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Search results for: MAGNETIC PROPERTIES OF NANOSTRUCTURES
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STRUCTURE AND MAGNETIC PROPERTIES OF Bi5Ti3FeO15 CERAMICS PREPARED BY SINTERING, MECHANICAL ACTIVATION AND EDAMM PROCESS. A COMPARATIVE STUDY
PublicationThree different methods were used to obtain Bi5Ti3FeO15 ceramics, i.e. solid-state sintering, mechanical activation (MA) with subsequent thermal treatment, and electrical discharge assisted mechanical milling (EDAMM). The structure and magnetic properties of produced Bi5Ti3FeO15 samples were characterized using X-ray diffraction and Mössbauer spectroscopy. The purest Bi5Ti3FeO15 ceramics was obtained by standard solid-state sintering...
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Tailoring of structural and magnetic properties of nanosized lithium ferrites synthesized by sol–gel self-combustion method
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Electrical Transport and Magnetic Properties of Metal/Metal Oxide/Metal Junctions Based on Anodized Metal Oxides
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Electrical Transport and Magnetic Properties of Metal/Metal Oxide/Metal Junctions Based on Anodized Metal Oxides
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Polyrhodanine cobalt ferrite (PRHD@CoFe2O4) hybrid nanomaterials - Synthesis, structural, magnetic, cytotoxic and antibacterial properties
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Effect of Thermal Treatment at Inert Atmosphere on Structural and Magnetic Properties of Non-stoichiometric Zinc Ferrite Nanoparticles
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A first-principles study of electronic and magnetic properties of 4d transition metals doped in Wurtzite GaN for spintronics applications
PublicationWe studied the electronic and magnetic properties of wurtzite GaN (w-GaN) doped with different concentrations of the 4d transition metal ions Nb, Mo, and Ru. We incorporated spin-polarized plane-wave density functional theory within an ultrasoft pseudopotential formalism. The 4d transition metals were doped at different geometrical sites to determine the geometry with the lowest total energy and the one that induced the largest...
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Novel Structures and Applications of Graphene-Based Semiconductor Photocatalysts: Faceted Particles, Photonic Crystals, Antimicrobial and Magnetic Properties
PublicationGraphene, graphene oxide, reduced graphene oxide and their composites with various compounds/materials have high potential for substantial impact as cheap photocatalysts, which is essential to meet the demands of global activity, offering the advantage of utilizing “green” solar energy. Accordingly, graphene-based materials might help to reduce reliance on fossil fuel supplies and facile remediation routes to achieve clean environment...
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Structure and characterization of physicochemical and magnetic properties of new complex containing monobridged oxygen copper(II) dinuclear cation
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Magnetic, Structural and Spectroscopic Properties of Iron(II)-Octacyanoniobate(IV) Crystalline Film Obtained by Ion-Exchange Synthesis
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Syntheses, structures, and chiroptical and magnetic properties of chiral clusters built from Schiff bases: a novel [MnIIMnIII6NaI2] core
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The influence of transition metals (Fe, Co) on the structural, magnetic and optical properties of TiO2 nanoparticles synthesized by the hydrothermal method
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The effects of crystallization on the magnetic properties and critical cur-rent in Bi-Sr-Ca-Cu-O glass-ceramics
PublicationW publikacji przedstawiono wpływ procesu krystalizacji na podatność magnetyczną oraz wewnątrzziarnowe i międzyziarnowe prądy krytyczne krystalizowanego szkła Bi4Sr4Ca3Cu4Ox. Próbki krystalizowano w temperaturze 800C w czasie od0,5 godz do 216 godz. Wszystkie próbki poniżej temp. 80k wykazywały cechy diamagnetyczne. Otrzymano małe wartości prądów krytycznych w badanych próbkach (50-100Acm-2 dla prądów wewnątrzziarnowych, w zależności...
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Thermal, electrical, and magnetic properties of Fe2O3–PbO–SiO2 glass prepared by traditional melt-quenching and twin roller fast-cooling methods
PublicationIn this study, Fe–Pb–Si oxide glasses containing between 12.5 and 17.5 mol% Fe2O3 were prepared using two different methods comprising traditional melt-quenching and twin roller fast-cooling techniques. The topography and structure of the materials obtained were characterized by X-ray powder diffraction and scanning electron microscopy. All of the materials were found to be amorphous. The topography of most of the glasses comprised...
