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Search results for: KATION HYDROFOBOWY
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Design of three control algorithms for an averaging tank with variable filing
PublicationAn averaging tank with variable filling is a nonlinear multidimensional system and can thus be considered a complex control sys-tem. General control objectives of such object include ensuring stability, zero steady state error and achieving simultaneously shortest possible settling time and minimal overshoot. The main purpose of this research work was the modelling and synthesis of three control systems for an averaging tank. In...
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Do Phenyl Substituents Affect the Properties of Azobenzocrown Derivatives?
PublicationNew products of photo- and thermal rearrangements of 19-membered azoxybenzocrown with phenyl substituents in benzene rings in the para positions to oligooxyethylene fragments are characterized. The yields of photochemical transformations depend on the solvent. Para-hydroxyazocrown is formed with yields over 50% in propan-2-ol. Ortho-hydroxyazobenzocrown is obtained with yields up to 70% in toluene/acetic acid mixture. Macrocyclic...
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Ionization and ionic fragmentation of tetrahydrofuran molecules by electron collisions
PublicationElectron impact ionization and ionic fragmentation of tetrahydrofuran molecules in the gas phase were studied in the energy range from ionization threshold up to 150 eV using the technique of mass spectrometry. The cation mass spectra, ionization and ionic fragmentation efficiencies were measured over this energy range. Well-resolved mass peaks were detected in the mass range 10-72 amu and assigned to corresponding ionic molecular...
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Searching for Critical Conditions During Lifeboat Launching – Simulations
PublicationThe article describes numerical simulations of the process of lifeboat launching at the ship’s side. The research is aimed at finding the values of ship motion parameters which appear to be most dangerous for people in the lowered lifeboat due to the generated accelerations. The simplified model of ship hull motion adopted at this research stage bases on a superposition of harmonic motions with given amplitudes and periods in six...
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Opracowanie potencjometrycznej wieloczujnikowej platformy wykonanej całkowicie w technologii All-Solid-State do jednoczesnego oznaczania kilku jonów w roztworach wodnych
PublicationW pracy przedstawiono charakterystykę i konstrukcje różnych elektrod jonoselektywnych (EJS), a także opisano elektrodę odniesienia i jej funkcję. Przybliżono możliwości zastosowania EJS do monitorowania śladowych ilości ołowiu (II) w otoczeniu kopalni rud cynku i ołowiu, oraz jako biowskaźnik stanu pacjenta w czasie wstrząsu septycznego. Opisano wieloczujnikowe platformy potencjometryczne (WPP) w technologii All-Solid-State (ASS). W...
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Z polsko-łacińskiej leksykografii przekładowej. Cz. I. Bibliografia słowników z językiem łacińskim za lata 1964–1989 w układzie chronologicznym [From the Polish translation lexicography. Part I. A bibliography of dictionaries with the Latin language, the years 1964–1989, in a chronological order]
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THE MICROBIOLOGICAL AND SANITARY STATE OF SAND IN THE MUNICIPAL BATHING BEACH IN SZCZECIN
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EFFECTIVENESS OF THE SANDPITS SECURITY SYSTEM AGAINST MICROORGANISMS AND INTESTINAL PARASITES SAND CONTAMINATION
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ASSESSMENT OF THE PROGRESS OF INTEGRATED PEST MANAGEMENT PRODUCTS IMPLEMENTATION INTO AGRICULTURAL PRODUCTION SPACE
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Zastosowanie wysokosprawnej kolumnowej chromatografii cieczowej w odwróconych układach faz (RP-HPLC) do rozdzielania i wstępnej identyfikacji składników hydrofilowych mieszanin po hydrolizie zasadowej biomasy ligno-celulozowej (BMLC)
PublicationWzrost konsumpcji paliw kopalnych, ich pozyskiwanie oraz eksploatacja niesie ze sobą wiele zagrożeń dla środowiska, dlatego alternatywnym źródłem energii stają się biopaliwa, w tym bio-wodór pozyskiwany w konwersji biomasy ligno-celulozowej, która poddawana jest obróbce wstępnej. Najczęściej wykorzystywaną metodą obróbki wstępnej jest hydroliza alkaliczna, podczas której powstaję bardzo dużo produktów ubocznych, nieprzydatnych...
