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Search results for: amines, nickel ions, polymeric metal-containing ionic liquids, solid-phase microextraction
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Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 16. Synthesis of 25, 26, 27, 28-tetrakis(piperidinethiocarbonylmethylene)-p-tert-butylcalix[4]arene and its interaction with metal ions
PublicationThe synthesis, characterisation and X-ray crystal structures of p-tert-butyl-calix[4]arenethioamide L and its complex with lead L-Pb2+ is reported. The cation-binding properties in solution have been assessed by liquid-liquid extraction of the metal picrates from water into dichloromethane and by stability constants determination in acetonitrile using UV-absorption spectrophotometry or potentiometry. The compound was used as active...
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Determination of Surfactants in Environmental Samples. Part III. Non-Ionic Compounds
PublicationNon-ionic surface active agents are a diverse group of chemicals which have an uncharged polar head and a non-polar tail. They have different properties due to amphiphilic structure of their molecules. Commercial available non-ionic surfactants consist of the broadest spectrum of compounds in comparison with other types of such agents. Typically, non-ionic compounds found applications in households and industry during formulation...
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Occurrence and Levels of Biogenic Amines in Beers Produced by Different Methods
PublicationThe concentration of biogenic amines (BAs) in beer depends, among other factors, on the activity of microorganisms, in particular lactic acid bacteria. In this work an analytical method based on derivatization with tosyl chloride and high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) was used to determine 17 BAs in samples of commercially available beers, and to monitor the changes in concentration of...
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Membranes for toxic- and heavy-metal removal
PublicationSince time ago, membranes have greatly attracted the attention of researchers for different types of water-treatment applications, such as wastewater treatment, water purification, removal of microorganisms, chemical compounds, and heavy metals. Nowadays, one of the current challenges of research community definitely deals with the removal of toxic and heavy metals from water. In this regard, the current chapter provides enough...
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Synthesis of thiol derivatives of azobenzocrown ethers. The preliminary studies on recognition of alkali metal ions by gold nanoparticles functionalized with azobenzocrown and lipoic acid
PublicationThe article presents the synthesis of novel 13- and 16-membered azobenzocrown derivatives with peripheral thiol moieties and preliminary studies assessing their possible application in plasmonic sensors based on gold nanoparticles. The effect of the length of the chain connecting the macrocycle with the thiol group and the effect of the presence of the additional functional compound,...
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From metal dithiocarbamates to metal sulfides
PublicationLigandy ditiokarbamianowe są szeroko stosowane w chemii koordynacyjnej. Układy zawierające metal mogą być z powodzeniem wykorzystane do otrzymania odpowiednich siarczków. W pracy przedstawiono syntezę, strukurę, właściwości, zastosowanie związków z tej grupy. Scharakteryzowano ich rozkład termiczny, jak równeiż zaprezentowano metody umożliwiające wykorzystanie ich jako pojedyncze prekursory molekularne
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Polymeric Bearings as a new base isolation system suitable for mitigating machine-induced vibrations
PublicationThe present paper summarizes the preliminary results of the experimental shaking table investigation conducted in order to verify the effectiveness of a new base isolation system consisting of Polymeric Bearings in reducing strong horizontal machine-induced vibrations. Polymeric Bearing considered in the present study is a prototype base isolation system, which was constructed with the use of a specially prepared flexible polymer...
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Solid phase extraction of explosives on Ni-doped carbosils prepared by mechanochemistry
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Determination of butyltin stabilizers in PVC using Liquid-Phase microextraction with electrothermal atomic absorption spectrometry
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Determination of the adsorption mechanism of imidazolium type ionic liquids onto kaolinite: implications for their fate and transport in the soil environment
PublicationNiniejsza publikacja szczegółowo opisuje sorpcję cieczy jonowych na powierzchni glin kaolinowych. Uzyskane wyniki wskazują na występowanie zjawiska sorpcji wielowarstwowej. Przy całkowitym wysyceniu najwyższy współczynnik podziału został zaaobserwowany dla cieczy jonowych podstawionych długim łańcuchem alkilowym. Średnie wartości energii swobodnej wyznaczone dla procesu sorpcji cieczy jonowych są niższe niż typowe energie swobodne...
