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Search results for: methanol steam reforming
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Microwave plasma application in decomposition and steam reforming of model tar compounds
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Selective H2 production from plastic waste through pyrolysis and in-line oxidative steam reforming
PublicationThis study deals with the proposal of pyrolysis and in-line oxidative steam reforming (P-OSR) for plastic waste valorization and assesses the potential of this strategy for the selective production of H2. Overall, the study aims at progressing towards the fine-tuning of the pyrolysis-reforming technology by co-feeding O2. Thus, a multi-point O2 injection system has been developed to ensure a suitable O2 distribution in the reforming...
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Effect of small quantities of potassium promoter and steam on the catalytic properties of nickel catalysts in dry/combined methane reforming
PublicationCarbon dioxide and methane are two of the principal greenhouse gases. Reduction of their content in the atmosphere is currently the subject of much worldwide research. Dry and combined reforming of methane are effective methods of CO2 and CH4 utilization and production of synthesis gas (syngas) in chemical technology. Testing of catalysts that provide the desired H2/CO ratio and long operation time is one of the critical aspects...
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Structural and catalytic properties of ceria layers doped with transition metals for SOFCs fueled by biogas
PublicationThe aim of this paper was to investigate an influence of the nanocrystalline Ce0.8A0.2O2-δ (A = Mn, Fe, Co, Ni, Cu) materials on the direct internal reforming of biogas in SOFC. Structural analysis of fabricated compounds has been done. An in-situ analysis of a composition of outlet gases from operating SOFC was performed using FTIR spectroscopy with simultaneous electrical tests. It was found out, that type of dopant strongly...
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Influence of steam cooking on pro-health properties of Small and Large variety of Momordica charantia
PublicationSteam cooking is one of the most common preparations of Momordicacharantia dishes. This method improved the tastiness of the fruits but at the same time, some changes occurred in the volatile and non-volatile parts of their food matrices. In this study, for the first time these properties were correlated with the found substances affecting the bioactivity of this fruit. Two varieties of Momordicacharantia were analysed and compared....
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Reduction of CO2 Emissions from Offshore Combined Cycle Diesel Engine-Steam Turbine Power Plant Powered by Alternative Fuels
PublicationDiverse forms of environmental pollution arise with the introduction of materials or energy that exert adverse effects on human health, climate patterns, ecosystems, and beyond. Rigorous emission regulations for gases resulting from fuel combustion are being enforced by the European Union and the International Maritime Organization (IMO), directed at maritime sectors to mitigate emissions of SOx, NOx, and CO2. The IMO envisions...
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Hydrogen production from biomass using dark fermentation
PublicationHydrogen applicability in the power, chemical and petrochemical industries is constantly growing. Efficientmethods of hydrogen generation from renewable sources, including waste products, are currently being de-veloped, even though hydrogen is mainly produced through steam reforming or thermal cracking of natural gasor petroleum fractions. In paper alternative methods of hydrogen production with a particular emphasis on darkfermentation...
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Performance of the PEM fuel cell module. Part 2. Effect of excess ratio and stack temperature
PublicationThe paper describes a fuel cell based system performance under different thermal conditions. The system could be fed with bottled hydrogen or with very high purity hydrogen obtained from reforming of methanol. The system is based on two fuel cell units (1.2 kW each, produced by Ballard Power Systems Inc. and called Nexa), DC/DC converter, DC/AC inverter, microprocessor control unit, load unit, bottled hydrogen supply system and...
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Nanostructure of the laser-modified transition metal nanocomposites for water splitting
PublicationAlthough hydrogen is considered by many to be the green fuel of the future, nowadays it is primarily produced through steam reforming, which is a process far from ecological. Therefore, emphasis is being put on the development of electrodes capable of the efficient production of hydrogen and oxygen from water. To make the green alternative possible, the solution should be cost-efficient and well processable, generating less waste...
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Biowodór, „paliwo przyszłości”, dotychczasowe metody otrzymywania , porównanie metod otrzymywania
PublicationWodór jest ważnym pierwiastkiem w przemyśle chemicznym. Biowodór wydaje się być użytecznym odnawialnym nośnikiem energii, który mógłby zastąpić paliwa kopalne. Największym problemem wodoru jest jego rzadkie występowanie w czystej formie molekularnej H 2 . Dlatego otrzymanie biowodoru w objętościach opłacalnych ja ko surowiec czy biopaliwo wiedzie przez bioodpady „przesycone” wodorem. Każdy związek...
