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Search results for: APPARENT MOLAR COMPRESSIBILITY
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Density, sound velocity, viscosity, and refractive index of new morpholinium ionic liquids with amino acid-based anions: Effect of temperature, alkyl chain length, and anion
PublicationIn this work, room temperature synthesis of twenty new ionic liquids (ILs) based on the N-alkyl-N-methylmorpholinium ([Mor1,R], R = 2, 3, 4, 6, 8) cation and N-acetyl-L-amino acid anions (L-alaninate, L-valinate, L-leucinate, L-isoleucinate) was described. The synthesized ILs were characterized by various spectroscopic techniques and high-resolution mass spectrometry. Furthermore, density (ρ), sound velocity (v), viscosity (η)...
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Measurements of the Hydraulic Fluids Compressibility
PublicationPerformance of the hydrostatic high-pressure drive systems is affected by the changes of working fluid’s volume. Presence of air bubbles in the fluid cause this problem to be even more serious. To study this phenomenon precise measurements of fluid’s bulk modulus are necessary. Differ-ent measurement methods are applied, but they are either limited to low pressure range or give inaccurate results. To solve the problem the new...
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Evaluation of apparent Young׳s modulus of the composite polymer layers used as sliding surfaces in hydrodynamic thrust bearings
PublicationHydrodynamic bearings with a polymer sliding layer are able to operate in severe conditions, mainly due to favorable properties of the polymers. The goal of this research was to evaluate apparent Young׳s modulus of two types of the polymer composite layers used for sliding surfaces in hydrodynamic bearings, as a function of temperature. The Young׳s modulus was evaluated on the basis of compression tests carried out on samples obtained...
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Influence of Soft Soil Samples Quality on the Compressibility and Undrained Shear Strength – Seven Lessons Learned From the Vistula Marshlands
PublicationThis technical article presents the influence of sample quality on the compressibility parameters and undrained shear strength ( c u ) of soft soils from the Vistula Marshlands. The analysis covers: (1) quality of soft soil according to three criteria: void ratio (Δ e / e 0 index), volumetric strain (Δ ɛ v ) and C r / C c ratio; (2) influence of storage time on quality; (3) influence of sample quality on undrained shear strength...
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Isothermal Calorimetry and Compressive Strength Tests of Mortar Specimens for Determination of Apparent Activation Energy
PublicationThe hydration process of cementitious materials involves a thermally activated reaction that depends on the composition of the mixture and the curing temperature. The main parameter affecting the temperature variation of cast-in-place concrete is the apparent activation energy, which can be used for the efficient prediction of the temperature evolution and maturity index of hardening concrete. This paper discusses two methods to...
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Flexoelectricity and apparent piezoelectricity of a pantographic micro-bar
PublicationWe discuss a homogenized model of a pantographic bar considering flexoelectricity. A pantographic bar consists of relatively stiff small bars connected by small soft flexoelectric pivots. As a result, an elongation of the bar relates almost to the torsion of pivots. Taking into account their flexoelectric properties we find the corresponding electric polarization. As a results, the homogenized pantographic bar demonstrates piezoelectric...
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At the Limits of Criticality-Based Quantum Metrology: Apparent Super-Heisenberg Scaling Revisited
PublicationWe address the question of whether the super-Heisenberg scaling for quantum estimation is indeed realizable. We unify the results of two approaches. In the first one, the original system is compared with its copy rotated by the parameter-dependent dynamics. If the parameter is coupled to the one-body part of the Hamiltonian, the precision of its estimation is known to scale at most as N−1 (Heisenberg scaling) in terms of the number...
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Representation of hypertext documents based on terms, Links and text compressibility
PublicationOpisano metody reprezentacji dokumentów tekstowych oparte na słowach, wzajemnych powiązaniach i metodach kompresji. Dokonano ich oceny w oparciu o klasyfikator SVM.
