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Search results for: MYCOPHENOLIC ACID
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Thermal and mechanical properties of polyurethanes modified with L-ascorbic acid
PublicationIn this study we report the thermal and mechanical properties of polyurethanes modified with ascorbic acid (AA). Ascorbic acid was used as a modifier at concentration of 1 or 2 mass%. The antioxidative properties of AA may improve the biocompatibility of the obtained materials, which were designed for biomedical applications. In this paper we describe characterization of obtained unmodified and ascorbic acid modified polyurethanes...
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Characterization of fatty acid composition in Eurasian badger (Meles meles)
PublicationPolyunsaturated fatty acids (PUFAs, LA and ALA) are not synthesized in mammals in the absence of their essential fatty acid precursors. However, hibernating animals and animals sleeping through the winter need sufficiently high amounts of these acids. The Eurasian badger does not hibernate, but sleeps over winter. In the autumn the body weight of adult badgers increases even twofold, since they put on fat before the winter. Fat...
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Dissociative electron attachment and anion-induced dimerization in pyruvic acid
PublicationWe report partial cross sections for the dissociative electron attachment to pyruvic acid. A rich fragmentation dynamics is observed. Electronic structure calculations facilitate the identification of complex rearrangement reactions that occur during the dissociation. Furthermore, a number of fragment anions produced at electron energies close to 0 eV are observed, that cannot originate from single electron-molecule collisions....
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Maternal smoking Modulates Fatty Acid Profile of Breast Milk
PublicationAIM: We hypothesized that the fatty acid composition of breast milk can be affected by a smoking habit in the mother. Consequently, this study verified whether maternal smoking modulates, and if so to what extent, the breast milk fatty acid profile. METHODS: The study included 20 postpartum women who declared smoking more than five cigarettes daily throughout a period of pregnancy and lactation, and 136 non-smoking postpartum women....
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Photoresponsive, amide-based derivative of embonic acid for anion recognition
PublicationThe synthesis and ion-binding properties of amide-based derivative of embonic acid andp-aminoazobenzenewere described. The new compound was characterized by X-ray structural analysis and spectroscopic methods.Ligand interacts in acetonitrile with Y-shaped anions (benzoates and acetates) and dihydrogen phosphatesforming complexes of 1:1 stoichiometry. In more polar DMSO the complexes stoichiometry changes to 2:1(L:anion). Light-inducedtranstocisisomerization...
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Thermal energy storage using stearic acid as PCM material
PublicationThis work presents an experimental study of thermal energy storage by use of PCM. The aim of the study was to establish the influence of different inlet temperature of heat transfer fluid (HTF) and different Reynolds number of HTF on intensity of charging process. The PCM used in this study was stearic acid and water was used as HTF. A copper helical coil mounted in cylindrical container served as a heat transfer surface.
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Dissociation of furan-2-carboxylic acid by low energy electrons
PublicationElectron attachment to molecular target can lead to a variety of negative fragment ions. We experi- mentally probe the main dissociative electron attachment channels in furan-2-carboxylic acid (C3H3O2 − COOH) - a molecular target composed of two important structural units: a furan ring and a carboxylic group. In our studies we utilise nearly mono-energetic electrons at electron energies from 0 eV up to 15 eV. Our detection setup...
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Photodynamic therapy with 5-aminolevulinic acid and diamino acid derivatives of protoporphyrin IX reduces papillomas in mice without eliminating transformation into squamous cell carcinoma of the skin
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Fluorinated Boronic Acids: Acidity and Hydrolytic Stability of Fluorinated Phenylboronic Acids
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4-[(tert-Butyldimethylsilyl)oxy]-6-methoxy-7-methyl-5-(oxiran-2-ylmethyl)-2-benzofuran-3(1H)-one
PublicationThe title compound, C19H28O5Si, was obtained in the reaction of 1,3-dihydro-4-[(tert-butyldimethylsilyl)oxy]-6-methoxy-7-methyl-3-oxo-5-(prop-2-enyl)isobenzofuran with meta-chloroperbenzoic acid. This reaction is one of the stages of the total synthesis of mycophenolic acid, which we attempted to modify. The title compound forms crystals with only weak intermolecular interactions. The strongest stacking interaction is found between...
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Fatty Acid-Binding Protein 7 (FABP-7), Glutamic Acid and Neurofilament Light Chain (NFL) as Potential Markers of Neurodegenerative Disorders in Psoriatic Patients—A Pilot Study
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Is the Fatty Acids Profile in Blood a Good Predictor of Liver Changes? Correlation of Fatty Acids Profile with Fatty Acids Content in the Liver
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Solvothermal synthesis and structural characterization of three polyoxotitanium-organic acid clusters
PublicationThree new titanium oxo-clusters Ti4O2(OiPr)10(OOCPhMe)2 (I), Ti6O4(OEt)8(OOCPhMe)8 (II) and Ti6O6(OEt)6(OOCCHPh2)6 (III) were obtained by easy one-step solvothermal reactions of titanium(IV) isopropoxide, alcohols and carboxylic acids. The three compounds were characterized by single-crystal and powder X-ray diffraction, TGA/DSC, optical and electron microscopy, and FTIR and NMR spectroscopy. X-ray powder diffraction and spectroscopy...
