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Search results for: ORGANIC PLANAR HETEROJUNCTION
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The photovoltaic effect in a heterojunction of molybdenyl phthalocyanine and perylene dye
PublicationPraca przedstawia wyniki pomiarów efektu fotowoltaicznego w układzie zbudowanego z warstw: tlenek indowo-cynowy, barwnik perylenowy, ftalocyjanina molibdenylu, złoto. Obserwowany efekt fotowoltaiczny jest wynikiem dysocjacji ekscytonów na granicy - barwnik perylenowy/ftalocyjanina. W interpretacji wyników uwzględniono procesy generacyjno-rekombinacyjne w złączu.
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Nonlinear planar modeling of massive taut strings travelled by a force-driven point-mass
PublicationThe planar response of horizontal massive taut strings, travelled by a heavy point-mass, either driven by an assigned force, or moving with an assigned law, is studied. A kinematically exact model is derived for the free boundary problem via a variational approach, accounting for the singularity in the slope of the deflected string. Reactive forces exchanged between the point-mass and the string are taken into account via Lagrange...
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On Unsupervised Artificial-Intelligence-Assisted Design of Antennas for High-Performance Planar Devices
PublicationDesign of modern antenna structures is a challenging endeavor. It is laborious, and heavily reliant on engineering insight and experience, especially at the initial stages oriented towards the devel-opment of a suitable antenna architecture. Due to its interactive nature and hands-on procedures (mainly parametric studies) for validating suitability of particular geometric setups, typical antenna development requires many weeks...
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Design and Characterization of a Planar Structure Wideband Millimeter-Wave Antenna with Wide Beamwidth for Wearable off-body Communication Applications
PublicationThis letter presents the design of a planar single-layer wideband antenna featuring wide beamwidth has well as high and stable in-band gain. The proposed antenna is a planar monopole fed by a bottom-grounded coplanar waveguide to realize wide beamwidth in both the xz- and yz-planes. Simultaneous optimization of all adjustable antenna parameters, carried out at the full-wave electromagnetic simulation level. The constructive interference...
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UWB planar antenna dipole in the sandwich configuration
PublicationW pracy przedstawiono wyniki badań nad planarną anteną dipolową o ramionach kołowych, przeznaczoną dla systemu UWB. Ramiona dipola umieszczono pomiędzy dwoma warstwami dielektryka (konfiguracja kanapki) uzyskując redukcję wymiarów anteny. Stwierdzono, że impedancja wejściowa jest mniejsza, niż w przypadku pojedynczego podłoża, co umożliwia łatwiejsze dopasowanie anteny do toru zasilającego. Współczynnik odbicia w całym paśmie...
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Fixed point indices of iterated planar maps
PublicationW artykule dokonuje się przeglądu wyników dotyczących indeksów punktu stałego iteracji odwzorowań planarnych, sformułowane zostają otwarte pytania i podane nowe dowody w przypadku gładkim.
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Fixed point indices of iterations of planar homeomorphisms.
PublicationW pracy bada się postać indeksów iteracji lokalnych homeomorfizmów płaszczyzny.
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Probabilistic analysis of slope with planar slip surface
PublicationPraca dotyczy probabilistycznej oceny stateczności zboczy. Omówiono sposób określania prawdopodobieństwa utraty stateczności przy wykorzystaniu metody momentów (ang. FOSM). Podejście takie zastosowano do analizy zsuwu konsekwentnego jednorodnego zbocza. Rozpatrzono wpływ zmienności statystycznej parametrów wytrzymałościowych na końcowe wyniki.
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Fabrication and photoactivity of organic-inorganic systems based on titania nanotubes and PEDOT containing redox centres formed by different Prussian Blue analogues
PublicationHerein, the heterojunction composed of an inorganic substrate: ordered hydrogenated titania nanotubes (H-TiO2NTs) and a deposited organic film: poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. The conducting polymer is modified with different transition metal haxacyanoferrates (Mehcf), wherein as metal: copper, iron, cobalt and nickel are introduced. The presence of various metal centres provides characteristic redox activity...
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Greener organic solvents in analytical chemistry
PublicationThe paper presents the most recent advances in analytical applications of greener organic solvents. Substitution of problematic solvents with more benign organic ones is much easier than shifting to technique applying alternative solvents, such as ionic liquids or supercritical fluids. In the area of liquid chromatography greener mobile phases, much attention is given to application ethanol or acetone instead of acetonitrile. Solvent-based...
