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Wyniki wyszukiwania dla: CONJUGATED POLYMERS
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Engineering boron and nitrogen codoped carbon nanoarchitectures to tailor molecularly imprinted polymers for PFOS determination
PublikacjaPer- and polyfluoroalkyl substances (PFAS) have gained significant attention as emerging contaminants due to their persistence, abundance, and adverse health effects. Consequently, the urgent need for ubiquitous and effective sensors capable of detecting and quantifying PFAS in complex environmental samples has become a priority. In this study, we present the development of an ultrasensitive molecularly imprinted polymer (MIP)...
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Synthesis, Structure, and Spectroscopic Properties of Calcium Thiophenecarboxylate Polymers. Structural Comparison with Analogous Lead Complexes
PublikacjaThree novel calcium coordination polymers [Ca(2tpCOO)2(2mpa)(H2O)]n (1), [Ca(3tpCOO)2(2mpa)(H2O)]n (2), and {[Ca(3tpacCOO)2(H2O)2]⋅⋅⋅H2O}n (3) (2tpCOO− or 3tpCOO− – thiophene-2- or thiophene-3-carboxylate, 3tpacCOO− – thiophene-3-acetate, 2mpa – 2-methylpropanal), were synthesised using a self-assembly method. The obtained polymers were characterised using SC-XRD, FTIR, UV-Vis DRS, thermogravimetric and luminescence analyses. The...
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Dispersing hydrophilic nanoparticles in hydrophobic polymers: HDPE/ZnO nanocomposites by a novel template-based approach
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Cyclodextrin polymers as efficient adsorbents for removing toxic non-biodegradable pimavanserin from pharmaceutical wastewaters
PublikacjaPresence of even small amount of active pharmaceutical ingredients in the environment carries risks tohuman and animal health, presenting an important issue. The paper presents issues related to the newdrug - pimavanserin (PMV). Biological treatment efficiency of pimavanserin (PMV) was evaluated usinglab-scale Sequencing Batch Reactor (SBR). It has been shown to have a negative effect on aquatic or-ganisms by classifying it as...
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Boronate-appended polymers with diol-functionalized ferrocene: an effective and selective method for voltammetric glucose sensing
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Polyurethanes modified with natural polymers for medical application. Part I. Polyurethane/chitosan and polyurethane/collagen
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Current knowledge about self-healing polymers in the aspect of application for full-rubber protective gloves
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Circular Dichroism Imaging: Mapping the Local Supramolecular Order in Thin Films of Chiral Functional Polymers
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New Coordination Polymers of Selected Lanthanides with 1,2-Phenylenediacetate Linker: Structures, Thermal and Luminescence Properties
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Coordination polymers and molecular structures among complexes of mercury(II) halides with selected 1-benzoylthioureas
PublikacjaSix new 1-benzoyl-3-phenylthiourea and 1-benzoyl-3-(2-methylphenyl)thiourea complexes of mercury( II) were obtained in the reactions of the ligands with HgX2 in methanol (X = Cl, Br, I). Their structures, determined by single-crystal X-ray diffraction analysis, exhibit different stoichiometries and molecular organization. Coordination centers adopt more or less distorted tetrahedral geometry (five structures) or distorted trigonal...
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Electrochemical and photoelectrochemical properties of the interface between titania nanotubes covered by conducting polymer in aqueous by conducting polymer in aqueous electrolytes – The effect of various geometry and electrolytes concentration
PublikacjaIn the present work we show the impact of nanotubes (NTs) geometry of titania utilized as a substrate in organic-inorganic systems acting as a p-n junction on efficient conversion of radiation energy into electrochemical energy. The electrolytic bath composition and electrolysis conditions were controlled in order to obtain TiO2NTs of various geometry as a result of electrochemical oxidation of titanium foil. The electrode material...
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Electrochemically Induced Synthesis of Triphenylamine-based Polyhydrazones
PublikacjaTriphenylamine-based hydrazones were subjected to electropolymerization process that gave well conductive hydrazone based polymers. The first example of polyhydrazone formation during the electrochemical process was shown. The estimation of polymer structure was demonstrated using IR spectroelectrochemistry. The EPR spectroelectrochemistry allowed to explain why in some cases dimer couldn’t be formed. The results of electrochemical,...
