Filters
total: 4433
filtered: 2698
displaying 1000 best results Help
Search results for: COMPLETE MULTIPARTITE
-
Cobalt(II) silanethiolato complexes with dimethylpyridines:crystal structures and spectroscopic studies
PublicationTri-tert-butoksysilanotiolany kobaltu(II) z 2,5-dimetylopirydną, 3,4-dimetylopirydną i 3,5-dimetylopirydną jako dodatkowymi ligandami zostały zsyntetyzowane w reakcji z bimetalicznym [Co{SSi(OtBu)3}(NH3)]2 z odpowiednią pochodną pirydyny. Kompleksy zostały zcharakteryzowane za pomocą rentgenografii strukturalnej, analizy elementarnej, spektroskopii FT-IR oraz UV-vis. Prezentowane kompleksy są cztero- i pięciokoordynacyjne o rdzeniu...
-
Methods of Incomplete and Uncertain Knowledge Acquisition in the Knowledge Processing Environemnt
PublicationThe authors in this paper present a concept of the environment to acquire and process knowledge about information technology. This solution is part of a project of which the objective is to build a system for the evaluation of IT tools and methodologies. Knowledge within this domain is always either uncertain or incomplete. Therefore, the authors focused on designing a dedicated algorithm for its acquisition and processing. One...
-
Sulfurization of phosphanylphosphinidene ligand: Access to phosphinothioyltrithiophosphonato platinum(II) complexes
PublicationThe reactivity of phosphanylphosphinidene Pt(0) complexes [DppePt(η2-P–PtBu2)] (1) and [(pTol3P)2Pt(η2-P–PtBu2)] (2) toward sulfur was studied. Reactions of 1 and 2 with an excess of sulfur led to the formation of the first transition metal complexes 3 and 4 with phosphinothioyltrithiophosphonato ligands with the formula [tBu2P(=S)–P(=S)S2]2-. In contrast to previous reports on the phosphanylphosphinidene moiety sulfurization,...
-
The Reactivity of Phosphanylphosphinidene Complexes of Transition Metals Toward Terminal Dihaloalkanes
PublicationThe reactivities of phosphanylphosphinidene complexes [(DippN)2W(Cl)(η2-P−PtBu2)]− (1), [(pTol3P)2Pt(η2- P=PtBu2)] (2), and [(dppe)Pt(η2-P=PtBu2)] (3) toward dihaloalkanes and methyl iodide were investigated. The reactions of the anionic tungsten complex (1) with stochiometric Br(CH2)nBr (n = 3, 4, 6) led to the formation of neutral complexes with a tBu2PP(CH2)3Br ligand or neutral dinuclear complexes with unusual tetradentate...
-
Weak Solutions within the Gradient-Incomplete Strain-Gradient Elasticity
PublicationIn this paper we consider existence and uniqueness of the three-dimensional static boundary-value problems in the framework of so-called gradient-incomplete strain-gradient elasticity. We call the strain-gradient elasticity model gradient-incomplete such model where the considered strain energy density depends on displacements and only on some specific partial derivatives of displacements of first- and second-order. Such models...
-
X-ray and UV Radiation Damage of dsDNA/Protein Complexes
PublicationRadiation and photodynamic therapies are used for cancer treatment by targeting DNA. However, efficiency is limited due to physico-chemical processes and the insensitivity of native nucleobases to damage. Thus, incorporation of radio- and photosensitizers into these therapies should increase both efficacy and the yield of DNA damage. To date, studies of sensitization processes have been performed on simple model systems, e.g.,...
-
The Reactivity of the Imine Bond within Polynuclear Nickel(II) Complexes
PublicationThree novel Ni complexes with the Schiff base ligand 2-methoxy-6-(E-2-pyridyliminomethyl)-phenol (L1) are described. In comparison with the similar 2-(pyridine-2-ylimino-methyl)phenol (pymp), the mode of coordination of L1 is altered due to the presence of methoxy substituent introducing the sterical hindrance. During the synthesis of the complexes, partial hydrolysis of the ligand was observed. Since such immediate hydrolysis...
