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Search results for: EXHAUST GAS RECIRCULATION
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Selectivity of amperometric gas sensors in multicomponent gas mixtures
PublicationIn recent years smog and poor air quality became a growing environmental problem. There is a need to continuously monitor the quality of air. The lack of selectivity is one of the most important problems limiting the use of gas sensors for this purpose. In this study, a selectivity of the six amperometric gas sensors is being investigated. Calibration of sensors has been performed in order to find a correlation between concentration...
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Change of exhaust gases concentration for LSCNT modified SOFC fueled by biogas mixture at 750 C
Open Research DataThe dataset changes of exhaust gases concentrations (CH4,CO,CO2,H2) over working time for SOFC with La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-s layer. Concentrations were calculated based on the FTIR measurements and calibration files presented in coupled dataset.
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Gas sampling system for matrix of semiconductor gas sensors
PublicationSemiconductor gas sensors are popular commercial sensors applied in numerous gas detection systems. They are reliable, small, rugged and inexpensive. However, there are a few problem limiting the wider use of such sensors. Semiconductor gas sensor usually exhibits a low selectivity, low repeatability, drift of response, strong temperature and moisture influence on sensor properties. Sample flow rate is one of the parameters that...
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Analytical method of determining dynamic properties of thermocouples used in measurements of quick – changing temperatures of exhaust gases in marine diesel engines
PublicationThe article presents selected issues of mathematical modeling of heat exchange between the thermocouple and the exhaust gas flowing them, in unsteady conditions. On the way of energy balancing consideration of thermodynamic processes developed differential equations describing the dynamic properties for three versions of the design sheathed thermocouples: with weld isolated from the sheath, with weld welded the sheath and with...
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Gas selectivity enhancement by sampling-and-hold method in resistive gas sensors
PublicationCommercial resistive gas sensors exhibit various sensitivity to numerous gases when working at different elevated temperatures. That effect is due to a change in velocity of adsorption and desorption processes which can be modulated by temperature. Thus, to reach better selectivity of gas detection, we propose to apply a known method (called the sampling-and-hold method) of cooling down the gas sensor in the presence of the investigated...
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Power augmentation of PGE Gorzow's gas turbine by steam injection - thermodynamic overview
PublicationThe impact of steam injection upon a gas turbine and a combined power plant performance has been investigated. This article describes and summarizes possibilities of modification for current gas turbine in PGE Gorzow power plant into the Cheng cycle. Our modification deals with a thermal cycle, in which steam produced in a heat recovery steam generator is injected into the gas turbine's combustion chamber. It has been proved that...
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SAMPLE-AND-HOLDING METHOD FOR GAS SENSING APPLIED FOR RESISTANCE GAS SENSORS
PublicationThe DC resistance of a Taguchi gas sensor is influenced by the ambient gas. To improve the selectivity and sensitivity of a sensor the fluctuation enhanced sensing (FES) was used. The paper proposes a novel methodology of utilizing FES technique that sample composition of an ambient atmosphere and hold it for further processing (sample-and-holding technique). The method uses the heated gas sensor to sample an ambient atmosphere...
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Technical and Economic Analysis of the Supercritical Combined Gas-Steam Cycle
PublicationCombined cycle power plants are characterized by high efficiency, now exceeding 60%. The record-breaking power plant listed in the Guinness Book of World Records is the Nishi-Nagoya power plant commissioned in March 2018, located in Japan, and reaching the gross efficiency of 63.08%. Research and development centers, energy companies, and scientific institutions are taking various actions to increase this efficiency. Both the gas...
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Flicker Noise in Resistive Gas Sensors—Measurement Setups and Applications for Enhanced Gas Sensing
PublicationWe discuss the implementation challenges of gas sensing systems based on low-frequency noise measurements on chemoresistive sensors. Resistance fluctuations in various gas sensing materials, in a frequency range typically up to a few kHz, can enhance gas sensing by considering its intensity and the slope of power spectral density. The issues of low-frequency noise measurements in resistive gas sensors, specifically in two-dimensional...