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Fundamentals of Steam and Gas Turbines OASIV
e-Learning CoursesApplication of turbines in industry and sea power plants. Basic thermodynamics and fluid flow mechanics in turbomachinery. Steam turbine power cycle and plants. Gas turbine power cycle and plants. Turbine blading systems operation.
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Remarks on steam condensation modeling related to steam turbine large output
PublicationIn the paper numerical simulations have been performed to predict the performance of the diferent steam models. All of the considered models of steam condensation have been validated on the base of benchmark experiment employing expansion in nozzle and next on the low pressure part of the steam turbine equipped with the so-called Baumann stage. For numerical analysis three models have been finally used - the ideal steam model without...
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Reforming the University
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Novel sugar-based nickel-tungsten carbide catalysts for dry reforming of hydrocarbons
PublicationThe search for new materials for dry reforming of hydrocarbons with high activity, stability, and ease of synthesis is still one of the main directions of research in the field of heterogeneous catalysis. Traditional methods of carbide synthesis require the use of combustible gases of petrochemical origin. The search for new catalysts based on renewable and safe carbon sources is highly demanded. Therefore, we report WC and Ni-WC...
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Development of Gas Sensor Array for Methane Reforming Process Monitoring
PublicationThe article presents a new method of monitoring and assessing the course of the dry methane reforming process with the use of a gas sensor array. Nine commercially available TGS chemical gas sensors were used to construct the array (seven metal oxide sensors and two electrochemical ones). Principal Component Regression (PCR) was used as a calibration method. The developed PCR models were used to determine the quantitative parameters...
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A concept of zero-dimensional and three-dimensional thermodynamic modelling of steam storage in a steam cycle
PublicationThis work presents the thermodynamic model of steam storage in a steam cycle. The innovative steam storage is an integral part of the unit and thus responds quickly to changes in load. This enhances the primary control reserve while maintaining high efficiency of energy conversion. With regard to power plants, it improves the operational safety of generation units, as it prevents boiler and turbines overload in the case of steep...
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Absolute Photoabsorption Cross-Sections of Methanol for Terrestrial and Astrophysical Relevance
PublicationWe investigate the methanol absorption spectrum in the range 5.5–10.8 eV to provide accurate and absolute cross-sections values. The main goal of this study is to provide a comprehensive analysis of methanol electronic-state spectroscopy by employing high-resolution vacuum ultraviolet (VUV) photoabsorption measurements together with state-of-the-art quantum chemical calculation methods. The VUV spectrum reveals several new features...
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A novel concept of H2/O2 steam generator
PublicationThis paper presents an idea of hydrogen utilization to steam generation to drive a turbine and produce electricity or to supply a condenser as an element of a heating system. Electrolysis process is considered as a source of hydrogen as well as oxygen. Hydrogen combustion with a stoichiometric ratio of pure oxygen produces steam at very high temperature. Steam temperature can be controlled by mixing the generated steam with liquid...
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A NOVEL CONCEPT OF H2/O2 STEAM GENERATOR
PublicationThis paper presents an idea of hydrogen utilization to steam generation to drive a turbine and produce electricity or to supply a condenser as an element of heating system. Electrolysis process is considered as a source of hydrogen as well as oxygen. Hydrogen combustion with a stoichiometric ratio of pure oxygen produces steam at very high temperature. Steam temperature can be controlled by mixing the generated steam with liquid...
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Investigation of functional layers of solid oxide fuel cell anodes for synthetic biogas reforming
PublicationSolid oxide fuel cells (SOFCs) are one of the most promising energy conversion devices due to their high efficiency, low pollution and fuel flexibility. Unfortunately, when hydrocarbons are used as a fuel, for example in the form of a biogas, solid carbon can deposit on the anode surface. This process leads to the degradation of the fuel cell performance. A possible solution to this problem is to apply an additional catalytic material,...
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Power enhancement of the Brayton cycle by steam utilization
PublicationThe paper presents thermodynamic analysis of the gas-steam unit of the 65 MWe combined heat and power station. Numerical analyses of the station was performed for the nominal operation conditions determining the Brayton and combined cycle. Furthermore, steam utilization for the gas turbine propulsion in the Cheng cycle was analysed. In the considered modernization, steam generated in the heat recovery steam generator unit is directed...
