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Search results for: CHEMICAL COMPOSITION OF LIPIDS
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The effect of mixed anionic-cationic films composition on flotation of hydrocarbon particles from water
PublicationBadano adsorpcję dodecylosulfonianu sodowego oraz jednego z bromków alkilo-trimetyloamoniowych z roztworów ich mieszanin na granicach faz woda/powietrze oraz woda/dodekan. Obliczone stężenia powierzchniowe poszczególnych surfaktantów wykorzystano do wyznaczenia składu filmów adsorpcyjnych. Skład filmów anionowo-kationowych był podstawą do przewidywania zmian ładunku elektrostatycznego kropli dodekanu oraz efektywności flotacji...
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The role of tungsten in formation of active sites for no SCR on the V-W-O catalyst surface — quantum chemical modeling (DFT)
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Euilibrium composition of CH4-CO2-CO-H2-H2O-C system under various compositions syngas methanation
Open Research DataThe equilibrium compositions of CH4, CO2, CO, H2, H2O and C under the methanation reaction of various syngas mixtures (different CO/H2 ratio) were supplied with this dataset
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Interactions between polyphenolic antioxidants quercetin and naringenin dictate the distinctive redox-related chemical and biological behaviour of their mixtures
PublicationFood synergy concept is suggested to explain observations that isolated antioxidants are less bioactive than real foods containing them. However, mechanisms behind this discrepancy were hardly studied. Here, we demonstrate the profound impact of interactions between two common food flavonoids (individual: aglycones quercetin—Q and naringenin—N− or their glycosides rutin—R and naringin—N+ vs. mixed: QN− and RN+) on their electrochemical...
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Imaging and chemical investigation of silver coating
Open Research DataThe recovery of silver from materials such as plates, still used in clinical radiography [1], or scrap jewelery is still very popular. The subject of the research, part of which was microscopic imaging, was to recreate the behavior of an electrochemically deposited silver coating. The copper electrodes were covered with a layer of silver obtained from...
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Depth chemical profile in a CeIr3 sample
Open Research DataThe polycrystalline sample of CeIr3 used in the present studies was synthesized by arc-melting cerium (4N) and iridium (3N5) in an arc furnace on a water-cooled copper hearth using a tungsten electrode under a high purity argon atmosphere. A piece of zirconium was used as an oxygen getter. First, a button of Ir was prepared by arc-melting the iridium...
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Tribological Properties of Ni-P/Si3N4 Nanocomposite Layers Deposited by Chemical Reduction Method on Aluminum Alloy AW-7075
PublicationThe article presents the results of tribological tests of Ni-P/Si3N4 nanocomposite and Ni-P nickel layers deposited on the AW-7075 aluminum alloy by chemical reduction method, and the AW-7075 alloy without coating. Nanocomposite layers were produced using Si3N4 siliconnitride in the form of a polydisperse powder whose particle sizes ranged from 20 to 25 nm. The influence of the content of the dispersion phase layer material on...
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Dissolved and colloidal organic nitrogen removal from WWTP effluents and reject waters using physical-chemical processes
PublicationFour physical-chemical processes were compared in terms of the efficiencies of dissolved and colloidal organic nitrogen (DON and CON) removal from the secondary effluents (SE) and reject water from full-scale biological nutrient removal activated sludge systems. Adsorption on activated carbon was most efficient and allowed to remove from the SE up to 80% and 100% of DON and CON, respectively. High efficiencies of DON removal from...
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International Conference on Software Composition
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Changes in the EPA and DHA content and lipids quality parameters of rainbow trout (Oncorhynchus mykiss, Walbaum) and carp (Cyprinus carpio, L.) at individual stages of hot smoking
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ELECTRICAL CONDUCTIVITY AND pH IN SURFACE WATER AS TOOL FOR IDENTIFICATION OF CHEMICAL DIVERSITY
PublicationIn the present study, the creeks and lakes located at the western shore of Admiralty Bay were analysed. The impact of various sources of water supply was considered, based on the parameters of temperature, pH and specific electrolytic conductivity (SEC25). All measurements were conducted during a field campaign in January-February 2017. A multivariate dataset was also created and a biplot of SEC25 and pH of the investigated waters...
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Chemical analysis of low carbon content coals and their applications as dye adsorbent
PublicationCoal is primarily a fuel material but lately it has been utilized as an adsorbent for removing toxic metal ions. However, its usage for removing organic pollutants is not well studied. We report here a systematic study on the use of coal samples of varying carbon contents as adsorbents for removing Basic Blue 41 as a model cationic dye. The coal samples were collected from coal mines and were thoroughly characterized. The concentrations...
