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Search results for: CURE KINETICS
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Properties of a lithium solid electrolyte gas sensor based on reaction kinetics
PublicationW artykule przedstawiono zasadę działania, budowę i właściwości czujnika gazu na bazie elektrolitu stałego z mobilnymi jonami litu. Czujnik został przygotowany w technologii grubowarstwowej. Przedstawiono wyniki badań czujnika w mieszaninach gazów toksycznych.
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Ab initio chemical kinetics of Isopropyl acetate oxidation with OH radicals
PublicationGlobal reactivity descriptors of isopropyl acetate (IPA) and thermo-kinetic aspects of its oxidation via OH radicals have been studied. Transition state theory (TST) was utilized to estimate the bimolecular rate constants. Ten oxidation pathways have been investigated, and all of them are exothermic. The potential energy diagram has been sketched using different pre- and post-reactive complexes for all reaction pathways. Rate coefficient...
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Thermal-Resistant Polyurethane/Nanoclay Powder Coatings: Degradation Kinetics Study
PublicationIn the present study, thermal degradation kinetics of polyurethane (PU) powder coatings reinforced with organo-modified montmorillonite (OMMT) was investigated. PU nanocomposites were prepared in different concentrations of 1, 3, and 5 wt.% of OMMT via the extrusion method. The microstructure of the nanocomposites was observed by scanning electron microscope (SEM) illustrating uniform dispersion of OMMT nano-clay platelets in the...
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<title>Manufacturing and measurements of triple-core, double-core, and twin-core single-mode soft-glass optical fibers</title>
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Biomedical Human Kinetics
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Limiting futile therapy as part of end-of-life care in intensive care units
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Utopian Kinetic Structures and Their Impact on the Contemporary Architecture
PublicationThis paper delves into relationships between twentieth century utopian concepts of movable structures and the kinematic solutions implemented in contemporary architectural projects. The reason for conducting this study is to determine the impact of early architectural conceptions on today's solutions. This paper points out close links that stem from the imagination of artists and architects working in 1960s and 70s and the solutions...
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GENETICS
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Oxidation kinetics of Zircaloy-4 alloy at 673 K determined by GDOES technique
PublicationOxidation of zirconium alloys is a process that takes place during the operation of nuclear reactors and is essential for assessing the durability of fuel claddings. The present study was aimed to determine the oxidation kinetics of the Zircaloy-4 alloy using GDOES (glow discharge optical emission spectroscopy) at temperature 673 K corresponding to the conditions of use of fuel pellets. The tests were performed on non-oxidized...
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Kinetics of Biotic and Abiotic CO Production during the Initial Phase of Biowaste Composting
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Thermoluminescence kinetics of undoped and doped (Ti, Cu, Ce) lithium aluminate crystals
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Vitamin D kinetics in the acute phase of critical illness: A prospective observational study
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Kinetics of spinodal decomposition in the Ising model with dynamic lattice liquid (DLL) dynamics
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The effect of slowly biodegradable substrate on the kinetics of biochemical processes in activated sludge bioreactors
PublicationCelem niniejszej rozprawy doktorskiej było określenie wpływu substratu wolnorozkładalnego (w postaci związków koloidalnych i zawiesinowych) na kinetykę wybranych procesów biochemicznych, zachodzących w komorach osadu czynnego (tj. denitryfikacja, uwalnianie i anoksyczny/tlenowy pobór fosforanów oraz pobór tlenu), opierając się na badaniach prowadzonych w dwóch dużych komunalnych oczyszczalniach ścieków "Wschód" w Gdańsku i "Dębogórze"...
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Numerical solution analysis of fractional point kinetics and heat exchange in nuclear reactor
PublicationThe paper presents the neutron point kinetics and heat exchange models for the nuclear reactor. The models consist of a nonlinear system of fractional ordinary differential and algebraic equations. Two numerical algorithms are used to solve them. The first algorithm is application of discrete Grünwald-Letnikov definition of the fractional derivative in the model. The second involves building an analog scheme in the FOMCON Toolbox...
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Kinetics of aquation of Ni(II) oxydiacetate complex induced by Fe(III) ions
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Kinetics of photochromic reactions of substituted azobenzenes in solutions, and in liquid crystalline and polymer matrices
PublicationBadano kinetykę fotochromowych reakcji pochodnych azobenzenu: eterów koronowych z resztą benzenu i 4-metoksy-4´-halogenoazobenzenów zdolnych do tworzenia fazy ciekłokrystalicznej. Fotoaktywne związki rozpuszczano w alkanach, polimerach i w ciekłokrystalicznej matrycy. Izomeryzacja odpowiada kinetyce pierwszego rzędu w niektórych polimerach, jednakże stwierdzono zróżnicowanie stałych szybkości reakcji. Termiczna izomeryzacja cis-trans...