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TERMODYNAMIC CALCULATIONS OF TURBINE STEAM PARAMETERS
PublicationIn this work a heat balance was made for the nominal conditions of a block working with 18K370 turbine. For the parameters obtained, the thermal-flow calculations of the steam turbine were performed, maintaining the actual geometry of its flow system. Based on the nominal values obtained, iterative thermal and flow calculations were made for both the heat cycle of the power plant block and the steam turbine itself, seeking to obtain...
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A Computational Analysis of the Aerodynamic and Aeromechanical Behavior of a Thermo-Well for Steam Temperature Measurement in a Steam Turbine
PublicationThe goal of the paper is twofold: firstly, it presents computational fluid dynamics analysis for finding maximum unsteady flow forces (and their frequencies) acting on a thermo-well for measuring steam temperature in a steam turbine control stage and secondly, it presents computational solid dynamics analysis of possibility of entry into resonance of the thermowell structure. There have been analyzed two cases of flow with changing...
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On energy, exergy, and environmental aspects of a combined gas-steam cycle for heat and power generation undergoing a process of retrofitting by steam injection
PublicationThe paper presents a study of retrofitting of a combined heat and power (CHP) plant aimed to increase the electric to heating power ratio. The modification would involve diverting part of the steam to the gas turbine, instead of letting it go to the steam turbine, using injection technique into a combustion chamber. Therefore, two potential retrofitting approaches are analyzed: steam injection gas turbine (STIGT) and combined steam...
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Estimation of the steam condensation flow via CFD methods
PublicationThe results of numerical simulations to predict the performance of different steam models have been presented. All of the considered models of steam condensation have been validated on the base of benchmark experiment employing expansion in nozzle and next on the low pressure part of the steam turbine stage. For numerical analysis three models have been finally used – the ideal steam model without condensation, an equilibrium steam...
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Comprehensive thermodynamic analysis of steam storage in a steam cycle in a different regime of work: A zero-dimensional and three-dimensional approach
PublicationDue to the current trends aiming to reduce carbon dioxide emissions by increasing the use of renewable energy sources, changes are required in the operation of coal-fired steam units. The unstable nature of renewable energy sources, depending on weather conditions, means that the amount of energy produced varies and is not always in line with peak demand. To ensure the security and stability of energy supplies in the energy system,...
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CeCu2O4 as a functional layer on solid oxide fuel cells for synthetic biogas reforming
PublicationSolid Oxide Fuel Cells (SOFC) are one of the most promising electrochemical devices, which can convert chemical energy to the electrical energy these days. Their ability to work with different kind of fuel makes them noteworthy. SOFC can work with biogas. The problem arises when solid carbon starts to be deposited in anode. That leads to degradation of fuel cell. Simple solution is to apply catalytic functional layer, which is...
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Catalytic Activity of Nickel and Ruthenium–Nickel Catalysts Supported on SiO2, ZrO2, Al2O3, and MgAl2O4 in a Dry Reforming Process
PublicationDry reforming of methane (DRM) is an eco-friendly method of syngas production due to the utilization of two main greenhouse gases—methane and carbon dioxide. An industrial application of methane dry reforming requires the use of a catalyst with high activity, stability over a long time, and the ability to catalyze a reaction, leading to the needed a hydrogen/carbon monoxide ratio. Thus, the aim of the study was to investigate the...
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Cu supported on various oxides as a candidate catalyst for dry methane reforming in DIR-SOFCs systems
PublicationA series of Cu-support systems were tested as potential candidates for DIR-SOFC (Direct Internal Reforming SOFC) catalysts towards a dry reforming of methane (DRM). The various supports (-Al2O3, CeO2, ZrO2, SrTiO3) with comparable specific surface area (SSA), and additionally -Al2O3 with SSA an order of magnitude larger than that of the other supports has been applied. The obtained Cu-support systems were characterized in terms...
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Apparent molar volumes and compressibilities of alkaline earth metal ions in methanol and dimethylsulfoxide
PublicationTemperature dependencies of density of magnesium (II), calcium (II), strontium (II), barium (II) perchlorates as well as beryllium (II), and sodium trifluoromethanesulfonates in methanol and dimethylsulfoxide have been determined over the composition range studied. From density data the apparent molar volumes and partial molar volumes of the salts at infinite dilution as well as the expansibilities have been evaluated. The apparent...