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Preliminary study on suitability of ionic liquids as potential passive-sampling media of polyaromatic-hydrocarbon (PAH) analyses in water
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Enzymatic Polymerization of Cyclic Monomers in Ionic Liquids as a Prospective Synthesis Method for Polyesters Used in Drug Delivery Systems
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Ionic liquids: predictions of physicochemical properties with experimental and/or DFT-calculated LFER parameters to understand molecular interactions in solution
PublicationPublikacja zawiera modele pozwalające na przewidywanie współczynnika podziału oktanol-woda (log P), rozpuszczalności w wodzie oraz krytycznego stężenia micelizacji (CMC) cieczy jonowych oraz współczynników aktywności anionowej i hydrofobowości w wodzie i w mieszaninie oktanolu z wodą. Modele oparte są na liniowych zależnościach energii swobodnej (LFER) i wykorzystują parametry zmierzone i/lub wyliczone na podstawie funkcjonalnej...
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Improvements to the two-phase sandwich method for calculating the melting points of pure metals
PublicationThe thermophysical properties of metal alloys are often investigated via molecular dynamics (MD) simulations.An exact and reliable estimation of the thermophysical parameters from the MD data requires a properly and carefullyelaborated methodology. In this paper, an improved two-phase sandwich method for the determination of the metal meltingtemperature is proposed, based on the solid-liquid equilibrium theory. The new method was...
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Nickel-nanodiamond coatings electrodeposited from tartrate electrolyte at ambient temperature
PublicationIn this study, nanocrystalline Ni and Ni-diamond coatings were obtained by electrodeposition from tartrate electrolyte at ambient temperature aiming at improving corrosion and wear properties of the material. The created surfaces were investigated with regard to microhardness, adhesion, wear- and corrosion-resistance. The various methods such as atomic force microscopy, scanning electron microscopy, electrochemical impedance spectroscopy...
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Polymeric Bearings – A New Base Isolation System to Reduce Structural Damage during Earthquakes
PublicationBase isolators, like lead rubber bearings, high damping rubber bearings or friction pendulum systems are extensively used in practice in many seismically active regions to protect structures against earthquake forces. The present paper reports the results obtained from the experimental study aimed to determine the effectiveness of the Polymeric Bearings in suppressing structural vibrations during dynamic excitations and therefore...
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Influence of Sn and Pb Ions Substitutions on Dielectric Properties of Barium Titanate
PublicationThe results of the microstructural and dielectric measurements of (Ba1-xPbx)(Ti1-xSnx)O3 (BPTSx) (x = 0, 0.05, 0.10, 0.30) polycrystalline samples are presented. The samples were obtained by means of a high temperature synthesis and their expected stoichiometry was confirmed by energy dispersive spectroscopy (EDS) measurements. The dielectric properties of BPTSx were studied with the use of broadband dielectric spectroscopy. The...
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The Mesoporous Porphyrinic Zirconium Metal-Organic Framework for Pipette-Tip Solid-Phase Extraction of Mercury from Fish Samples Followed by Cold Vapor Atomic Absorption Spectrometric Determination
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Effect of metal ions from Ginkgo biloba extracts on the oxidative stability of rapeseed oil and its triacylglycerols
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Quantification of Compatibility Between Polymeric Excipients and Atenolol Using Principal Component Analysis and Hierarchical Cluster Analysis
PublicationAn important challenge to overcome in the solid dosage forms technology is the selection of the most biopharmaceutically efficient polymeric excipients. The excipients can be selected, among others, by compatibility studies since incompatibilities between ingredients of the drug formulations adversely affect their bioavailability, stability, efficacy, and safety. Therefore, new, fast, and reliable methods for detecting incompatibility...
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Assessment and design of greener deep eutectic solvents – A multicriteria decision analysis
PublicationDeep eutectic solvents (DES) are often considered as green solvents because of their properties, such as negligible vapor pressure, biodegradability, low toxicity or natural origin of their components. Due to the fact that DES are cheaper than ionic liquids, they have gained many applications in a short period of time. However, claims about their greenness sometimes seem to be exaggerated. Especially, bearing in mind lots of data...
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Experimental Study on Effectiveness of a Prototype Seismic Isolation System Made of Polymeric Bearings
PublicationSeismic isolation is identified as one of the most popular and effective methods of protecting structures under strong dynamic excitations. Base isolators, such as Lead Rubber Bearings, High Damping Rubber Bearings, and Friction Pendulum Bearings, are widely used in practice in many earthquake-prone regions of the world to mitigate structural vibrations, and therefore minimize loss of life and property damage during seismic events....
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Impedance spectroscopy of BaTiO3 cubes suspended in lossy liquids as a physical model of two-phase system
PublicationTechniki spektroskopii impedancyjnej zostały wykorzystane do analizy modelu fizycznego w układzie dwufazowym w celu wyznaczanie stałej dielektrycznej dielektryka umieszczonego w cieczy. Badania eksperymentalne przeprowadzono z użyciem BaTiO3 jako materiału dielektrycznego, który został przygotowany jako kostki o jednakowej wielkości 2x2x1 mm3.
