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Wyniki wyszukiwania dla: ANALYTICAL CHEMSITRY
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A comparison of three solvent-free techniques coupled with gas chromatography for determining trihalomethanes in urine samples
PublikacjaDążenie do oznaczania lotnych analitów organicznych w próbkach płynów biologicznych charakteryzujących się złożonym, a często zmiennym składem matrycy, stanowi siłę napędową do działań analityków w zakresie poszukiwania nowych rozwiązań metodycznych i aparaturowych. Publikacja ta przedstawia porównanie trzech technik zastosowanych do tych celów: technikę analizy fazy nadpowierzchniowej z generacją strumienia ciekłego sorbentu...
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Determination of tributylotin (TBT) in marine sediment using pressurised liquid extraction-gas chromatography-isotope dilution mass spectrometry (PLE-GC-IDMS) with a hexane-tropolone mixture
PublikacjaOpracowano metodę oznaczania zawartości tributylocyny w próbkach osadu morskiego. Na etapie izolacji zastosowano technikę przyspieszonej ekstrakcji za pomocą roztworu tropolonu w heksanie.Na etapie oznaczeń końcowych wykorzystano technikę chromatografii gazowej, stosując metodę spektrometrii mas rozcieńczenia izotopowego. Wyznaczono parametry walidacyjne opracowanej metody: granicę wykrywalności, precyzję, poprawność i niepewność.
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Metal-coated fused silica fibres as a support for immobilized compounds yielding a volatile analyte (C2H4)
PublikacjaPrzedstawiono wyniki badań dotyczących wykorzystania chemicznie modyfikowanych włókien szklanych pokrytych warstwą metalu (aluminium), jako nośników związków powierzchniowych. W trakcie procesu termicznego rozkładu z tak zmodyfikowanych włókien uwalnia się eten, który stanowi składnik mierzony uzyskiwanej gazowej mieszaniny wzorcowej. Ilość uwalnianego etenu zależy jedynie od długości danego rodzaju i typu modyfikowanego włókna...
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Electroanalytical and spectroscopic procedures for examination of interactions between double stranded DNA and intercalating drugs
PublikacjaPrzedstawiono metodę elektrochemicznego opisu oddziaływań dsDNA ze związkiem biologicznie czynnym w warunkach, w których zarówno badany związek jak i cząsteczka DNA są w roztworze elektrolitu. Opracowano warunki pomiaru, gdzie ani związek, ani DNA nie adsorbuje na elektrodzie. Wykazano, podobnie jak podczas badania innymi metodami, że oddziaływania są dwojakiego rodzaju: elektrostatyczne i poporzez interkalację.
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A nontargeted approach to determine the authenticity of Ginkgo biloba L. plant materials and dried leaf extracts by liquid chromatography-high-resolution mass spectrometry (LC-HRMS) and chemometrics
PublikacjaThe lack of stringent regulations regarding raw materials for herbal supplements used for medicinal purposes has been a constant challenge in the industry. Ginkgo biloba L. leaf extracts attract consumers because of the supposed positive effect on mental performance and memory. Supplements are produced using dried leaf materials and standardized leaf extracts such as EGb 761. Adulteration of Ginkgo biloba L. plants and extracts...
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Stabilities of bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, and their derivatives under controlled conditions analyzed using liquid chromatography coupled with tandem mass spectrometry
PublikacjaBisphenol A diglycidyl ether (BADGE), bisphenol F diglycydyl ether (BFDGE), and their related compounds are widely used as precursors in production of epoxy resins. The high reactivity of these compounds makes the development of analytical methodologies that ensure appropriate metrological accuracy crucial. Consequently, we aimed to determine whether and to what extent the composition of the solution and storage conditions affect...
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Derivatisation in gas chromatographic determination of acidic herbicides inaqueous environmental samples.
PublikacjaW pracy przedstawiono przegląd literaturowy dotyczący wykorzystania derywatyzacji w oznaczaniu herbicydów kwasowych w wodnych próbkach środowiskowych za pomocą chromatografii gazowej. Omówiono główne typy reakcji (transestryfikacja, estryfikacja, sililowanie, alkilacja, alkilacja ekstraktywna i pirolityczna), które powodują utworzenie pochodnych, łatwych do analizy techniką chromatografii gazowej. Scharakteryzowano także...
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Determination of organotin compounds in biological samples using accelerated solvent extraction, sodium tetraethylborate ethylation, and multicapillary gas chromatography flame photometric detection.
