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Wyniki wyszukiwania dla: SUSTAINABLE HYDROGELS
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Investigating BiMeVOx compounds as potential photoelectrochemical and electrochemical materials for renewable hydrogen production
PublikacjaIn this study, BiMeVOx compounds (where Me: Co, Mo, Ce, Zr) were synthesized and characterized as potential photoelectrochemical materials for solar water splitting, the hydrogen evolution reaction (HER), and oxygen evolution reaction (OER). The analysis confirmed the successful formation of phase BiMeVOx compounds with the desired crystal structure. Among the tested materials, BiCoVOx(800) showed the highest photocurrent density...
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Effect of plasma nitrided layers on low-alloy steel on its hydrogen degradation
PublikacjaPrzedstawiono badania wpływu warstw azotowanych jarzeniowo na stali 34CrAlNi7-10 na jej podatność na niszczenie wodorowe. Wytworzono warstwy azotowane w atmosferach technologicznych o różnym udziale wodoru. Próbki materiału rodzimego i z warstwami azotowanymi poddano próbie rozciągania z małą prędkością odkształcania w środowisku 0,01 N kwasu siarkowego przy polaryzcaji katodowej. Względny spadek plastyczności i charakter przełomu...
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Alkyl Monolayers on Silicon Prepared from 1-Alkenes and Hydrogen-Terminated Silicon
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Cleaner energy for sustainable future using hybrid photovoltaics-thermoelectric generators system under non-static conditions using machine learning based control technique
PublikacjaIn addition to the load demand, the temperature difference between the hot and cold sides of the thermoelectric generator (TEG) module determines the output power for thermoelectric generator systems. Maximum power point tracking (MPPT) control is needed to track the optimal global power point as operating conditions change. The growing use of electricity and the decline in the use of fossil fuels have sparked interest in photovoltaic-TEG...
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Transport Mechanism of Paracetamol (Acetaminophen) in Polyurethane Nanocomposite Hydrogel Patches—Cloisite® 30B Influence on the Drug Release and Swelling Processes
PublikacjaThis article describes the swelling and release mechanisms of paracetamol in polyurethane nanocomposite hydrogels containing Cloisite® 30B (organically modified montmorillonite). The transport mechanism, swelling and release processes of the active substance in nanocomposite matrix were studied using gravimetric and UV-Vis spectroscopic methods. Swelling and release processes depend on the amount of clay nanoparticles in these...
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Pd nanoparticles with tunable diameter deposited on carbon nanotubes with enhanced hydrogen storage capacity
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Crystal structure, hydrogen bonds, and lattice dynamics in kanemite from first-principles calculations
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In situ deposition of Pd nanoparticles with controllable diameters in hollow carbon spheres for hydrogen storage
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Effect of Pd loading on hydrogen storage properties of disordered mesoporous hollow carbon spheres
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PANI/NaTaO3 composite photocatalyst for enhanced hydrogen generation under UV light irradiation
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Oxidized SWCNT and MWCNT as co-catalysts of polymeric carbon nitride for photocatalytic hydrogen evolution
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Enhancement of photocatalytic hydrogen evolution with catalysts based on carbonized MOF-5 and g-C3N4
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Niszczenie wodorowe stali o podwyższonej wytrzymałości = Hydrogen degradation of high-strength steels.
PublikacjaW artykule przedstawiono niszczenie wodorowe stali 18G2A i jej symulowanej strefy wpływu ciepła (SWC). Jako parametry niszczenia wodorowego wybrano względne wartości energii zniszczenia, czasu do pęknięcia, wydłużenia, przewężenia i wytrzymałości na rozciąganie. Parametry te wyznaczono w próbie odkształcania z małą prędkością na próbkach gładkich, okrągłych. Stwierdzono, że stal 18G2A w środowisku kwaśnym (0,1 N H2SO4) podczas...
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High temperature air/steam gasification of biomass in view of hydrogen rich gas production.