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Linear-scaling calculation of Hartree-Fock exchange energy with Non-orthogonal Generalised Wannier Functions
PublicationWe present a method for the calculation of four-centre two-electron repulsion integrals in terms of localised non-orthogonal generalised Wannier functions (NGWFs). Our method has been imple- mented in the ONETEP program and is used to compute the Hartree-Fock exchange energy component of Hartree-Fock and Density Functional Theory (DFT) calculations with hybrid exchange-correlation functionals. As the NGWFs are optimised in situ...
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Trialkoksysilanotiolany amoniowe. Anion silanotiolanowy jako akceptor w wiązaniu wodorowym N-H..S.**2004, 161 s. 74 rys. 48 tab. bibliogr. 148 poz. maszyn. Rozprawa doktorska /24.03.2004/Wydz. Chemiczny PG Promotor: dr hab. inż. Barbara Becker
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Projekt architektoniczny V_KAMiPN 2022/23 M. Podwojewska, T. Szymański
e-Learning CoursesKurs dotyczy prowadzenia zajęć z przedmiotu Projekt architektoniczny V w KAMiPN.
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Projekt architektoniczny V_KAMiPN 2024/25 M. Podwojewska, T. Szymański
e-Learning CoursesKurs dotyczy prowadzenia zajęć z przedmiotu Projekt architektoniczny V w KAMiPN.
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A method to synthesise groove cam Geneva mechanisms with increased dwell period
PublicationThe present study develops a method to synthesise the groove cam Geneva mechanism with increased dwell period. The main condition of the synthesis is to provide the desired law of motion of the wheel. Additional synthesis conditions are the limitation of the maximum pressure angle and the limitation of the minimum curvature radius of the cam profile. Unlike the conventional Geneva mechanisms, the synthesised groove cam Geneva mechanisms...
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Dehydrogenation in electron-induced dissociative ionization of pyridine molecule
PublicationThe electron-impact dissociative ionization of pyridine has been investigated using mass spectrometry. Thirty-two well-resolved mass peaks have been identified in the cation mass spectra and assigned to the most likely ionic molecular fragments. The new sixteen ionic fragments' appearance energies have been determined, and sixteen others remeasured. The total cross-section for electron-impact ionization of pyridine has been measured...
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Bioactive quaternary ammonium ionic liquids.
PublicationAn ionic liquid (IL) is an organic compound that contains at least one ionic bond. It consists of an organic cation and an organic or inorganic anion. It is an organic salt having a melting point below 100C. A very interesting group of IL are those with a long chain quaternary ammonium cation. They are formed by direct synthesis or by an anion-exchange reaction in quaternary ammonium halides. Popular and cheap precursors for the...
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A Note on Shannon Capacity for Invariant and Evolving Channels
PublicationIn the paper we discuss the notion of Shannon capacity for invariant and evolving channels. We show how this notion is involved in information theory, graph theory and Ramsey theory.
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Oskar Kalin
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Joanna Rymaszewska prof. dr hab. n. med.
PeopleCV Joanna Rymaszewska Wroclaw University of Science and Technology, Wroclaw, Poland +48 601 98 26 24, joanna.rymaszewska@pwr.edu.pl orcid.org/0000-0001-8985-3592 2023 → Professor of Wroclaw University of Science and Technology (WUST), Poland 2011 → 2023 Professor of Wroclaw Medical University (WMU), PL 2016 → 2022 Head of the Department of Psychiatry, Wroclaw Medical University 2016 → 2022 Head of the Clinic of Psychiatry,...
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Is Digital Government Advancing Sustainable Governance? A Study of OECD/EU Countries
PublicationInternational bodies and numerous authors advocate a key role for Digital Government (DG) in improving public governance and achieving other policy outcomes. Today, a particularly relevant outcome is advancing Sustainable Governance (SG), i.e., the capacity to steer and coordinate public action towards sustainable development. This article performs an empirical study of the relationship between DG and SG using data about 41 OECD/EU...
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Piotr Szczuko dr hab. inż.