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GRAPHENE IN GAS CHEMIRESISTORS
PublicationGraphene has a range of unique physical properties which could be exploited in gas sensing. Every atom of graphene may be considered as a surface atom, able to interact even with single molecule of the target gas or vapour species resulting in the ultrasensitive sensor response. In this paper the potential of graphene as a nanomaterial for fabricating chemiresistors was described. Recent development in graphene sensors was considered...
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Change of exhaust gases concentration for reference SOFC and SOFC with LSCNT layer fueled by biogas mixture at 750 C
Open Research DataThe dataset changes of exhaust gases concentrations (CH4,CO,CO2,H2) over working time for SOFC with La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-s layer as well as reference SOFEC (unmodified). Concentrations were calculated based on the FTIR measurements and calibration curves presented in different dataset. Longterm measurements of SOFC were performed using in-house...
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Gas Detection Using Resistive Gas Sensors And Radial Basis Function Neural Networks
PublicationWe present a use of Radial Basis Function (RBF) neural networks and Fluctuation Enhanced Sensing (FES) method in gas detection system utilizing a prototype resistive WO3 gas sensing layer with gold nanoparticles. We investigated accuracy of gas detection for three different preprocessing methods: no preprocessing, Principal Component Analysis (PCA) and wavelet transformation. Low frequency noise voltage observed in resistive gas...
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Investigation of the Combustion Processes in the Gas Turbine Module of an FPSO Operating on Associated Gas Conversion Products
PublicationIn this paper, we consider the issue of thermo-chemical heat recovery of waste heat from gas turbine engines for the steam conversion of associated gas for offshore vessels. Current trends in the development of offshore infrastructure are identified, and the composition of power plants for mobile offshore drilling units and FPSO vessels is analyzed. We present the results of a comparison of power-to-volume ratio, power-to-weight...
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Limited selectivity of amperometric gas sensors operating in multicomponent gas mixtures and methods of selectivity improvement
PublicationIn recent years, smog and poor air quality have became a growing environmental problem. There is a need to continuously monitor the quality of the air. The lack of selectivity is one of the most important problems limiting the use of gas sensors for this purpose. In this study, the selectivity of six amperometric gas sensors is investigated. First, the sensors were calibrated in order to find a correlation between the concentration...
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Energy requirements for methods improving gas detection by modulating physical properties of resistive gas sensors
PublicationAbstract. One of the most important disadvantage of resistive gas sensors is their limited gas selectivity. Therefore, various methods modulating their physical properties are used to improve gas detection. These methods are usually limited to temperature modulation or UV light irradiation for the layers exhibiting photocatalytic effect. These methods cause increased energy consumption. In our study we consider how much energy...
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Portable exhaled breath analyzer employing fluctuation-enhanced gas sensing method in resistive gas sensors
PublicationThis paper presents a portable exhaled breath analyser, developed to detect selected diseases. The set-up employs resistive gas sensors: commercial MEMS sensors and prototype gas sensors made of WO3 gas sensing layers doped with various metal ingredients. The set-up can modulate the gas sensors by applying UV light to induce physical changes of the gas sensing layers. The sensors are placed in a tiny gas chamber of a volume...
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The Effect of Oxygenated Diesel-N-Butanol Fuel Blends on Combustion, Performance, and Exhaust Emissions of a Turbocharged CRDI Diesel Engine
PublicationThe article deals with the effects made by using various n-butanol-diesel fuel blends on the combustion history, engine performance and exhaust emissions of a turbocharged four-stroke, four-cylinder, CRDI 1154HP (85 kW) diesel engine. At first, load characteristics were taken when running an engine with normal diesel fuel (DF) to have ‘baseline’ parameters at the two ranges of speed of 1800 and 2500 rpm. Four a fossil diesel (class...
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Extraction and evaluation of gas-flow-dependent features from dynamic measurements of gas sensors array
PublicationGas analyzers based on gas sensors are the devices which enable recognition of various kinds of volatile compounds. They have continuously been developed and investigated for over three decades, however there are still limitations which slow down the implementation of those devices in many applications. For example, the main drawbacks are the lack of selectivity, sensitivity...
