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Wyniki wyszukiwania dla: solid state chemistry
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Solid-Contact pH Sensor without CO2Interference with a Superhydrophobic PEDOT-C14as Solid Contact: The Ultimate “Water Layer” Test
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Experimental and theoretical studies on the Sulfamethazine-Urea and Sulfamethizole-Urea solid-liquid equilibria
PublikacjaThe miscibility of active pharmaceutical ingredients with excipients is an important aspect in pharmaceutical technology protocols. In this study, the differential scanning calorimetry (DSC) was used for Sulfamethazine-Urea (SI–U) and Sulfamethizole-Urea (SO–U) solid-liquid phase diagrams determination. Both sulfonamides form simple binary eutectics with Urea. The lack of new co-crystal phase formation was confirmed by inspection...
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state aid for entrepreneurs - access to finance
Dane BadawczeThe dataset encompasses a choice of important legal acts, a list of selected Polish bibliography and a list of important individual sentences issued on the topic of state aid for entreprenuers in the form of better access to finance their development and filling the capital gap. It emcompasses the period 2004-2020 Thanks to that the reader gets the...
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A headspace solid-phase microextraction method development and itsapplication in the determination of volatiles in honeys by gas chromatography
PublikacjaThe first part of the paper presents the detailed optimisation of all steps of the determination procedureof volatiles from Polish honeys by headspace solid-phase microextraction (HS-SPME) as the sample preparationmethod and gas chromatography/mass spectrometry (GC-MS) as the method of final determination.The methodology of semi-quantative analysis allowed the isolation and identification of volatile fractioncompounds from popular...
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Surface Chemistry & Experimental Techniques
Kursy Onlinewykłady prowadzone przez prof. G. Jerkiewicza
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Chemistry - Energy Technologies 2022/2023
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Selection of Effective HTRA3 Activators Using Combinatorial Chemistry
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Surface chemistry aspects of fluorosurfactants as components in AFFF preparation
PublikacjaZbadano właściwości powierzchniowe fluorowanych surfaktantów anionowych a także roztworów środków pianotwórczych na bazie fluorowanych surfaktantów stosowanych w gaszeniu pożarów substancji ropopochodnych ze szczególnym uwzględnieniem ich zdolności do obniżania napięć międzyfazowych. Wyselekcjonowana para surfaktantów wykazała się wysoką zdolnością obniżania napięć międzyfazowych na granicy faz olej-woda, porównywalną z roztworami...
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The structure and conductivity of solid polyurethane electrolyte
PublikacjaPrzedstawiono badania właściwości i struktury stałych elektrolitów poliuretanowych. Otrzymano je z prepolimeru zsyntezowanego z MDI oraz PTMG. Jako przedłużacz łańcucha wykorzystano butanodiol. W celu poprawy przewodnictwa domieszkowano poliuretan solami LiClO4 lub LiCl, które wprowadzono za pomocą wytłaczarki dwuślimakowej. Otrzymane elektrolity poddano badaniom: wytrzymałościowym, twardości, spektroskopii FTIR oraz przewodnictwa...
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THE ROLE OF THIN FUNCTIONAL LAYERS IN SOLID OXIDE FUEL CELLS
PublikacjaWidespread commercialization of solid oxide fuel cells requires lowering its cost. It is generally accepted that to lower the cost of solid oxide fuel cells it is necessary to use metal alloys as interconnectors and, consequently, lower its operating temperature to slow down interconnectors degradation. As a result the area specific resistance of the cathodes should be lowered to sustain the performance of the cells. In order to...
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Oznaczanie fazy stałej w tłuszczach. Determination of solid fat content in fats.
PublikacjaW pracy dokonano przeglądu metod oznaczania indeksu fazy stałej (SFI - solid fat index) oraz zawartości fazy stałej (SFC - solid fat content) w tłuszczach. Obok metody NMR, obecnie powszechnie stosowanej i zalecanej przez normy, przedstawiono też inne metody analityczne które stosowano, lub stosuje się do tego typu analiz.
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Enhanced energy conversion as a result of fluid-solid interaction in micro- and nanoscale
PublikacjaIt is known that nano- and micromechanics require new approaches to right describing of surface-like phenomena which lead to an enhanced energy conversion. In this work, a general form of surface forces that consist of a contribution from both the friction and mobility components has been extended to collect the effects of bulk and surface motion of a fluid. Quite similar impact can be observed for a solid-fluid mixture, where...