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Assessment of fitness for service of Cr-Mo steel tubes in catalytic reforming charge heaters
PublicationIn this paper characteristic features of metal dusting corrosion in high temperature gas mixtures of high carbon activity in catalytic reforming units, including Continuous Catalyst Regeneration (CCR) platformer are presented. Examples of 2.25Cr-1Mo and 9Cr-1Mo steel tubes at advanced stages of metal dusting process after long-term service in charge heaters are used to prove that destructive examinations are necessary to provide...
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Influence of steam drying process on wood mechanical properties
PublicationResults of influence of gas-steam mixture drying process on mechanical properties of material are presented. Wood species, namely oak (Quercus L.), beech (Fagus L.), pine (Pinus L.) and spruce (Picea K.) from the northern part of Pomerania region in Poland, were subject of air-steam mixture drying process in a laboratory kiln especially arranged for that reason. Measurements of the global coefficient of elasticity and bending strength...
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Enhancement of the Brayton cycle efficiency by water or steam utilization
PublicationIn the paper, thermodynamic analysis of two modifications of a Brayton cycle into enhancement cycles with water/steam injection are discussed. The first one deals with a STIG modified system with both interstage compressed air cooling and air heating (heat regeneration) before combustion chamber. The second one, mainly devoted to higher steam/air ratio, is connected with separate steam production in a HRSG. The analysis has been...
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Equilibrium constants (Keq) of reforming reactions
Open Research DataThe equilibrium constants (K) of reforming reactions in SOFC were supplied with this dataset
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Modelling of Nuclear Power Plant Steam Turbine
PublicationThe paper describes the approach to a Nuclear Power Plant steam turbine modelling which would enable on-line optimal process control (model based) and diagnosis over wide range of operating conditions caused by changing power demand. Presented model is static, multivariable and nonlinear. Such model enables analyzing the heat cogeneration aspects. Developed model is validated and verified by using archive data gained from researches...
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Modelling of Nuclear Power Plant Steam Turbine
PublicationThe paper describes the approach to a Nuclear Power Plant steam turbine modelling which would enable on-line optimal process control (model based) and diagnosis over wide range of operating conditions caused by changing power demand. Presented model is static, multivariable and nonlinear. Such model enables analyzing the heat cogeneration aspects. Developed model is validated and verified by using archive data gained from researches...
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Apparent molar volumes, expansibilities, and isentropic compressibilities of selected electrolytes in methanol
PublicationDensities of solutions of sodium bromide, sodium perchlorate, sodium tetraphenylborate, and tetraphenylphosphonium bromide in methanol at the temperatures ranging from 283.15 to 313.15 K have been measured. Ultrasound velocities for the above systems at T = 298.15 K have been determined. From the obtained data, the partial molar volumes and the partial molar isentropic compressibilities for electrolytes in solution have been estimated....
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The thermal effort during marine steam turbine flooding with water
PublicationThe work discussed an extreme case of cooling a steam turbine. The ship's steam turbine was used as an example. In marine transport units with low-speed engines dominate, however, there are also units with steam turbines. An example of analysed marine steam turbine is shown in Fig. 1. When considering the issue of cooling steam turbines, it is necessary to estimate the extreme conditions that may occur during operation of the turbine....
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Study of Direct Methanol Fuel Cell Process Dynamics Using Dynamic Electrochemical Impedance Spectroscopy
PublicationA new technique, which was developed to characterize the direct methanol fuel cell under work conditions, has been presented in this paper. The impedance measurements were made using dynamic electrochemical impedance spectroscopy research technique in the galvanostatic mode, using multiple sinusoidal excitation. Obtained results show, that together with an increase of the temperature and working load, the global impedance...
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INFLUENCE OF INLET GEOMETRY ON THE EFFICIENCY OF 1MW STEAM TURBINE
PublicationThe process of the design of the 1MW steam turbine includes designing the stator and rotor blades, the steam turbine inlet and exit, the casing and the rotor. A turbine that operates at rotation speeds other than 3000 rpm requires a gear box and generator with complex electronic software. This paper analyses the efficiency of eight turbine variants, including seven inlet geometries and three stages of stator as well as an eight...