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Optical photoluminescent, and electroluminescent properties of organic solids
PublicationThis chapter discusses optical, photoluminescence and electroluminescence properties of organic materials. First, the spectral features of individual molecules and molecular solid states are analysed. Next, the excitonic processes in organic materials are discussed. The chapter reviews experimental methods leading to the determination of basic excitonic parameters. Finally, the electroluminescence phenomena in organic materials...
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Growth and Isolation of Large Area Boron‐Doped Nanocrystalline Diamond Sheets: A Route toward Diamond‐on‐Graphene Heterojunction
PublicationMany material device applications would benefit from thin diamond coatings, but current growth techniques, such as chemical vapor deposition (CVD) or atomic layer deposition require high substrate and gas‐phase temperatures that would destroy the device being coated. The development of freestanding, thin boron‐doped diamond nanosheets grown on tantalum foil substrates via microwave plasma‐assisted CVD is reported. These diamond...
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Unravelling the role of electron–hole pair spin in exciton dissociation in squaraine-based organic solar cells by magneto-photocurrent measurements
PublicationA high absorption coefficient and narrow absorption bands in squaraine (SQ) dyes have resulted in rapidly growing interest in them as a donor material in photovoltaic devices. The exciton dissociation process in organic systems proceeds via a multistep mechanism where the electron–hole pairs (charge transfer states) involved in the current generation process determine the recombination losses and subsequently limit the overall...
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Compact Planar Balun for the UWB Dipole Feeding Network
PublicationW pracy opisano wyniki z badań numerycznych ultra szerokopasmowego symetryzatora planarnego o zredukowanych wymiarach. Układ został zaprojektowany w oparciu o konfigurację opisaną w literaturze. Względem konfiguracji bazowej, układ przeprojektowano na inne podłoże. W celu weryfikacji przydatności układu, przeprowadzono symulację anteny dipolowej zasilanej opisywanym symetryzatorem. Na podstawie otrzymanych rezultatów przekazano...
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Local fixed point indices of iterations of planar maps
PublicationW artykule podana zostaje postać indeksów iteracji dla pewnej klasy odwzorowań planarnych. Podstawowymi narzędziami stosowanym w pracy są liczba Nielsena i indeks Conleya.
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Fixed points of planar homeomorphisms of the form Identity + Contraction
PublicationW pracy dowodzi się, przy użyciu indeksu, istnienia punktów stałych dla planarnych homeomorfizmów, których orbity spełniają pewien geometryczny warunek.
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Resonant and nonresonant excitation of waves in a planar magnetosonic flow
PublicationForced propagation of perturbations in a magnetosonic wave are considered. The driving force may be caused by stimulated Mandelstam–Brillouin scattering of optic waves or by intense magnetosonic exciter. Some heating-cooling function which takes into account radiative cooling and unspecified heating is taken into consideration, as well as nonlinearity of a medium. Both these factors make the excitation particular. The analytical...
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Photovoltaic effect in a heterojunction of di-(pyridyl)-perylenetetracarboxylic diimide and bromophosphorus phthalocyanine
PublicationFtalocyjniny i barwniki perylenowe są materiałami bardzo często wykorzystywanymi w organicznych układach fotowoltaicznych. Obie grupy materiałów charakteryzują się dużą odpornością chemiczną i termiczną oraz silną absorpcją światła w zakresie widzialnym. Ta praca przedstawia wyniki badań efektu fotowoltaicznego w heterozłączu utworzonym z ftalocyjaniny bromofosforowej (PBrPc) i pochodnej pirydylowej (PyPTC) barwnika perylenowego....
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Spectral dependences of photocurrent of the aluminium-nickel phthalocyanine-tetracene-aluminium heterojunction
PublicationAnalizowano charakterystyki spectralne fotoprądu płynącego przez heterozłącze tetracen-ftalocyjanina niklu. Obserwowany fotoprąd jest prądem dziurowym generowanym w trzech obszarach: w pobliżu obu elektrod Al i międzypowierzchni tetracen-ftalocyjanina niklu.
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Heterojunction of (P, S) co-doped g-C3N4 and 2D TiO2 for improved carbamazepine and acetaminophen photocatalytic degradation
PublicationNovel photocatalysts of phosphorus and sulfur co-doped graphitic carbon nitride incorporated in 2D TiO2 structure were successfully fabricated and applied for solar-driven degradation of emerging pollutants from the group of pharmaceuticals not susceptible to biodegradation. The hybrid photocatalysts with different loadings of (P, S)-doped g-C3N4 were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR),...