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Structural, spectral and magnetic properties of Ni(II), Co(II) and Cd(II) compounds with imidazole derivatives and silanethiolate ligands
PublicationA series of new metal heteroleptic complexes have been obtained in simple reactions of 1-(3-aminopropyl)-imidazole (api) and 1,4-bis(imidazol-1-yl)-butane (bbi) ligands with metal silanethiolates or acetylacetonates. The obtained complexes are the coordination polymers [Ni{SSi(tBuO)3}2(μ-api)]n1, [Co{SSi(tBuO)3}2(μ-api)]n2, [Cd{SSi(tBuO)3}2(μ-api)·2CH3OH]n3, [Cd{SSi(tBuO)3}2(μ-bbi)·CHCl3]n4 and the dimer [Co{SSi(tBuO)3}2(μ-bbi)·3CH3OH]25....
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Size-defined synthesis of magnetic nanorods by Salvia hispanica essential oil with electromagnetic excitation properties useful in microwave imagining
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A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties
PublicationMononuclear and polymeric complexes of zinc(II) and copper(II) have been synthesized using two isomers of the hemi-salen ligand with a different mutual orientation of donor atoms. The heterometallic Cu/Zn metallocycle features a catalytic niche filled with the molecule of water and molecules of methanol. This unusual compound exhibits both pronounced catalytic activity in the reaction of oxidation of a secondary alcohol to ketone...
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Investigation of magnetic and magnetomechanical hysteresis properties of Fe Si alloys with classical and mechanical Barkhausen effects and magnetoaco ustic emission.
PublicationW stopach Fe 3,5% Si o strukturze GO oraz NO badano własności histerezowe za pomocą polowego HBE i mechanicznego MEB efektu Barkhausena oraz emisji magnetoakustycznej EMA. Rozkład naprężeń wewnętrznych został wyznaczony wykorzystując zależność natężenia MEB od naprężeń zewnętrznych (próba pierwszego naprężania). Stwierdzenie MEB oraz EMA o znaczącym naprężeniu dowodzi występowania granic typu 90 deg. Są to granice domen typu...
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Structural, optical and magnetic properties of Y3−0.02−xEr0.02Yb x Al5O12 (0 < x < 0.20) nanocrystals: effect of Yb content
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Zmiany właściwości magnetycznych stali austenitycznych eksploatowanych w kotłach energetycznych = Evolution of magnetic properties of austenite steels exploited at power plant boilers
PublicationOpisano wyniki badań właściwości magnetycznych stali austenitycznych eksploatowanych w kotłach energetycznych. Wykazano, że warstwa zgorzeliny zawiera składniki ferromagnetyczne (magnetyt). Wykazano, iż materiał rodzimy zawiera fazy magnetyczne. Sugeruje się, iż tego typu właściwość może być wykorzystywana dla diagnozowania stopnia zdegradowania eksploatowanego materiału
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The X-ray crystallographic structures, spectral and magnetic properties of nickel(II), copper(II) and cobalt(II) complexes with tetra(3-iso-propylpyrazol-1-yl)borate
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Ln2(SeO3)2(SO4)(H2O)2 (Ln=Sm, Dy, Yb): A Mixed‐Ligand Pathway to New Lanthanide(III) Multifunctional Materials Featuring Nonlinear Optical and Magnetic Anisotropy Properties
PublicationBottom-up assembly of optically nonlinear and magnetically anisotropic lanthanide materials involving precisely placed spin carriers and optimized metal-ligand coordination offers a potential route to developing electronic architectures for coherent radiation generation and spin-based technologies, but the chemical design historically has been extremely hard to achieve. To address this, we developed a worthwhile avenue for creating...
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O zastosowaniu metody prądów wirowych do technicznego pomiaru własności elektrycznych i magnetycznych metali = About application of eddy current method for technical measurement of electric and magnetic properties of metals
PublicationOpisano wyniki badań nad wykorzystaniem efektu prądów wirowych do badania własności elektrycznych i magnetycznych metali. Badania wykonano za pomocą sondy różnicowej. Wyniki pomiarów zależności częstotliwościowej wykonane dla modelowych materiałów porównano z wynikami modelowania metodą elementów skończonych.
