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Wyniki wyszukiwania dla: THERMODYNAMIC PROPERTIES
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Thermodynamic properties and phase stability of wadsleyite II
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Heat capacities and thermodynamic properties of antimony substituted lanthanum orthoniobates
PublikacjaThe results of heat capacity measurements for the lanthanum orthoniobate substituted with 10, 20 and 30 mol% of antimony (LaNb0.9Sb0.1O4, LaNb0.8Sb0.2O4 and LaNb0.7Sb0.3O4) are presented and discussed. Temperature dependence of low temperature heat capacity was analyzed within the Debye and Einstein models. The Debye temperature decreased, whereas the Einstein temperature increased with antimony content. The decrease of the Debye...
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Differential Scanning Calorimetry for Determining the Thermodynamic Properties of Selected Honeys
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Application of the tetraphenylphosphonium tetraphenylborate (TPTB) assumption to the thermodynamic properties of solvated ions in dimethylsulfoxide
PublikacjaW niniejszej pracy za pomocą spektroskopii ATR FTIR sprawdzano możliwość zastosowania tetrafenyloboranu tetrafenylofosfoniowego w metodzie elektrolitu wzorcowego, służącej do podziału wielkości termodynamicznych elektrolitów w dimetylosulfotlenku na udziały jonowe. Jednoznacznie stwierdzono, że poza termodynamiczne założenie o identycznych oddziaływaniach jonów w elektrolicie wzorcowym z cząsteczkami DMSO jest nieprawdziwe. Uzyskane...
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Description of the thermodynamic properties of BiH 5 and BiH 6 superconductors beyond the mean-field approximation
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Effect of choline chloride based natural deep eutectic solvents on aqueous solubility and thermodynamic properties of acetaminophen
PublikacjaIn this work, natural deep eutectic solvents (NADESs) containing choline chloride as hydrogen bond acceptor and 1,2-propanediol, malic acid and tartaric acid as hydrogen bond donors have been synthesized and applied to enhance the aqueous solubility of model sparingly water-soluble drug – acetaminophen. The results indicate that the greatest impact on the solubility of acetaminophen have deep eutectic solvents based on 1,2-propanediol...
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Mechanical and thermodynamic properties of Aβ42, Aβ40, and α-synuclein fibrils: a coarse-grained method to complement experimental studies
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Thermodynamic properties of inorganic salts in nonaqueous solvents. II. Apparent molar volumes and compressibilities of divalent transition-metal perchlorates in acetonitrile
PublikacjaW oparciu w wyniki pomiarów gęstości wykonanych w temperaturze 15,20,25,30,35,40 i 50 stopni Celsjusza oraz pomiaru szybkości dżwięku w temperaturze 25 stopni Celsjusza, wyznaczono pozorne objętości molowe oraz ściśliwości adiabatyczne roztworów nadchloranów manganu(II), kobaltu(II), niklu(II) i cynku(II). Obliczono odpowiednie wartości standardowe oraz rozszerzalności izobaryczne. Przeanalizowano związki między strukurą elektronową...
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Thermodynamic properties of inorganic salt in nonaqeous solvents. IV. Apparent molar volumes and compressibilities of divalent transition-metal bromides and chlorides in acetonitrile
PublikacjaWykonano pomiary gęstości roztworów chlorków i bromków w acetonitrylu w temperaturze 288.15, 293.15, 298.15, 303.15, 308.15, 313.15 K oraz pomiar szybkości rozchodzenia się dźwięku w badanych roztworach w temperaturze 298.15 K. Uzyskane wartości pozwoliły wyznaczyć pozorne objętości molowe oraz pozorne adiabatyczne ściśliwości, których wartości oraz zmiany ze stężeniem tłumaczone są obecnością złożonych układów komplesów w roztworze.
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Thermodynamic properties of inorganic salts in nonaqueous solvents. III. Apparent molar volumes and compressibilities of divalent transition-metal chlorides in N,N-dimethylformamide
PublikacjaZmierzono gęstości i szybkości dźwięku dla roztworów chlorków dwuwartościowych metali przejściowych w N,N-dimetyloformamidzie. W oparciu o uzyskane wyniki wyznaczono pozorne objętości molowe, cząstkowe objętości molowe, rozszerzalności izobaryczne oraz ściśliwości adiabatyczne. Dokonano analizy oraz zbadano wpływ kompleksowania na wyznaczone wielkości.