PublikacjaPrzedstawiono metodę oznaczania związków cynoorganicznych w próbkach biologicznych. Procedura oparta jest na wykorzystaniu ekstrakcji pod zwiększoną temperaturą i ciśnieniem (ASE) do izolacji związków cynoorganicznych z próbek wątroby morświnów odłowionych w Morzu Bałtyckim. Walidacji metody dokonano na podstawie analizy materiału odniesienia NIES No 11.
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Protein overproduction alters exosome secretion in Chinese hamster ovary cells
PublikacjaDespite the abundance of available cell lines, nearly 70% of all recombinant therapeutic proteins today are produced in Chi-nese hamster ovary (CHO) cells. The impact of protein overproduction on the secretion of exosomes by CHO cells has been investigated here. Increased secretion of extracellular vesicles (EVs) by protein overexpressing CHO cells was demonstrated with protein content assay, nanoparticle tracking analysis, and...
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Plant-based meat substitute analysis using microextraction with deep eutectic solvent followed by LC-MS/MS to determine acrylamide, 5-hydroxymethylfurfural and furaneol
PublikacjaFor the analysis of plant-based meat substitutes and the determination of Maillard reaction products such as acrylamide, 5-hydroxymethylfurfural and furaneol, a novel and effective procedure based on hydrophobic natural deep eutectic solvent and liquid chromatography coupled with tandem mass spectrometry was developed for the first time. The 49 compositions of the deep eutectic solvents were designed and screened to select the...
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Intercomparison on measurements of PCBs in pork fat during the Belgian PCB-crisis
PublikacjaW pracy przedstawiono wyniki porównania międzylaboratoryjnego oznaczania PCB w tłuszczu wieprzowym. Porównanie międzylaboratoryjne przeprowadzono w związku z tzw. "belgijskim kryzysem PCB" w latach 1999-2000. W porównaniu uczestniczyło 31 laboratoriów. Materiałem do badań były wyprodukowane w Instytucie Metod i Pomiarów Odniesienia (IRMM) w Geel - Belgia, trzy materiały odniesienia zawierające PCB w tłuszczu wieprzowym (suma PCB...
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How to evaluate methods used in chemical laboratories in terms of the total chemical risk? – a ChlorTox Scale
PublikacjaReliable assessment of the health and environmental risk associated with the use of chemicals is critical to ob- jectively evaluate the greenness and whiteness of an analytical method. An objective and useful way of risk assessment should take into account all the relevant properties of used substances, their actual amounts needed for application of the method, and quantify the assessment result using a standardized unit. This...
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Immunoanalityka – użyteczne podejście analityczne w badaniach środowiska
PublikacjaWażnym krokiem w rozwoju bezpośrednich metodyk analitycznych było opracowanie technik immunoanalitycznych. Początkowo znalazły one zastosowanie praktyczne w analityce medycznej a później także w analityce środowiskowej. Dzięki temu możliwe jest ilościowe oznaczenie stosunkowo szerokiego spektrum ksenobiotyków w próbkach charakteryzujących się złożonym składem matrycy bez praco- i czasochłonnego etapu przygotowania tych próbek do...
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On the convergence of a nonlinear finite-difference discretization of the generalized Burgers–Fisher equation
PublikacjaIn this note, we establish analytically the convergence of a nonlinear finite-difference discretization of the generalized Burgers-Fisher equation. The existence and uniqueness of positive, bounded and monotone solutions for this scheme was recently established in [J. Diff. Eq. Appl. 19, 1907{1920 (2014)]. In the present work, we prove additionally that the method is convergent of order one in time, and of order two in space. Some...
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The Application of Dynamic Electrochemical Impedance Spectroscopy (DEIS) Technique in Corrosion and Corrosion Inhibition Studies
Publikacjaorrosion studies have attracted considerable interest in the areas of materials chemistry and industrial chemistry, as it affects the direct and indirect costs of industry, leading to huge economic setbacks due to the need for repair, maintenance, and even shutdowns due corrosion damage. This new volume is a comprehensive resource that presents new and up-to-date, theoretical, and experimental corrosion inhibition studies.
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Quality of service in optical burst switched networks
PublikacjaIn the paper analytical models of two service differentiation schemes for optical burst switched network: extended offset time based and PPS (Preemptive Priority Scheme) are revised. Also accordance of analytical models for those schemes is studied when complete class isolation is assumed. Furthermore authors introduce an analytical model which describes an effective degree of isolation when burst switched network employs both...