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INVESTIGATION OF THE CHARACTERISTICS OF A LOWEMISSION GAS TURBINE COMBUSTION CHAMBER OPERATING ON A MIXTURE OF NATURAL GAS AND HYDROGEN
PublicationT his article is devoted to the investigation of the characteristics of a low-emission gas turbine combustion chamber, which can be used in Floating Production, Storage and Offloading (FPSO) vessels and operates on a mixture of natural gas and hydrogen. A new approach is proposed for modelling the processes of burning out a mixture of natural gas with hydrogen under preliminary mixing conditions in gaseous fuel with an oxidizer...
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Oil and Gas Geology
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Natural Gas Geoscience
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Medical Gas Research
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OIL & GAS JOURNAL
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Gas Science and Engineering
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Gas mixtures recognition using an array of amperometric gas sensors with drifting or faulty sensors
PublicationIn this study, the possibility of using selected methods for diagnostics of performance of matrix composed with six amperometric electrochemical gas sensors is investigated. Measurements of sensor responses in selected concentrations of single toxic gases or gas mixtures were performed and were repeated over time to show sensor drift. Additionally, the studies on the sensors’ drift were performed. The drift has been recognized...
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Hydrogen sulphide electrocatalytic gas sensor
PublicationIn this article measurement results of the electrocatalytic gas sensor in different concentrations of hydrogen sulphide are presented. Working principle of such sensor is based on electric current acquisition, while voltage ramp is applied to the sensor. During voltage sweep oxidation and reduction reactions occurs on the sensor electrodes. Obtained current-voltage plot has unique shape connected...
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Efficiency of linear and non-linear classifiers for gas identification from electrocatalytic gas sensor
PublicationElectrocatalytic gas sensors belong to the family of electrochemical solid state sensors. Their responses are acquired in the form of I-V plots as a result of application of cyclic voltammetry technique. In order to obtain information about the type of measured gas the multivariate data analysis and pattern classification techniques can be employed. However, there is a lack of information in literature about application of such...
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Devices for the production of reference gas mixtures
PublicationFor many years there has been growing demand for gaseous reference materials, which is connected with development in many fields of science and technology. As a result, new methodological and instrumental solutions appear that can be used for this purpose. Appropriate quality assurance/quality control (QA/QC) must be used to make sure that measurement data are a reliable source of information. Reference materials are a significant...
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Transportable, Portable and Micro Gas Chromatographs
PublicationSignificant benefits can be obtained by miniaturization of conventional benchtop gas chromatographs. The attractive features arising from miniaturization include low-power requirements, low heat capacity of separation columns, low consumption of mobile phase, enhanced performance, higher portability, and easily coupling to detectors and secondary chromatographic systems. In separation sciences, including gas phase separations,...
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Fluctuation enhanced gas sensing with WO3-based nanoparticle gas sensors modulated by UV light at selected wavelengths
PublicationThe sensitivity and selectivity of WO3-based gas sensors can be enhanced by UV-irradiation-induced modulation, especially if different wavelengths are employed. We used fluctuation-enhanced gas sensing, based on measurements of resistance fluctuations in the gas sensor, to study the effects of such modulation on the noise intensity for ambient atmospheres of synthetic air without and with additions of small amounts of ethanol,...
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Quantum dots in gas sensing a review
PublicationAir pollution becomes an increasing problem in the recent years. There is a need to develop more sensitive gas sensors. Much effort has been performed to develop different types of gas sensors, such as electrochemical sensors or polymer sensors. One of the most promising approaches to improve sensors performance is the application of the nanostructures as sensing materials. State of the art of quantum...
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Real-time working gas recognition system based on the array of semiconductor gas sensors and portable computer Raspberry PI
PublicationThe gas-analyzing systems based on the array of partially selective gas sensors and pattern-recognition techniques are potentially fast and low-cost alternative for other devices, like gas analysers. They give the possibility of recognition the type and the concentration of measured volatile compounds in their working environment. In this work we present the implementation of gas recognition system, in which the signals from an...
