadmium tri-tert-butoxysilanethiolates. Structural and spectroscopic models of metal sites in proteins.
PublikacjaW publikacji opisano syntezy i struktury dla dwóch heteroleptycznych kompleksów kadmu z rdzeniem CdS2NO2 i CdS2N2. Bis(tri-tert-butoksysilanotiolato)(1-metyloimidazol)kadmu(II) oraz bis(tri-tert-butoksysilanotiolato)bis(1-metyloimidazol)kadmu(II) współistnieją w roztworze chloroformu przy różnych stężeniach Bis(tri-tert-butoksysilanotiolanu) kadmu(II) i 1 metyloimidazolu. Rotzwór ten został scharakteryzowany za pomocą analizy spektralnej...
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Hybrid electrodes composed of electroactive polymer and metal hexacyanoferrates in non-aqueous electrolytes
PublikacjaMateriały hybrydowe złożone z polimeru elektroaktywnego poli(3,4-etylenodioksytiofenu) (pEDOT) i heksacyjanożelazianów wybranych metali Mehcf (Me = Fe, Co, Ni) zostały poddane testom w elektrolitach niewodnych składających się z mieszaniny rozpuszczalników węglan etylenu (EC) : węglan propylenu (PC) w stosunku objętościowym 1:1 oraz wybranych soli: KPF6 i LiPF6. Właściwości elektrochemiczne materiałów badane były metodami woltamperometrii...
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Analysis of airborne metal containing particles with EDX/EDS detectorsin electron microscopes
PublikacjaIn years 2006-2010 particulate matter analysis was undertaken for dust samples collected from Gdansk and London area in orderto compare their morphology and composition. Part of those studies was devoted to analysis of particulate matter (PM) bearingmetals. Characterization of the morphology and size of the particles collected onto the filters was performed using a scanning electronmicroscope (SEM) and transmission electron microscope...
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Use of clinoptilolite for the immobilization of heavy metal ions and preparation of autoclaved building composites
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Bottom up approach of metal assisted electrochemical exfoliation of boron towards borophene
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Tuning Carbon Nanotubes Through Poor Metal Addition to Iron Catalysts in CVD
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Hollow carbon sphere/metal oxide nanocomposites anodes for lithium-ion batteries
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Novel method for metal-oxide glass composite fabrication for use in thermoelectric devices
PublikacjaA novel method for thermoelectric materials fabrication using a reduction of oxide precursors in hydrogen was reported. On the example of Bi-Sb, Bi-Sb-Te and Te-Ag-Ge-Sb compounds it was shown that this simple and easy method is suitable for fabrication of two-, three- and even multicomponent thermoelectric materials. It allows controlling a composition, microstructure and even type a of electrical charge carriers. As a result...
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Novel Photocatalytic Nanocomposite Made of Polymeric Carbon Nitride and Metal Oxide Nanoparticles
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Free-ranging domestic cats are characterized by increased metal content in reproductive tissues
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Optical and photocatalytic properties of rare earth metal-modified ZnO quantum dots
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Structure Analysis of the Modified Cast Metal Matrix Composites by Use of the Rve Theory
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Identification of multisite behavior in a broadly emitting transition-metal system using pressure
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Material Balance for Stepwise Extraction of Freshwater Algae Biomass with Heavy Metal Sequestration
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Thermodynamic properties of Ga-In-Li alloys - a potential material for liquid metal batteries
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Elastic-plastic properties of metal matrix composites: Validation of mean-field approaches
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Heavy-metal tolerance of photobiont in pioneer lichens inhabiting heavily polluted sites
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Removal of metal particles from carbon nanotubes using conventional and microwave methods
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The Influence of Hybridization of Epoxy–Glass Laminates Modified with Metal Oxides and Graphite Particles
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Detailed investigation on FAME capped metal nanocomposite synthesis as potential antifungal agent
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Energy transfer mechanisms in heavy metal oxide glasses doped with lanthanide ions
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2.7 μm emission in heavy metal oxide glasses doped with erbium ions
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Cadmium tri-tert-butoxysilanethiolates: Structural and spectroscopic models of metal sites in proteins
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Apparent molar volumes of divalent transition metal bromides in dimethyl sulfoxide solutions
PublikacjaWyznaczono pozorne i cząstkowe molowe objętości bromków dwuwartościowych metali przejściowych szeregu Mn(II)-Zn(II)w roztworach w dimetylosulfotlenku. Przedyskutowano korelacje między objętościami molowymi a stanami koordynacyjnymi i sposobem jonizacji soli.
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Left-handed propagation characteristics of a dielectric and metal-loaded periodic circular waveguide
PublikacjaIn this paper, a periodic dielectric/metallic rod is located in a circular waveguide to obtain left-handed operation. Two geometries of the dielectric/metallic rod are proposed and examined. The dispersion characteristics of the investigated waveguides are obtained using a surface impedance model. Moreover, equivalent circuit models are proposed allowing for calculation of the dispersion characteristics and scattering parameters...