-
Syntheses and Structures of Transition Metal Complexes with Phosphanylphosphinidene Chalcogenide Ligands
PublicationThe reactivity of the phosphanylphosphinidene complex [(DippN)2W(Cl)(η2-P-PtBu2)]− (1) toward chalcogens (Ch = Se, S) was studied. Reactions of stoichiometric amounts of 1 with chalcogens in DME yielded monomeric tungsten complexes with phosphanylphosphinidene chalcogenide ligands of the formula tBu2P−P−Ch (Ch = Se (in 2) and S (in 5)), which can be regarded as products of the addition of a chalcogen atom to a P=W bond in starting...
-
Group 11 complexes with a phosphanylphosphaalkene ligand: preparation and stability study
PublicationThe reactivities of two selected phosphanylphosphaalkenes, Ph2C=P-PtBu2 (1a) and (p-MeO-Ph)2C=P-PtBu2 (1b), toward CuCl, AgCl and (tht)AuCl (tht = tetrahydrothiophene) were investigated. As a result, new phosphanylphosphaalkene dimeric and monomeric complexes were formed (Cu and Ag dimeric and Au monomeric). All obtained products were air and moisture stable and light insensitive.
-
Human voice modification using instantaneous complex frequency
PublicationThe paper presents the possibilities of changing human voice by modifying instantaneous complex frequency (ICF) of the speech signal. The proposed method provides a flexible way of altering voice without the necessity of finding fundamental frequency and formants' positions or detecting voiced and unvoiced fragments of speech. The algorithm is simple and fast. Apart from ICF it uses signal factorization into two factors: one fully...
-
On the use of instantaneous complex frequency for pitch and formant tracking.
PublicationW pracy opisano algorytm śledzenia częstotliwości podstawowej i formantów mowy z wykorzystaniem zespolonej pulsacji chwilowej. Działanie algorytmu przetestowano na nagraniach polskich samogłosek, których wysokość zmieniała się płynnie. Wyniki testów wraz z porównaniem działania opisanej metody i metody predykcji liniowej zawarto w artykule.
-
ASIC Design Example of Complex SoC with FPGA Prototyping
PublicationThe paper presents an example of the System on a Chip design, where the FPGA prototyping has been used. Two FPGA prototypes have been realized. The first FPGA prototype uses AVNET board containing Xilinx Virtex4 device accompanied by custom board with required devices. The second FPGA prototype has been built using the custom PCB with Xilinx Virtex-4 XC4VLX60 FPGA accompanied by all needed external components. The final system...
-
A complex variable fractional-delay FIR filter structure
PublicationW artykule wprowadzamy strukturę zespolonego filtru o skończonej odpowiedzi impulsowej (ang. finite impulse response - FIR) ze zmiennym opóźnieniem ułamkowym (ang. fractional delay - FD). Strukturę tę otrzymujemy na podstawie przestrajanego filtru FD FIR o współczynnikach rzeczywistych. Stanowi ona połączenie zbioru liniowo-fazowych filtrów FIR o współczynnikach stałych rzeczywistych i dwóch łańcuchów mnożąco-akumulujących, zawierających...
-
Charge orderings and lattice distortions in complex TCNQ salts
Publication -
New Insights into Thermodynamics of Solutes in Neat and Complex Solvents
Publication -
Semi complex navigation with an active optical gesture sensor
PublicationThis paper presents the methods of diversified touchless interactions between a user and a mobile platform utilizing the optical gesture sensor. The sensor uses 8 photodiodes to measure the reflected light in the active mode (using embedded LEDs) or it measures shadows caused by fingers in the passive mode. Several algorithms were implemented: automatic mode switching, adaptive illumination level compensation, resolution improvements...
-
ASIC Design Example of Complex SoC with FPGA Prototyping
PublicationThe paper presents an example of the System on a Chip design, where the FPGA prototyping has been used. Two FPGA prototypes have been realized. The first FPGA prototype uses AVNET board containing Xilinx Virtex4 device accompanied by custom board with required devices. The second FPGA prototype has been built using the custom PCB with Xilinx Virtex-4 XC4VLX60 FPGA accompanied by all needed external components. The final system...
-
The structure of levorin A3, a minor component of levorin complex
PublicationBudowa chemiczna składnika kompleksu leworyn, leworyny A3, została ustalona na podstawie analizy z wykorzystaniem metod spektroskopowych UV, MS i NMR metoksykarbonylometyloamido pochodnej leworyny A3. Widmo UV wskazało obecność chromoforu heptaenowego. Ciężar cząsteczkowy leworyny A3 ustalono jako 1110 j.m. za pomocą spektrometrii masowej z wykorzystaniem techniki FAB, co po uwzględnieniu uwarunkowań biogenetycznych pozwoliło wydedukować...