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Arsenic concentrations in Baltic Sea sediments close to chemical munitions dumpsites
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Chemical and thermal stability of core-shelled magnetite nanoparticles and solid silica
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Evaluation of Chemical Changes in Laboratory-Induced Colistin-Resistant Klebsiella pneumoniae
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Application of Coordination Compounds with Transition Metal Ions in the Chemical Industry—A Review
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Exposure status of sea-dumped chemical warfare agents in the Baltic Sea
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Deep sea habitats in the chemical warfare dumping areas of the Baltic Sea
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Application of Chemical Sensors and Olfactometry Method in Ecological Audits of Degraded Areas
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Chemical and magnetic functionalization of graphene oxide as a route to enhance its biocompatibility
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Development of Chemical Tools to Monitor Human Kallikrein 13 (KLK13) Activity
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Polymer films based on silk fibroin and collagen - the physico-chemical properties
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Improving of Cherry Fruit Quality and Bearing Regularity by Chemical Thinning with Fertilizer
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Polylactide Films with the Addition of Olive Leaf Extract—Physico-Chemical Characterization
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Chemical characterization of dew water collected in different geographic regions of Poland
PublicationPrzedstawiono wyniki badań składu chemicznego próbek rosy zebranych na terenie Polski w okresie od 2004 do 2006 roku na terenach: rolniczym (Wrocław, Dziemiany), miejskim w strefie wybrzeża (Gdańsk, Gdynia, Sopot), miejskim, położonym poza strefą wybrzeża (Bytów, Kraków, Mława). Próbki rosy badano w celu uzyskania informacji o składzie jakościowym i ilościowym. Celem badań było dostarczenie informacji o składzie chemicznym (i wybranych...
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Chemical characterization of dew water collected in different geographic regions of Poland
PublicationOkreślono poziomy stężeń składników śladowych obecnych w próbkach rosy zebranych na terenach wyraźnie różniących się pod względem położenia geograficznego jak również poziomem antropopresji. Próbki rosy były zbierane na terenie ośmiu stacji pomiarowych w cyklu dobowym w okresie od sierpnia 2004 do listopada 2006 roku. W zależności od położenia miejsc zbierania próbek oraz charakteru tła emisji zanieczyszczeń dokonano podziału na...
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Ecotoxicity and chemical sediment data classification by the useof self-organising maps
PublicationArtykuł dotyczy przedstawiania nowej interpretacji szacowania jakości osadów. To oryginalne podejście bada powiązania między parametrami ekotoksyczności (ostrej i chronicznej) i składnikami chemicznymi (zanieczyszczenia takie jak polichlorowane bifenyle, pestycydy, wielopierścieniowe węglowodory aromatyczne, metale ciężkie) próbek osadów Jeziora Turawskiego (Polska) poprzez zastosowanie samoorganizujących się map (SOM) wobec badanego...
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Quality Assurance and Quality Control in the Analytical Chemical Laboratory: A Practical Approach.
PublicationNowe opracowanie książkowe z zakresu QA/QC to praktyczny podręcznik zarówno dla studentów jak i pracowników laboratoriów. Opisano systemu jakości wyników pomiarów analitycznych i poszczególnych jego składników: spójności pomiarowej, niepewności pomiaru, walidacji procedury analitycznej, materiałów odniesienia i badań międzylaboratoryjnych. Opisano i przedstawiono narzędzia statystyczne służące do obliczania parametrów walidacyjnych,...
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Application of electrochemical sensors and sensor matrixes for measurement of odorous chemical compounds
PublicationIn this paper describes the principle of operation of the electrochemical sensors and the sensor matrixes comprised of electrochemical sensors intended for measurement of odorous compounds. Critical comparison of these sensors’ advantages and disadvantages has been made. The fields of economy contributing to release of odours and the potential sources of their emission have been identified. Commercially available electrochemical...
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Chemical Aspects of Biological Activity of Isothiocyanates and Indoles, the Products of Glucosinolate Decomposition
PublicationThere is growing evidence that cancer chemoprevention employing natural, bioactive compounds may halt or at least slow down the different stages of carcinogenesis. A particularly advantageous effect is attributed to derivatives of sulfur-organic phytochemicals, such as glucosinolates (GLs) synthesized mainly in Brassicaceae plant family. GLs are hydrolysed enzymatically to bioactive isothiocyanates (ITC) and indoles, which exhibit strong...
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Ab initio chemical kinetics of Isopropyl acetate oxidation with OH radicals
PublicationGlobal reactivity descriptors of isopropyl acetate (IPA) and thermo-kinetic aspects of its oxidation via OH radicals have been studied. Transition state theory (TST) was utilized to estimate the bimolecular rate constants. Ten oxidation pathways have been investigated, and all of them are exothermic. The potential energy diagram has been sketched using different pre- and post-reactive complexes for all reaction pathways. Rate coefficient...
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A Molecular dynamics study of the influence of chemical reduction on the structure of amorphous germania
PublicationPraca poświęcona jest badaniom struktury blisko- i średniozasięgowej redukowanego amorficznego tlenku germanu o składzie 1Ge 1GeO2 za pomocą symulacji dynamiczno-molekularnych. Symulacje MD realizowano w zespole mikrokanonicznym (NVE), z wykorzystaniem dwuciałowego potencjału oddziaływania miedzyatomowego Borna-Mayera-Hugginsa. Wyraźnie widoczna tendencja do aglomeracji neutralnych atomów Ge została porównana z tendencją do aglomeracji...
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A Chemical Recognition Element for Lithium Ions Based on Optical Electronic Absorption.