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Thermodynamic properties of inorganic salts in nonaqueous solvents. V. Apparent molar volumes and compressibilities of divalent transition metal bromides in N,N-dimethylformamide
PublikacjaZmierzono gęstości i szybkości rozchodzenia się dźwięku roztworów bromków dwuwartościowych metali przejściowych w N,N-dimetyloformamidzie. W oparciu o uzyskane parametry wyznaczono pozorne objętości i ściśliwości molowe. Dokonano analizy oraz zbadano wpływ kompleksowania na wyznaczone wielkości.
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Thermodynamic properties of inorganic salts in nonaqueous solvents. I. Apparent molar volumes and compressibilities of divalent transition-metal perchlorates in N,N-dimethylformamide.
PublikacjaZmierzono gęstości i szybkość dźwięku dla roztworów nadchloranów dwuwartościowych metali przejściowych w N,N-dimetyloformamidzie. W oparciu o uzyskane wyniki wyznaczono pozorne objętości molowe, cząstkowe objętości molowe, rozszerzalności izobaryczne oraz ściśliwości adiabatyczne. Dokonano analizy oraz zbadano wpływ rodzaju kationu metalu.
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Thermodynamic Properties of Inorganic Salts in Nonaqueous Solvents. VI. Apparent Molar Volumes, Expansibilities, and Compressibilities of Divalent Transition Metal Ions in Methanol and Dimethylsulfoxide
PublikacjaThe temperature dependence of the density of divalent transition metal perchlorates in dimethylsulfoxide as well as cobalt(II), nickel(II) perchlorates, and copper(II) trifluoromethanesulfonate in methanol was determined. Moreover, sound velocities for solutions of cobalt(II), nickel(II) perchlorates, and copper(II) trifluoromethanesulfonate in methanol have been measured at 298.15 K. From these data, the partial molar volumes,...
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Magnetic, thermodynamic, and magnetotransport properties of CeGaGe and PrGaGe single crystals
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Thermodynamic and electromagnetic properties of hard-core charged bosons on a lattice
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Thermodynamic and electrostatic properties of ternary Oxytricha nova TEBP-DNA complex
PublikacjaZa pomocą metod chemi obliczeniowej badano właściwości molekularne kompleksu telomerowego białka TEBP z Oxytricha nova w kompleksie trójskkładnikowym z DNA o sekwencji telomerowej. Wyliczone wartości energii kompleksowania wskazują specyficznie na jedną z dróg tworzenia kompleksu, gdzie wpierw podjednostka alfa łaczy się z DNA a następnie podjednostka beta dołącza się do takiego dwuskładnikowego kompleksu. Policzone rozkłady molekularnego...
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Thermodynamic, Anticoagulant, and Antiproliferative Properties of Thrombin Binding Aptamer Containing Novel UNA Derivative
PublikacjaThrombin is a serine protease that plays a crucial role in hemostasis, fibrinolysis, cell proliferation, and migration. Thrombin binding aptamer (TBA) is able to inhibit the activity of thrombin molecule via binding to its exosite I. This 15-nt DNA oligonucleotide forms an intramolecular, antiparallel G-quadruplex structure with a chair-like conformation. In this paper, we report on our investigations on the influence of certain...
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Novel binary mixtures of alkanolamine based deep eutectic solvents with water - thermodynamic calculation and correlation of crucial physicochemical properties
PublikacjaThis paper demonstrates the assessment of physicochemical and thermodynamic properties of aqueous solutions of novel deep eutectic solvent (DES) built of tetrabutylammonium chloride and 3-amino-1-propanol or tetrabutylammonium bromide and 3-amino-1-propanol or 2-(methylamino)ethanol or 2-(butylamino)ethanol. Densities, speeds of sound, refractive indices, and viscosities for both pure and aqueous mixtures of DES were investigated...
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Novel Binary Mixtures of Alkanolamine Based Deep Eutectic Solvents with Water—Thermodynamic Calculation and Correlation of Crucial Physicochemical Properties
PublikacjaThis paper demonstrates the assessment of physicochemical and thermodynamic properties of aqueous solutions of novel deep eutectic solvent (DES) built of tetrabutylammonium chloride and 3-amino-1-propanol or tetrabutylammonium bromide and 3-amino-1-propanol or 2-(methylamino)ethanol or 2-(butylamino)ethanol. Densities, speeds of sound, refractive indices, and viscosities for both pure and aqueous mixtures of DES were investigated...
