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Wyniki wyszukiwania dla: ORGANIC COAGULANTS
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Graphene nanoflakes functionalized with cobalt/cobalt oxides formation during cobalt organic framework carbonization
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Carbonized metal–organic frameworks with trapped cobalt nanoparticles as biocompatible and efficient azo-dye adsorbent
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Carbonized Lanthanum-Based Metal-Organic Framework with Parallel Arranged Channels for Azo-Dye Adsorption
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Determination of Volatile Organic Compounds in Indoor Air in the Gdansk Area Using Permeation Passive Samplers
PublikacjaPassive dosimetry — known for over a hundred years — is still a useful tool in monitoring air pollutants. In this work, permeation passive samplers were used to determine indoor air quality in 22 apartments located in the Gdansk area in the northern part of Poland. The results obtained by the passive sampling technique were compared to those obtained by dynamic sampling. Attempts were also made to identify indoor sources of...
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Elemental and organic carbon in aerosols over urbanized coastal region (southern Baltic Sea, Gdynia)
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Electric field effect on luminescence, and photoconduction in electron donor - electron acceptor organic solid films
PublikacjaZaobserwowano silne wygaszenie fotoluminescencji (80%) i duże fotoprądy (1mA/cm2) w układzie dendrymer aminowy m-MTDATA (donor elektronu) : pochodna fenantroliny BPT (akceptor elektronu) niedomieszkowanym oraz zawierającym domieszkę w postaci organicznego kompleksu platyny PtL2Cl. W interpretacji wyników uwzględniono elektrycznopolową dysocjację singletowych ekscypleksów m-MTDATA:BPT i trypletowych ekscypleksów m-MTDATA : PtL2Cl...
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Evidence for electric field dependent dissociation of exciplexes in electron donor-acceptor organic solid films
PublikacjaBadano wpływ zewnętrznego pola elektrycznego na zanik luminescencji w układzie dendrymer aminowy m-MTDATA:fenantrolina BPT:poliwęglan PC oraz domieszkowanym organicznym kompleksem platyny. Zaobserwowano silne wygaszenie luminescencji na skutek dysocjacji ekscypleksów singletowych i trypletowych. Pole elektryczne obniżało zarówno amplitudę, jak i czas życia luminescencji.
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Enhanced sunlight photo-catalytic performances of ZnO/ZnNb2O6/Nb2O5 composites for organic pollutant degradation
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Distribution of pollutants in the Odra River system part II. Organic pollutants in Odra River water
PublikacjaW pracy przedstawiono wyniki oznaczeń zanieczyszczeń organicznych (pestycydy, lotne związki chlorowcoorganiczne, wielopierścieniowe węglowodory aromatyczne, chlorobenzeny, polichlorowane bifenyle) w próbkach wody zebranych w trakcie 8 Kampanii (w okresie 1997-2000) zorganizowanej w ramach Międzynarodowego Projektu Badań Dorzecza Rzeki Odry (IOP).
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Bio-mitigation of organic pollutants using horseradish peroxidase as a promising biocatalytic platform for environmental sustainability
PublikacjaA wide array of environmental pollutants is often generated and released into the ecosystem from industrial and human activities. Antibiotics, phenolic compounds, hydroquinone, industrial dyes, and Endocrine-Disrupting Chemicals (EDCs) are prevalent pollutants in water matrices. To promote environmental sustainability and minimize the impact of these pollutants, it is essential to eliminate such contaminants. Although there are...
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Fluctuation-Enhanced Sensing of Organic Vapors by Ink-Printed MoS2 Devices under UV Irradiation
PublikacjaThis work presents the results of fluctuationenhanced sensing (FES) of selected organic gases by MoS2 sensor fabricated via a simple ink printing method. We demonstrate that low-frequency noise measured under UV irradiation (275 nm) is more sensitive to different gases than measured in the dark. The noise at 1 Hz under UV light increased 3.3, 3.5, 1.6, and 2.9 times for chloroform, tetrahydrofuran, acetonitrile, and acetone ambiances, respectively....