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Neural Modelling of Steam Turbine Control Stage
PublicationThe paper describes possibility of steam turbine control stage neural model creation. It is of great importance because wider application of green energy causes severe conditions for control of energy generation systems operation Results of chosen steam turbine of 200 MW power measurements are applied as an example showing way of neural model creation. They serve as training and testing data of such neural model. Relatively simple...
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ENHANCED MASTER CYCLE - SIGNIFICANT IMPROVEMENT OF STEAM RANKINE CYCLE
PublicationThe present paper focuses on an enhancement of the Master Cycle. In the first part, the paper presents a classical Master Cycle which is a modification of the double reheat Rankine cycle. This modification allows to slightly increase efficiency, resolves problems caused by superheated steam on bleeds and decreases mass flow rate of steam directed to reheat. These improvements include the implementation of a tuning turbine from...
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Simplified, multiregional fuzzy model of a nuclear power plant steam turbine
PublicationPower systems, including steam turbines and synchronous generators, are complex nonlinear systems with parameters varying over time. The paper presents the developed simplified, multiregional fuzzy model of the steam turbine of a nuclear power plant turbine generator set and compares the results with a full nonlinear model and commonly used linear input-output model of a steam turbine. The proposed model consist of series of linear...
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Proposition of the steam turbine governor structure modification
PublicationThere is considered the steam turbine governor operation during defense and restoration of the power system. It points out weaknesses of currently used governor structures. The new controller is proposed, that takes advantages of those curently used. The new controller allows for more effective control of the turbine in emergency situations, at frequencies much different from the nominal value.
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Possibilities of Increasing the Overall Efficiency of Gas-steam CHP Microplant
PublicationThe paper presents ways to increase the efficiency of a gas-steam micro power plant by modifying the cycle combination. The modification consists in partial release of the fluid downstream of the gas turbine and using it for ORC fluid overheating and evaporation. Advantages of this solution over the simplest gas and steam cycles’ combination are demonstrated.
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Modeling of entrained flow steam gasification of sewage sludge
PublicationProper management of sewage sludge becomes increasingly problematic due to legal requirements aiming at diminishing environmental impact, as well as rationalizing the utilization from the point of view of logistics. Steam gasification of sewage sludge can result in very good quality of the producer gas. So far, the works have been focused on the gasification in fixed bed gasifiers. However, this does not allow to take full advantage...
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Technical and Economic Analysis of the Supercritical Combined Gas-Steam Cycle
PublicationCombined cycle power plants are characterized by high efficiency, now exceeding 60%. The record-breaking power plant listed in the Guinness Book of World Records is the Nishi-Nagoya power plant commissioned in March 2018, located in Japan, and reaching the gross efficiency of 63.08%. Research and development centers, energy companies, and scientific institutions are taking various actions to increase this efficiency. Both the gas...
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Corrosion of evaporator tubes in low emission steam boilers
PublicationPurpose of this paper is to reveal the mechanisms of corrosion processes of outer surfaces of low-emission steam boiler evaporator tubes. Examinations were performed to find the reasons of different corrosion susceptibility of tubes situated at combustion chamber on various levels. Examinations were conducted on several segments of 57 x 5.0 mm evaporator tubes made of 16M (16Mo3) steel grade. Segments were taken from level of...
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Slowly-closing valve behaviour during steam machine accelerated start-up
PublicationThe paper discusses the state of stress in a slowly-closing valve during accelerated start-up of a steam turbine. The valve is one of the first components affected by high temperature gradients and is a key element on which the power, efficiency and safety of the steam system depend. The authors calibrated the valve model based on experimental data and then performed extended Thermal-FSI analyses relative to experiment. The issue...
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Comparison of the coordination geometries of Zn(II) and Cd(II) ions in complexes with water, methanol and bulky aryloxysilanethiolate ligands
PublicationZinc and cadmium complexes containing silanethiolate anions and methanol or water were synthesized and characterized by X-ray diffraction, FT-IR and NMR spectroscopy, and DFT calculations. Contrary to zinc, the cadmium ion utilizes very weak donors to complete its coordination sphere; it forms contacts to phenyl rings of the silanethiolate ligand. Two zinc analogs of the general formula [Zn{SSi(OAr)3}2(L)2] where L = CH3OH (2)...