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Thermodynamic Characteristics of Phenacetin in Solid State and Saturated Solutions in Several Neat and Binary Solvents
PublikacjaThe thermodynamic properties of phenacetin in solid state and in saturated conditions in neat and binary solvents were characterized based on differential scanning calorimetry and spectroscopic solubility measurements. The temperature-related heat capacity values measured for both the solid and melt states were provided and used for precise determination of the values for ideal solubility, fusion thermodynamic functions, and...
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Thermodynamic analysis of the Compressed Air Energy Storage system coupled with the Underground Thermal Energy Storage
PublikacjaImprovement of flexibility is one of the key challenges for the transformation of the Polish Power System aiming at a high share of renewable energy in electricity generation. Flexible and dispatchable power plants will contribute to this ongoing transformation process as they compensate for fluctuations in electricity generation from renewable energy sources such as wind and photovoltaics. In this context, CAES storage tanks are...
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Development, characterization and evaluation of composite adsorbent for the adsorption of crystal violet from aqueous solution: Isotherm, kinetics, and thermodynamic studies
PublikacjaThe purpose of this work focuses on the production and investigations of a new composite material as alternative low-cost adsorbent for the removal of crystal violet (CV) dye from waste solution. The production method was performed by in-situ thermal activation technology via extrusion process of polymer wastes containing tire rubber (50 wt%) and polyurethane foam (50 wt%) using single-screw extruder under processing temperature...
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Curves of thermodynamic states in some fluids with dispersion
Publikacjavariations in the thermodynamic state of a dispersive medium, caused by sound, are studied. A bubbly liquid and a Maxwell fluid are considered as examples. Curves in the plane of thermodynamic states are plotted. They are in fact pictorial images of linear relations of excess pressure and excess density in the acoustic wave which reflect irreversible attenuation of the sound energy. The curves account for the nonlinear generation...
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Subcritical Thermodynamic Cycles with Organic Medium and Isothermal Expansion
PublikacjaThe efffciencies of the Organic Rankine Cycle (ORC) are not very high and only very seldom do they exceed 20%. The increase and optimization of initial parameters and certain modifications of the thermodynamic cycle make it possible to overcome these drawbacks. A new modified cycle has been described and analyzed in detail in the paper. Similarly to the Ericsson cycle for gas turbines, isothermal expansion in the turbine is suggested...
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Organic Supercritical Thermodynamic Cycles with Isothermal Turbine
PublikacjaOrganic Rankine cycles (ORC) are quite popular, but the overall efficiencies of these plants are rather very low. Numerous studies have been conducted in many scientific centers and research centers to improve the efficiency of such cycles. The research concerns both the modification of the cycle and the increase in the parameters of the medium at the inlet to the turbine. However, the efficiency of even these modified cycles rarely...
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Thermodynamic vs. extrathermodynamic modeling of chromatographic retention
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Alternative cogeneration thermodynamic cycles for domestic ORC
PublikacjaThe Organic Flash Cycle (OFC) is suggested as a vapor power cycle that could potentially improve the efficiency of utilization of the heat source. Low and medium temperature finite thermal sources are considered in the cycle. Additionally the OFC’s aim is to reduce temperature difference during heat addition. The study examines 2 different fluids. Comparisons are drawn between the OFC and an optimized basic Organic Rankine Cycle...
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Magnetic properties of ferromagnetic Pu2Pt3Si5
PublikacjaThe structural, magnetic, and thermodynamic properties of a new plutonium based compound, Pu2Pt3Si5, are reported. Single crystals produced by a Sn-flux technique have been analyzed showing a ferromagnetic behavior at 58 K. Pu2Pt3Si5 crystallizes in the U2Co3Si5-type orthorhombic Iabm structure (s.g. 72) with atomic parameters a = 9.9226(2) Å, b = 11.4436(2) Å and c = 6.0148(1) Å. The effective (leff 0.74 lB/Pu) and saturated (rsat...
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Experimental methods in thermodynamic and kinetic studies on photocatalytic materials
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THERMODYNAMIC ANALYSIS OF A GENERATION IV SCWR NUCLEAR POWER PLANT CYCLE
PublikacjaThis article presents a flow and thermodynamic analysis of a Generation IV nuclear cycle. An SCWR (Supercritical water reactor) is a high temperature and high pressure reactor that uses water at a temperature above its thermodynamic critical point as the working fluid. The cycle used for the calculations consists of one interstage superheater and 7 regenerative heat exchangers. Division pressure was optimized in view of the cycle efficiency,...