PublikacjaArtykuł przedstawia opis nowej i zaawansowanej metody konwersji termochemicznej biomasy i miejskich odpadów stałych w paliwo gazowe, bogate w wodór. W porównaniu z tradycyjnym procesem gazyfikacji, w metodzie tej wykorzystuje się powietrze/parę wodną przegrzane do wysokiej temperatury (powyżej 1300 st. C). Przegrzanie powietrza lub pary wodnej odbywa się z zastosowaniem ceramicznego przegrzewacza wysokotemperaturowego. W celu...
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Hydrogen rich gas production from high temperature air/steam gasification of biomass
PublikacjaW pracy przedstawiono nowoczesną technikę konwersji biomasy oraz stałych odpadów komunalnych w celu produkcji paliwa gazowego bogatego w wodór. Opisany proces gazyfikacji przebiega w wysokiej temperaturze przy obniżonej koncentracji tlenu i udziale pary wodnej. Dzięki temu możliwa jest produkcja gazów palnych, w szczególności H2, który można wykorzystać do produkcji energii elektrycznej i cieplnej.
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Hydrogen-enhanced stress corrosion cracking and corrosion fatigue of HSLA steels in sea-water
PublikacjaPrzedstawiono ocenę podatności stali o wysokiej wytrzymałości na naprężeniowe pękanie korozyjne i zmęczenie korozyjne wspomagane przez wodór. Wykonano próby powolnego rozciągania i zmęczenia niskoczęstotliwościowego na stalach 17HMBVA i 14HNMBCu oraz ich złączach spawanych, w środowisku wody morskiej, przy polaryzacji katodowej. Zamieszczono wyniki badań elektrochemicznych oraz przełomów na skaningowym mikroskopie elektronowym.
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Pressure and temperature effect on hypergolic ignition delay of triglyme-based fuel with hydrogen peroxide
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Experimental determination of critical conditions for hydrogen-air detonation propagation in partially confined geometry
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Effect of wet Hydrogen Sulfide on Carbon Steels Degradation in Refinery Based on Case Study
PublikacjaMaterial degradation caused by wet hydrogen sulfide (Wet H2S) is one of the major issues in refineries. Carbon steel is the main construction material used in refineries and is subjected not only to thickness loss but the hydrogen is the major concern. H2S leads to high atomic hydrogen penetration in steel which causes degradation in the form of blistering and/or cracking (HIC/SOHIC) and stress cracking in the area of welds and...
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Photocatalytic mineralisation of humic acids using TiO2 modified by tungsten dioxide/ hydrogen peroxide
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Novel non-metallic carbon-nitrogen photocatalysts deposited in cold plasma for hydrogen production
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Review of hydrogen production technologies for automotive sector – thermodynamic analysis of energy and exergy losses
PublikacjaFew recent years has shown that hydrogen technology has a good chance to replace petroleum technology in automotive sector. However, hydrogen in pure form practically does not occur on Earth. That is why H2 form is used only as an energy carrier and it must be produced using another source of energy form water or hydrocarbon fuels. In this paper short overview of hydrogen production technology has been presented, with energy and...
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The effect of pre-hydrogen charging on corrosion behaviour of superduplex stainless steel welded joints
PublikacjaThe paper presents results of research undertaken to determine the influence of hydrogen on passivity and corrosion resistance of 2507 super duplex stainless steel welded joints. Butt welded joints were made with low heat input using flux corded arc welding (FCAW) method. Coupons of 5.0 x 5.0 mm were cut from the welded joints containing weld metal (WM), heat affected zone (HAZ) and parent metal (PM). Hydrogen was introduced...
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Effect of shielded electrode wet welding conditions on diffusible hydrogen content in deposited metal
PublikacjaWet welding is the most popular method of joining in water enviroment. During underwater welding, the weldability of steel is limited by the higher cooling rates and hydrogen content in weld metal. Article presents results of preliminary tests on the effects of wet welding conditions on diffusible hydrogen amount. Seven parameters were optimized using a Plackett-Burman plan to get the most relevant variables. These parameters were:...