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The effect of impacted third molars on second molar external root resorption, a cross-sectional cone beam computed tomography study
PublicationBackground: Third molars have the highest prevalence of impaction in teeth and can cause pathological damage on the adjacent second molars. This study aims to evaluate the effects of factors related to impacted third molars on external root resorption (ERR) in adjacent second molars using cone-beam computed tomography (CBCT). Material and Methods: In CBCTs, the effect of impacted third molars on the root surface of adjacent second...
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Strength and Compressibility of Ammonia-Soda Residue from the Solvay Sodium Plant
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Volume efficiency loss in axial pumps caused by working fluid compressibility.
PublicationPrzedstawiono teoretyczną analizę wpływu ściśliwości cieczy roboczej konstrukcji mechanizmu rozrządu pompy wielotłoczkowej osiowej na straty energetyczne w przestrzeni martwej. Podano wyniki uzyskane dla typowych konstrukcji.
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Molar volumes and heat capacities of electrolytes and iIons in N,N-dimethylformamide
PublicationZmierzono gęstości i molowe pojemności elektrolitów typu 1:1 oraz o soli o wyższych liczbach ładunkowych jonów w roztworach w N,N-dimetyloformamidzie w temperaturze 25 stopni Celsjusza. W oparciu o te pomiary wyznaczono standardowe objętości molowe oraz standardowe wartości izobarycznych ciepeł molowych. Uzyskane wartości podzielono na udziały jonowe wykorzystując tetrafenyloboran tetrafenylofosfoniowy (TPTB) jako elektrolit odniesienia....
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Optimization of briquetting technology of fine-grained metallurgical materials based on statistical models of compressibility
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Effect of molar ratio [NCO]/[OH] groups during prepolymer chains extending step on the morphology and selected mechanical properties of final bio‐based thermoplastic poly(ether‐urethane) materials
PublicationThe main aim of this work was to investigate the effect of [NCO]/[OH] molar ratio used during the prepolymer chain extending step (with bio‐based diols) on the chemical structure, and thermomechanical and mechanical properties of thermoplastic poly(ether‐urethane)s. Thermoplastic poly(ether‐urethane)s were obtained from bio‐based polyol (polytrimethylene ether glycol), bio‐based glycol (1,4‐butanediol or 1,3‐propanediol), and 4,4'diphenylmethane...
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MiMSeg - an algorithm for automated detection of tumor tissue on NMR apparent diffusion coefficient maps.
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Selenium and mercury concentrations, Se:Hg molar ratios and their effect on the antioxidant system in wild mammals
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Solvation numbers of manganese(II) and zinc(II) perchlorates in methanol obtained from volumetric and compressibility properties
PublicationZmierzono gęstości roztworów nadchloranów manganu(II) i cynku(II) w metanolu w temperaturach: 283.15, 288.15, 293.15, 298.15, 303.15, 308.15, 313.15 K. Ponadto wyznaczono szybkości rozchodzenia się dźwięku w badanych roztworach w 298.15 K. Uzyskane wielkości pozwoliły na obliczenie pozornych objętości molowych oraz pozornych molowych ściśliwości adiabatycznych elektrolitów w metanolu. Oszacowane wielkości graniczne wykorzystane...
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No apparent effect of invasive alien goldenrod on soil microbial communities or soil fauna feeding activity
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Solvation and partial molar volumes of some transition metal cations in N,N-dimethylacetamide, triethylphosphate and acetonitrile.
PublicationW oparciu o precyzyjne pomiary gęstości roztworów nadchloranów metali przejściowych szeregu Mn(II)-Zn(II) w DMA, TEP i AN wyznaczono pozorne molowe oraz graniczne wartości cząstkowych molowych objętości sole w temperaturach 293, 298 i 303,15 K. Wyznaczone wartości rozdzielono na udziały jonowe. Przeanalizowano czynniki decydujące o wielkości cząstkowych molowych objętości solwatowanych kationów.