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Quality of service in optical burst switched networks
PublikacjaIn the paper analytical models of two service differentiation schemes for optical burst switched network: extended offset time based and PPS (Preemptive Priority Scheme) are revised. Also accordance of analytical models for those schemes is studied when complete class isolation is assumed. Furthermore authors introduce an analytical model which describes an effective degree of isolation when burst switched network employs both...
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Cavity-expansion approximation for projectile impact and penetration into sand
PublikacjaA one-dimensional problem of a spherical cavity expanding at a constant velocity from zero initial radius in an infinite granular medium, which has the first-kind self-similar solution, is considered. We are solving this dynamic spherical cavity-expansion problem to model rigid spheres penetrating into a granular media. Elastic–plastic deformation of the granular media is described in a barotropic approximation, using the high-pressure...
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Magnetizability of the relativistic hydrogenlike atom in an arbitrary discrete energy eigenstate: Application of the Sturmian expansion of the generalized Dirac-Coulomb Green function
PublikacjaThe Sturmian expansion of the generalized Dirac--Coulomb Green function [R.\/~Szmytkowski, J.\ Phys.\ B 30 (1997) 825; erratum 30 (1997) 2747] is exploited to derive a closed-form expression for the magnetizability of an arbitrary discrete state of the relativistic one-electron atom with a point-like, spinless and motionless nucleus of charge $Ze$. The result has the form of a double finite sum involving the generalized hypergeometric...
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Opportunities and shortcomings of ionic liquids in single-drop microextraction
PublikacjaThe synergistic combination of ionic liquids (ILs) and single-drop microextraction (SDME) involves a powerful coupling toward the development of sustainable analytical methodologies. This overview provides a survey of the literature regarding the IL-SDME, including a database on relevant physicochemical properties of ILs for their application in SDME, the strategies implemented to combine IL-based SDME methods efficiently with...
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New Polymeric Materials for Solid Phase Extraction
PublikacjaSolid phase extraction (SPE) is a popular sample preparation technique, which can be applied directly in gas–solid phase and liquid–solid phase, or indirectly to solid samples by using, e.g., thermodesorption with subsequent chromatographic analysis. Although SPE can be described as a physical extraction process involving a liquid phase and a solid phase, the increased use of packed sorbent formats seems to have led to a bias toward...
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Comparative Analysis of Laboratory-Made and Industrial-Made Sewage Sludge Ash: Implications for Effective Management Strategy Development
Publikacjafirst_pageDownload PDFsettingsOrder Article Reprints Open AccessArticle Comparative Analysis of Laboratory-Made and Industrial-Made Sewage Sludge Ash: Implications for Effective Management Strategy Development by Bartłomiej Michał Cieślik 1,*ORCID,Oskar Ronda 1ORCID,Elżbieta Grządka 2ORCID,Jolanta Orzeł 2 andJustyna Płotka-Wasylka 1 1 Department of Analytical Chemistry, Faculty of Chemistry, Gdańsk University of Technology, Gabriela...
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Biomedical Engineering at Gdansk University of Technology
PublikacjaShort history of education in Biomedical Engineering at Gdansk University of Technology is presented. The last initiative- implementation of the new programme, Biomedical Engineering - an interfaculty direction of study, supported by a grantfinanced by the European Social Fund is presented. Curricula of four specializations: Chemistry in Medicine, run by the Facultyof Chemistry; Electronics in Medicine and Informatics in Medicine,...
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Numerical modeling of the combustion in a lab-scale pulverized-coal fired combustion chamber
PublikacjaThis work presents results of numerical modeling of the combustion process inside a lab-scale drop-tube chamber, designed to investigate the slagging properties of the flue ashes, created through the solid fuel firing. Interaction between turbulence and chemistry is accounted by use of probability density function (PDF). FLUENT inputs for non-premixed combustion chemistry modeling are defined. A discrete second phase of the coal...
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Numerical modeling of the combustion in a lab-scale pulverized-coal fired combustion chamber
PublikacjaThis work presents results of numerical modeling of the combustion process inside a lab-scale drop-tube chamber, designed to investigate the slagging properties of the flue ashes, created through the solid fuel firing. Interaction between turbulence and chemistry is accounted by use of probability density function (PDF). FLUENT inputs for non-premixed combustion chemistry modeling are defined. A discrete second phase of the coal...