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Superconductivity in Metal-Rich Chalcogenide Ta2Se
PublicationThe metal–metal bond in metal-rich chalcogenide is known to exhibit various structures and interesting physical properties. Ta2Se can be obtained by both arc-melting and solid-state pellet methods. Ta2Se crystallizes a layered tetragonal structure with space group P4/nmm (No. 129; Pearson symbol tP6). Each unit cell consists of four layers of body-centered close-packing Ta atoms sandwiched between two square nets of Se atoms, forming...
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Separation of Volatile Oxygen-containing Organic Compounds by Gas Chromatography - selectivity comparison of different polarity stationary phases
PublicationThis paper present a results of the separation of 36 reference compounds belonging to the group of Volatile Oxygen-Containing Organic Compounds (OVOCs) using capillary gas chromatography with flame ionization detector (GC-FID) and three stationary phases of different polarity. A selectivity has been studied regarding to OVOCs and n -alkanes. The most useful for the separation of the group OVOCs is a polar ionic liquid stationary...
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Room temperature ionic liquid-based dispersive liquid–liquid microextraction of uranium in water samples before spectrophotometric determination
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Compatibilization of polymeric composition filled with ground tire rubber – short review
PublicationWaste rubber is recognized as valuable materials resource and searching for new recycling methods is the main activity of many research institutions and companies. At the turn of the last years only few scientific papers about foamed polymer compositions filled with ground tire rubber were published. In paper review about progress in compatibilization and foaming of polymeric compositions filled with ground tire rubber.
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Effect of isovalent substitution on microstructure and phase transition of LaNb1−xMxO4 (M=Sb, V or Ta; x=0.05–0.3)
PublicationLaNb1−xMxO4 oxides with pentavalent elements of different ionic sizes (M=Sb, Ta and V, x=0.05–0.3) were synthesized by the solid state reaction method. Special interest was devoted to the antimony substituted lanthanum niobate which is a new material in this group. Rietveld analysis of the X-ray diffraction patterns was used to determine the influence of the material composition on unit cell parameters. On the basis of dilatometric...
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On the mechanism of oscillations in three-phase system containing coationc surfactant and nitrobenzene liquid membrane
PublicationObserwuje się oscylacje różnicy potencjału elektochemicznego między fazami wodnymi oscylatora zawierającego bromek heksadecylotrimetyloamoniowy. Ta różnica potencjału składa sie z potencjałów na granicach faz między membraną a fazą wodną donorową oraz membraną a fazą wodną akceptorową. Wykazano, że oscylacje zachodzą na granicy fazy akceptorowej i membrany. Są one spowodowane procesami adsorpcji/desorpcji pary jonowej surfaktantu...
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Determination of ionic conductivity in the Bi-Si-O and Pb-Si-O glasses
PublicationImpedance spectroscopy measurements in various gas atmospheres were carried out in order to explain the doubts about the type of carriers and the mechanism of electrical conductivity in Bi-Si-O and Pb-Si-O glasses. In bismuth silicate glass, a typical ionic conductivity with oxygen ions as charge carriers was observed. The level of electrical conductivity of the glass at 400 °C was 5 × 10−8 S·cm−1 , with the activation energy of...
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Nickel Oxide Thin Film Sensor for Fluctuation-Enhanced Gas Sensing of Formaldehyde
PublicationNanocrystalline nickel-oxide-based thin films were prepared by advanced reactive gas deposition, and the response of these films to formaldehyde was studied by fluctuationenhanced sensing. Morphological and structural analyses showed porous deposits of nickel oxide particles with face-centered cubic structure. Resistance fluctuations were measured upon exposure to ethanol, formaldehyde and methane at 200 °C. Power density spectra...
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Polymeric bisphosphonate derivative of ciprofloxacin – synthesis, structural analysis and antibacterial activity of the prospective conjugate
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Investigation methods of ionic conductivity measurements in polycrystalline MIEC (mixed ionic-electronic conductor) based on perovskite ceramics
PublicationPaper about the measurements of ionic conductivity in LSM and strontium titanate ceramics.
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Structure and hyperfine interactions in Bi1−xNdxFeO3 solid solutions prepared by solid-state sintering
PublicationThe series of polycrystalline ceramic powders, Bi1xNdxFeO3 (x = 0.11) was successfully synthesized by mixed oxide method followed by pressureless sintering. X-ray diffraction and Mössbauer spectroscopy were used as complementary methods to study structure and hyperfine interactions of the samples. It was found that with an increase of Nd content, within the range of x = 0.20.3 a structural phase transition from rhombohedral to...