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Selection of New Chromogenic Substrates of Serine Proteinases Using Combinatorial Chemistry Methods
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Chiral and achiral crystals, charge-assisted hydrogen-bond patterns and self-organization of selected solid diaminium thiosulfates
PublikacjaAbstract A series of diaminium thiosulfates, derivatives of diamines: NH2CH2CH(CH3)NH2 (1) and NH2(CH2)nNH2, n = 3-6 (2-5 respectively)and thiosulfuric acid were prepared and their structures determined by crystal X-ray diffraction analysis. Compounds 1, 2 and 4 turned out to be hydrates. The crystal structure of 1,2-proylenediaminium thiosulfate is chiral and exhibits spontaneous resolution. Crystals for both enantiomers...
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Factors affecting low-temperature cracking of asphalt pavements: analysis of field observations using the ordered logistic model
PublikacjaAccurate identification of factors that primarily affect the number of low-temperature cracks is crucial for selection of road materials and planning of pavement maintenance. Field investigations of lowtemperature cracks were performed in the years 2014 and 2020 on the same 68 road sections being in service in typical traffic conditions. The collected data were statistically analysed using the ordered logistic regression model....
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ANALYZING TITLES OF ECONOMY NEWS TO UNDERSTAND IMPACT OF COVID-19 ON ECONOMICAL SITUATION
PublikacjaCovid-19 affected the whole world in a short time, causing serious panic and uncertainty in society. Because it was an unprecedented disease, the medical community has worked hard to find out how to deal with it, and it continues to do so. The rapid spread of the disease, the shortage of hospital capacity and the increase in deaths drove the whole world to a closure, so to speak. In this time period, life in the world came to a...
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Closer look into the structures of tetrabutylammonium bromide–glycerol-based deep eutectic solvents and their mixtures with water
PublikacjaIn recent years, deep eutectic solvents (DES) and it’s mixture with water have become more and more attention as green solvents used in chemistry. However, there are only a few theoretical studies on the mechanisms of pure DES and DES-water complex formation. Therefore, the structural properties of tetrabutylammonium bromide–glycerol-based deep eutectic solvents and their mixtures with water have been investigated by means of Molecular...
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AN ORIGINAL APPROACH IN THE FIELD OF PREPARATION REFERENCE MATERIALS OF VOLATILE ANALYTES
PublikacjaStandard gas mixtures (SGM) are indispensable reference materials for ensuring the reliability of analytical work. Reference materials are an excellent tool for the quality control and assurance of analytical results. Standard gas mixtures are unique among reference materials. The rapid progress of SGM production is connected with the instability of gaseous analytes which make them difficult to obtain. The use of standards with...
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Analysis of pesticide residue in fruits and vegetables using analytical analytical protocol based on application of QuEChERS technique and GC-ECD system
PublikacjaQuEChERS sample preparation method was used for the determination of 10 pesticides and their metabolites in fruits (apple, grape) and vegetables (tomato, paprika), coupled to gas chromatography with electron capture detector (GC-ECD). The experimental parameters including amount of the sample, types of solvents, extraction time and types of sorbent at the purification stage were optimized. The GC-ECD method was validated in terms...
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Ranking of Heterogeneous Catalysts Metals by Their Greenness
PublikacjaCatalysis is very important process in industry and laboratory practice, especially from the point of green chemistry principles. However, eco-friendly character of heterogeneous catalysts, containing transition metal components has not been evaluated, yet. Therefore, we perform a comprehensive assessment of 18 heterogeneous metal catalysts (Pd, Pt, V, Co, Ni, Mo, Ru, Mn, Au, Cu, Cd, Zr, Fe, Rh, Ir, Sn, Zn, Ag) using multicriteria...
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Inter Applied Chemistry Programme 1 Morrison Forensic
Kursy OnlineInter Applied Chemistry Programme 1 Lecture 1 background reading Read the following : Chapter 1 Introduction to Forensic Science ( From Jackson, Jackson, Mountain and Brealey, Forensic Science, Pearson 4th Ed (2016)) Very general professional guidance/Introduction United Nations can be found within these guides, (these are mainly for reference purposes) https://www.unodc.org/documents/scientific/Crime_scene_awareness__Ebook.pdf https://www.unodc.org/documents/justice-and-prison-reform/cjat_eng/Forensic_services_and_infrastructure.pdf Task...