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The Impact of Material Selection on Durability of Exhaust Valve Faces of a Ship Engine – A Case Study
Publicationwo alloys were used in order to extend the service life of marine engine exhaust valve head. Layers of cobalt base alloys were made of the powders with with chemical composition as follow: the layer marked L12; C-1,55%; Si-1,21%; Cr-29,7%; W-9%; Ni-2%; Mo<0,01%; Fe-1,7%; Co-54,83% and the layer marked N; C-1,45%; Co-38,9%; Cr-24,13%; Ni-10,43%; W-8,75%; Fe-7,64%; Mo-7,56%; Si-2,59%. Base metal was valve steel after heat treatment....
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GAS SENSORS WITH TEMPERATURE MODULATION – AN OVERVIEW
PublicationAlthough different methods of improving semiconductor gas sensor properties have been proposed, a technique involving temperature modulation seems to be the most promising. Semiconductor gas sensors working with modulated temperature can be more stable and are more selective comparing with sensor working at one temperature. In this paper, various approaches to temperature modulation are reviewed.
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AUTOMATED SYSTEM FOR FLUCTUATION ENHANCED GAS SENSING
PublicationResistance gas sensors exhibit random phenomena (resistance noise) which can be utilized to improve gas sensitivity and selectivity. That new emerging technique has to be investigated to recognize optimal parameters for gas detection. It means that a measurement system has to have ability of numerous parameters adjustment (e.g., sampling frequency, heater voltage, polarization current, voltage noise amplification). That fact induced...
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Perforating systems in shale gas recovery
PublicationHydraulic fracturing is common method of shale gas recovery. Due to environmental, economical and technological problems many alternative technologies have been developed. One of the most promising group of technologies is based on perforating systems. This paper describes theoretical and practical aspects of best known technologies used to create perforations. New perforating/fracturing technologies which can replace hydraulic fracturing...
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Electrocatalytic gas sensor with reference layer
PublicationIn recent years electrochemical gas sensors based on solid state electrolytes have been intensively developed. They are easy to obtain, use and relative durable. Nasicon is one of the most promising materials, which have been used in construction of gas sensors. Most of these devices work in potentiometric or amperometric mode. However, some works are dedicated to sensors working in electrocatalytic mode. Principle of operation...
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APPLICABILITY OF INLET AIR FOGGING TO MARINE GAS TURBINE
PublicationThe dependency of marine gas turbine on the ambient temperature leads to a decrease of the gas turbine power output in arid areas. Very often gas turbine power output demand is high and the power margins originally designed into the driver , has been exhausted. In such circumstances the inlet air fogging is an effective compensation of gas turbine power. In this paper an analysis of inlet air fogging applicability to marine gas...
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Dopants and gas modifiers in ion mobility spectrometry
PublicationThe ion mobility techniques, including the most commonly used drift-tube ion mobility spectrometry (IMS) and differential mobility spectrometry (DMS), are used successfully for the detection of a wide range of organic compounds in the gas phase. In order to improve detection quality, admixtures are added to gas streams flowing through the detector. Dopants mostly prevent the ionization of interfering chemicals however, better detection...
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Design Analysis of Micro Gas Turbines in Closed Cycles
PublicationThe problems faced by designers of micro-turbines are connected with a very small volume flow rate of working media which leads to small blades’ height and high rotor speed. In the case of gas turbines this limitation can be overcome by the application of a closed cycle with very low pressure at the compressor inlet (lower than atmospheric pressure). In this way we may apply a micro gas turbine unit of accepted efficiency to work...
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Exhaled breath analysis by resistive gas sensors
PublicationBreath analysis has attracted human beings for centuries. It was one of the simplest methods to detect various diseases by using human smell sense only. Advances in technology enable to use more reliable and standardized methods, based on different gas sensing systems. Breath analysis requires the detection of volatile organic compounds (VOCs) of the concentrations below individual ppm (parts per million). Therefore, advanced detection...