-
Complex multiplier based on the polynomial residue number system
PublicationPrzedstawiono próbę zaprojektowania mnożnika zespolonego 4x4 opartego na algorytmie Skavantzosa i Stouraitisa. W algorytmie stosuje siękodowanie liczb n-bitowych jako wielomianów stopnia 7 w pierścieniu wielomianów modulo (x^8-1) z n/4-bitowymi współczynnikami. Mnożenie zespolone jest wykonywane jako 8-punktowy splot cykliczny. Podanoopóżnienie i złożoność sprzętową jak również porównanie ze standardowym.rozwiązaniem.
-
Procesing the complex signal in the acoustic processor of a sonobuoy system
PublicationW artykule przedstawiono metody cyfrowego przetwarzania sygnału kompleksowego w procesorze akustycznym systemu radiohydroboi. Omówiono ogólną postać systemu oraz sygnału kompleksowego. Opisano dwie alternatywne metody przetwarzania sygnału: pierwszą w dziedzinie czasu, drugą w dziedzinie częstotliwości. Zaprezentowano schematy blokowe algorytmów obu sposobów przetwarzania. Omówiono problemy praktycznej realizacji poszczególnych...
-
Modelling of complex economic systems : toward conceptual platform
PublicationW artykule opisano rolę modelowania opisowego w ekonomicznych systemach złożonych w kontekście trzech funkcji naukowych: opisu, wyjaśniania i przewidywania. Fazy dekompozycji i opisu jakościowego modelowanych systemów, w tym ekonomicznych, są nieodzowne w całym procesie budowania modelu.
-
Integration of compute-intensive tasks into scientific workflows in BeesyCluster
PublicationArtykuł prezentuje szczegóły projektowe i implementacyjne jak również symulacje naukowych scenariuszy z wymagającymi zadaniami na klastrach i komputerach PC. Autor wdrożył wsparcie dla scenariuszy naukowych do wcześniej opracowanego systemu BeesyCluster wdrożonego w Akademickim Centrum Komputerowym sieci TASK w Gdańsku na klastrze holk z 288 procesorami Itanium2. BeesyCluster pozwala użytkownikom na zarządzanie różnymi kontami...
-
Complex Root Finding Algorithm Based on Delaunay Triangulation
PublicationA simple and flexible algorithm for finding zeros of a complex function is presented. An arbitrary-shaped search region can be considered and a very wide class of functions can be analyzed, including those containing singular points or even branch cuts. The proposed technique is based on sampling the function at nodes of a regular or a self-adaptive mesh and on the analysis of the function sign changes. As a result, a set of candidate points...
-
Online pitch estimation using instantaneous complex frequency
PublicationW pracy opisano nowe wyniki dotyczące skuteczności algorytmu potokowego estymującego częstotliwość podstawową sygnału mowy. Algorytm wykorzystuje zespoloną pulsację chwilową dla klasyfikacji mowy na dźwięczną i bezdźwięczną oraz estymacji częstotliwości podstawowej dla każdej próbki sygnału. Skuteczność klasyfikacji oraz dokładność estymacji zostały ocenione eksperymentalnie z wykorzystaniem dwóch baz nagrań, zawierających wypowiedzi...
-
A Framework for Training and Testing of Complex Pattern Recognition Systems
PublicationW pracy przedstawiono szkielet aplikacji stworzony po to, by uprościć konstruowanie systemów rozpoznawania obrazów oraz zapewnić środowisko testowe umożliwiające ocenę algorytmów przy użyciu dużych zestawów danych. Jasno zdefiniowana architektura wraz z wieloma gotowymi do użycia modułami pozwala skoncentrować się na implementacji najważniejszych algorytmów. Szkielet wspiera tworzenie modułów, który mogą być wielokrotnie używane,...
-
On root finding algorithms for complex functions with branch cuts
PublicationA simple and versatile method is presented, which enhances the complex root finding process by eliminating branch cuts and branch points in the analyzed domain. For any complex function defined by a finite number of Riemann sheets, a pointwise product of all the surfaces can be obtained. Such single-valued function is free of discontinuity caused by branch cuts and branch points. The roots of the new function are the same as the...