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Limiting partial molar volumes and expansibilities of ammonium perchlorate, tetraalkylammonium perchlorates, and tetrabutylammonium tetraphenylborate in N,N-dimethylformamide
PublicationWyniki pomiarów gęstości i szybkości rozchodzenia się dźwięku w roztworach nadchloranu amonu, nadchloranów alkiloamoniowych i tetrafenyloboranu tetrabutylomoniowego w N,N-dimetyloformamidzie wyznaczono wartości graniczne cząstkowych molowych objętości i rozszerzalności. Dokonano rozdziału tych wartości na udziały jonowe. Przeanalizowano wpływ temperatury oraz długości łańcucha na te wielkości.
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Effect of Cl/Ni molar ratio on the catalytic conversion of polypropylene into Cu–Ni/C composites and their application in catalyzing “Click” reaction
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Effect of the working liquid compressibility on the picture of volumetric and mechanical losses in a high pressure displacement pump used in a hydrostatic drive Part II Mechanical losses in a pump
PublicationŚciśliwość cieczy roboczej może znacząco zmienić wartości i proporcje współczynników strat objętościowych i mechanicznych w pompie wyporowej zastosowanej w układzie napędu hydrostatycznego. Wpływ ten jest szczególnie widoczny w trakcie pracy pod wysokim ciśnieniem a także wówczas, gdy występuje zapowietrzenie cieczy roboczej. W części II przedstawiono model matematyczny momentu strat mechanicznych w pompie oraz jego laboratoryjną...
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Excess Gibbs energies and excess molar volumes for binary mixtures: (2-pyr-rolidone+water), (2-pyrrolidone+methanol), and (2-pyrrolidone+ethanol) at the temperature 313.15K
PublicationZmierzono całkowite prężności pary oraz zmiany objętości mieszania dla tytułowych układów dwuskładnikowych w temperaturze 313.15K. Rezultaty zostały porównane z wynikami uzyskanymi poprzednio dla pozostałych amidów N-metylofor-mamidu, N,N-dimetyloformamidu oraz N-metyloacetamidu.
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Effect of the working liquid compressibility on the picture of volumetric and mechanical losses in a high pressure displacement pump used in a hydrostatic drive. Part I Energy losses in a drive system, volumetric losses in a pump
PublicationŚciśliwość cieczy roboczej może znacząco zmienić wartości i proporcje współczynników strat objętościowych i mechanicznych w pompie wyporowej zastosowanej w układzie napędu hydrostatycznego. Wpływ ten jest szczególnie widoczny w trakcie pracy pod wysokim ciśnieniem a także wówczas, gdy występuje zapowietrzenie cieczy roboczej. W części I przedstawiono wykres zaproponowany przez autora, wzrostu mocy w układzie napędu hydrostatycznego...
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Effect of the working liquid compressibility on the picture of volumetric and mechanical losses in a high pressure displacement pump used in a hydrostatic drive. Part I Energy losses in a drive system, volumetric losses in a pump
PublicationŚciśliwość cieczy roboczej może znacząco zmienić wartości i proporcje współczynników strat objętościowych i mechanicznych w pompie wyporowej zastosowanej w układzie napędu hydrostatycznego. Wpływ ten jest szczególnie widoczny w trakcie pracy pod wysokim ciśnieniem a także wówczas, gdy występuje zapowietrzenie cieczy roboczej. W części I przedstawiono wykres zaproponowany przez autora, wzrostu mocy w układzie napędu hydrostatycznego...
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Thermodynamic interpretation and prediction of CO2 solubility in imidazolium ionic liquids based on regular solution theory
PublicationRegular solution theory (RST) is the most popular model for the interpretation of the interaction between CO2 and ionic liquids. In the present work, the parameters of this model were determined for the CO2 absorption in eleven imidazolium ionic liquids. The y-intercept (A) of the RST model for the investigated imidazolium liquids increases with increasing temperature whereas the slope (B) remains constant. The values of RST parameters...
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Luminescent properties of Ln3+ doped tellurite glasses containing AlF3
PublicationThe low-phonon energy tellurite glasses TeO2-BaO-Bi2O3 and TeO2-BaO-Bi2O3-AlF3 triply doped with Eu3+, Tb3+, Tm3+ ions in two different molar ratios were synthesized using melt-quenching technique. Their structure and luminescence properties were widely investigated by X-ray Diffraction (XRD), Differential Scanning Calorimetry (DSC), Fourier Transform Infrared Spectroscopy (FTIR) and Photoluminescence Spectroscopy (PL). The luminescence...