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Diffusible hydrogen management in underwater wet self-shielded flux cored arc welding
PublikacjaThis article reports the effect of underwater wet welding parameters and conditions on the diffusible hydrogen content in deposited metal for welding with a self-shielded flux cored wire. The diffusible hydrogen content in deposited metal was determined using the glycerin method according to the Plackett-Burman design determining the significance of the effect of the stick out length, welding current, arc voltage, travel speed...
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Conversion of Biomass and Municipal Wastes into Syngas and Hydrogen using Highly Preheated Agent (HTAG)
PublikacjaGasification is considered to be one of the most promising energy recovery technologies for the widespread utilization of biomass and wastes. During this process raw feedstock is converted into a combustible gas, which can then be burnt to produce thermal energy, or to run engines for mechanical or electrical power. The studies of biomass gasification demonstrate it as a friendly alternative to fossil fuels as one of renewable...
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Hydrogen Production from Energy Poplar Preceded by MEA Pre-Treatment and Enzymatic Hydrolysis
PublikacjaThe need to pre-treat lignocellulosic biomass prior to dark fermentation results primarily from the composition of lignocellulose because lignin hinders the processing of hard wood towards useful products. Hence, in this work a two-step approach for the pre-treatment of energy poplar, including alkaline pre-treatment and enzymatic saccharification followed by fermentation has been studied. Monoethanolamine (MEA) was used as the...
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Low-energy electron scattering from molecular hydrogen: Excitation of the X1Σg+ to b3Σu+ transition
PublikacjaWe present time-of-flight differential cross-section measurements and convergent close-coupling calculations of differential cross sections for the electron-impact excitation of the X 1 g + → b 3 u + transition in molecular hydrogen. A part of this work was recently published [M. Zawadzki et al., Phys. Rev. A 97, 050702(R) (2018)]. In this work, agreement between theory and experiment is excellent overall, and marks a transition...
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Aluminum-TiO2 NPs Composites as Non-precious Catalysts for Efficient Electrochemical Generation of Hydrogen
PublikacjaIn this paper, we demonstrated, for the first time, aluminum titania nanoparticle (Al-TiO2 NP) composites with variable amounts of TiO2 NPs as nonprecious active catalysts for the electrochemical generation of H2. These materials were synthesized by mixing desired amounts of hydrogen titanate nanotubes (TNTs), fabricated here by a cost-effective approach at moderate hydrothermal conditions, with aluminum powder (purity 99.7%; size...
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Preliminary investigations of effect of conditions of FCAW process on diffusible hydrogen content in deposited metal
PublikacjaOne of the types of hydrogen degradation of steel welded joints is cold cracking. The direct cause of the formation of cold cracks is simultaneous presence of hydrogen, residual stresses and brittle structure. The way of preventing the occurring of degradation is to eliminate at least one of these factors. Practice has shown that the best solution is to control the amount of hydrogen in deposited metal. In this paper the state...
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Bismuth-Doped Nano Zerovalent Iron: A Novel Catalyst for Chloramphenicol Degradation and Hydrogen Production
PublikacjaIn this study, we showed that doping bismuth (Bi) at the surface of Fe0 (Bi/Fe0, bimetallic iron system)—synthesized by a simple borohydride reduction method—can considerably accelerate the reductive degradation of chloramphenicol (CHP). At a reaction time of 12 min, 62, 68, 74, 95, and 82% degradation of CHP was achieved with Fe0, Bi/Fe0-1 [1% (w/w) of Bi], Bi/Fe0-3 [3% (w/w) of Bi], Bi/Fe0-5 [5% (w/w) of Bi], and Bi/Fe0-8 [8%...