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Chiral [Mn II Mn III 3 M′] (M′=Na I , Ca II , Mn II ) and [Mn II Mn III 6 Na I 2 ] Clusters Built from an Enantiomerically Pure Schiff Base: Synthetic, Chiroptical, and Magnetic Properties
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Flexomagneticity in Functionally Graded Nanostructures
PublicationFunctionally graded structures have shown the perspective of materials in a higher efficient and consistent manner. This study reports a short investigation by concentrating on the flexomagnetic response of a functionally graded piezomagnetic nano-actuator, keeping in mind that the converse magnetic effect is only taken into evaluation. The rule of mixture assuming exponential composition of properties along with the thickness...
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Magnetic nanocomposites for biomedical applications
PublicationTissue engineering and regenerative medicine have solved numerous problems related to the repair and regeneration of damaged organs and tissues arising from aging, illnesses, and injuries. Nanotechnology has further aided tissue regeneration science and has provided outstanding opportunities to help disease diagnosis as well as treat damaged tissues. Based on the most recent findings, magnetic nanostructures (MNSs), in particular,...
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Torsional stability capacity of a nano-composite shell based on a nonlocal strain gradient shell model under a three-dimensional magnetic field
PublicationThis paper considers a single-walled composite nano-shell (SWCNS) exposed in a torsional critical stability situation. As the magnetic field affects remarkably nanostructures in the small size, a three-dimensional magnetic field is assessed which contains magnetic effects along the circumferential, radial and axial coordinates system. Based on the results of the nonlocal model of strain gradient small-scale approach and the first-order...
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Crystal facet effects in photocatalytic degradation of organic pollutants over anatase TiO2
PublicationPresented work show detailed effect of the exposed crystal facets of anatase TiO2 on the photocatalytic degradation of organic pollutants. The most important existing information about the geometry and electronic properties of the low index anatase facets are summarised. During the performed works, anatase nanoparticles with the dominant exposition of either {0 0 1}, {1 0 0} or {1 0 1} crystal facets were prepared and their photocatalytic...
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Nanomateriały o właściwościach magnetycznych, fotokatalitycznych, biobójczych
PublicationTematyka badawcza pracy doktorskiej obejmuje preparatykę i charakterystykę nanomateriałów o właściwościach magnetycznych, fotokatalitycznych, biobójczych. Celem pracy była preparatyka nanomateriałów na bazie TiO2 oraz ZnFe2O4 oraz zastosowanie nanokompozytów w fotokatalizie heterogenicznej do degradacji ksenobiotyków niepodatnych na rozkład biologiczny i otrzymywania funkcjonalnych materiałów budowlanych. Otrzymane nanokompozyty...
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Improved finite element method for flow, heat and solute transport of Prandtl liquid via heated plate
PublicationIn the current study, a vertical, 3D-heated plate is used to replicate the generation of heat energy and concentration into Prandtl liquid. We discuss how Dufour and Soret theories relate to the equations for concentration and energy. In order to see how efectively particles, interact with heat and a solvent, hybrid nanoparticles are used. It does away with the phenomena of viscous dissipation and changing magnetic felds. The motivation...
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Magnetization reversal process in flat and patterned exchange-biased CoO/[Co/Pd] thin films
PublicationNanostructured magnetic materials have gained great interest due to their possible technological applications in electronic and spintronic devices or in medicine as drug carriers. The key issue which decides on their potential industrial utilization is an exhibited type of a magnetization reversal process. Two main approaches used to describe the switching mechanism are the domain wall motion and coherent magnetization rotation,...
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Właściwości elektryczne szkło-ceramiki zawierającej ferroelektryczną fazę BiV
PublicationKompozyty szklano - ceramiczne zawierające nanokryształy posiadają właściwości fizyczne, które nie są możliwe do uzyskania w innych materiałach. Dzięki możliwości wytworzenia szkło - ceramik posiadających kryształy o różnej wielkości (nano, mikro...) i różnorodnego typu, można w istotny sposób kontrolować właściwości elektryczne takich materiałów. Stała dielektryczna faz ferroelektrycznych jest bardzo wrażliwa na zmiany rozmiarów...