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The river water influence on cationic and anionic dyes collection by nickel foam with carbonized metal-organic frameworks and carbon nanotubes
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Catalytic Activity of Nickel and Ruthenium–Nickel Catalysts Supported on SiO2, ZrO2, Al2O3, and MgAl2O4 in a Dry Reforming Process
PublicationDry reforming of methane (DRM) is an eco-friendly method of syngas production due to the utilization of two main greenhouse gases—methane and carbon dioxide. An industrial application of methane dry reforming requires the use of a catalyst with high activity, stability over a long time, and the ability to catalyze a reaction, leading to the needed a hydrogen/carbon monoxide ratio. Thus, the aim of the study was to investigate the...
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Nickel alendronate
PublicationKryształy tytułowego związku [Ni2(C4H12NO7P2)4(H2O)2]*2H2O, zostały otrzymane w warunkach hydrotermalnych. Jego struktura jest izotypowa ze strukturą analogicznego związku Co(II).
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Possibilities of radioisotope measuring in control of an unstable solid particles hydrotransport
PublicationThe paper presents γ-radiation proposal to control a multiphase flow, independently from circumstances. So this method may be applied even in compound industrial or environmental processes. Moreover in many cases, it is the only method for applications for dense mixture containing coarse angular grains. The constructed equipment allows continuous measurement of density as well as solid phase for both concentration and average velocity....
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TMSCL as a rate accelerating additive in acylations of amines with 5-(α- amino-α'-hydroxy)methylene meldrum's acids
PublicationAspects are presented of the acylation of amines, alcohols and thiols with 5-(α-amino- α'-hydroxy)methylene Meldrum's acids. We placed special emphasis on the acylation reaction of secondary amines with 5-(α-amino- α'-hydroxy)methylene Meldrum's acids, which, due to their basicity, caused problems concerning salt formation with a Meldrum acid derivative. We found that secondary amines, which react at the slowest rate and with a...
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Tmscl as a rate accelerating additive in acylations of amines with 5-(α-amino- α'-hydroxy)methylene meldrum's acids
PublicationAspects are presented of the acylation of amines, alcohols and thiols with 5-(α-amino- α'-hydroxy)methylene Meldrum's acids. We placed special emphasis on the acylation reaction of secondary amines with 5-(α-amino- α'-hydroxy)methylene Meldrum's acids, which, due to their basicity, caused problems concerning salt formation with a Meldrum acid derivative. We found that secondary amines, which react at the slowest rate and with a...
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Direct Screening ofWater Samples for Benzene Hydrocarbon Compounds by Headspace Liquid-Phase Microextraction--Gas Chromatography
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Direct screening of ground water samples for fuel oxygenates by headspace liquid phase microextraction–gas chromatography
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Usuwanie lotnych związków organicznych z fazy gazowej z zastosowaniem cieczy jonowych
PublicationUżycie cieczy jonowej do usuwania LZO jest limitowane przez rozpuszczalność usuwanych związków. Dane literaturowe sugerują, że ciecze jonowe jako faza membranowa mogą być z powodzeniem stosowane do selektywnej separacji węglowodorów aromatycznych z mieszanin węglowodorów aromatycznych i alifatycznych. Przedmiotem pracy było kompleksowe opisanie procesu separacji LZO z fazy gazowej z uwzględnieniem czynników wpływających na efektywność...
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Solid phase synthesis and biological activity of linear tuftsin and retro-tuftsin derivatives
PublicationPrzedstawiono syntezę na fazie stałej nowych pochodnych tuftsyny i retro-tuftsyny i ich mikrobiologiczne właściwości. Otrzymane pochodne zawierały wiązanie izopeptydowe między epsilon-aminową grupą lizyny a takimi aminokwasami jak: Ala, beta-Ala, Val, Ile, Gly.
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Solid phase synthesis of conjugates of tuftsin analogues with 1-nitro-acridine derivatives
PublicationZsyntetyzowano na fazie stałej koniugaty 1-nitro-akrydyny z pochodnymi tuftsyny modyfikowanymi na grupie epsilon-aminowej lizyny prostymi aminokwasami, np. alaniną, valiną, beta-alaniną. Końcowe produkty były charakteryzowane za pomocą MS, NMR, analizy elementarnej i przekazane do badań ich aktywności przeciwnowotworowej.
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Silicon polypodands: a new class of efficient solid–liquid phase-transfer catalysts
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Application of a new class B-podands in solid–liquid phase transfer catalysis
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A new type of B-podand catalysts for solid–liquid phase transfer reactions
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Matrix solid-phase dispersion with sand in chromatographic analysis of essential oils in herbs
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The triple-sorbents solid-phase extraction for pharmaceuticals and estrogens determination in wastewater samples
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