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Kinetic characterization of hydrogen sulfide inhibition of suspended anammox biomass from a membrane bioreactor
PublikacjaThe inhibition effects of hydrogen sulfide (H2S) on anammox-enriched biomass from a laboratory membrane reactor were analyzed in a series of batch respirometric experiments. The determined half maximal inhibitory concentration (IC50) was 4.67 mg H2S-S L−1 at the constant pH = 7.0 and the total sulfide concentration varying between 1 and 15 mg TS-S L−1. In another test, the IC50 was found to be 4.25 mg H2S-S L−1 under a constant...
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Laboratory bioreactor with pH control system for investigations of hydrogen production in the dark fermentation process
PublikacjaThe work presents the construction of a low-cost research bioreactor equipped with a pH control sys-tem. The developed bioreactor was applied for hydrogen production in the dark fermentation process using Enterobacter aerogenes ATCC 13048. Presented paper compares the results obtained during the process without and with pH regulation for different feed materials: glucose, energetic poplar hydro-lysates, acid whey and glycerol....
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Effect of the welding environment and storage time of electrodes on the diffusible hydrogen content in deposited metal
PublikacjaIn the study the glycerin displacement method was used for determination of diffusible hydrogen content in deposited metal. Specimens were welded in the air and in the water with covered rutile electrodes. The first part of the specimens was made immediately after opening the package of the electrodes. The electrodes were then stored in opened packages in laboratory conditions that allowed for contact with the air for three years....
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Mathematical modeling of hydrogen production performance in thermocatalytic reactor based on the intermetallic phase of Ni3Al
PublikacjaThe main goal of the following work is to adjust mathematical modelling for mass transfer, to specific conditions resulting from presence of chemical surface reactions in the flow of the mixture consisting of helium and methanol. The thermocatalytic devices used for decomposition of organic compounds incorporate microchannels coupled at the ends and heated to 500 oC at the walls regions. The results of the experiment were compared...
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Tereny zdegradowane w UE: skala problemu, przyczyny powstawania i zasady zrównoważonej rewitalizacji = Brownfields in the EU : Scale of the problem, reasons of generation and principles of sustainable revitalization
PublikacjaRosnąca liczba terenów zdegradowanych staje się istotnym problemem w wielu krajach na całym świecie. Celem pracy jest przedstawienie holistycznego podejścia do zarządzania terenami zdegradowanymi rozwijanego w ramach europejskiego projektu HOMBRE (Holistic Management of Brownfield Regeneration). Koncepcja koncentruje się na osiągnięciu najwyższych możliwych korzyści ekonomicznych z uwzględnieniem zasad zrównoważonego rozwoju oraz...
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Macro-nutrients recovery from liquid waste as a sustainable resource for production of recovered mineral fertilizer: Uncovering alternative options to sustain global food security cost-effectively
PublikacjaGlobal food security, which has emerged as one of the sustainability challenges, impacts every country. As food cannot be generated without involving nutrients, research has intensified recently to recover unused nutrients from waste streams. As a finite resource, phosphorus (P) is largely wasted. This work critically reviews the technical applicability of various water technologies to recover macro-nutrients such as P, N, and...
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Peculiar hydrogen bonding behaviour of water molecules inside the aqueous nanochannels of lyotropic liquid crystals
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A giant 2-dimensional dielectric response in a compressed hydrogen-bonded hybrid organic–inorganic salt
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Determination of carbon monoxide, methane and carbon dioxide in refinery hydrogen gases and air by gas chromatography
PublikacjaW pracy przedstawiono metodę oznaczania śladowych zawartości tlenku węgla, metanu oraz dwutlenku węgla w rafineryjnych gazach wodorowych oraz powietrzu; granica oznaczalności metody wynosi odpowiednio 0,15, 0,15 oraz 0,20 mikro-gram/litr. Zaprezentowano w pracy prostą modyfikację chromatografu gazowego wyposażonego w detektor płomieniowo-jonizacyjny (FID). Zastosowano kolumnę typu PorapakQ, dodatkowo połączono szeregowo z krótką...