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Automated analyser for monitoring trace amounts of volatile chloro-organic compounds in recirculated industrial water
PublikacjaOpisano konstrukcję oraz badania laboratoryjne modelu nowego automatycznego analizatora śladowych ilości lotnych związków chlorowco-organicznych w wodzie do celów przemysłowych (o wysokiej czystości). Praca analizatora oparta jest na: - przeciwprądowym ciągłym wypłukiwaniu analitów ze strumienia próbki, - okresowym zatrzymywaniu uwolnionych analitów na złożu sorbenta, - desorpcji termicznej, - oznaczaniu sumy związków chlorowco-organicznych...
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Monitoring of volatile organic compounds (VOCs) in atmospheric air. Part I. On-line gas analyzers
PublikacjaThe paper reviews the subject literature concerning the analytical instruments routinely used for monitoring volatile organic compounds in atmospheric air. The analyzers are classified as stationary or mobile according to their ease of transport. Stationary DOAS (Differential Optical Absorption Spectroscopy) analyzer is characterized, as are MIMS (Membrane Introduction Mass Spectrometry), MESI (Membrane Extraction with Sorbent...
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Monitoring of volatile organic compounds (VOCs) in atmospheric air. Part II. Sample collection and preparation
PublikacjaThe paper reviews literature information on air sampling techniques commonly used for monitoring volatile organic compounds (VOCs) levels in atmospheric air. It describes containers for collecting samples of atmospheric air, such as vacuum canisters and bags made from synthetic materials. It discusses dynamic, passive and denudational techniques for sampling analytes from air combining isolation with preliminary enrichment, and...
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Organic Rankine cycle turbogenerator cooling – Optimization of the generator water jacket heat exchange surface
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Removal of persistant organic pollutants from landfill leachates treated in three constructed wetland systems
PublikacjaThe objective of the study was assessment of occurrence and removal of two groups of persistent organic pollutants: polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in landfill leachate (LL) treated in three constructed wetland systems (CWs) of different construction and flow regime. Two subsurface flow systems (SSF) were analyzed: one with horizontal flow and the second one consisting of two vertical...
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The role of biodegradable particulate and colloidal organic compounds in biological nutrient removal activated sludge systems
PublikacjaThe efficiency of denitrification and enhanced biological phosphorus removal in biological nutrient removal activated sludge systems is strongly dependent on the availability of appropriate carbon sources. Due to high costs of commercial compounds (such as methanol, ethanol, acetic acid, etc.) and acclimation periods (usually) required, the effective use of internal substrates is preferred. The aim of this study was to determine...
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Effect of some organic solvent - water mixtures composion on precipitated calcium carbonate in carbonation process
PublikacjaPrecipitated calcium carbonate particles were obtained during carbonation of calcium hydroxide slurry with carbon dioxide. Aqueous solutions of isopropyl alcohol, n-butanol and glycerol were used as solvents. Concentration of organic additives in the reactive mixture was from 0 to 20 % (vol.). Precipitation process were performed in a stirred tank reactor equipped with gas distributor. Multimodal courses of particles size distribution...
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Modeling hydrolysis of slowly biodegradable organic compounds in biological nutrient removal activated sludge systems
PublikacjaHydrolysis is an important process in biological wastewater treatment and is known to be the ratelimiting step in organic carbon removal from municipal or industrial wastewater. The influence of the readily biodegradable chemical oxygen demand fraction in biological wastewater treatment systems has been extensively investigated, but little is known about the effects of slowly biodegradable substrate (XS) on denitrification and...
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IDENTIFICATION OF ODOR OF VOLATILE ORGANIC COMPOUNDS USING CLASSICAL SENSORY ANALYSIS AND ELECTRONIC NOSE TECHNIQUE
PublikacjaThe paper compares two methods of analysis of odour of volatile organic compounds: classical sensory analysis and electronic nose technique. Eight volunteers participated in the classical sensory analysis investigations, which lasted two weeks. An instrumental odour analysis involved a prototype of 6-sensor electronic nose designed by the authors. The research performed with this device provided higher reproducibility and reliability...