PublicationOtrzymano próbki kserożeli techniką zol-żel. Otrzymane materiały zastosowano do konstrukcji czujników optycznych. Rolę elementu rozpoznającego w uzyskanych próbkach pełnią chromogeniczne etery koronowe zawierające w makro pierścieniu dwie grupy azowe oraz resztę fenolu. W obecności soli metali I grupy układ u okresowego obserwowano zmiany w widmach absorpcyjnych. Dla matrycy zawierającej jako materiał czujnikowy 21-członową...
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Biological fluids as a source of information on the exposure of man to envinonmental chemical agents.
PublicationWiele związków (min. lotne związki chlorowcoorganiczne, metale) ma szkodliwy wpływ na tkanki i narządy organizmu ludzkiego, wywołując nieodwracalne zmiany chorobowe. W celu określenia zagrożenia zawodowego coraz częściej wykonuje się pomiar stężeń substancji chemicznych i ich metabolitów w płynach biologicznych - moczu, krwi, rzadziej w mleku matki, żółci, ślinie, czy też spermie. Aby oznaczyć poziomy tych stężeń, pobrane próbki...
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Investigations of dissimilar stainless steels welded joints for chemical tankers construction
PublicationArtykuł przedstawia właściwości mechaniczne złączy różnoimiennych stali typu duplex oraz austenitycznej typu 316L otrzymanych za pomocą spawania automatycznego łukiem krytym. Wykazano możliwość wykorzystania wysokowydajnej metody SAW w miejsce dotychczas stosowanych metod GTAW i GMAW do spawania blach zbiorników statków do przewozu chemikaliów.
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Corrosion Inhibition of Aluminium Alloy AA6063-T5 by Vanadates: Local Surface Chemical Events Elucidated by Confocal Raman Micro-Spectroscopy
PublicationChemical interactions between aqueous vanadium species and aluminium alloy AA6063-T5 were investigated in vanadate-containing NaCl solutions. Confocal Raman and X-ray photoelectron spectroscopy experiments were utilised to gain insight into the mechanism of corrosion inhibition by vanadates. A greenish-grey coloured surface layer, consisting of V+4 and V+5 polymerized species, was seen to form on the alloy surface, especially on...
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Biogeochemistry of three different shallow gas systems in continental shelf sediments of the South-Eastern Baltic Sea (Gulf of Gdańsk): Carbon cycling, origin of methane and microbial community composition
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The impact of interactions between polyphenolic antioxidants on the redox-related chemical and biological properties of their mixtures – the extension of food synergy concept.
PublicationThe results of studies indicate that chemopreventive efficiency of isolated phytochemicals is lower than that of polyphenol-rich foods. This discrepancy has been ascribed to the food synergy concept that assumes additive or even synergistic influence of different food ingredients on human health. The results presented in the dissertation made it possible to propose an alternative and innovative explanation of these observations. The...
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Chemical variability of Rhododendron tomentosum (Ledum palustre) essential oils and their pro-apoptotic effect on lymphocytes and rheumatoid arthritis synoviocytes
PublicationRhododendron tomentosum (Ledum palustre) is an aromatic plant traditionally used for alleviating rheumatic complaints which makes it a potential candidate for a natural drug in rheumatoid arthritis (RA) treatment. However, the effects of plants’ volatiles on apoptosis of synovial fibroblasts and infiltrating leucocytes of RA synovia, have not been reported. Volatile fraction of R. tomentosum is chemically variable and chemotypes...
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Mater-Bi/Brewers’ Spent Grain Biocomposites—Novel Approach to Plant-Based Waste Filler Treatment by Highly Efficient Thermomechanical and Chemical Methods
PublicationThermoplastic starch (TPS) is a homogenous material prepared from native starch and water or other plasticizers subjected to mixing at a temperature exceeding starch gelatinization temperature. It shows major drawbacks like high moisture sensitivity, poor mechanical properties, and thermal stability. To overcome these drawbacks without significant cost increase, TPS could be blended with bio-based or biodegradable polymers and...
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Composition and In Vitro Effects of Cultivars of Humulus lupulus L. Hops on Cholinesterase Activity and Microbial Growth
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The X-ray photoelectron spectroscopy of surface composition of aged mixed copper manganese oxide catalysts
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Wheat bread enriched with raspberry and strawberry oilcakes: effects on proximate composition, texture and water properties
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Understanding element composition of medicinal plants used in herbalism—A case study by analytical atomic spectrometry
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Iron and other metal species as phase-composition controllers influencing the photocatalytic activity of TiO2 materials
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Composition engineering of Tb3-xGdxAl5-yGayO12:Ce single crystals and their luminescent, scintillation and photoconversion properties
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Stress-related expression of the chloroplast EGY3 pseudoprotease and its possible impact on chloroplasts’ proteome composition
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Investigations of changes in the arabinogalactan proteins (AGPs) structure, size and composition during the fruit ripening process
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Photocatalytic decomposition of benzo-[a]-pyrene on the surface of acrylic, latex and mineral paints. Influence of paint composition
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Effect of crystalline emulsifier composition on structural transformations of water-in-oil emulsions: Emulsification and quiescent conditions
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