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Effects of Xanthan Gum Biopolymer on the Permeability, Odometer, Unconfined Compressive and Triaxial Shear Behavior of a Sand
PublicationBiopolymers, which are microbially induced polymers, can be used as an alternative material to improve engineering performance of soils. In this paper, a laboratory study of 0.075-1.0 mm size sand and biopolymer (i.e., xanthan gum) mixtures with various mix ratios (0%, 0.5%, 1.0%, and 1.5%) was performed. The materials, specimen preparation, and test methods are described, as are the results of a suite of permeability, odometer, unconfined...
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Właściwości termoizolacyjne kompozytu wapienno-cementowego z udziałem paździerzy konopnych=Thermal insulation properties of the lime-cement composite with hemp shives
PublicationPrzedstawiono wyniki badań kompozytów wykonanych na bazie wapna budowlanego, cementu i dolomitu - spoiwa wiążącego z udziałem paździerzy konopi. Określono ich podstawowe właściwości, tj.: gęstość objętościową, współczynnik przewodzenia ciepła oraz wytrzymałości na ściskanie. Otrzymane wyniki dowodzą, że wytworzone kompozyty wapienno-cementowe z udziałem paździerzy konopnych są lekkie i charakteryzują się niskim współczynnikiem...
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Solubility of Carbon Dioxide in Deep Eutectic Solvents Based on 3-Amino-1-Propanol and Tetraalkylammonium Salts at Low Pressure
PublicationDeep eutectic solvents (DESs) became an object of a great interest as an alternative to ionic liquids (ILs) and commonly used in CO2 capture amine solutions. In the present study, five different DESs based on 3-amino-1-propanol as physical-chemical CO2 absorbents were used. The composition was chosen in order to estimate the effects of hydrogen bond acceptor:hydrogen bond donor (HBA:HBD) molar ratio, anion type and length of alkyl...
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Propagation of acoustic pulses in some fluids with yield stress
PublicationThis study is devoted to the derivation of approximate equations governing acoustic pulses in flows with yieldstress, including some time-dependent flows with a slow dependence on time of yield stress and apparent viscosity. Themodeling of yield stress and apparent viscosity in the vicinity of a zero deformation rate allows us to consider a thixotropicfluid as a Bingham plastic with coefficients that are dependent on time. The...
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Development of Gas Sensor Array for Methane Reforming Process Monitoring
PublicationThe article presents a new method of monitoring and assessing the course of the dry methane reforming process with the use of a gas sensor array. Nine commercially available TGS chemical gas sensors were used to construct the array (seven metal oxide sensors and two electrochemical ones). Principal Component Regression (PCR) was used as a calibration method. The developed PCR models were used to determine the quantitative parameters...
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Wpływ właściwości cieczy hydraulicznej na wartość skoków ciśnienia w komorach pomp tłoczkowych osiowych
PublicationPublikacja dotyczy badań skoków ciśnienia w komorach roboczych pomp tłoczkowych osiowych. Skupiono się w nim na wpływie właściwości cieczy hydraulicznej na wartość skoków ciśnienia. Przeanalizowano wpływ takich parametrów jak: -gęstość, -lepkość, -ściśliwość, -zapowietrzenie. Do określenia wpływu właściwości cieczy na skoki ciśnienia wykorzystano badania laboratoryjne i symulacje komputerowe.
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Mathematical model defining volumetric losses of hydraulic oil compression in a variable capacity displacement pump
PublicationThe objective of the work is to develop the capability of evaluating the volumetric losses of hydraulic oil compression in the working chambers of high pressure variable capacity displacement pump. Volumetric losses of oil compression must be determined as functions of the same parameters, which the volumetric losses due to leakage, resulting from the quality of design solution of the pump, are evaluated as dependent on and also...