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Supramolecular Assemblies of Hydrogen Bonded Carboxylic Acid Dimers Mediated by Phenyl-Pentafluorophenyl Stacking Interactions.
PublikacjaKwas pentafluorobenzoesowy tworzy heterodimery z kwasami benzoesowym i 2,4,6-trimetylobenzoesowym w wyniku oddziaływań typu pi-pi reszt fenylowych i pentafluorofenylowych. Otrzymane kokryształy wymienionych kwasów z 1,4-bisarylobutadiynami zawierały homodimery tworzone przez cząsteczki kwasów, pomiędzy którymi znajdowały się cząsteczki diarylodiacetylenów.
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AN EXPERIMENTAL STUDY OF THE PHOTOCATALYTIC HYDROGEN PRODUCTION IN THE LABORATORY-SCALE SET-UP DEPENDING ON THE PROCESS CONDITIONS
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A spectroscopic study into the decomposition process of titanium isopropoxide in the nitrogen–hydrogen 100kHz low-pressure plasma
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Resistance changes of carbon nanotubes decorated with platinum nanoparticles in the presence of hydrogen at different and constant concentrations
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Cubane Like Structure of a Silanethiol Primary Amine Assembly a Novel, Unusual Hydrogen Bond Pattern.
PublikacjaMetodą rentgenowskiej analizy strukturalnej wyznaczono struktury krystaliczne i cząsteczkowe trzech soli amoniowych: (t-BuO)3SiS(-)H3N(+)Bu-t, (i-PrO)3SiS(-)H3N(+)Bu-t i (t-BuO)3SiS(-)H3N(+)(CH2)2CH(CH3)2. Wszystkie trzy związki w ciele stałym tworzą tetramery w których atomy S i N wyznaczają w przybliżeniu naroża sześcianu. Trwałość tych agregatów, oprócz sił elektrostatycznego przyciągania, zapewnia sieć wiązań wodorowych N-H
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Low-Barrier Hydrogen Bond Determines Target-Binding Affinity and Specificity of the Antitubercular Drug Bedaquiline
PublikacjaThe role of short strong hydrogen bonds (SSHB) in ligand-target binding remains largely unexplored, thereby hin- dering a potentially important avenue in the rational drug de- sign. Here, we investigate the interaction between bedaquiline (Bq), a potent anti-tuberculosis drug, and the mycobacterial ATP synthase, to unravel the role of a specific hydrogen bond to a conserved acidic residue in the target affinity and specificity....
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Adaptive resolution simulation of liquid para-hydrogen: testing the robustness of the quantum-classical adaptive coupling
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Interspecies distances between propionic acid degraders and methanogens in syntrophic consortia for optimal hydrogen transfer
PublikacjaA mixed culture from an anaerobic biowaste digester was enriched on propionate and used to investigate interspecies hydrogen transfer in dependence of spatial distances between propionate degraders and methanogens. From 20.3 mM propionate, 20.8 mM acetate and 15.5 mM methane were formed. Maximum specific propionate oxidation and methane formation rates were 49 and 23 mmol mg−1day−1, respectively. Propionate oxidation was inhibited by...
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Effect of underwater local cavity welding method conditions on diffusible hydrogen content in deposited metal
PublikacjaOne of the methods with great potential for applications in underwater repairs is local cavity welding. In local cavity method, cooling conditions and diffusible hydrogen amount in weld metal are nearly the same as those existed during welding in the air. This paper presents the results of literature survey and preliminary tests of the effect of local cavity welding conditions on diffusible hydrogen amount in a deposited metal....
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Relationship between the static dipole polarizability and the static dipole magnetizability of the relativistic hydrogen-like atom
PublikacjaZnaleziono prostą liniową zależność pomiędzy statycznymi dipolowymi podatnościami: elektryczną i magnetyczną relatywistycznego atomu wodoropodobnego w stanie podstawowym.