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The Product of Matrix Metalloproteinase Cleavage of Doxorubicin Conjugate for Anticancer Drug Delivery: Calorimetric, Spectroscopic, and Molecular Dynamics Studies on Peptide–Doxorubicin Binding to DNA
PublikacjaMatrix metalloproteinases (MMPs) are extracellular matrix degradation factors, promoting cancer progression. Hence, they could provide an enzyme-assisted delivery of doxorubicin (DOX) in cancer treatment. In the current study, the intercalation process of DOX and tetrapeptide-DOX, the product of the MMPs' cleavage of carrier-linked DOX, into dsDNA was investigated using stationary and time-resolved fluorescence spectroscopy, UV-Vis...
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Heterozłącze planarne polimer-materiał małocząsteczkowy
PublikacjaPolimerowe ogniwa fotowoltaiczne ze względu na szereg zalet cieszą się dużym zainteresowaniem. Praca ta zawiera krótki opis zasady działania tego typu urządzeń oraz podstawowych zjawisk zachodzących we wnętrzu materiałów organicznych i na ich złączach. Przedstawiona została struktura heterozłącza planarnego i objętościowego oraz ich porównanie, z uwagi na fakt, że są to dwa najczęściej stosowane w ogniwach fotowoltaicznych typy...
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New Polymeric Materials for Solid Phase Extraction
PublikacjaSolid phase extraction (SPE) is a popular sample preparation technique, which can be applied directly in gas–solid phase and liquid–solid phase, or indirectly to solid samples by using, e.g., thermodesorption with subsequent chromatographic analysis. Although SPE can be described as a physical extraction process involving a liquid phase and a solid phase, the increased use of packed sorbent formats seems to have led to a bias toward...
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On the possibility of using liquid or lipid - polymer membrane systems as taste sensors
PublikacjaMembrany ciekłe z anionowym surfaktanetem mogą być użyte do rozpoznawania molekularnego substancji smakowych ale nie mogą stanowić podstawy sensora smaku głównie z powodu chaotycznych zachowań. Przeciwnie membrany polimerowo-lipidowe mogą być zastosowane w sensorze smaku do badania jakości pewnych napojów handlowych.
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Investigation of energy deposition and its optical imaging in polymer gel dosimeters
PublikacjaThis following chapter describes methods for verifying the absorbed dose during radiotherapy. Special attention is paid to the method using polymer-gel dosimeters, the dose reading of which is performed by means of Laser Computed Tomography. The chapter also includes considerations on alternative solutions for dosimetric measurements and various types of radiotherapy and their pros and cons. In addition, both the methods of structural...
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Influence of the Addition of Recycled Aggregates and Polymer Fibers on the Properties of Pervious Concrete
PublikacjaThe aim of the study was to check the possibility of reusing aggregate from recycled concrete waste and rubber granules from car tires as partial substitution of natural aggregate. The main objective was to investigate the effects of recycled waste aggregate modified with polymer fibers on the compressive and flexural strength, modulus of elasticity and permeability of pervious concrete. Fibers with a multifilament structure and...
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Radiation therapy dosimetry using magnetic resonance imaging of polymer gels
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Polymer films based on silk fibroin and collagen - the physico-chemical properties
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Characteristics of Hybrid Bioglass-Chitosan Coatings on the Plasma Activated PEEK Polymer
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Effect of low-temperature plasma on chitosan-coated PEEK polymer characteristics
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Potential of Functionalized Polyolefins in a Sustainable Polymer Economy: Synthetic Strategies and Applications
PublikacjaPolymers play a crucial role in our modern life as no other material exists that is so versatile, moldable, and lightweight. Consequently, the demand for polymers will continue to grow with the human population, modernization, and technological developments. However, depleted fossil resources, increasing plastic waste production, ocean pollution, and related growing emission of greenhouse gases has led to a change in the way we...
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CARBOCHAIN POLYMER-GLUCOSE HYBRIDS: SYNTHESIS, THERMAL/MECHANICAL PROPERTIES AND BIODEGRADABILITY
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Application of non-metal doped titania for inverted polymer solar cells
PublikacjaDomieszkowany jodem oraz domieszkowany jodem ditlenek tytanu uzyto jako warstwę buforową w ogniwie ITO/X-TiO2?P3HT-PCMB /MnO2/ Ag.Warswty X-TiO2 nalożono metodą spin-coatingu z zawiesiny nanocząstek w DMSO. Jednorodne struktury scharakteryzowane pod względem morfologii mikroskopowo metodą AFM. Charakterystyka prądowo-napięciowa urzdzeń wskazuje iż domieszkowany jodem TiO2 pozwala osiągnąć lepsze parametry PCE (1,67%) i prąd zwarcia...