-
Identity verification using complex representations of handwritten signature
PublicationThis paper is devoted to handwritten signature verification using the cross-correlation approach (adopted by the authors from telecommunications) and dynamic time warping. The following invariants of the handwritten signature: the net signature, the instantaneous complex frequency and the complex cepstrum are analyzed. The problem of setting the threshold for deciding whether the current signature is authentic or forged is discussed....
-
Role of public space in designing complex urban structures
PublicationThe aim of this article is to present the main assumptions about design studios as held in the Faculty of Architecture at Gdańsk University of Technology (FA-GUT), Gdańsk, Poland, adapted to the development of key competencies in the urban planning of complex urban structures. One of these competencies is the design of public spaces. The main goal of the studios was to deliver knowledge of the role of public spaces in the design...
-
Complex Predictive Solution for Computerized Processes in Tire Industry
PublicationFollowing increasing market needs of productivity, cost reduction and safety requirements, computerized industry are faced to finding optimum between economic aspects of business and safety-related risk management. Modern factories equipped with computerized processes and extended diagnostic tools to support operator do not often use of all information’s which comes from the equipment. Some of the relations between the events are...
-
Copper(i) complexes with phosphine derived from sparfloxacin. Part III: multifaceted cell death and preliminary study of liposomal formulation of selected copper(i) complexes
Publication -
Complete Nucleotide Sequence of the pCTX-M3 Plasmid and Its Involvement in Spread of the Extended-Spectrum β-Lactamase GeneblaCTX-M-3
Publication -
On the complex formation of iron(III) bromide in the space-demanding solvent N,N'-dimethylpropyleneurea and the structure of the trisbromoiron(III) complex i solution and crystalline state
PublicationPrzeprowadzono badania kalorymetryczne równowag kompleksów koordynacyjnych jonu żelaza(III) z jonami bromkowymi w DMPU. Stwierdzono, że w DMPU powstają trzy: mono-, di- i tribromkowe kompleksy żelaza(III) a ich powstawanie jest uwarunkowane zmianą entropii. Badania krystalograficzne dowiodły, że FeBr3 w roztworze DMPU ma konfigurację płaskiego trójkąta równobocznego, żadna cząsteczka rozpuszczalnika nie jest związana z jonem metalu,...
-
Effects of dinuclear berenil-platinum(II) complexes on fibroblasts redox status
Publication -
Blind prediction of homo‐ and hetero‐protein complexes: The CASP13‐CAPRI experiment
Publication -
Thermal properties of rare earth elements complexes with 1,3,5-benzenetricarboxylic acid
Publication -
Some properties of Nd and Er complexes with 1,2,3,4,5,6-benzenehexacarboxylic (mellitic) acid
Publication -
Chiral Schiff base complexes as an effective catalyst in Diels-Alder reaction
PublicationDiels Alder reaction is a very important tool in carbon-carbon bond formation. It is a cycloaddition between a conjugated diene and a second compound called dienophile. Where one or more heteroatoms are present in the diene and/or dienophile framework, the cycloaddition is called hetero-Diels-Alder reaction (HDA). The asymmetric Diels-Alder reaction is among the most powerful available methodologies for that construction of optically...
-
Metal complexes with mixed s-donor ligands - a route via silanethiolates
PublicationW ramach prezentowanej pracy przedstawiono pierwsze próby syntezy mieszanych układów zawierających jednocześnie przykoordynowane reszty ditiokarbaminianową oraz silanotiolanowych. W badaniach posłużono się - jako substratami tri-tert-butoksysilanotiolanami kompleksami Cd, Zn, Cu, Pb, Hg, Ag i Co, a także solami kwasów: dietyloditiokarbaminowego oraz pirolidynoditiokarbaminowego. W przypadku związku Ag nie udało się wyizolować stałych...
-
Heteroleptic tri-tert-butoxysilanethiolate complexes of manganese(II) - thermal studies
PublicationThe thermal behavior of Mn(II) silanethiolate series [Mn(SR)2L(MeOH)n], where R=SSi(OBut)3, L=heterocyclic nitrogen base and n=0, 1 or 2 has been comparatively investigated using differential scanning calorimetry (DSC), thermogravimetry (TG) and TG-infrared spectoscopy (IR) techniques. The TG curves indicate the differences in the thermal decomposition due to presence of distinct N-donor ligands and labile MeOH molecules coordinated...