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Photoconduction in the archetype organic hole transporting material TPD
PublicationW pracy przedstawiono charakterystykę fotoprzewodnictwa w zależności od przyłożonego pola elektrycznego, długości fali i natężenia światła wzbudzającego molekuły pochodnej diaminy (TPD)wykorzystywanej powszechnie jako organiczny przewodnik dziurowy w organicznych diodach elektroluminescencyjnych. Układy z pojedynczą warstwą TPD, kwarc/ITO/TPD/Al i kwarc/Al/TPD/Al, zostały wzbudzane od strony podłoża kwarcowego. Przy długościach...
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Photoconduction in the archetype organic hole transporting material TPD
PublicationW pracy opisano mechanizm fotoprzewodnictwa w układzie ITO/warstwa TPD/Al oraz Al/warstwa TPD/Al, gdzie TPD oznacza dwaminę powszechne stosowaną jako transporter dziur w organicznych diodach EL.
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Comment on "On accurate capacitance characterization of organic photovoltaic cells"
PublicationIn the 100th volume of Applied Physics Letters Carr and Chaudhary have presented a work on capacitance characterization of organic photovoltaic cells. The work concerns small signal measurements of various organic photovoltaic structures. The authors however limit their considerations to one part of small signal response, namely to capacitance measured either in parallel mode or in series mode. This attitude generally does not...
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Spetiation of organic matter in Vertical Flow Constructed Wetlands
PublicationThe object of the research were VFCWs which are a component of biological treatment of two hybrid hydrophyte systems located in Wieszyno and Wiklino, close to Słupsk, Poland. The facilities that are subject to analyses are unified in terms of structure (filtration material, depth of the bed and time of operation), but they differ in organic matter load, amounting respectively to: 8.0 gCOD/m2day and 31.0 gCOD/m2day.The intensity...
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Determination and identification of organic acids in wine samples. Problems and challenges.
PublicationFor long time, organic acids were underestimated. However, during last two decades there is an increasing interest of natural compounds having antioxidant, antimicrobial and anti-inflammatory properties thus organic acids are very preferable. Wine stands as one of the sources of organic acids since they are responsible for its organoleptic and aestethic character. Nevertheless, it is important to not exceed acceptable level of...
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Unified design procedure for planar dipoles oriented on uwb application
PublicationW pracy zaproponowaną ujednoliconą metodę projektowania dipoli planarnych dla zastosowań UWB. Prowadzi ona do uzyskania dobrych wyników dopasowania impedancji w paśmie UWB. Zagadnienie projektowania zostało podzielone na dwie części: projekt radiatora (dla którego określono współczynnik jakości - Radiator Quality Factor) oraz projekt symetryzatora. W oparciu o zaproponowany algorytm zaprojektowano i zrealizowano dwie anteny charakteryzujące...
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Redundant Actuation of 3RRR over-actuated Planar Parallel Manipulator
PublicationPraca opisuje zagadnienia modelowania i napędzania manipulatorów równoległych. Cechą charakterystyczną manipulatorów równoległych jest występowanie jednego lub kilku łańcuchów kinematycznych zamkniętych (gałęzi równoległych). Standardowo, konstrukcje takie są napędzane jedynie silnikami montowanymi w parach kinematycznych łączących łańcuchy kinematyczne z podstawą. Niekiedy konstrukcje takie są układami napędzanymi nadmiarowo (liczba...
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A Concept and Design Optimization of Compact Planar UWB Monopole Antenna
PublicationA novel structure concept of a compact UWB monopole antenna is introduced together with a low-cost design optimization procedure. Reduced footprint is achieved by introduction of a protruded ground plane for current path increase and a matching transformer to ensure wideband impedance matching. All geometrical parameters of the structure are optimized simultaneously by means of surrogate based optimization involving variable-fidelity...
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Connecting orbits for a periodically forced singular planar Newtonian system
PublicationW niniejszym artykule badamy problem istnienia i krotności rozwiązań homoklinicznych i heteroklinicznych dla nieautonomicznych układów Newtonowskich na płaszczyźnie z potencjałem okresowym ze względu na zmienną czasową, mającym maksimum globalne właściwe przyjmowane w dwóch punktach płaszczyzny i punkt osobliwy (studnię nieskończonej głębokości), w otoczeniu którego potencjał spełnia warunek Gordona (gradient potencjału ze względu...