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EFFECT OF ANTIOXIDANTS ON THE STABILITY OF PITCH- BASED POLYMER TO THERMO-OXIDATIVE ACTION
PublikacjaThe influence of stabilizers – hydrogen donors – on the processes of thermooxidative destruction of pitch-based polymer has been investigated. It is shown that Irganox has not stabilizing effect on pitch-based polymer and melamine slightly retards the destructive process. A mixture of melamine and Irganox exhibits synergetic stabilizing effect and at the optimum ratio it can be used to prevent unwanted thermooxidative processes...
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Bulk-Surface Modification of Nanoparticles for Developing Highly-Crosslinked Polymer Nanocomposites
PublikacjaSurface modification of nanoparticles with functional molecules has become a routine method to compensate for diffusion-controlled crosslinking of thermoset polymer composites at late stages of crosslinking, while bulk modification has not carefully been discussed. In this work, a highly-crosslinked model polymer nanocomposite based on epoxy and surface-bulk functionalized magnetic nanoparticles (MNPs) was developed. MNPs were...
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Polymer biodegradable coatings as active substance release systems for urological applications
PublikacjaCatheter-associated urinary tract infections are the result of catheterization of the bladder. The risk of infection is directly proportional to the length of the bladder catheterization. Bacteria cells have the ability to adhere and create the biofilm on the surface of catheter materials. Bacteria’s biofilm is an extremely beneficial environment of existence for microorganisms. Microorganisms that are an integral part of the biofilm...
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Technological aspects of manufacturing polymer packaging materials degradable in seawater environment
PublikacjaIn recent years, the number of polymer materials used in the food packaging market was growing extremely fast. This contributed to depletion of non-renewable resources and more intense degradation of the environment due to resistant polymer. Therefore, such a dramatic situation has forced researchers to look for biodegradable materials, decomposable under action of microorganism. Currently, only a small number of researches examine...
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Intermolecular Interactions in Selected Polymer-Water Systems as Seen by Raman Spectroscopy
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Characterization of PVC-based polymer inclusion membranes with phosphonium ionic liquids
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Modified Polymer Materials for Use in Selected Personal Protective Equipment Products
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Development of a Formability Prediction Model for Aluminium Sandwich Panels with Polymer Core
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Chiral Diketopyrrolopyrrole-Helicene Polymer With Efficient Red Circularly Polarized Luminescence
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Imprinted polymer particles for iron uptake: Synthesis, characterization and analytical applications
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Metal heksacyanoferrate network synthesized inside polymer matrix for electrochemical capacitors
PublikacjaPrzedmiotem publikacji jest charakterystyka elektrochemiczna polimeru przewodzącego (poli(3,4-etylenodioksytiofenu)) modyfikowanego błękitem pruskim oraz jego pochodnymi, pochodną kobaltową oraz pochodną niklową. Materiały są stabilne elektrochemicznie, a uzyskane wartości pojemności elektrycznej pozwalają na wykorzystanie ich przy konstrukcji kondensatorów elektrochemicznych.
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Interferometric Sensor of Wavelength Detuning Using a Liquid Crystalline Polymer Waveplate
PublikacjaOperation of a polarization interferometer for measurement of the wavelength changes of a tunable semiconductor laser was investigated. A lambda/8 waveplate made from liquid crystalline polymer is placed in one of interferometers’ arms in order to generate two output signals in quadrature. Wavelength was measured with resolution of 2 pm in the wavelength range 628–635 nm. Drift of the interferometer, measured in the period of 500...
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Potential applications of crude glycerol in polymer technology–Current state and perspectives
PublikacjaThe increasing use of bio-based fuels and fuel additives, among them biodiesel, causes significant surplus of crude glycerol on the market which creates new challenges in terms of its sustainable utilization. A lot of ways for the incorporation of this by-product into different branches of industry requires purification by expensive and complicated processes. Therefore, researchers are seeking for applications of untreated crude...
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Polarization interferometer using a Liquid Crystalline Polymer waveplate for wavelength measurement
PublikacjaA two-beam polarization interferometer for measuring wavelength changes of a tunable semiconductor laser was designed, built and tested. This interferometer uses a λ/8 waveplate made from Liquid Crystalline Polymer in order to generate two output signals in quadrature. The λ/8 waveplate can be manufactured either on a beamsplitter face or on the mirror surface, reducing the cost and complexity of the optomechnical assembly. Experiment...