PeoplePiotr Szczuko received his M.Sc. degree in 2002. His thesis was dedicated to examination of correlation phenomena between perception of sound and vision for surround sound and digital image. He finished Ph.D. studies in 2007 and one year later completed a dissertation "Application of Fuzzy Rules in Computer Character Animation" that received award of Prime Minister of Poland. His interests include: processing of audio and video, computer...
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Andrzej Klimczuk
PeopleAndrzej Klimczuk, PhD, a sociologist and public policy expert, assistant professor in the Department of Social Policy of the Collegium of Socio-Economics at the SGH Warsaw School of Economics, Poland. Editor and correspondent of publications about computer and video games in the years 2002-2009. In 2011-2013, Vice President of the Foundation's Laboratory Research and Social Action "SocLab." External expert of institutions such...
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Dependence between Ionic Liquid Structure and Mechanism of Visible-Light-Induced Activity of TiO2 Obtained by Ionic-Liquid-Assisted Solvothermal Synthesis
PublicationBecause of the tremendous structural diversityof ionic liquids (ILs), simple transfer of observations performed for one IL used for IL-TiO2 preparation on different samples is not possible. Therefore, four ionic liquids, all containing distinct nitrogen-bearing organic cations (pyridinium, pyrrolidinium, ammonium, imidazolium), were used for the first time for the preparation of IL-TiO2 composites. The role of the individual IL...
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Planning of the green road system as an element of spatial management in suburbs and small towns
PublicationThe premise for the development of sustainable forms of road infrastructure in small towns is the appropriate plan at an early stage or modifi cation in the case of existing spaces. A multi-directional approach is extremely important, which takes into account the specifi city of the regional (country) road system, availability, and capacity of traffi c network, but also social and environmental factors. Effi cient management...
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Studies on micellar aggregation of nonionic surfactants in imidazolium liquids
PublicationA number of imidazolium ionic liquids, with 2-8 carbon atoms in cation alkyl chains, and tetrafluoroborate, hexafluorophosphate, bis(trifluoromethylsulfony)imide and trifluoromethanesulfonate anions, were characterized for their ability to support micellar aggregation of nonionic surfactants in binary solutions.
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Proceedings of ITST 2017 - 15th International Conference on ITS Telecommunications
PublicationRedakcja naukowa materiałów konferencji ITST 2017
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Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 16. Synthesis of 25, 26, 27, 28-tetrakis(piperidinethiocarbonylmethylene)-p-tert-butylcalix[4]arene and its interaction with metal ions
PublicationThe synthesis, characterisation and X-ray crystal structures of p-tert-butyl-calix[4]arenethioamide L and its complex with lead L-Pb2+ is reported. The cation-binding properties in solution have been assessed by liquid-liquid extraction of the metal picrates from water into dichloromethane and by stability constants determination in acetonitrile using UV-absorption spectrophotometry or potentiometry. The compound was used as active...
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Assessment of the physical fitness of road cyclists in the step and ramp protocols of the incremental test
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Experiments and calibration of a bond-slip relation and efficiency factors for textile reinforcement in concrete
PublicationTextile reinforcement yarns consist of many filaments, which can slip relative each other. At modelling of the global structural behaviour, interfilament slip in the yarns, and slip between the yarns and the concrete can be considered by efficiency factors for the stiffness and strength of the yarns, and by applying a bond-slip relation between yarns and concrete. In this work, an effective and robust method for calibration of...
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Artificial neural network prophecy of ion exchange process for Cu (II) eradication from acid mine drainage
PublicationThe removal of heavy metal ions from wastewater was found to be significant when the cation exchange procedure was used effectively. The model of the cation exchange process was built using an artificial neural network (ANN). The acid mine drainage waste’s Cu(II) ion was removed using Indion 730 cation exchange resin. Experimental data from 252 cycles were recorded. In a column study, 252 experimental observations validated the...
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AeroSense Measurements: Wind Tunnel EPFL
Open Research DataData from wind tunnel tests of Aerosesne measurement system installed on NACA63418 at EPFL wind tunnel.