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NATURAL DEEP EUTECTIC SOLVENTS IN EXTRACTION PROCESS
PublikacjaDeveloping new, eco-friendly solvents which would meet technological and economic demands is perhaps the most popular aspects of Green Chemistry. Natural deep eutectic solvents (NADES) fully meet green chemistry principles. These solvents offer many advantages including biodegradability, low toxicity, sustainability, low costs and simple preparation. This paper provides an overview of knowledge regarding NADES with special emphasis...
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Investigation of tetrabutylammonium bromide-glycerol-based deep eutectic solvents and their mixtures with water by spectroscopic techniques
PublikacjaDeep eutectic solvents (DES) are formed by an acceptor and a donor of hydrogen bonds. They are generally considered as a possible alternative to hazardous organic solvents in various fields. Very recently they have also appeared in analytical chemistry, used mainly for the separation of analytes before instrumental quantification. For the development of new extraction procedures, it is important, among other things, to understand...
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Hydrophobic deep eutectic solvents in microextraction techniques–A review
PublikacjaOver the past decade, deep eutectic solvents (DES) have been widely studied and applied in sample preparation techniques. Until recently, most of the synthesized DES were hydrophilic, which prevented their use in the extraction of aqueous samples. However, after 2015 studies on the synthesis and application of hydrophobic deep eutectic solvents (HDES) has rapidly expanded. Due to unique properties of HDES i.e. density, viscosity,...
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Trustworthiness and Subversion in Large Service- Oriented Multi-Agent Systems under Virtual Anonymity and Blind Provider Selection
PublikacjaTo promote honest service provision in multi-agent systems, a Computational Trustworthiness and Rating scheme collects service ratings and computes agents' trustworthiness levels (TLs). Studies of existing schemes fail to reflect closed-loop dynamics of TLs arising from the mutual influence of agents' behavior and TLs, and to capture relevant properties. Recent simulative and analytical models produce results tied to a particular...
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Burst loss probability for the combination of extended offset time based service differentiation scheme and PPS in optical burst switching network
PublikacjaIn the paper analytical model for calculating burst loss probabilities for the combination of two service differentiation schemes for OBS network namely: extended offset time based scheme and PPS (Preemption Priority Schemes) is revised. Moreover authors introduce analytical model for calculating burst loss probabilities for an optical path when OBS network employs both service differentiation schemes and JET signaling. The comparison...
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Ekspertyza dotycząca bezzasadności zarzutów odnośnie parametrów metrologicznych analizatorów pyłu PM2,5 postawionych firmom EAS Envimet Polska Sp. z o.o. i EAS Envimet Analytical Systems GmbH przez spółkę MLU Sp. z o.o. z siedzibą w Katowicach w postępowaniu odwoławczym o sygn. akt: KIO/UZP 435/09
PublikacjaW ekspertyzie sporządzonej dla EAS Envimet Polska sp. z o.o. z siedzibą w Wieliczce wykazano bezzasadność zarzutów zgłoszonych przez Spółkę MLU w Katowicach w odniesieniu do urządzenia BAM1020 w postępowaniu odwoławczym toczącym się przed Prezesem Urzędu Zamówień Publicznych w związku z zaskarżeniem rozstrzygnięcia przetargu o zamówienie publiczne nr DM/5211-06-02/09/ABA na zakup automatycznego miernika pyłu zawieszonego PM2,5...
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Buckling of thin-walled columns accounting for initial geometrical imperfections
PublikacjaThe paper is devoted to the effect of some geometrical imperfections on the critical buckling load of axially compressed thin-walled I-columns. The analytical formulas for the critical torsional and flexural buckling loads accounting for the initial curvature of the column axis or the twist angle respectively are derived. The classical assumptions of theory of thin-walled beams with non-deformable cross-sections are adopted. The...
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JMATRIX - a package for relativistic J-matrix calculations in elastic scattering of electrons from model potentials
PublikacjaWe present a software package JMATRIX, consisting of two computer codes written in FORTRAN 95 and parallelized with OpenMP, implementing the so-called J-matrix method, applied to elastic scattering of electrons on the radial potential, vanishing faster than Coulomb one. In the J-matrix method, physical scattering problem is replaced by using well-defined model, which is solved analytically. Presented software implements both non-relativistic...
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PBDEs in environmental samples: Sampling and analysis
PublikacjaThe paper reviews the subject literature concerning analytical procedures routinely sed for monitoring polybrominated diphenyl ethers (PBDE) in environmental samples. It describes and summarizes subsequent stages of analytical procedure including sample collection and preparation, extraction, clean-up and final determination. Different approaches with their advantages and limitations are presented. Special attention is drawn to...