-
Assestment of the anti-cancer activity of the copper complexes with imidazole and pivalato ligands
PublicationDespite the development of science and technology progress so far there have not been found effective drugs for cancer. Many coordination compounds were investigated due to their antitumor potential. The most known cis-diamminedichloroplatinum(II) is used as anti-cancer therapeutic agent. The copper complexes are the coordination compounds possessing anti-tumour properties. Their capability to kill cancer cells is mainly linked...
-
Ranking decision variants by subjective paird comparisons in cases with incomplete data.
PublicationMetoda porównań parami wykorzystywana jest do szeregowania skończonej,zwykle niewielkiej liczby wariantów decyzyjnych. W metodzie tej ekspert lub grupa ekspertów proszona jest o wyrażenie swojej opinii dotyczącej każdej pary wariantów w postaci względnej preferenecji jednego wariantu nad drugim.Zdarza się jednak często, że ekspert nie jest w stanie ocenić pary lub par wiariantów i mamy wtedy do czynienia z sytuacją...
-
Impact of AlphaFold on structure prediction of protein complexes: The CASP15‐CAPRI experiment
PublicationWe present the results for CAPRI Round 54, the 5th joint CASP-CAPRI protein assembly prediction challenge. The Round offered 37 targets, including 14 homodimers, 3 homo-trimers, 13 heterodimers including 3 antibody–antigen complexes, and 7 large assemblies. On average 70 CASP and CAPRI predictor groups, including more than 20 automatics servers, submitted models for each target. A total of 21 941 models submitted by these groups...
-
Anticancer Study on IrIII and RhIII Half-Sandwich Complexes with the Bipyridylsulfonamide Ligand
PublicationTwo non-platinum compounds, organometallic half-sandwich complexes [(η 5 -Cp)IrCl(L)]PF 6 (1) and [(η 5 -Cp)RhCl(L)]PF 6 (2) were prepared by treating pentamethylcyclopentadienyl chloride dimers of iridium(III) or rhodium(III) with the obtained 4-amino-N-(2,2'-bipyridin-5- yl)benzenesulfonamide ligand (L) and ammonium hexafluorophosphate. The crystal structures of ligand (L) and complexes 1 and 2 were obtained and then analyzed. Coordination...
-
Potentiometric and AM1d studies of silicon and phosphorous podands-silver (I) complexes
Publication -
Potentiometric and AM1d studies of silicon and boron podands—silver (I) complexes
Publication -
Pincer Complexes Based on Phosphinoaminopyridines: Synthesis, Structural Characterization and Catalytic Applications
Publication -
Bonding interactions in oxydiacetate and thiodiacetate cobalt(II) and nickel(II) complexes
Publication -
Computational methods for calculation of binding free energy for ligand-receptor complexes
PublicationAccurate description of the molecular complexes energetic influence is required for understanding of many biological functions carried out by proteins. Therefore, estimation of binding free energy for ligand-receptor complexes is of highest importance for structure-based ligand design and drug discovery approaches.Experimental methods of determination of difference in Gibbs'es free energy have many limitations. Thus, computational...
-
Dissociative multi-photon ionization of isolated uracil and uracil-adenine complexes
PublicationRecent multi-photon ionization (MPI) experiments on uracil revealed a fragment ion at m/z 84 that was proposed as a potential marker for ring opening in the electronically excited neutral molecule. The present MPI measurements on deuterated uracil identify the fragment as C3H4N2O+ (uracil+ less CO), a plausible dissociative ionization product from the theoretically predicted open-ring isomer. Equivalent measurements on thymine...
-
Aggregation properties of some zirconium phosphate loaded with dirhenium(III) complexes
PublicationOne of the important areas of modern science is the selection of the right forms of drug delivery. Layered inorganic nanoparticles, such as zirconium phosphate, have proven themselves well in this area. The study of the properties of these systems and methods of their preparation makes it possible to determine a rational technology of their manufacture, storage conditions as well as suggest a possible mechanism of therapeutic action....