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Magnetic organic xerogels: efficient adsorbents for the removal of heavy metal ions from aqueous solutions
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The role of colloidal and particulate organic compounds in idenitrification and EBPR occurring in a full-scale activatedsludge system
PublikacjaThe aim of this study was to determine the immediate effects of slowly biodegradable substrates on the denitrification capability andphosphate release/uptake interactions for a full-scale biomass process from the ''Wschod'' wastewater treatment plant (WWTP) in Gdansk (Poland). Since it is hard to distinguish the slowlybiodegradable substrate in a direct way, a novel procedure based on batch experiments was developed and implemented....
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Small signal admittance spectroscopy applied for extraction of charge carrier mobility in thin organic layers
PublikacjaPraca przedstawia nowy sposób wyznaczania ruchliwości nośników ładunku w cienkich warstwach organicznych w oparciu o pomiary widm małosygnałowej admitancji.
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Main complications connected with detection, identification and determination of trace organic constituents in complex matrix samples
PublikacjaIt is well known that some problems with the determination of organic analytes at trace level can occur. This issue is connected with contamination during each stage of the analytical procedure from sampling to sample preparation up to chromatographic analysis, which often leads to false-positive or overestimated results. Another problem associated with determination of analytes occurs at trace- and ultra-trace level is a background...
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Non-metaldoped TiO2 nanotube arrays for high efficiency photocatalytic decomposition of organic species in water
PublikacjaTitanium dioxide is a well-known photoactive semiconductor with a variety of possible applications. The procedure of pollutant degradation is mainly performed using TiO2 powder suspension. It can also be exploited an immobilized catalyst on a solid support. Morphology and chemical doping have a great influence on TiO2 activity under illumination. Here we compare photoactivity of titania nanotube arrays doped with non-metal atoms:...
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Determination of Volatile Organic Compounds in indoor air in the Gdansk area using permeation passive samplers.
PublikacjaDozymetria pasywna, znana od wielu lat, jest użytecznym narzędziem w monitoringu poziomu zanieczyszczeń. Do określenia jakości powietrza wewnętrznego w 22 pomieszczeniach mieszkalnych, zlakoalizowanych na terenie Gdańska, wykorzystano dozymetry pasywne typu permeacyjnego na etapie pobierania próbek analitów. Uzyskane wyniki porównano z wynikami uzyskanymi przy wykorzystaniu matedy dynamicznej. Podjęto również próbę identyfikacji...
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Modeling hydrolysis of slowly biodegradable organic compounds in biological nutrient removal activated sludge systems
PublikacjaHydrolysis is an important process in biological wastewater treatment and has been known as the rate limiting step in organic carbon removal from municipal or industrial wastewater. The biodegradation of XS is initiated by hydrolysis which is an integral part of activated sludge models, such as the Activated Sludge Model no. 2d (ASM2d). The aim of this study was to evaluate different concepts of modeling the hydrolysis process...
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Developments in ultrasound-assisted microextraction techniques for isolation and preconcentration of organic analytes from aqueous samples
PublikacjaThe great potential of ultrasonic assistance in sample preparation, especially extraction, is being recognized. In this review, we discuss the applications of ultrasonic radiation in assisting microextraction. Topics covered include ultrasound-assisted emulsification microextraction, ultrasound-assisted-emulsification-dispersive liquid-liquid microextraction, and ultrasound-assisted hollow-fiber liquid-phase microextraction with...
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PARTICLE SIZE ANALYSIS OF SUSPENSIONS IN REMOVING OF ORGANIC MATTER AND PHOSPHORUS FROM WASTEWATER AND SURFACE WATER
PublikacjaIn this paper the particle size of suspended solids in the removing of organic matter and phosphorus compounds from lake water and wastewater treated in the Ecological Treatment Systems (ETS) was analyzed. The invesigated materials were taken from two ETS located in Pomerania Region/Poland. Object in Swarzewo is 3rd stage of biological treatment of municipal wastewater, while object in Kartuzy has task to remove a phosphorus from...