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Electrochemical properties of porous Sr0.86Ti0.65Fe0.35O3 oxygen electrodes in solid oxide cells: Impedance study of symmetrical electrodes
PublikacjaThis work evaluates porous Sr0.86Ti0.65Fe0.35O3 (STF35) as a possible oxygen electrode material for Solid Oxide Cells. The powder synthesis was performed by solid state method. Characterization included DC electrical conductivity study of sintered bulk samples and impedance spectroscopy study of symmetrical electrodes deposited on gadolinium doped ceria substrates. Measurements were carried out in atmospheres with different pO2...
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Adaptive prediction of stock exchange indices by state space wavelet networks
PublikacjaThe paper considers the forecasting of the Warsaw Stock Exchange price index WIG20 by applying a state space wavelet network model of the index price. The approach can be applied to the development of tools for predicting changes of other economic indicators, especially stock exchange indices. The paper presents a general state space wavelet network model and the underlying principles. The model is applied to produce one session...
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state aid for employment of disadvantaged persons
Dane BadawczeThe dataset encompassed a choice of the most important legal acts, a list of selected Polish and foreign bibliography, together with a list of important individual EC decisions issued on the topic of state aid dedicated to including persons with disabilities to the labour market in Poland and some UE countries in the period 2001-2019. Thanks to that...
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Synthesis of a state feedback controller for an averaging tank with variable filling
PublikacjaIn paper, a nonlinear averaging tank with variable filling is considered. The main purpose of this research work was the modelling and control system synthesis of an averaging tank. The control objectives included ensuring stability and zero steady-state error of the system and achieving settling time as short as possible, while maintaining a minimal overshoot. In order to achieve the intended purpose, firstly a mathematical model...
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The Only Stable State of O2- Is the X 2Πg Ground State and It (Still!) Has an Adiabatic Electron Detachment Energy of 0.45 eV
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State aid for entrepreneurs at special economic zones
Dane BadawczeThe dataset encompasses a choice of important legal acts, a list of selected Polish bibliography and a list of important individual sentences issued on the topic of state aid for entreprenuers investing at special economic zones. Thanks to that the reader gets the possibility do acquire basic knowledge on the above mentioned topic.
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Theoretical Assessment of Excited State Gradients and Resonance Raman Intensities for the Azobenzene Molecule
PublikacjaThe ground state geometries and vibrational frequencies as well as the excitation energies and excited state gradients of the S 1(nπ*) and S 2(ππ * ) states of trans - and cis -azobenzene are investigated by several DFT methods, namely B3LYP, PBE, M06-2X, CAM-B3LYP, and ω B97X. Excited state properties and in particular gradients are also assessed using the wave function based methods EOM-CCSD and RASPT2/RASSCF. Comparison with...
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State Interventionism in Tax System - Example of Action in a COVID-19 Crisis
PublikacjaThe following article presents and classifies changes in tax systems of selected countries as well as counts them as the response to the emergence of the crisis caused by the COVID-19 pandemic. Such actions were undertaken the context of state interventionism in the tax system. In order to achieve the objective of presenting the state interventionism in the context of tax rates, an analysis of the literature on the phenomenon described,...
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Investigation of solid polymer electrolyte gas sensor with different electrochemical techniques
PublikacjaIn this work solid polymer electrolyte (SPE) amperometric sulphur dioxide sensor is investigated. Nafion was used as a membrane electrode and 1M sulphuric acid as an internal electrolyte. Sensor response to sulphur dioxide was measured. Besides traditional constant voltage amperometry also different electrochemical techniques were used. Results obtained by these methods are compared.
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Behavioral state classification in epileptic brain using intracranial electrophysiology
PublikacjaOBJECTIVE: Automated behavioral state classification can benefit next generation implantable epilepsy devices. In this study we explored the feasibility of automated awake (AW) and slow wave sleep (SWS) classification using wide bandwidth intracranial EEG (iEEG) in patients undergoing evaluation for epilepsy surgery. APPROACH: Data from seven patients (age [Formula: see text], 4 women) who underwent intracranial depth electrode...