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Sulfur compounds: Gas chromatography
PublicationSulfur compounds, due to their properties, are responsible for the damage of our environment. For this reason sulfur containing compounds are of constant concern in many fields. Gas chromatography (GC), due to combination of separation capability and sensitive detection is a prime technique for the analysis of thes compounds in various matrices. The chapter rewies general problems of the determination of these compounds by GC and...
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New developments in preparation and use of standard gas mixtures
PublicationStandard gas mixtures are commonly applied in all stages of analytical work related to the analysis of gaseous samples. Numerous techniques for generating standard gas mixtures are in use. In this article, we present new developments regarding the production of standard gas mixtures, with particular focus on improvements in the application of dynamic techniques for generating them. Furthermore, we describe the application of new...
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VOCs absorption from gas streams using deep eutectic solvents – A review
PublicationVolatile organic compounds (VOCs) are one of the most severe atmospheric pollutants. They are mainly emitted into the atmosphere from anthropogenic sources such as automobile exhaust, incomplete fuel combustion, and various industrial processes. VOCs not only cause hazards to human health or the environment but also adversely affect industrial installation components due to their specific properties, i.e., corrosive and reactivity....
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Behavior of the exhaust valve cladding face under the service conditions
PublicationPodczas eksploatacji silnika okrętowego kluczowym problemem jest trwałośc zaworów wylotowych a w szczególności wąskiego fragmentu - przylgni grzybka zaworu, która decyduje o szczelności zaworu.Przylgnia wykonana przez laserowe napawanie stopu kobaltu została poddana badaniom w warunkach normalnej eksploatacji silnika L22 przez 2 lata. W tym czasi silnik był zasilany zarówno paliwem lekkim jak i biopaliwem. Po zdemontowaniu głowicy...
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Resistive gas sensors – Perspectives on selectivity and sensitivity improvement
PublicationResistive gas sensors are very popular and relatively inexpensive; they can operate at elevated or room temperature for years on end. The main disadvantage of resistive gas sensors is their limited selectivity and sensitivity, but various methods have been applied to improve their behavior. The composition of the porous gas sensing layer, or changes in the sensor’s operating temperature, can enhance the gas detection ability. Furthermore, emerging...
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FTIR spectra of gas mixtures from the methanation chamber filled with 50-50wt.% NiO-Al2O3
Open Research DataThe dataset includes the FTIR spectra collection of the outlet gas mixtures (CO2, CO, CH4) from reactor chamber filled with 50/50 wt.% NiO-Al2O3 catalyst for perfoming methanation reaction. The inlet gas mixture was composed of 3:1 by vol. H2:CO. Spectra were collected using PerkinElmer FTIR every 1 min.
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FTIR spectra of gas mixtures from the methanation chamber filled with 25-75wt.% NiO-Al2O3
Open Research DataThe dataset includes the FTIR spectra collection of the outlet gas mixtures (CO2, CO, CH4) from reactor chamber filled with 25/75 wt.% NiO-Al2O3 catalyst for perfoming methanation reaction. The inlet gas mixture was composed of 3:1 by vol. H2:CO. Spectra were collected using PerkinElmer FTIR every 1 min.
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Design analysis of combined gas-vapour micro power plant with 30 kW air turbine
PublicationThe article presents basic results of the design analysis of a combined gas-vapour micro power plant with a waste-heat boiler without exhaust reheat, working in the vapour section in the Organic Rankine Cycle (ORC) system. The analysis concerned working media most frequently used in those types of power plants and planned to be used in future. The object of the analysis was a micro power plant with a 30 kW gas (air) turbine for...
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Design analysis of combined gas-vapour micro power plant with 30 kW air turbine
PublicationThe article presents basic results of the design analysis of a combined gas-vapour micro power plant with a waste-heat boiler without exhaust reheat, working in the vapour section in the Organic Rankine Cycle (ORC) system. The analysis concerned working media most frequently used in those types of power plants and planned to be used in future. The object of the analysis was a micro power plant with a 30 kW gas (air) turbine for...