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On a flexomagnetic behavior of composite structures
PublicationThe popularity of the studies is getting further on the flexomagnetic (FM) response of nano-electro-magneto machines. In spite of this, there are a few incompatibilities with the available FM model. This study indicates that the accessible FM model is inappropriate when considering the converse magnetization effect that demonstrates the necessity and importance of deriving a new FM relation. Additionally, the literature has neglected...
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Projektowanie, synteza i charakterystyka fotokatalizatorów nowej generacji na bazie związku Ti3C2Tx do usuwania aktywnych substancji farmaceutycznych
PublicationCelem niniejszej pracy było zastosowanie materiałów nowej generacji na bazie związku Ti3C2Tx w procesach fotokatalitycznej degradacji aktywnych substancji farmaceutycznych: karbamazepiny, acetaminofenu i ibuprofenu. Zakres prac badawczych obejmował syntezę fotokatalizatorów, charakterystykę ich właściwości fizykochemicznych, oraz ocenę aktywności fotokatalitycznej. Przedstawiono możliwość zastosowania węglika tytanu jako kokatalizatora...
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The decay of quantum correlations between quantum dot spin qubits and the characteristics of its magnetic-field dependence
PublicationWe address the question of the role of quantum correlations beyond entanglement in the context of quantum magnetometry. We study the evolution of the rescaled variant of the geometric quantum discord of two electron-spin qubits interacting with an environment of nuclear spins via the hyperfine interaction. We have found that quantum correlations display a strong magnetic-field sensitivity which can be utilized for decoherence-driven...
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Spectroscopic and magnetic studies of highly dispersible superparamagnetic silica coated magnetite nanoparticles
PublicationSuperparamagnetic behavior in aqueously well dispersible magnetite core-shell Fe3O4@SiO2 nanoparticles is presented. The magnetic properties of core-shell nanoparticles were measured with use of the DC, AC magnetometry and EPR spectroscopy. Particles were characterized by HR-TEM and Raman spectroscopy, showing a crystalline magnetic core of 11.5 ± 0.12 nm and an amorphous silica shell of 22 ± 1.5 nm in thickness. The DC, AC magnetic...
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Structural, optical and electrochemical performance of black phosphorus and black arsenic-phosphorus nanostructures
PublicationBlack phosphorus (BP)-based nanostructures have drawn a lot of attention due to their tunable bandgap and extraordinary properties such as: high surface-to-volume ratio, large number of active sites, and prominent edges. However, low dimensional structures of black phosphorus oxidize easily, which hamper their application on a broader scale. One way to overcome these difficulties is to modify the black phosphorus structure by substituting...
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Magnetic disturbances caused by magnetic contamination of plastics
PublicationIn the study of low magnetic fields precision magnetometers working in a differential system are used. Two optically pumped magnetometers working in a differential system allow for precise measuring of disturbances in the magnetic field. In order to attain high accuracy of magnetic field measurement, it is necessary to use appropriate materials for the construction of a magnetometric system, particularly of those located closely...
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Transformation of bimetallic Ag–Cu thin films into plasmonically active composite nanostructures
PublicationFormation of plasmonically active silver, copper and composite silver-copper nanostructures were studied in this paper. Metallic nanostructures were fabricated by thermal disintegration, so called dewetting, of the thin films in an argon atmosphere. The formation process of the nanostructures was in-situ observed by a novel method, based on resistance measurements. The influence of the material and thickness of the initial thin...
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Magnetic photocatalysts for water treatment
PublicationThe concept of magnetic photocatalysts with separation function requires ferromagnetic material with high magnetic susceptibility to an external magnetic field to enable recycling of composite nanoparticles. Currently, much attention is devoted to functionalization of photocatalyst using MFe2O3, where M =Fe, Zn, Co, Mn. However direct contact between photocatalyst and magnetic iron oxide particles leads to photodissolution of iron...
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Insight into (Electro)magnetic Interactions within Facet-Engineered BaFe12O19/TiO2 Magnetic Photocatalysts
PublicationA series of facet-engineered TiO2/BaFe12O19 composites were synthesized through hydrothermal growth of both phases and subsequent deposition of the different, faceted TiO2 nanoparticles onto BaFe12O19 microplates. The well-defined geometry of the composite and uniaxial magnetic anisotropy of the ferrite allowed alternate interfaces between both phases and fixed the orientation between the TiO2 crystal structure and the remanent...