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Thermodynamic study of binary mixtures of 2-propanol with ionic liquids, 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexylammonium bis(trifluoromethylsulfonyl)imide
PublikacjaIn this work, densities, speeds of sound, refractive indices and viscosities of three binary mixtures containing the ionic liquids 1-hexyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl)imide, 1-hexyl-3-methylimidazolium trifluoromethanesulfonate and triethylhexyl-ammonium bis(trifluoromethylsulfonyl)imide, mixed with 2-propanol at wide temperature and composition ranges at atmospheric pressure have been measured. From these...
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Thermodynamic Cycles of Air Microturbine Power Plants Working on Biomass Fuels
PublikacjaThe gas turbine engine is modified to work as an air turbine set which consists, in the simplest arrangement, of a compressor, a heat exchanger and a turbine. Air is a working medium for both: the compressor and the turbine. This kind of air turbine set can be applied in power plants working on biomass fuels. In this solution we can burn fuels of varying parameters in the external combustion chamber without any harmful effects...
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Thermodynamic modeling of combustion process of the internal combustion engines – an overview
PublikacjaThe mathematical description of combustion process in the internal combustion engines is a very difficult task, due to the variety of phenomena that occurring in the engine from the moment when the fuel-air mixture ignites up to the moment when intake and exhaust valves beginning open. Modeling of the combustion process plays an important role in the engine simulation, which allows to predict incylinder pressure during the combustion,...
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Nonlinear properties of the Gotland Deep – Baltic Sea
PublikacjaThe properties of the nonlinear phenomenon in water, including sea water, have been well known for many decades. The feature of the non homogeneous distribution of the speed of sound along the depth of the sea is very interesting from the physical and technical point of view. It is important especially in the observation of underwater area by means of acoustical method ( Grelowska et al ., 2013; 2014). The observation of the underwater...
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Comparison of soil models in the thermodynamic analysis of a submarine pipeline buried in seabed sediments
PublikacjaThis paper deals with mathematical modelling of a seabed layer in the thermodynamic analysis of a submarine pipeline buried in seabed sediments. The existing seabed soil models: a “soil ring” and a semi-infinite soil layer are discussed in a comparative analysis of the shape factor of a surrounding soil layer. The meaning of differences in the heat transfer coefficient of a soil layer is illustrated based on a computational example...
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Thermodynamic analysis of the double Brayton cycle with the use of oxy combustion and capture of CO2
PublikacjaIn this paper, thermodynamic analysis of a proposed innovative double Brayton cycle with the use of oxy combustion and capture of CO2, is presented. For that purpose, the computation flow mechanics (CFM) approach has been developed. The double Brayton cycle (DBC) consists of primary Brayton and secondary inverse Brayton cycle. Inversion means that the role of the compressor and the gas turbine is changed and firstly we have expansion...
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Thermodynamic study of binary mixtures of toluene with ionic liquids, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide and 1-butylpyridinium bis(trifluoromethylsulfonyl)imide
PublikacjaDensities, refractive indices and viscosities at 293.15, 298.15, 303.15, 308.15 and 313.15 K of binary mixtures of toluene with 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide and 1-butylpyridinium bis(trifluoromethylsulfonyl)imide have been measured over the miscible region at p = 0.1 MPa. From the experimental data, values of excess molar volume,...
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Power augmentation of PGE Gorzow's gas turbine by steam injection - thermodynamic overview
PublikacjaThe impact of steam injection upon a gas turbine and a combined power plant performance has been investigated. This article describes and summarizes possibilities of modification for current gas turbine in PGE Gorzow power plant into the Cheng cycle. Our modification deals with a thermal cycle, in which steam produced in a heat recovery steam generator is injected into the gas turbine's combustion chamber. It has been proved that...
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THE THERMODYNAMIC ANALYSIS OF THE SZEWALSKI HIERARCHIC VAPOUR CYCLE COOPERATED WITH THE SYSTEM OF HEAT RECOVERY
PublikacjaIn this paper, thermodynamic analysis of the Szewalski hierarchic vapour cycle cooperated with the system of heat recovery from exhaust gases are presented. According to that purpose, the CFM (Computation Flow Mechanics [1,3]) approach has correctly been used. The whole system consists of the first traditional steam cycle, the second organic Rankine cycle (ORC) and system of heat recovery with use of water with temperature 90...
