displaying 1000 best results Help
Search results for: ARENE RUTHENIUM COMPLEX
-
Post-Activation Performance Enhancement: Save Time With Active Intra-Complex Recovery Intervals
Publication -
Influence of hydrophobic nanosilica and hydrophobic medium on water bound in hydrophilic components of complex systems
Publication -
Comprehensive two-dimensional gas chromatography - promising technique for analysis of complex food matrices
PublicationThe present paper is focused on brief description of operational principle of comprehensive two-dimensional gas chromatography (GC×GC) technique, instrumentation and data processing. Furthermore, the examples of application in the field of food analysis, performed also in the author's laboratory, are given. The detailed discussion of GC×GC characterization and comparison of the volatile composition of berries of different blue...
-
Networked Object Monitor - A distributed system for monitoring, diagnostics and control of complex industrial facilities
PublicationRozwój mobilności i technologii internetowych, a także globalizacji gospodarki światowej, uwzględniający kluczowe aspekty zarządzania przepływem informacji, otworzył zupełnie nowe możliwości opracowywania i konstruowania innowacyjnych rozwiązań technicznych. Z taką myślą powstał prototyp Sieciowego Monitora Obiektu, aplikacji umożliwiającej nie tylko ciągłą kontrolę parametrów obiektów przemysłowych i biznesowych, ale również zarządzanie...
-
Distribution of relaxation times as a method of separation and identification of complex processes measured by impedance spectroscopy
PublicationImpedance spectroscopy is one of the most commonly performed measurements to characterize electronic and electrochemical systems. Impedance spectra have limited resolution and many different processes may overlap what could be the reason of obstructions in its proper later analysis. Up to date, there are three approaches to solve this problem: examining impedance spectra itself, fitting spectra with equivalent circuits, and calculating...
-
Lower Rim Substituted tert-Butyl Calix[4]arenes (Part IV). Calix[4]arene-Crown Ethers as Ionophores in Plasticized PVC-membrane electrodes.
PublicationPrzedstawiono syntezę i charakterystykę trzech p-tert-butylokaliks[4]aren-koron-4, -5, -6 (związki 2 - 4 o różnej długości łańcucha polyoksaetylenowego łączącego distalne grupy OH). Syntezowane związki wykazują wysoką selektywność na kationy sodu, potasu lub cezu. Badano zależność pomiędzy stereochemiczną strukturą tych ligandów, a wyznaczonymi potencjometrycznie współczynnikami selektywności oraz wyznaczonymi stałymi trwałości...
-
TD (trans-disciplinarity) as a conceptual research approach to address complex collective action problems in governance and planning research
e-Learning Courses -
Reactivity study of a β-diketiminate titanium(III) complex with a phosphanylphosphido ligand towards chlorophosphanes. A new method of synthesis of β-diketiminate titanium(IV) complexes with versatile phosphanylphosphinidenes
PublicationThe reactivity of ab-diketiminate titanium(III) complex with a phosphanylphosphido ligand, [MeNacNacTi(Cl){g2-P(SiMe3)-PtBu2}] (1)(MeNacNac= [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr2Ph), was investigatedtowards selected chlorophosphanes, such astBu2PCl,iPr2PCl, Cy2PCl, (Cy)tBuPCl, (Me)tBuPCl, (Ph)tBuPCl, Ph2PCl, (iPr2N)tBuPCl and (Et2N)2PCl. The reactions withtBu2PCl and Ph2PCl lead mainly to theearlier described complex [MeNacNacTi(Cl){g2-P-PtBu2}]...
-
Reactions of cobalt(ii) chloride and cobalt(ii) acetate with hemisalen-type ligands: ligand transformation, oxidation of cobalt and complex formation. Preliminary study on the cytotoxicity of Co(ii) and Co(iii) hemisalen complexes
PublicationSeveral molecular cobalt(II) complexes, one Co(II) coordination polymer, and one ionic cobalt(III) complex with imine hemisalen ligands were synthesized. The hemisalen ligands were synthesized from o-vanillin (oVP) and diverse aminopyridines (compounds HL1–HL4) or aminophenol (compound HL5). It was observed that cobalt(II) chloride in dry acetonitrile catalyzes a transformation of HL1 and HL3 instead of complex formation. The conversion...