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Fundamentals of Data-Driven Surrogate Modeling
PublicationThe primary topic of the book is surrogate modeling and surrogate-based design of high-frequency structures. The purpose of the first two chapters is to provide the reader with an overview of the two most important classes of modeling methods, data-driven (or approx-imation), as well as physics-based ones. These are covered in Chap-ters 1 and 2, respectively. The remaining parts of the book give an exposition of the specific aspects...
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Interaction of imidazolium type ionic liquids with the solid phase
PublicationNiektóre ciecze jonowe, w szczególności te posiadające kation organiczny podstawiony długim łańcuchem alkilowym, wykazują strukturalne podobieństwo do surfaktantów. Samoczynne formowanie się agregatów cieczy jonowych może wpływać na procesy przenoszenia masy w wielu operacjach jednostkowych jak: ekstrakcja, nanofiltracja lub kataliza oraz transport i rozmieszczenie tych związków w środowisku naturalnym. W niniejszej publikacji...
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Deformation degree estimators for several basic structural units in numerically simulated materials
PublicationW pracy wprowadzono i zdefiniowano kilka estymatorów stopnia deformacji dla serii bazowych jednostek strukturalnych typu CA_n (C-kation, A-anion) występujących w strukturach symulowanych numerycznie. Do wyznaczenia rozkładu wartości estymatoróww funkcji stopnia deformacji kształtu zadanego wielościanu zastosowano symulacje Monte Carlo. Otrzymane rozkłady są danymi referencyjnymi, które są bardzo użyteczne przy jakościowej analizie...
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Application of the tetraphenylphosphonium tetraphenylborate (TPTB) assumption to the thermodynamic properties of solvated ions in dimethylsulfoxide
PublicationW niniejszej pracy za pomocą spektroskopii ATR FTIR sprawdzano możliwość zastosowania tetrafenyloboranu tetrafenylofosfoniowego w metodzie elektrolitu wzorcowego, służącej do podziału wielkości termodynamicznych elektrolitów w dimetylosulfotlenku na udziały jonowe. Jednoznacznie stwierdzono, że poza termodynamiczne założenie o identycznych oddziaływaniach jonów w elektrolicie wzorcowym z cząsteczkami DMSO jest nieprawdziwe. Uzyskane...
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Ryszard Woźniak dr inż.
PeopleRyszard Woźniak received his M.Sc. (1984) from the Lublin University of Technology specializing in Cars and Tractors. In 2002, at the Gdansk University of Technology he defended his doctoral thesis on: "Tyre/road noise when large longitudinal forces are applied in tyre/road contact patch" and obtained a doctorate degree in technical sciences in the field of construction and operation of machines. Currently he is an adjunct at the...
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Pin Angle Thermal Effects on Friction Stir Welding of AA5058 Aluminum Alloy: CFD Simulation and Experimental Validation
PublicationThe friction stir welding (FSW) of tool pin geometry plays a critical role in the final properties of the produced joint. The tool pin geometry directly affects the generation of heat and the flow of internal materials during the FSW process. The effects of the FSW tool pin angle on heat generation and internal flow have not been quantitatively investigated in detail. In this manuscript, a validated Computational Fluid Dynamic...
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Membrane Solid Phase Microextraction - a new concept of sorbent preparation
PublicationOpracowano nowy układ sorpcyjny do izolacji i/lub wzbogacania polarnych analitów organicznych z próbek wody z zastosowaniem techniki solid phase microextraction (SPME). Układ bazuje na oddzieleniu sorbentu polarnego od próbki za pomocą membrany hydrofobowej. Próbnik membrane-SPME (M-SPME) sporządzono z zastosowaniem polietylenoglikolu (PEG)o masie cząsteczkowej 20 kDa. Polimer ten jest rozpuszczalny w wodzie i w typowych warunkach...
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Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based on p-tert-Butyl-calix[4]arene Thioamides.
PublicationTetra podstawione tioamidowe pochodne para-tert-butylokaliks[4]arenu (1-5) zostały zastosowane jako jonofory w membranowych elektrodach jonoselektywnych (EJS) selektywne na kationy Pb(II). Wyznaczono współczynniki selektywności. Czwartorzędowe kaliks[4]aren-tioamidy (1,2) wykazują nadzwyczaj dobrą selektywność na kationy Pb(II) w porównaniu z kaliks[4]aren-amidami. Membrany z tymi ligandami wykazują dużą trwałość, a charakterystyki...