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Homoclinic and Heteroclinic Orbits for a Class of Singular Planar Newtonian Systems
PublicationThe study of existence and multiplicity of solutions of differential equations possessing a variational nature is a problem of great meaning since most of them derives from mechanics and physics. In particular, this relates to Hamiltonian systems including Newtonian ones. During the past thirty years there has been a great deal of progress in the use of variational methods to find periodic, homoclinic and heteroclinic solutions...
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On the low-cost design of abbreviated multisection planar matching transformer
PublicationA numerically demanding wideband matching transformer composed of three nonuniform transmission lines (NUTLs) has been designed and optimized at a low computational cost. The computational feasibility of the design has been acquired through the exploitation of low-fidelity NUTL models in most steps of the design procedure and an implicit space mapping optimization engine, providing high accuracy results with only a handful of EM...
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Design and Optimization of a Compact Planar Radiator for UWB Applications and Beyond
PublicationA compact monopole antenna for ultra-wideband (UWB) and beyond applications has been proposed. The radiator is based on the monopole topology. The super-wideband behavior has been achieved using a combination of spline-based modifications applied to the driven element, as well as utilization of a tapered feed and a slot-modified ground plane. The electrical performance of the structure has been tuned using a numerical optimization...
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Historical records of organic pollutants in sediment cores
PublicationAnalyses of sediment core samples are primary sources of historical pollution trends in aquatic systems. Determining organic compounds, such as POPs, in the dated sediments enables the estimation of their temporal concentration changes and the identification of the contaminant origin in local regions. Wars, large-scale fires, economical transitions, and bans on certain chemicals are reflected in the sediment organic compound concentrations....
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Influence of dissolved organic nitrogen on surface waters
PublicationThe aim of this study was to determine the susceptibility of dissolved organic nitrogen (DON) contained in biologically treated wastewater disposed from municipal wastewater treatment plants (WWTPs) to biodegradability and bioavailability in a water environment. Additionally an evaluation was performed of the participation of this organic nitrogen fraction, including bioavailable DON (bDON), in the nitrogen balance for the Baltic...
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Functionalization of graphene: does the organic chemistry matter?
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The role of organic and mineral constituents on kerogen transformation ratio
PublicationThe main aim of this dissertation is to determine the role of mineral and organic matter constituents in kerogen transformation ratio. Practical aspects of the work include application of the results in the assessment of hydrocarbon production potential; to make process of hydrocarbon recovery more predictable consistent and efficient. The work used shale from the Vaca Muerta formation from the Nequen basin in Argentina. The formation...
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Organic Supercritical Thermodynamic Cycles with Isothermal Turbine
PublicationOrganic Rankine cycles (ORC) are quite popular, but the overall efficiencies of these plants are rather very low. Numerous studies have been conducted in many scientific centers and research centers to improve the efficiency of such cycles. The research concerns both the modification of the cycle and the increase in the parameters of the medium at the inlet to the turbine. However, the efficiency of even these modified cycles rarely...
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Metal-Organic Framework (MOF)/Epoxy Coatings: A Review
PublicationEpoxy coatings are developing fast in order to meet the requirements of advanced materials and systems. Progress in nanomaterial science and technology has opened a new era of engineering for tailoring the bulk and surface properties of organic coatings, e.g., adhesion to the substrate, anti-corrosion, mechanical, flame-retardant, and self-healing characteristics. Metal-organic frameworks (MOFs), a subclass of coordinative polymers...
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Sano-Tachiya-Noolandi-Hong, Onsager and Braun models vs Monte Carlo simulation of charge photogeneration in organic solids
PublicationThe Sano-Tachiya-Noolandi-Hong (STNH), Onsager, and Braun models as well as Monte Carlo (MC) simulations of charge recombination/separation have been applied for the first time to reproduce the results of the electromodulated photoluminescence measurements in vacuum-evaporated films of fluorescent materials commonly used in optoelectronic devices. The values of the electron-hole pair final recombination speed in the monomer emitters:...