-
Preparation and evaluation of 1,3-alternate 25,27-dibenzyloxy-26,28-bis-[3-propyloxy]-calix[4]arene - bonded silica stationary phase for high performance liquid chromatography
PublicationOtrzymano nową fazę stacjonarną na bazie dibenzyloksy pochodnej kaliks[4]arenu w konformacji 1,3-naprzemianległej, chemicznie związaną z żelem krzemionkowym. Przeprowadzano badania selektywności i sprawności tej fazy w rozdzielaniu izomerów konstytucyjnych benzenu i pochodnych fenoli. Zaprezentowano wyniki badania wpływu pH fazy ruchomej oraz stężenia metanolu na zdolność rozdzielczą nowej fazy stacjonarnej.
-
Preparation and HPLC evaluation of a new 1,3-alternate 25,27-bis-[p-chlorobenzyloksy]26,28-bis-[3-propyloxy]-calix[4]arene silica bonded stationary phase
PublicationPrzeprowadzono syntezę nowej fazy stacjonarnej HPLC na bazie pochodnej 25,27-bis-[p-chlorobenzyloksy]26,28-bis-[3-propyloksy]-kaliks[4]arenu zablokowanego w konformacji 1,3-naprzemianległej. Zbadano selektywność i sprawność fazy w stosunku do aromatycznych izomerów pozycyjnych, alkilobenzenów, WWA, sulfonamidów i niesterydowych leków przeciwbólowych.
-
Preparation and evaluation of 1,3-alternate 25,27-bis[p-nitrobenzyloxy]-26,28-bis[3-propyloxy]-calix[4]arene-bonded silica gel stationary phase for LC
PublicationPrzeprowadzono syntezę nowej fazy stacjonarnej na bazie sililowej pochodnej 25,27-bis[p-nitrobenzyloksy]-26,28-bis-[3-propyloksy]kaliks[4]arenu zablokowanego w konformacji 1,3-naprzemianległej. Zbadano selektywność i sprawność fazy w stosunku do szeregu klas związków organicznych techniką wysokosprawnej chromatografii cieczowej.
-
Evaluation of the possibility of identifying a complex polygonal tram track layout using multiple satellite measurements
Publication -
Molecular dynamics simulation and MM-PBSA analysis of Oxytricha nova TEBP ternary complex with ssDNA
PublicationPraca dotyczy badań metodami chemii obliczeniowej właściwości elektrostatycznych i termodynamicznych kompleksu telomerowego białka TEBP pochodzącego z organizmu Oxytricha z jednoniciowym telomerowym DNA (ssDNA).
-
Adsorption of a metalorganic complex at a metal surface: A density functional theory study vs. model description
Publication -
A total scoring system and software for complex modified GAPI (ComplexMoGAPI) application in the assessment of method greenness
PublicationEvaluating analytical methods with innovative metrics is essential to ensure the effectiveness of analytical procedures. Various approaches have been proposed to assess the performance of an analytical method and its environmental consequences, as sustainable environment and green chemistry ideology are of high importance nowadays. Considering greenness evaluation of developed analytical procedures, Green Analytical Procedure Index...