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The effect of morphology and crystalline structure of Mo/MoO3 layers on photocatalytic degradation of water organic pollutants
PublikacjaMolybdenum oxide layers were formed by anodization of the Mo metallic foil in a water/ethylene glycol-based electrolyte containing fluoride ions. The as-prepared, amorphous samples were annealed in air at different temperatures in a range from 100 �C to 700 �C. The crystal phase and morphology of anodized and annealed MoO3 layers were investigated using X-ray diffraction, Raman spectroscopy, and scanning electron microscopy. The...
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Structural, mechanical and thermal behavior assessments of PCL/PHB blends reactively compatibilized with organic peroxides
PublikacjaThe efficiency of two commercially available organic peroxides, dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB), during reactive processing of poly (ε-caprolactone)/poly (3-hydroxybutyrate) (PCL/PHB) blends was investigated. The changes in chemical structure of PCL/PHB blends, as a function of organic peroxide type (DCP/BIB) and content (in range: 0–1.0 parts by weight - pbw), were characterized by Fourier...
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Family Tree for Aqueous Organic Redox Couples for Redox Flow Battery Electrolytes: A Conceptual Review
PublikacjaRedox flow batteries (RFBs) are an increasingly attractive option for renewable energy storage, thus providing flexibility for the supply of electrical energy. In recent years, research in this type of battery storage has been shifted from metal-ion based electrolytes to soluble organic redox-active compounds. Aqueous-based organic electrolytes are considered as more promising electrolytes to achieve “green”, safe, and low-cost...
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Ag modified ZnO microsphere synthesis for efficient sonophotocatalytic degradation of organic pollutants and CO2 conversion
PublikacjaThe synthesis and design of non-precious and efficient sonophotocatalyts by an environment friendly technique are requisites for solar energy conversion and environmental remediation. This work reports the preparation of Ag/ZnO microspheres with different Ag contents through deposition–precipitation method for pollutant degradation and CO2 conversion. Detail structural investigation reveals that ZnO microspheres and Ag-ZnO microspheres...
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Removal of Volatile Organic Compounds (VOCs) from Air: Focus on Biotrickling Filtration and Process Modeling
PublikacjaBiotrickling filtration is a well-established technology for the treatment of air polluted with odorous and volatile organic compounds (VOCs). Besides dozens of successful industrial applications of this technology, there are still gaps in a full understanding and description of the mechanisms of biotrickling filtration. This review focuses on recent research results on biotrickling filtration of air polluted with single and multiple...
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Generalized Einstein relation in disordered organic semiconductors: Influence of the acoustic phonons–charge carriers scattering
PublikacjaIn this work, we analyze the generalized Einstein relation for disordered organic semiconductors with a non-equilibrium Druyvesteyn-type distribution function. The Druyvesteyn behavior of hot electrons in a solid state is associated with the acoustic phonons–charge carriers scattering. Such a case has been experimentally demonstrated in electroluminescent inorganic rare–earth–doped zinc chalcogenides. Therefore, we can assume that,...
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Elemental and water-insoluble organic carbon in Svalbard snow: a synthesis of observations during 2007–2018
PublikacjaLight-absorbing carbonaceous aerosols emitted by biomass or fossil fuel combustion can contribute to amplifying Arctic climate warming by lowering the albedo of snow. The Svalbard archipelago, being near to Europe and Russia, is particularly affected by these pollutants, and improved knowledge of their distribution in snow is needed to assess their impact. Here we present and synthesize new data obtained on Svalbard between 2007...
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Investigations on the removal of hydrophobic odorous volatile organic compounds by biotrickling filtration monitored with electronic nose
PublikacjaThe presented paper presents the results of research on the removal of selected hydrophobic volatile organic compounds (VOCs) from their mixture with air by means of a trickled-bed biofiltration. The efficiency of the removal of toluene and α-pinene, as model VOCs, in a three-section biotrickling filter is evaluated using GCFID and additionally monitored with an electronic nose. The results show that the removal of the model mixture...