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The Dynamic Model of Magnetic Hysteresis
PublicationThis paper presents the scalar dynamic magnetic hysteresis model based on the Preisach theory. The important role in this theory played hysteresis operator states. The changes of these operators` states are not immediate in the dynamic model but they are a function of time and parameter k representing the magnetic properties of the material. In this paper the transient state of the hysteresis operator is defined by the nonlinear...
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CuO-decorated MOF derived ZnO polyhedral nanostructures for exceptional H2S gas detection
PublicationConsidering that H2S is a hazardous gas that poses a significant risk to people's lives, research into H2S gas sensors has garnered a lot of interest. This work reports a CuO/ZnO multifaceted nanostructures(NS) created by heat treating Cu2+/ZIF-8 impregnation precursors, and their microstructure and gas sensing characteristics were examined using various characterization techniques (XRD, XPS, SEM, TEM, and BET). The as-prepared...
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Influence of plastic deformation on stray magnetic field distribution of soft magnetic steel sample
PublicationThe effect of various combinations of conditions, i.e., presence of the Earth’s magnetic field during and after deformation on the distribution of stray magnetic field of S355 steel sample, which is locally deformed, was investigated. Some of the stages of the experiment were carried out in zero magnetic field. Compensation of the Earth’s magnetic field was obtained by the application of a pair of Helmholtz coils. These coils are...
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Preparation and characterization of TiO2 nanostructures for catalytic CO2 photoconversion
PublicationThe titanium dioxide target (99.7%) of 1 cm in dia was ablated in vacuum by laser pulses(6 ns) at 266 nm and at repetition rate of 10 Hz. During deposition the laser fluence between 1 and 3.5 J/cm2 and the O2 pressure from the range of 10-2 - 1 Pa were applied. The thin TiO2 films were deposited on glass substrate (1 × 1 cm2) heated up to 500 °C. The chemical composition of the film and samples produced by annealing were investigated...
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Model of ship's magnetic signature
PublicationShips made of ferromagnetic metals interfere with Earth's magnetic field in their surrounding. The disturbance of the magnetic field makes possible localization and even identification of the ship, which could determine a threat to the ship. The measurement of the magnetic field around the ship enables to determine its magnetic signature. The paper presents a multidipoles model of the ship magnetic field, which allows to determine...
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Magnetic deep eutectic solvents – Fundamentals and applications
PublicationMagnetic deep eutectic solvents (MDES), a relatively new subclass of conventional deep eutectic solvents (DES) containing additional paramagnetic components in their structure. MDES exhibit a strong response toward external magnetic fields, thus they can improve many industrial and analytical applications. In addition, this new group of solvents present unique physicochemical properties that can be easily tuned by selecting the...
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Evolution of Ag nanostructures created from thin films: UV–vis absorption and its theoretical predictions
PublicationAg-based plasmonic nanostructures were manufactured by thermal annealing of thin metallic films. Structure and morphology were studied using scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM) and X-ray photoelectron spectroscopy (XPS). SEM images show that the formation of nanostructures is influenced by the initial layer thickness as well as the...
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Low-Dimensional Magnetic Semimetal Cr0.65Al1.35Se3
PublicationWhile exploring novel magnetic semiconductors, the new phase Cr0.65Al1.35Se3 was discovered and characterized by both structural and physical properties. Cr0.65Al1.35Se3 was found to crystallize into orthorhombic CrGeTe3-type structure with space group Pnma (no. 62). Vacancies and mixed occupancies were tested, and the results show that one of the 4c sites accommodates a mixture of Cr and Al atoms, while the other 4c site is fully...
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Investigation of magnetic order in a new intermetallic compound Nd2PtGe3
PublicationIn the present study we report a successful synthesis of the new intermetallic compound Nd2PtGe3 by an arc-melting method. The powder X-ray diffraction analysis indicates that this compound crystallizes in an disordered variant of the AlB2-type structure (space group P6/mmm, no. 191) with lattice parameters a = 4.2455 Å and c = 4. 1933 Å. The compound exhibits a cluster-glass transition below Tf = 2.9 K, characterized through ac...