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Miniaturized solid phase extraction techniques for different kind of pollutants analysis: State of the art and future perspectives – PART 2
PublikacjaDetermination of pollutants present in environmental samples at a low concentration level very often requires the analytical protocol that includes analytes isolation and/or enrichment prior to the final quantification. Miniaturized SPE offers an interesting alternative to LLE. Nowadays, many types of sorbents are available and can be used as selective materials for extraction of varied analytes in different kinds of samples. The...
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Quantum and carbon dots conjugated molecularly imprinted polymers as advanced nanomaterials for selective recognition of analytes in environmental, food and biomedical applications
PublikacjaSamples with complex matrix analyzed during explanation of pathogenesis of various diseases and food or environmental monitoring request advanced analytical and instrumental devices. Among the materials used for described purposes, quantum (QDs) or carbon dots (CDs) layered by molecularly imprinted polymer (MIP) shells have gained widespread attention. Unique optical and physicochemical properties of QDs/CDs together with high...
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Miniaturized Solid Phase Extraction techniques for different kind of pollutants analysis: State of the art and future perspectives – PART 1
PublikacjaSolid Phase Extraction (SPE) has been practiced in a modern form for more than half a century. It was constantly developing, driven by the analysts needs. These needs are coming from the importance to select an appropriate analytical method, which should have satisfactory accuracy, precision and sensitivity. In the case of sorbent-based microextraction techniques, the choice of miniaturized variants that meet these requirements...
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Application of Passive Samplers in Monitoring of Organic Constituents of Air
PublikacjaThe principles of passive dosimetry, which has been known for over 100 years, are finding an ever increasing use in analytical practice and are being used as a convenient technique for isolation and enrichment of analytes from various environmental media. Due to its simplicity, a variety of designs, as well as the possibility of using a number of different final determination techniques, passive dosimetry has been applied in...
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Miniaturized Passive Emission Chambers for In Situ Measurement of Emissions of Volatile Organic Compounds
PublikacjaThe results of many different studies have demonstrated unequivocally that the quality of indoor air is often much worse than that of atmospheric air. The presence of dangerous chemical compounds in indoor air can have an adverse impact on human health and cause numerous diseases of the respiratory and circulatory systems. Such harmful chemicals get into indoor air as a result of their emission from building and indoor materials....
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LC-MS and LC-NMR as Complementary Techniques for the Determination of Pharmaceuticals in Dosage Formulations
PublikacjaPharmaceuticals contain not only pharmacologically active compounds but also a range of excipients. The danger exists that impurities may also be present in such drugs, which may adversely affect their efficacy and even endanger patient health and life. Monitoring the composition of pharmaceutical products is therefore essential. The trace amounts of such impurities in pharmaceuticals are often identified and determined with liquid...
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Human hair as a biomarker of human exposure to persistent organic pollutants (POPs)
PublikacjaThe main aim of this article is to investigate the possibility of using human hair as a biomarker with particular emphasis on persistent organic pollutants (POPs). We report previous results of studies of this topic. We critically review the available information on analytical procedures applied during analysis of human hair. Finally, we discuss future trends and possibilities arising from hair analysis.
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Recent breakthroughs in the stability testing of pharmaceutical compounds
PublikacjaPharmaceutical development is mostly focused on the research leading to approval of a new and viable active substance. However, there is a number of old generation compounds that are still being used in contemporary medicinal practice. So that new analytical developments should cover not only the safety of newly developed drug substances, which is obvious, but should also be directed into the search of individual stability issues...
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Complementarity of electronic and vibrational circular dichroism based on stereochemical studies of vic-diols
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Recent achievements in element analysis of bee honeys by atomic and mass spectrometry methods
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Advances in assessing the elemental composition of distilled spirits using atomic spectrometry
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Critical evaluation of recent achievements in low power glow discharge generated at atmospheric pressure between a flowing liquid cathode and a metallic anode for element analysis by optical emission spectrometry
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Development of direct-current, atmospheric-pressure, glow discharges generated in contact with flowing electrolyte solutions for elemental analysis by optical emission spectrometry
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Impact and practicability of recently introduced requirements on elemental impurities
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Cold atmospheric plasma-induced chemical vapor generation in trace element analysis by spectrometric methods
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Determination of aminoglycoside antibiotics: Current status and future trends
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