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Acid Rider. Idea „komunizmu kwasowego” Marka Fishera a doświadczenie zewnętrzności
PublicationAcid communism pozostaje intrygującym wstępem Marka Fishera do planowanej przezeń historycznej rekonstrukcji radykalnych projektów politycznych wyrosłych na gruncie kultury psychodelicznej. Idea ta nie narodziła się w próżni, lecz stanowi konsekwencję jego poszukiwań teoretycznych. Artykuł próbuje osadzić koncepcję „komunizmu kwasowego” w szerszym kontekście, skupiając się na refleksji poświęconej doświadczeniu psychodelicznemu...
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Diameter sensitive effect in singlewalled carbon nanotubes upon acid treatment
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Molecular self-assembly and optical activity of chiral thionooxalamic acid esters
PublicationZsyntezowano kilka optycznie czynnych estrów dietylowych kwasu bis(tiooksamowego). Związki te, z powodu ich zdolności do tworzenia ze sobą komplementarnych cyklicznych wiązań wodorowych, są potencjalnie użytecznym materiałem budulcowym większych układów supramolekularnych. Odpowiednie układy modelowe otrzymano z optycznie czynnych 1,2-diamin, które poddano acylowaniu chlorooksooctanem etylu, a następnie otrzymane półprodukty tionowano...
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Effect of citric acid esterification conditions on the properties of the obtained resistant starch
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In Depth Analysis of Chiroptical Properties of Enones Derived from Abietic Acid
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Double amino acid – A novel molecule enabling peptide interpenetrating structures
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Spectroscopic Studies of Amino Acid Ionic Liquid-Supported Schiff Bases
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Modulation of TET2 Activity By Ascorbic Acid and Factors Affecting Lysine Acetylation
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Thermal properties of rare earth elements complexes with 1,3,5-benzenetricarboxylic acid
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Bringing a New Flexible Mercaptoacetic Acid Linker to the Design of Coordination Polymers
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Some properties of Nd and Er complexes with 1,2,3,4,5,6-benzenehexacarboxylic (mellitic) acid
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Serum Fatty Acid-Binding Protein 4 is Increased in Patients with Psoriasis
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Determination of Flavonoids, Tannins and Ellagic acid in leaves fromRubus L. species
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The effect of renal replacement therapy on the concentration of selected arachidonic acid derivatives
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Spectroscopic insight into supramolecular assemblies of boric acid derivatives and β-cyclodextrin
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Effect of renal replacement therapy on selected arachidonic acid derivatives concentration
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3D composites based on the blends of chitosan and collagen with the addition of hyaluronic acid
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Surface and thermal properties of collagen/hyaluronic acid blends containing chitosan
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Recovery of hydrochloric acid from metal pickling solutions by membrane distillation
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Thermal degradation of butyl acrylate-methyl acrylate-acrylic acid-copolymers
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Reactions in nanofilms of trifluoroacetic acid (CF3COOH) driven by low energy electrons
PublicationBadano modyfikacje chemiczne indukowane przez niskoenergetyczne elektrony (0-20eV) w cienkich warstwach skondensowanych molekuł CF3COOH. Do badań zastosowano dwie metody: desorpcję jonów w wyniku bombardowania elektronami (ESD - Electron Stimulated Desorption) oraz termiczną desorpcję jonów (TDS - Thermal Desorption Spectroscopy).
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Reaction of thio and seleno phosphoric acid derivatives with O-thioacylated hydroxylamine
PublicationZbadano reakcję siarkowych i selenowych analogów kwasu O,O-neopentylidenofosforowego z O-tiopiwaloilo-N-tert-butylohydroksyloaminą, w której to następuje rozszczepienie wiązania N-O. Znaleziono korelację pomiędzy potencjałem utleniającym anionu pochodnej kwasu fosforowego a przebiegiem badanej reakcji.
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Interaction of low energy electrons with formic acid monomer, dimer and trimer
PublicationConfigurations of the formic acid monomer, dimer and trimer are presented. We have calculated the total energies for these structures. We have considered also the negatively charged clusters and discussed the possible pathways of interaction of low energy electrons with monomers and clusters. Calculations have been executed using 6-311G** and 6-311++G** basis sets. The electron affinities of monomer and clusters are presented....
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Collagen and hyaluronic acid hydrogel in water-in-oil microemulsion delivery systems
PublicationThe efficacy of microemul-sion in dermal and transdermal delivery of active ingredients. Here, we assessed the water-in-oilmicroemulsion capacity to incorporate two natural polymers, i.e. collagen and hyaluronic acid withlow and high molecular weight. Systems were extensively characterized in terms of conductivity, phaseinversion studies, droplet diameter, polydispersity index and rheological properties. The results of thisresearch...
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CROSS SECTIONS CALCULATIONS FOR ELECTRON SCATTERING FROM RHODANINE AND CYANOACETIC ACID
PublicationCross sections for electron-impact ionization and for elastic electron scattering for rhodanine (C3H3NOS2) and cyanoacetic acid (C3H3NO2) have been calculated in wide impinging electron energy range.