-
SERRATE interacts with the nuclear exosome targeting (NEXT) complex to degrade primary miRNA precursors in Arabidopsis
Publication -
Visualizing the macroscale spatial distributions of biofilms in complex flow channels using industrial computed tomography
Publication -
Poly(amidoamine) Dendrimer/Camptothecin Complex: From Synthesis to In Vitro Cancer Cell Line Studies
Publication -
<title>Multi-cavity complex controller with vector simulator for TESLA technology linear accelerator</title>
Publication -
An investigation on the chemistry of the R2P=P ligand: reactions of a phosphanylphosphinidene complex of tungsten(VI) with electrophilic reagents
PublicationThe nucleophilic properties of the title compound [(2,6-i-Pr2C6H3N)2(Cl)W(η2-t-Bu2PvP)]Li·3DME (1) were investigated in reactions with selected electrophilic reagents such as MeI, M(CO)5THF (M = Cr, Mo, W), AlCl3, and GaCl3. Methylation of 1 by MeI yields phosphanylphosphido complexes [(2,6-i-Pr2C6H3N)2W(X)(1,2-η-t-Bu2PvP–CH3)] (X = Cl, I) (2-Cl/2-I) with the formation of a new P–C bond. Moreover, 1 reacts with electrophilic compounds...
-
Green Therapy w projektowaniu ośrodków medycznych Green Therapy in complex design of health centres
PublicationKoncepcja przestrzenna ogrodu terapeutycznego podporządkowana jest generalnej idei otwierania się projektantów na poszukiwanie nowych możliwości poprawy samopoczucia odbiorcy - poprzez zapewnienie użytkownikom poczucia bezpieczeństwa, komfortu i odprężenia, harmonii. Dotyczy to nie tylko grupy osób chorych, które dręczone są przez niepokoje i napięcia wywołane przez niepełnosprawność czy chorobę, ale także pacjentów w różnym wieku...
-
Port Cities within Port Regions: Shaping Complex Urban Environments in Gdańsk Bay, Poland
PublicationPort cities located within various metropolitan or functional regions face very different development scenarios. This applies not only to entire municipalities but also to particular areas that play important roles in urban development—including ports as well as their specialized parts. This refers also to the various types of maritime industries, including the processing of goods, logistics operations, shipbuilding, or ship repairing,...
-
Reactions of (Ph)tBuP-P(SiMe3)Li·3THF with [(PNP)TiCl2] and [MeNacNacTiCl2·THF]. Synthesis of first PNP titanium(IV) complex with phosphanylphosphinidene ligand [(PNP)Ti(Cl){η2-P-P(Ph)tBu}]
PublicationLithium derivative of diphosphane (Ph)tBuP-P(SiMe3)Li (1) was isolated for the first time and investigated in reactions with β-diketiminate (MeNacnac− = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr2C6H3) and PNP-pincer (PNP = N[2-PiPr2-4-methylphenyl]2) Ti(III) complexes. The β-diketiminate titanium(III) complex containing phosphanylphosphido ligand [MeNacNacTi(Cl){η2-P(SiMe3)-P(Ph)tBu}] (2) was prepared in reaction of [MeNacNacTiCl2·THF]...
-
FRACTALS-COMPLEX GEOMETRY PATTERNS AND SCALING IN NATURE AND SOCIETY
Journals -
Lower rim substituted p-tert-Butylcalix[4]arenes: Part XI. New ester derivatives of calix[4]arene, their ionophoric properties and x-ray structure studies
PublicationPrzedstawiono syntezę 6-ciu nowych estrowych pochodnych kaliks[4]arenuw konformacji stożkowej. Pierwsze badania kompleksowania jonów metali przeprowadzone w membranach elektrod jonoselektywnych (ISE) potwierdziły kompleksowanie jonów sodu w sposób selektywny. Zaprezentowano strukturę rentgenowską monokryształów związku 6.
-
Complex modulus of Cement Bitumen Treated Material Mixture C3E4 laboratory mixed/laboratory compacted (7-365 days of curing at 20C)
Open Research DataDataset presents data of complex modulus determined for cold recycled mixture – cement bitumen treated material mixture with following binding agents: 3% cement, 4% emulsion (C3E4). Mixture was designed according to Polish requirements for the base course of pavement. Mixture was mixed in laboratory conditions on the basis of materials obtained from...