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Methods of the privatization process of Polish state-owned enterprises in years 1990‒2015
PublikacjaThis article presents methods of the privatization process of state-owned enterprises in Poland in the period of years 1990‒2015. The author presents the change of number of state-owned companies over the selected period as well as describes the main methods of ownership transformation used in Poland. First part presents the mechanism of commercialization. Second discusses the indirect privatization and contribution to NFI. Next,...
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state aid for sustainable urban development
Dane BadawczeThe dataset encompassed a choice of important legal acts with respect on the usage of EFRD for urban projects, a list of selected bibliography as well as a list of selected individual notifications of state aid measures being part of the Sustainable Urban Development Programme in the period 2014- 2020. As a comparison, an example of individual EC decision...
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Porous material-based sorbent coatings in Solid-phase microextraction technique: Recent trends and future perspectives
PublikacjaThe use of porous materials as sorbents in sample preparation techniques has gained recent scientific attention in the context of developing novel fibers for the Solid-phase microextraction (SPME) technique. SPME requires the appropriate selection of a robust sorbent for successful utilization under variable conditions. A deeper understanding of the nature of newly developed porous SPME coatings and the impact of their structures...
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CeCu2O4 as a functional layer on solid oxide fuel cells for synthetic biogas reforming
PublikacjaSolid Oxide Fuel Cells (SOFC) are one of the most promising electrochemical devices, which can convert chemical energy to the electrical energy these days. Their ability to work with different kind of fuel makes them noteworthy. SOFC can work with biogas. The problem arises when solid carbon starts to be deposited in anode. That leads to degradation of fuel cell. Simple solution is to apply catalytic functional layer, which is...
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Studies on applicability of new solid-phase microextraction and determination of short - chain monocarboxylic acids
PublikacjaA convenient approach to monitor the short-chain monocaroboksylic acids (SCAMs) in different samples is gas chromatography (GC) preceded by sample preparation based on solid-phase microextraction (SPME). The fiber with polar coatings were used to extract the SCAMs from headspace of liquid and solid samples. Recently polimeric ionic liquid (PIL) fiber coatings have been proposed to extract volatile organic compounds, minly polar...
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Possibilities of radioisotope measuring in control of an unstable solid particles hydrotransport
PublikacjaThe paper presents γ-radiation proposal to control a multiphase flow, independently from circumstances. So this method may be applied even in compound industrial or environmental processes. Moreover in many cases, it is the only method for applications for dense mixture containing coarse angular grains. The constructed equipment allows continuous measurement of density as well as solid phase for both concentration and average velocity....
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The Current State-of-the-Art in the Determination of Pharmaceutical Residues in Environmental Matrices Using Hyphenated Techniques
PublikacjaSeveral thousand tons of pharmaceuticals and their transformation products (metabolites and degradation products) are introduced into the environment each year. They affect both human health and the environment, therefore, analytical procedures enabling the determination of a wide range of pharmaceuticals at trace levelswithminimal effort, time, and energy are required. Nowadays, hyphenated techniques are commonly applied in pharmaceutical...
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Study of the chemical state of Gd in a Ba-La-Gd-Co based ceramic
Dane BadawczeBarium, Lanthanum, Gadolinium and Cobaltium precursors were used for production of ceramic materials. Samples were produced by standard solid state reaction. Samples were annealed at 300 Celsius degree in wet and dry atmosphere. Annealing takes 72h or 2h. Results of annealing on a Gadolinum were observed by X-Ray photoemission spectroscopy (XPS), OmicronNanotechnology....
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Structured deformation of granular material in the state of active earth pressure
PublikacjaThe paper focuses on the ability of granular materials to undergo structured deformation by analysing the data from the retaining wall model tests and discrete element simulations. The structured deformation means the movement of a granular material which produces a stable, regular pattern of multiple shear bands. The paper's primary purpose is to study this kind of deformation for the selected data representing the state of active...
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EU state aid for fisheries and aquaculture in the perspective 2014-2020
Dane BadawczeThe dataset encompassed a choice of the most important legal acts, a list of selected Polish bibliography, and some examples of decisions issued by the EC on the topic of state aid for fisheries and aquaculture in Poland and in Germany. The data constitute a description of the basic state aid instruments used in practice in the period 2014-2020 for...