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Effective degradation of sulfide ions and organic sulfides in cavitation-based Advanced Oxidation Processes (AOPs)
PublikacjaThe paper presents the results of investigations on the effectiveness and reaction rate constants of the oxidation of sulfide ions and organic sulfides in real industrial effluents from the production of bitumens (2000 mg S2- L-1) using hydrodynamic and acoustic cavitation. The content of the effluents was analysed in terms carbon disulfide, dimethyl sulfide, and di-tert-butyl disulfide concentration. A possibility of complete...
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Real-time monitoring of the emission of volatile organic compounds from polylactide 3D printing filaments
PublikacjaEstablishing the emission profile of volatile organic compounds generated during fused deposition modeling 3D printing using polymer filaments is important in terms of both understanding the processes taking place during thermal degradation of thermoplastics, and assessing the user's exposure to potentially harmful volatiles. However, obtaining detailed, real-time qualitative and quantitative results poses a challenge. In this...
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Macromolecular Templates for Synthesis of Inorganic Nanoparticles
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Studies on removal of hydrophobic organics from contaminated soil by washing process
PublikacjaZbadano efektywność wymywania NAPL ze złoża piaskowego za pomocą roztworów dwóch niejonowych surfaktantów: polioksyetylenowanego alkoholu tłuszczowego (Rokanol NL6) oraz alkiloglukozydu (Triton BG10). Jako NAPL zastosowano dwa węglowodory - dodekan i heksadekan. Oba surfaktanty były relatywnie efektywne w usuwaniu dodekanu. Ze wzrostem stężenia surfaktantu obserwowano wzrost efektywności wymywania dodekanu, jednakże Rokanol NL6...
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Identification of organic acids as potential biomarkers in the urine of autistic children using gas chromatography/mass spectrometry
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Citropin 1.1 Trifluoroacetate to Chloride Counter-Ion Exchange in HCl-Saturated Organic Solutions: An Alternative Approach
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Hierarchical porous carbon materials from nanosized metal-organic complex for high-performance symmetrical supercapacitor
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Retention time and peak width in the combined pH/organic modifier gradient high performance liquid chromatography
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Soil organic carbon, macro- and micronutrient changes in soil fractions with different lability in response to crop intensification
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Comparison of Chemical Composition and Colour Parameters of Different Mentha Genus Plants Grown under Organic Conditions
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Electric-field-induced quenching of photoluminescence in photoconductive organic thin film structures based on Eu3+ complexes
PublikacjaW pracy badano elektrycznopolowe wygaszenie fotoluminescencji w organicznych kompleksach europu Eu(III) rozdyspergowanych w matrycy poliwęglan: dwuamina TPD. W układzie z elektrodami Al/Al obserwowano wygaszenie fotoluminescencji wywołane dysocjacją ekscytonów. W układzie z elektrodami ITO(+)/Au(-) oprócz dysocjacji ekscytonów obserwowano również silne wygaszenie ekscytonów na ładunku elektrycznym wstrzykniętym do próbki. Analiza...
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Mixing of excimer and exciplex emission: A new way to improve white light emitting organic electrophosphorescent diodes
PublikacjaW pracy opisano konstrukcję wydajnych diod elektrofosforescencyjnych emitujących światło białe. Emisja diod pochodzi od trypletowych monomerów PtL2Cl, trypletowych ekscymerów (PtL2Cl:PtL2Cl) i trypletowych ekscypleksów m-MTDATA (donor elektronu):PtL2Cl (akceptor elektronu), gdzie PtL2Cl oznacza organiczny kompleks platyny (II), a m-MTDATA - dendrymer aminowy. Kwantowa wydajność EL diody wynosi 6.5% fot./e. Współrzędne charakteryzujące...
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Second harmonic generation on crystalline organic nanoclusters under extreme nanoconfinement in functionalized silica–benzil composites
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