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Transdermal transport of collagen and hyaluronic acid using water in oil microemulsion
PublicationCollagen and hyaluronic acid (HA) are biopolymers that affect the appearance and condition of the skin. Delivery of these compounds into the skin is highly challenging since have a number of disadvantageous properties, such as high molecular weight and hydrophilicity. Here, we evaluated the transdermal penetration of low and high molecular weight collagen and HA from microemulsions. A number of microemulsion formulations, differing...
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Physical crosslinking of hyaluronic acid in the presence of phospholipids in an aqueous nano-environment
PublicationHyaluronic acid and phospholipids are two components in the synovial joint cavity that contribute to joint lubrication synergistically. Molecular dynamics simulations were performed and hydrogen bonds in hyaluronic acid were analyzed to identify specific sites that are responsible for its physical cross-linking. Two molecular masses of hyaluronic acid, 10 kDa and 160 kDa, were considered. We use molecular dynamics simulations and...
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Complexation of amino acids derivatives in water by calix[4]arene phosphonic acids
PublicationSeries of the calix[4]arene phosphonic acids with various substituents at the lower rim was synthesized. Complexing properties of these receptors towards methyl esters of six amino acids strongly depended on the calix[4]arene conformation flexibility. The complex formation processes were monitored using 1H NMR spectroscopy (deuterated phosphate buffer at pD 7.3, 22 oC) and association constant values were evaluated. Inherently...
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Pochodne oleju makowego jako związki biologicznie czynne
PublicationW pracy przebadano skład kwasów tłuszczowych oleju makowego z nasion maku niskomorfinowego (Michałko, Agat, Mieszko, Zambo, Rubin i Przemko) i wysokomorfinowego (Lazur). Do dalszych badań wybrano olej makowy odmiany Michałko ze względu na wysoką zawartość kwasu linolowego (72,8%), niską zawartość kwasu oleinowego (12,6%) i kwasu linolenowego (0,8%). Kwasy nasycone głównie palmitynowy (11,3%) mogą być usunięte w odrębnym postępowaniu....
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The content of conjugated linoleic acid and vaccenic acid in the breast milk of women from Gdansk and the surrounding district, as well as in, infant formulas and follow-up formulas. Nutritional recommendation for nursing women
PublicationFatty acids are some of the most important components of human milk. Polyunsaturated fatty acids (PUFAs) are essential nutrients required for the optimal growth and development of infants, especially the central nervous system, brain and retina. AIM: To determine the conjugated linolenic acid (CLA) and vaccenic acid (VA) content of human breast milk from mothers consuming different diets, and to compare the results with CLA and...
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Novel “acid tuned” deep eutectic solvents based on protonated L-proline
PublicationThe paper presents new types of deep eutectic solvents (DESs) based on L-proline protonated using three different acids (hydrochloric, sulfuric and phosphoric)and playing the role of a hydrogen bond acceptor(HBA). Glucose and xylitol were used as hydrogen bond donors (HBD). A series of deep eutectic solvents with various mole ratios were obtained for the systems L-proline: glucose and L-proline: xylitol. Density, melting point,...
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Thermal degradation of polylactic acid (PLA)/polyhydroxybutyrate (PHB) blends: A systematic review
PublicationPolylactic acid (PLA) and polyhydroxybutyrate (PHB) are two biopolyesters obtained from renewable resources like corn or sugar under bacterial fermentation. PLA is the most widely used biopolymer in diverse applications. Addition of PHB to PLA can improves the crystallinity of PLA, and thereby its mechanical strength. However, both PLA and PHB suffer from poor thermal stability, which limits their potential industrial application....
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Reaction of aniline with ammonium persulphate and concentrated hydrochloric acid: Experimental and DFT studies
PublicationIn this paper, the reaction of aniline with ammonium persulphate and concentrated HCl was studied. As a result of our experimental studies, 2,4,6-trichlorophenylamine was identified as the main product. This shows that a high concentration of HCl does not favour oxidative polymerisation of phenylamine, even though the ammonium persulphate/HCl system is widely used in polyaniline synthesis. On the basis of the experimental data...
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Enhanced thermal properties of poly(lactic acid)/MoS2/carbon nanotubes composites
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Effect of sodium acetate on citric acid production from glucose by Yarrowia lipolytica
PublicationZbadano wpływ octanu sodu na produkcję kwasu cytrynowego z glukozy w hodowli wgłębnej przez nie utylizującego octanu mutanta (oct-) Yarrowia lipolytica A-101.1.31. Octan będący ko-substratem glukozy w pożywce zwiększał produktywność i plon kwasu cytrynowego w ciągu pierwszych 24 godzin procesu. Największy pozytywny wpływ na biosyntezę kwasu cytrynowego przez Y. lipolytica A-101.1.31 miał dodatek 2g/L octanu sodu (przy zbadanych...
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Effect of Long-Term Potato Starch Retention with Citric Acid on Its Properties
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Surface Property Modification of Collagen, Hyaluronic Acid, and Chitosan Films with the Neodymium Laser
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