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Investigation of solid polymer electrolyte gas sensor with different electrochemical techniques
PublikacjaIn this work solid polymer electrolyte (SPE) amperometric sulphur dioxide sensor is investigated. Nafion was used as a membrane electrode and 1M sulphuric acid as an internal electrolyte. Sensor response to sulphur dioxide was measured. Besides traditional constant voltage amperometry also different electrochemical techniques were used. Results obtained by these methods are compared.
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Construction and investigation of SO2 amperometric sensor with a solid polymer electrolyte membrane
Publikacjan this paper a sensor for detection of the sulphur dioxide based on three electrode cell configuration with a liquid electrolyte, a mercury sulphate reference electrode and a solid polymer electrolyte working electrode is presented. Working elec- trode was obtained by using Takenaka-Torikai chemical deposi- tion method by precipitation of Au particles into the pores of the Nafion membrane. Sensors characteristics measurements were...
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Investigation of behaviour of metal structures with polymer dampers under dynamic loads
PublikacjaA large number of accidents concerning structures subjected to dynamic loads have been recently observed. One of the examples of such a structure is a temporary steel grandstand erected using scaffolding system. Dynamic load that is generated by crowd movement has a significant influence on the behaviour of the structure and may lead to excessive structural vibrations. The aim of the study is to consider the idea of using polymer...
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The effect of macro polymer fibres length and content on the fibre reinforced concrete
PublikacjaThe paper presents studies of a ready-mix concrete containing polymer fibres of three different lengths: 24, 38 and 54 mm. The performed tests allowed to determine the effect of fibre volume fraction and length on the concrete strength. The basic parameters of concrete mixture (consistency, air content and bulk density) were identified. Fibre reinforced concrete belongs to a group of composite materials. The polymer fibres are...
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TESTING CONTRACTION AND THERMAL EXPANSION COEFFICIENT OF CONSTRUCTION AND MOULDING POLYMER COMPOSITES
PublikacjaThe paper presents results of systematic tests of contraction and thermal expansion coefficients of materials based on polymer composites. The information on the above material properties is essential both at the design stage and during the use of finished products. Components for the samples were selected in such a way as to represent typical materials used for production of construction and moulding elements. The performed tests...
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Investigation of Taste Substances by five Channel Lipid-Polymer Membrane Sensor.
PublikacjaBadano substancje o różnych stężeniach należące do czterech klas smaku za pomocą pięcio-kanałowego sensora opartego o elektrody jonoselektywne z różnymi membranami polimerowo-lipidowymi. Stwierdzono, że sensor jest czuły na zmiany stężeń chlorowodorku chininy, kawsu cytrynowego i chlorku sodu, przeciwnie jak w przypadku sacharozy. Na podstawie tych wyników można przypuszczać, że sensor może być zastosowany do roztworów składających...
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Determination of buckling strength of silos composed of corrugated walls and thin-walled-columns using simplified wall segment models
PublikacjaW artykule przedstawiono wyniki obszernych analiz numerycznych wyboczenia i stateczności metalowych silosów z blachy falistej wzmocnionych cienkościennymi słupami. Wykonano analizy liniowe i nieliniowe. Do obliczeń zaproponowano proste modele segmentów ścian zamiast skomplikowanych modeli całych silosów. Otrzymano bardzo dobrą zgodność wyników numerycznych. Wyniki obliczeń numerycznych porównano dodatkowo z wynikami normowymi.
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Stability of cylindrical steel silos composed of corrugated sheets and columns based on FE analyses versus Eurocode 3 approach
PublikacjaComprehensive static and dynamic 3D stability finite element analyses of a cylindrical steel silo composed of corrugated sheets and open thin-walled vertical stiffener profiles were carried out by taking the geometric and material non-linearity into account. The silowas subjected to axisymmetric and non-axisymmetric loads imposed by a bulk solid following Eurocode 1. Theoretical and measured initial geometric imperfections were...
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Antibacterial properties of laser-encapsulated titanium oxide nanotubes decorated with nanosilver and covered with chitosan/Eudragit polymers
PublikacjaTo provide antibacterial properties, the titanium samples were subjected to electrochemical oxidation in the fluoride-containing diethylene glycol-based electrolyte to create a titanium oxide nanotubular surface. Afterward, the surface was covered by sputtering with silver 5 nm film, and the tops of the nanotubes were capped using laser treatment, resulting in an appearance of silver nanoparticles (AgNPs) of around 30 nm in diameter...
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New devices to capture the temperature effect under dynamic compression and impact perforation of polymers, application to PMMA
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Spatially Resolved Degradation in Heterophasic Polymers From 1D and 2D Spectral–Spatial ESR Imaging Experiments
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