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Correlations between organic pollution indicators in municipal wastewater
PublicationThe paper presents the results of a study of parameters used for determining the amount of organic pollutants in wastewater flowing into a collective wastewater treatment plant with a population equivalent of about 120 000 PE. The plant constituted part of a sewage system. Assays were performed for biochemical oxygen demand (BOD5), chemical oxygen demand (CODCr), permanganete index (CODMn) and total organic carbon (TOC). In addition,...
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Enhanced trap-assisted recombination in organic semiconductors
PublicationAn analytical model to describe the interaction of excitons and charge transfer states with deep traps is formulated for the case of molecular materials. Here, we have considered the influence of a trap-assisted recombination on this phenomenon. The final expression for the effective recombination rate has been derived from the Shockley–Read–Hall theory and kinetic equations which characterize different photophysical processes....
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Ion Chromatography in Environmental Analysis of Selected Organic Acids
PublicationLow molecular mass carboxylic acids (LCAs) occur in many environmental compartments dueto natural processes and human activity. When volatile and nonvolatile acids are to be monitored then liquidchromatography, including ion chromatography seems a method of choice. At high pH the acids are inionized form and can be separated as carboxylats by means of anion exchange chromatography. LCAs canalso be separated at low pH by ion exclusion...
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The Use of Organic Coagulants in the Primary Precipitation Process at Wastewater Treatment Plants
PublicationMeasurements for determining the effect of chemically enhanced primary treatment (CEPT) on the efficiency of pollutant removal from wastewater were carried out using conventional inorganic coagulants PIX113 with polymer A110 (Kemipol, Police, Poland) and unconventional cationic organic coagulants Cofloc (Attana, Coalville, UK) C29510 (Kemipol, Police, Poland) and Sedifloc 575 (3F Chimica, Sandrigo, Italy). The average removal efficiency...
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Mineral and Organic Matter Constituents in Weak Interfaces in Shales
PublicationThis paper identifies formation interfaces that would appear to be "weak interfaces", in the Jurassic, Early- Cretaceous Vaca Muerta formation, in the Neuquén Basin, Argentina. Significant distribution of the weak interfaces was observed including contacts between volcanic ash layers of varying thicknesses, calcite-filled veins, and contacts between lithology changes, such as between argillaceous mudstone and mottled carbonates....
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An automated microwave planar filter design based on space mapping optimization
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Compact-planar monopole loop antennas for 802.11b/g WLAN systems
PublicationZaproponowano planarne anteny monopolowe dla systemów komunikacji bezprzewodowej WLAN pracujących w pasmach 2.45GHz i 5.25GHz. W strukturze radiatorów zasilanych poprzez linię mikropaskową wykorzystano krzywe fraktalne: pętlę Kocha oraz pętlę Minkowskiego. W obu przypadkach uzyskano dwuzakresową pracę anten dzięki wprowadzeniu nowej konfiguracji zminiaturyzowanych transformatorów impedancji w układzie zasilania.
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3D reconstruction of nuclear reactions using GEM TPC with planar readout
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On the design of planar high directivity proximity couplers in the mm-wave range
PublicationPrzedyskutowano problemy projektowania sprzęgaczy zbliżeniowych wykonywanych w technologii planarnej i przeznaczonych do pracy w zakresie fal milimetrowych. Zasadniczym celem badań było zaprojektowanie, wykonanie i przebadanie układu sprzęgacza o wysokiej kierunkowości i umiarkowanym poziomie sprzężenia pracującego w zakresie 40-50GHz. Przedyskutowano i zamodelowano różne konfiguracje sprzęgaczy. Stwierdzono, że znane zasady projektowania...
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Fast surrogate-assisted frequency scaling of planar antennas with circular polarisation
PublicationIn this work, the problem of computationally efficient frequency scaling (re-design) of circular polarisation antennas is addressed using surrogate-assisted techniques. The task is challenging and requires the identification of the optimum geometry parameters to enable the operation of the re-designed structure at a selected (required) centre frequency. This involves handling several performance figures such as the antenna gain,...
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Subcritical Thermodynamic Cycles with Organic Medium and Isothermal Expansion
PublicationThe efffciencies of the Organic Rankine Cycle (ORC) are not very high and only very seldom do they exceed 20%. The increase and optimization of initial parameters and certain modifications of the thermodynamic cycle make it possible to overcome these drawbacks. A new modified cycle has been described and analyzed in detail in the paper. Similarly to the Ericsson cycle for gas turbines, isothermal expansion in the turbine is suggested...