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Computational fluid dynamics - lustres and shadows.
PublicationThe paper is devoted to the different aspects of CFD. The advantages of this concept are evident and obvious; powerfuk and effective tools bring this technology closer to the quantifiable world. However, certain weaknesses in this structure are apparent. Sometimes, a simplistic tendency towards simplifications and facilitations may degenerate and lead to negative behaviours and signs. These have not been serious up to date, but...
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Transforming the Gdansk Bay Area
PublicationThe political transformation of Poland in the early nineties from a centrally steered economy to a free market economy entailed changes of the spatial planning system. The impact of these changes on the spatial transformations and current shape of urban structures in the Gdansk Bay Metropolitan Area is apparent and significant. The paper concentrates on the present spatial phenomena of Gdansk Agglomeration resulting from the main...
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Core-Shell Nanoparticles with Hyperbranched Poly(arylene-oxindole) Interiors
PublicationCore-shell type star polymers composed of poly(tert-butyl acrylate) (poly(t-BuA)) arms and 100% hyperbranched poly(arylene-oxindole) interiors were synthesized via the "core-first" method. Atom transfer radical polymerization of t-BuA initiated by 2-bromopropionyl terminal groups of the hyperbranched core was applied for the synthesis of the stars. The resultant star structures were characterized by gel permeation chromatography...
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Theoretical and Economic Evaluation of Low-Cost Deep Eutectic Solvents for Effective Biogas Upgrading to Bio-Methane
PublicationThis paper presents the theoretical screening of 23 low-cost deep eutectic solvents (DESs) as absorbents for effective removal of the main impurities from biogas streams using a conductor-like screening model for real solvents (COSMO-RS). Based on thermodynamic parameters, i.e., the activity coefficient, excess enthalpy, and Henry’s constant, two DESs composed of choline chloride: urea in a 1:2 molar ratio (ChCl:U 1:2), and choline...
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Novel bio-based thermoplastic poly(ether-urethane)s. Correlations between the structure, processing and properties
PublicationThe main purpose of this work was to analyze the effect of the number of unreacted isocyanate groups and the [NCO]/[OH] molar ratio during the chain extension of a prepolymer during the polymerization process on the structure, processing and selected properties of thermoplastic poly(ether-urethane)s. Three series of novel thermoplastic polyurethanes were obtained via a prepolymer route. Three prepolymers were synthesized from diisocyanate...
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Influence of Properties of Hydraulic Fluid on Pressure Peaks in Axial Piston Pumps’ Chambers
PublicationThe article concentrates on the research of the pressure peaks in a working chamber of an axial piston pump. The main focus of the article is the influence of fluid properties on the pressure peaks value. Experimental and analytical methods were used to determine the impact of the fluid density, viscosity, compressibility and aeration. The article describes the pressure peak generation process and explains the theoretical basis...
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Method of determining the degree of liquid aeration in a variable capacity displacement pump
PublicationThe Author concludes, that there is a possibility of determining a concrete value of the liquid aeration coefficient during the pump operation by finding such value of coefficient with which the increase of torque of mechanical losses is proportional to the indicated torque determined with a fixed value of increase of pressure in the pump working chambers. The fixed value of increase of pressure assumed in searching the liquid...
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Determination of the Theoretical and Actual Working Volume of a Hydraulic Motor—Part II (The Method Based on the Characteristics of Effective Absorbency of the Motor)
Publication: In this article, the second method of determination of the theoretical and actual working volume of a hydraulic motor is described. The proposed new method is based on the characteristics of effective absorbency of the motor. The effective absorbency has been defined as the ratio of flow rate in a motor to the rotational speed of the motor’s shaft. It has been shown that the effective absorbency is a nonlinear function of the...