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Optimal control at energy performance index of the mobile robots following dynamically created trajectories
PublicationIn practice, the problem of motion control of the wheeled mobile robots is often neglected. Wheeled mobile robots are strongly nonlinear systems and restricted by non-holonomic constraints. Motion control of such systems is not trivial task and usage of non-optimal control signals can lead to deterioration of the overall robot system’s performance. In case of autonomous application of the mobile robots all parts of its control...
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Barbara Kusznierewicz dr hab. inż.
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Ewa Kamieńska-Piotrowicz dr hab. inż.
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Fundamentals of classical and analytical mechanics
PublicationThe book is a monographic description of the present attempt to Newtonian and Lagrangian mechanics. But also, it could be found as a supplementary educational material useful for the graduate courses in mechanics taken by students majoring in mechanical engineering, physics or physical science. In the book you can find a brief introduction to concepts and principles of algebra of vectors; Kinematics of particles, mainly focused...
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The Role of Electrostatics in Enzymes: Do Biomolecular Force Fields Reflect Protein Electric Fields?
PublicationPreorganization of large, directionally oriented, electric fields inside protein active sites has been proposed as a crucial contributor to catalytic mechanism in many enzymes, and it may be efficiently investigated at the atomistic level with molecular dynamics simulations. Here, we evaluate the ability of the AMOEBA polarizable force field, as well as the additive Amber ff14SB and Charmm C36m models, to describe the electric...
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Electrostatic interactions in finite systems treated with periodic boundary conditions: Application to linear-scaling density functional theory
PublicationWe present a comparison of methods for treating the electrostatic interactions of finite, isolated systems within periodic boundary conditions (PBCs), within density functional theory (DFT), with particular emphasis on linear-scaling (LS) DFT. Often, PBCs are not physically realistic but are an unavoidable consequence of the choice of basis set and the efficacy of using Fourier transforms to compute the Hartree potential. In such...
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Badania eksperymentalne słupów CFST z betonem zwykłym i ekspansywnym
PublicationPraca przedstawia badania eksperymentalne ponad 40 słupów CFST. Analizie poddano wyniki siły niszczącej słupy w aspekcie grubości stalowego płaszcza, smukłości słupa, rodzaju betonu wypełniającego stalową rurę (zwykły i ekspansywny) i jego wytrzymałości a także sposobu obciążania słupa (przez rdzeń lub przez cały przekrój). Sprawdzono efektywność słupów CFST z użyciem betonu ekspansywnego i zwykłego rozumianą jako stosunek nośności...
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Mössbauer Spectroscopy and Magnetoelectric Effect Studies of Multiferroic Ceramics Based on BiFeO<sub>3</sub>
PublicationIn this work the results of investigations for (BiFeO3)x(BaTiO3)1-x and Bi1-xNdxFeO3 solid solutions are described. Samples were prepared by the conventional solid-state sintering method. X-ray diffraction, 57Fe Mössbauer spectroscopy, and magnetoelectric effect measurements were applied as complementary methods to determine the structure and magnetic properties of materials. For (BiFeO3)x(BaTiO3)1-x solid solutions Mössbauer...
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How thermal stability of ionic liquids leads to more efficient TiO2-based nanophotocatalysts: Theoretical and experimental studies
PublicationIonic liquids (ILs) containing distinct nitrogen-bearing organic cations (pyridinium, pyrrolidinium, imidazolium, ammonium, morpholinium) were first used for the preparation of 23 IL-TiO2 types of composites by ionic liquid assisted solvothermal synthesis. These 23 optimal ILs structures (i.e. compounds exhibiting an optimal combination of specific properties, functionality, and safety) for synthesis and experimental validation...
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Experimental examination and modification of chip suction system in circular sawing machine
PublicationThe article presents the results of experimental examination of the wood chip suction system in the existing sliding table saw before and after its modifi cation. The studies focused on the extraction hood of the mentioned system. The methodical experimental research of the pressure distribution inside the hood during wood chip removal for the selected rotational speed of saw blades of 3500 and 6000 min-1 with a diameter of 300...