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EU state aid - compatible with the internal market for social reasons
Dane BadawczeThe dataset encompasses a choice of Polish and foreign bibliography, together with a list of important individual EC decisions issued in the period 2007-2013 on state aid delivered to final consumers for social reasons ( in Poland and in selected UE member states), in form of different financial instruments. Thanks to this compilation the reader is...
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Color prediction from first principle quantum chemistry computations: a case of alizarin dissolved in methanol
PublikacjaThe electronic spectrum of alizarin (AZ) in methanol solution was measured and used as reference data for color prediction. The visible part of the spectrum was modelled by different DFT functionals within the TD-DFT framework. The results of a broad range of functionals applied for theoretical spectrum prediction were compared against experimental data by a direct color comparison. The tristimulus model of color expressed in terms...
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Metals and metal-binding ligands in wine: Analytical challenges in identification.
PublikacjaBackground Due to important role of metals in the vinification process as well as their impact on the human health, their content in this alcoholic beverage has been extensively studied by many researchers. It is already known that speciation of metals determines their toxicity and bioavailability as well as influences their activity. Understanding the chemistry and knowing the structures of metal complexes could have relevant...
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Investigation of tetrabutylammonium bromide-glycerol-based deep eutectic solvents and their mixtures with water by spectroscopic techniques
PublikacjaDeep eutectic solvents (DES) are formed by an acceptor and a donor of hydrogen bonds. They are generally considered as a possible alternative to hazardous organic solvents in various fields. Very recently they have also appeared in analytical chemistry, used mainly for the separation of analytes before instrumental quantification. For the development of new extraction procedures, it is important, among other things, to understand...
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New Screening Protocol for Effective Green Solvents Selection of Benzamide, Salicylamide and Ethenzamide
PublikacjaNew protocol for screening efficient and environmentally friendly solvents was proposed and experimentally verified. The guidance for solvent selection comes from computed solubility via COSMO-RS approach. Furthermore, solute-solvent affinities computed using advanced quantum chemistry level were used as a rationale for observed solvents ranking. The screening protocol pointed out that 4-formylomorpholine (4FM) is an attractive...
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Mitigating metal-organic framework (MOF) toxicity for biomedical applications
PublikacjaMetal-organic frameworks (MOFs) are a novel class of crystalline porous materials, consisting of metal ions and organic linkers. These hybrid materials are highly porous and have a large specific surface area, making them of great interest for applications in gas separation, energy storage, biomedical imaging, and drug delivery. As MOFs are being explored for biomedical applications, it is essential to comprehensively assess their...
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Quinoline-based thiazolyl-hydrazones target cancer cells through autophagy inhibition
PublikacjaHeterocyclic pharmacophores such as thiazole and quinoline rings have a significant role in medicinal chemistry. They are considered privileged structures since they constitute several Food and Drug Administration (FDA)-approved drugs for cancer treatment. Herein, we report the synthesis, in silico evaluation of the ADMET profiles, and in vitro investigation of the anticancer activity of a series of novel thiazolyl-hydrazones based...
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Heptaene macrolides biosynthesis by Streptomyces species
PublikacjaPolyene macrolides are one of the groups of secondary metabolites, generated by microorganisms belonging to the Streptomyces genus. These compounds, containing 3 - 7 conjugated double bonds systems in their molecules exhibit high antifungal activity against a broad spectrum of fungal pathogens with heptaenes demonstrating the highest antifungal potential. At the large extent, efficiency of biosynthesis of these natural products...
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The pulsed laser ablation synthesis of colloidal iron oxide nanoparticles for the enhancement of TiO2 nanotubes photo-activity
PublikacjaThe rapid, only a few minutes long synthesis of FeO, Fe3O4, and Fe2O3nanoparticles mixture utilizing the pulsedlaser ablation using simply pure iron target and water was demonstrated. The size and crystal phase of Fe-basedNPs were characterized using DLS and HR-TEM techniques, respectively. The metastable suspension of FeO,Fe3O4, and Fe2O3nanoparticles was used to the decoration of anodized TiO2nanotubes (TiO2-NTs) by means ofthe...