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Determination of Chemical Diffusion Coefficient of Lithium Ions in Ceramics Derived from Pyrolysed Poly(1,2-dimethylsilazane) and Starch
PublicationThe apparent chemical diffusion coefficient Li+ (DappLI+) in pyrolysed poly(1,2-dimethylsilazane)/starch (PSN/S) (weight ratio: 30/70) ceramic anode composite is determined by galvanostatic intermittent titration technique (GITT). The electrode material composition is C6.00N0.14H0.47O0.12Si0.13. The calculated values of DappLI+, depend on the applied potential, vary from 10-14 to 10-9 [cm2/s]. The diffusion coefficient of lithium...
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Comprehensive evaluation of physical properties and carbon dioxide capacities of new 2-(butylamino)ethanol-based deep eutectic solvents
PublicationThe aim of this research was to assess the impact of the components of alkanolamine deep eutectic solvents (DESs) on the physical properties of those DESs and their carbon dioxide capacity. To achieve this goal, novel deep eutectic solvents were synthesized by using 2-(butylamino)ethanol (BAE) as the hydrogen bond donor (HBD), along with tetrabutylammonium bromide TBAB), tetrabutylammonium chloride (TBAC), or tetraethy- lammonium...
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Transport properties of microemulsions with ionic liquid apolar domains as a function of ionic liquid content
PublicationThe specific conductivity, dynamic viscosity and apparent diffusion coefficient of each of four aqueous ionic liquid microemulsions (IL-MEs) were measured as a function of ionic liquid (IL) content. The investigated systems were composed of water, hydrophobic ILs (1-butyl-3-methylimidazolium hexafluorophosphate or bis(trifluoromethanesulphonyl)imide) and the nonionic surfactant Triton X-100 or its mixture with cosurfactant (butanol)....
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Tensile and flexural moduli for human orbital wall bones – comparative study
PublicationThe main aims of the current research were: (1) to analyze in detail the tensile modulus and ultimate tensile strength (UTS) of orbital wall bones separately for the left and right orbit of the same cadaver and (2) to compare the obtained results with a flexural modulus of the left and right orbit reported earlier by A. C. van Leeuwen et al. [14]. A set of 54 specimens of orbital superior and/or medial walls harvested from 16 human...
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Deep Eutectic Solvents or Eutectic Mixtures? Characterization of Tetrabutylammonium Bromide and Nonanoic Acid Mixtures
PublicationDeep eutectic solvents have quickly attracted the attention of researchers because they better meet the requirements of green chemistry and thus have the potential to replace conventional hazardous organic solvents in some areas. To better understand the nature of these mixtures, as well as expand the possibilities of their use in different industries, a detailed examination of their physical properties, such as density, viscosity,...
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Removal of Siloxanes from Model Biogas by Means of Deep Eutectic Solvents in Absorption Process
PublicationThe paper presents the screening of 20 deep eutectic solvents (DESs) composed of tetrapropylammonium bromide (TPABr) and glycols in various molar ratios, and 6 conventional solvents as absorbents for removal of siloxanes from model biogas stream. The screening was achieved using the conductor-like screening model for real solvents (COSMO-RS) based on the comparison of siloxane solubility in DESs. For the DES which was characterized...
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Remarkable visible-light induced hydrogen generation with ZnIn2S4 microspheres/CuInS2 quantum dots photocatalytic system
PublicationA new and active material in the form of ZnIn2S4 microspheres decorated by CuInS2 quantum dots have been obtained by hydrothermal method for the first time. The optimum amount of CuInS2 quantum dots (1.13 wt.%) introduced into rection medium during ZnIn2S4 microspheres synthesis increased the photocatalytic H2 generation rate by 2.5 times than that of bare ZnIn2S4 photocatalysis under visible light irradiation. This sample exhibited...
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Tensile modulus of human orbital wall bones cut in sagittal and coronal planes
PublicationIn the current research, 68 specimens of orbital superior and/or medial walls taken from 33 human cadavers (12 females, 21 males) were subjected to uniaxial tension untill fracture. The samples were cut in the coronal (38 specimens) and sagittal (30 specimens) planes of the orbital wall. Apparent density (ρapp), tensile Young’s modulus (E-modulus) and ultimate tensile strength (UTS) were identified. Innovative test protocols were...