-
Complex modulus of Cement Bitumen Treated Material Mixture C3E4 field mixed/laboratory compacted (7-365 days of curing at 20C)
Open Research DataDataset presents data of complex modulus determined for cold recycled mixture – cement bitumen treated material mixture with following binding agents: 3% cement, 4% emulsion (C3E4). Mixture was designed according to Polish requirements for the base course of pavement. Mixture was mixed in the field conditions and later compacted in laboratory. Mixture...
-
LED Light Sources and Their Complex Set-Up for Visually and Biologically Effective Illumination for Ornamental Indoor Plants
PublicationOrnamental plants are often used in indoor environments as part of biophilic design to improve the health and wellbeing of occupants, and to support sustainable, green architecture. Unfortunately, many plants do not thrive and need to be continuously replaced, which is economically unsustainable. The wavelengths and spectrum ratio of commonly used light sources such as light emitting diode (LED), and the lack of an appropriate...
-
Estimation of time-frequency complex phase-based speech attributes using narrow band filter banks
PublicationIn this paper, we present nonlinear estimators of nonstationary and multicomponent signal attributes (parameters, properties) which are instantaneous frequency, spectral (or group) delay, and chirp-rate (also known as instantaneous frequency slope). We estimate all of these distributions in the time-frequency domain using both finite and infinite impulse response (FIR and IIR) narrow band filers for speech analysis. Then, we present...
-
Buffer contribution to formation enthalpy of copper(II)–bicine complex determined by isothermal titration calorimetry method
Publication -
Crystal structure and isothermal titration calorimetry studies of new cobalt(II) complex with 2-methylnitrilotriacetate ion
Publication -
Analysis of spectral data by complementary methods. Inspection of the molecular complex in N,N-dimethylformamide - methanol mixtures
PublicationDane widmowe FTIR mieszanin N,N-dimetyloformamidu z metanolem poddano anlizie faktorowej oraz analizie metodą ważonych widm różnicowych. Przydatność obu metod analizy w odniesieniu do układów z wiązaniem wodorowym poddano krytycznej dyskusji. Stwierdzono obecność kompleksu molekularnego typu 1:1 w całym zakresie składów mieszanin. Forma tego kompleksu zależy jednak od składu roztworu. Postulowano występowanie słabych wiązań wodorowych...
-
Formation of 2-chloroallyl alcohol oligomers using a new crystalline dipicolinate complex of Cr(III) as a catalyst
Publication -
The application of checklists in the field of complex operation based on the operating experiences of a liquefied petroleum gas handling simulator.
PublicationOmówiono pojęcie list sprawdzających (z ang. checklists). Podano charakterystykę techniczną symulatora operacji ładunkowych gazowca typu LPG znajdującego się w laboratorium Katedry Siłowni Okrętowych Akademii Morskiej w Gdyni wraz z jego możliwościami dydaktycznymi. Przedstawiono zasady tworzenia list sprawdzających czynności obsługowe wraz z przykładem takiej listy.
-
Immunomodulatory and antibacterial effect of red wine concentrate rich in a natural complex of polyphenols under diabetes mellitus
Publication -
A concerted evolution of supramolecular interactions in a {cation; metal complex; π-acid; solvent} anion-π system
Publication -
Evaluation of electrical parameters of traction supply system for complex railway traffic conditions, using simulation methods
PublicationDevelopment of electrified transport systems, railways modernization, expansion of urban transport networks, purchases of modern rolling stock causes that updating of electric traction supply system is necessary. This chapter presents an effective method for electrical parameters of traction supply system evaluation, using simulation methods.