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Design and Thermodynamic Analysis of an SOFC System for Naval Surface Ship Application
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Influence of Antimony Substitution on Spontaneous Strain and Thermodynamic Stability of Lanthanum Orthoniobate
PublikacjaThe analysis of the antimony substitution influence on temperature dependence of unit cell distortion has been done. The values of spontaneous strain and Landau order parameter for three different antimony contents varied had been calculated. The phase transition occurring for antimony substituted lanthanum orthoniobate was found to be second order. The high temperature solution calorimetry method has been used to investigate...
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A concept of zero-dimensional and three-dimensional thermodynamic modelling of steam storage in a steam cycle
PublikacjaThis work presents the thermodynamic model of steam storage in a steam cycle. The innovative steam storage is an integral part of the unit and thus responds quickly to changes in load. This enhances the primary control reserve while maintaining high efficiency of energy conversion. With regard to power plants, it improves the operational safety of generation units, as it prevents boiler and turbines overload in the case of steep...
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The thermodynamic critical field and specific heat of superconducting state in phosphorene under strain
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Theoretical Organic Rankine Cycle efficiency depending on different thermodynamic work variables.
PublikacjaOne of promising technologies of utilizing low- temperature waste heat is through ORC (Organic Rankine Cycle) system implementation. A primary objective in designing in-stallations based on such systems is to maximize the installation's work efficiency. On the other hand, ecological factors are commonly considered a natural barrier in introducing new, often very expensive technologies. Ecological effect of a potential modernization...
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Nonlocalized thermal behavior of rotating micromachined beams under dynamic and thermodynamic loads
PublikacjaRotating micromachined beams are one of the most practical devices with several applications from power generation to aerospace industries. Moreover, recent advances in micromachining technology have led to huge interests in fabricating miniature turbines, gyroscopes and microsensors thanks to their high quality/reliability performances. To this end, this article is organized to examine the axial dynamic reaction of a rotating...
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A thermodynamic criterion for selection of working fluid for subcritical and supercritical domestic micro CHP
PublikacjaW pracy przedstawiono kryterium termodynamiczne doboru czynnika roboczego dla mikrosiłowni pracującej w warunkach podkrytycznych i nadkrytycznych. Przeanalizowano 20 płynów możliwych do wykorzystania w mikrosiłowni ORC. Z analizy wynika, że najlepszym płynem roboczym jest etanol, R123 oraz R141b.
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Quantitative study of free convective heat losses from thermodynamic partitions using Thermal Imaging
PublikacjaThe following paper presents a simple method of determining the presence, distribution and values of heat losses from external building walls as thermodynamic partitions using a Thermal Imaging Camera (TIC). According to Fourier's equation, the value of heat loss is proportional to the temperature gradient ∂t/∂y|y=0 in air in the y direction perpendicular to the heated surface. Unfortunately, air temperature cannot be measured...
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Thermodynamic Cycle Concepts for High-Efficiency Power Plans. Part A: Public Power Plants 60+
PublikacjaAn analysis was carried out for different thermodynamic cycles of power plants with air turbines. Variants with regeneration and different cogeneration systems were considered. In the paper, we propose a new modification of a gas turbine cycle with the combustion chamber at the turbine outlet. A special air by-pass system of the combustor was applied and, in this way, the efficiency of the turbine cycle was increased by a few points....
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Thermodynamics of solid phases containing rare earth oxides
PublikacjaRare earth elements (RE) are incorporated into a large variety of complex oxide phases to provide tailored mechanical, electrical, optical, and magnetic properties. Thermodynamics control phase stability, materials compatibility in use, corrosion, and transformation. This review presents, in one compilation, the thermodynamic properties of a large number of such materials and discusses systematic trends in energetics and the factors...
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Criteria for selection of working fluid in low-temperature ORC
PublikacjaThe economics of an ORC system is strictly linked to thermodynamic properties of the working fluid. A bad choice of working fluid could lead to a less efficient and expensive plant/generation unit. Some selection criteria have been put forward by various authors, incorporating thermodynamic properties, provided in literature but these do not have a general character. In the paper a simple analysis has been carried out which resulted...