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Optical and photocatalytic properties of rare earth metal-modified ZnO quantum dots
PublikacjaA series of novel ZnO quantum dots modified with rare earth metals was successfully prepared by a simple sol-gel approach. The effects of types (Eu, Er, Tb, Yb, Ho, La) and amounts (from 0.09 to 0.45 mmol) of lanthanides on the optical properties, structural characterization and photocatalytic activity of ZnO/RE QDs were systematically investigated. The X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform...
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Transition-Metal-Promoted Oxidative Cyclization To Give 1,2,4-Trisubstituted Carbazole Scaffolds
PublikacjaHerein, we describe the synthesis of a 1,2,4-trisubstituted carbazole core from 5-(1H-indol-3-yl)-3-oxopentanoic acid esters or amides. For oxidative cyclization, we tested two different approaches. First, we used manganese triacetate as a conventional moderate oxidizer to ensure the radical course of the reaction. Second, we examined the use of a more complex oxidizing agent I2/Me(OTf)3. In both cases, formation of a fused-ring...
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Determination of stability constants of complexes of selected amide ionophores with alkali metal cations
PublikacjaPodano właściwości kompleksujące jony litowców czterech jonoforów typu amidów. Wyznaczono wartości stałych kompleksów z jonów Li+, Na+, K+ metodą potencjometryczną z zastosowaniem elektrod jonoselektywnych stosując dwie różne procedury: 1) stosując jako kation referencyjny TMA+, 2) stosując chromofor kompleksujący H+.
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Enhancement of the Magnetoresistance in the Mobility‐Engineered Compensated Metal Pt 5 P 2
PublikacjaThe magnetoresistance (MR) in nonmagnetic materials continues to be a fertile research area in materials science. The search for giant, positive MR has been limited to a rather small window of materials such as high-mobility semimetals in single-crystalline form. Here, the observation of a very large positive MR in metallic Pt5P2 in polycrystalline form is reported. The observations reveal that improvement of the crystallinity...
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Dynamic FE simulations of buckling process in thin-walled cylindrical metal silos
PublikacjaW artykule przedstawiono wyniki dynamicznej analizy wyboczeniowej cienkościennych silosów metalowych o przekroju kołowym. Analizy MES wykonano dla wstępnych imperfekcji geometrycznych o różnym kształcie i amplitudzie. Wyniki analizy dynamicznej porównano z analizami statycznymi.
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Defected Ag/Cu-MOF as a modifier of polyethersulfone membranes for enhancing permeability, antifouling properties and heavy metal and dye pollutant removal
PublikacjaIn this study, a novel bimetallic metal-organic framework (MOF) i.e. Ag/Cu-MOF was synthesized using a solvothermal method and later incorporated at different concentrations (0.1–2 wt%) using a phase inversion method for modification and antifouling property improvement of polyethersulfone (PES) membranes. The resulting Ag/Cu-MOF characteristics were investigated using different techniques, such as FTIR, XRD, FE-SEM and EDX. The...
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Reactions of lithiated diphosphanes R2P-P(SiMe3)LiTHF (R = tBu, iPr) with [(PNP)TiCl2]. Two different coordination types of phosphanylphosphido ligand to the metal center.
Publikacja[(PNP)TiCl2] (PNP = N[2-PiPr2-4-methylphenyl]2) reacts with one equivalent of lithium derivative of diphosphane R2P-P(SiMe3)LinTHF (R = tBu, iPr) in toluene and forms the first complex with g1-coordination [(PNP)Ti(Cl){g1-P(SiMe3)-PtBu2}] (1) and complex with g2-coordination [(PNP)Ti(Cl){g2-P(SiMe3)-PiPr2}] (2) of phosphanylphosphido ligands to the titanium center. The similar reaction with two equivalents of tBu2P-P(SiMe3)LinTHF...
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Solid Supports and New Advanced Materials used in Microextraction processes Metal-organic framework-based solid-phase microextraction for air samples analysis: a mini-review
PublikacjaSPME methods are now extremely popular. Recent advances in SPME have focused on the development of new materials as sorbent coatings capable of providing high extraction efficiencies, as well as high selectivity with high mechanical and chemical stability. Metal-organic frameworks (MOFs) have become an extremely popular material due to their unique properties (large surface area, selective gas adsorption, tunable structures, high...
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Titania nanotubes modified by a pyrolyzed metal-organic framework with zero valent iron centers as a photoanode with enhanced photoelectrochemical, photocatalytical activity and high capacitance
PublikacjaThe paper discusses the synthesis, photoelectrochemical and electrochemical behaviour of titania nanotube arrays modified by a pyrolyzed metal-organic framework (MOF). A poly(3,4–ethylenedioxyphene) (PEDOT) matrix with an embedded inorganic network of iron hexacyanoferrate (BP) covering TiO2 nanotubes (TNT) is used as a MOF for the further sintering procedure, resulting in a novel, thin film of carbonaceous wrap supported Fe catalytic...