-
Yield surface identification of CP-Ti and its evolution reflecting pre-deformation under complex loading
Publication -
Acute Effects of Complex Conditioning Activities on Athletic Performance and Achilles Tendon Stiffness in Male Basketball Players
Publication -
Hierarchical porous carbon materials from nanosized metal-organic complex for high-performance symmetrical supercapacitor
Publication -
CCDC151 Mutations Cause Primary Ciliary Dyskinesia by Disruption of the Outer Dynein Arm Docking Complex Formation
Publication -
Complex Corrosion Properties of AISI 316L Steel Prepared by 3D Printing Technology for Possible Implant Applications
Publication -
A high-accuracy complex-phase method of simulating X-ray propagation through a multi-lens system
PublicationThe propagation of X-ray waves through an optical system consisting of many X-ray refractive lenses is considered. For solving the problem for an electromagnetic wave, a finite-difference method is applied. The error of simulation is analytically estimated and investigated. It was found that a very detailed difference grid is required for reliable and accurate calculations of the propagation of X-ray waves through a multi-lens...
-
Efficient and Systematic Solution of Real and Complex Eigenvalue Problems Employing Simplex Chain Vertices Searching Procedure
PublicationW artykule zaprezentowano nowatorską metodę, pozwalającą w bardzo efektywny sposób rozwiązywać rzeczywiste i zespolone zagadnienia własne (które przekształcić można w równania nieliniowe) często spotykane w elektrodynamice obliczeniowej. Idea metody oparta jest o śledzenie miejsc zerowych otrzymanego równania nieliniowego. W proponowanej technice zastosowano regularne wielościany, budując z nich łańcuch (ścieżkę) poszukiwanych...
-
Improving the Accuracy of Automatic Reconstruction of 3D Complex Buildings Models from Airborne Lidar Point Clouds
PublicationDue to high requirements of variety of 3D spatial data applications with respect to data amount and quality, automatized, effcient and reliable data acquisition and preprocessing methods are needed. The use of photogrammetry techniques—as well as the light detection and ranging (LiDAR) automatic scanners—are among attractive solutions. However, measurement data are in the form of unorganized point clouds, usually requiring transformation...
-
Rafał Łangowski dr inż.
PeopleRafał Łangowski received the M.Sc. and the Ph.D. degrees (Hons.) in control engineering from the Faculty of Electrical and Control Engineering at the Gdańsk University of Technology in 2003 and 2015, respectively. From 2007 to 2014, he held the specialist as well as manager positions at ENERGA, one of the biggest energy enterprises in Poland. He is currently an Assistant Professor with the Department of Intelligent Control and...
-
Lower rim substituted tert-butylcalix[4]arenes (Part VI). Synthesis and ionophoric properties of 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis(3-diethoxyphosphorylpropoxy)calix[4]arene.
PublicationSyntezowano nowy związek: 5,11,17,23-tetra-tert-butylo-25,26,27,28-tetrakis(3-dietoksyfosforylopropoksy)kaliks[4]aren i badano jego właściwości kompleksujące w membranowych elektrodach jonoselektywnych. Związek wykazuje selektywność na jony wapnia oraz na kationy litu. Wyznaczono stałe tworzenia kompleksów z wymienionymi jonami w membranie elektrody.
-
An facile Fortran-95 algorithm to simulate complex instabilities in three-dimensional hyperbolic systems
Open Research DataIt is well know that the simulation of fractional systems is a difficult task from all points of view. In particular, the computer implementation of numerical algorithms to simulate fractional systems of partial differential equations in three dimensions is a hard task which has no been solved satisfactorily. Here, we provide a Fortran-95 code to solve...
-
Development of an orbital shaker-assisted fatty acid-based switchable solvent microextraction procedure for rapid and green extraction of amoxicillin from complex matrices: Central composite design
PublicationIn this study, a cheap, fast and simple orbital shaker-assisted fatty acid-based switchable solvent microextraction (OS-FASS-ME) procedure was developed for the extraction of amoxicillin (AMOX) in dairy products, pharmaceutical samples and wastewater prior to its spectrophotometric analysis. Fatty acid-based switchable solvents were investigated for extracting AMOX. The key factors of the OS-FASS-ME procedure were optimized using...