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Experimental Study of Polish Sausage Drying Kinetics and Contraction by Image Data Analysis
PublicationThe goal of this paper has been to add an experimental data set for drying a meat product and provide a comparison with well-established thin-layer drying models. This article presented experimental investigations on the convective drying of Polish sausage slices at a temperature of 40°C. Slices have been in the thickness of 3 to 8mm. Measurements of mass loss and size change were performed. The data have been presented in the...
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Removal of diphenols using pine biochar. Kinetics, equilibrium, thermodynamics, and mechanism of uptake
PublicationThermal pyrolysis synthesized activated biochar from the Pinus elliottii sawdust (PS) at 600° C. The obtained activated biochar (PB600) was used for the removal of three diphenols, catechol (CAT), resorcinol (RES), and hydroquinone (HYD), which are utilized mainly in different industries. The PB600 was characterized by several analytical techniques. The BET surface area of 1473 m2.g−1 and a total pore volume of 0.707 cm3 g−1 was...
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The effect of slowly biodegradable substrate on the kinetics of biochemical processes in activated sludge bioreactors
PublicationCelem niniejszej rozprawy doktorskiej było określenie wpływu substratu wolnorozkładalnego (w postaci związków koloidalnych i zawiesinowych) na kinetykę wybranych procesów biochemicznych, zachodzących w komorach osadu czynnego (tj. denitryfikacja, uwalnianie i anoksyczny/tlenowy pobór fosforanów oraz pobór tlenu), opierając się na badaniach prowadzonych w dwóch dużych komunalnych oczyszczalniach ścieków "Wschód" w Gdańsku i "Dębogórze"...
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Kinetics of pollutants removal in vertical and horizontal flow constructed wetlands in temperate climate
PublicationThis paper reports a comparative study on kinetics of organic matter expressed as BOD5 and nitrogen removal in constructed wetlands operated in Poland. Analyzed data were collected at eight wetland systems, composed of subsurface flow beds: horizontal flow (HF) and vertical flow (VF), in different number and sequences. The analysis involved particularly mass removal rates (MRR) and first-order removal rate coefficients of BOD5...
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Polyurethane/Silane-Functionalized ZrO2 Nanocomposite Powder Coatings: Thermal Degradation Kinetics
PublicationA polyurethane (PU)-based powder coating reinforced with vinyltrimethoxysilane (VTMS)-functionalized ZrO2 nanoparticles (V-ZrO2) for thermal stability was developed. Chemical structure, microstructure and thermal degradation kinetics of the prepared coatings were investigated. The peak of aliphatic C–H vibrating bond in the Fourier transform infrared (FTIR) spectrum of V-ZrO2 was a signature of VTMS attachment. Scanning electron...
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Pharmaceutical care in the neonatal intensive care unit: Perspectives of Polish medical and pharmacy students
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Properties of nano-Fe3O4 incorporated epoxy coatings from Cure Index perspective
PublicationThe mission of an advanced epoxy-based nanocomposite coating is to provide a given substrate with protection against an unwelcome guest; e.g. corrosive molecules/media, environmental stress, flame, thermal degradation or microorganisms. In such systems, the degree to which superior properties can be guaranteed depends on the state of network formation in the epoxy in the presence of nanoparticles. For low-filled epoxy nanocomposite coatings,...
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On unique kinematics for the branching shells
PublicationWe construct the unique two-dimensional (2D) kinematics which is work-conjugate to the exact, resultant local equilibrium conditions of the non-linear theory of branching shells. Several types of junctions are described. For each type the explicit form of the principle of virtual work is derived.
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Models of the kinematics of lapping machines.
PublicationPrzedstawiono wyniki analiz symulacyjnych układów kinematycznych docierania jednotarczowego powierzchni płaskich. Analizowano układ standardowy i układy niekonwencjonalne, zmieniając ich parametry geometryczne i kinematyczne. Wytypowano układ optymalny w aspekcie równomierności zużycia tarczy docierającej.
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Smoothed transition curve for railways
PublicationThe work draws attention to the existing situation in the area of transition curves used in the geometric layouts of the railway track. Difficulties in the practical implementation and maintenance of very small horizontal ordinates of the transition curve and the ordinates of the gradient due to cant in the initial section, appearing on smooth transition curves, were indicated. The main reason for this situation was the excessive...
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The J-curve phenomenon revisited
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The role of pharmacist in palliative care
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A Note on Fractional Curl Operator
PublicationIn this letter, we demonstrate that the fractional curl operator, widely used in electromagnetics since 1998, is essentially a rotation operation of components of the complex Riemann–Silberstein vector representing the electromagnetic field. It occurs that after the wave decomposition into circular polarisations, the standard duality rotation with the angle depending on the fractional order is applied to the left-handed basis vector...
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Kinetic analysis of the stage for a high speed steam turbine
PublicationThis article analyzes possibilites of resonances within a control stage for a high speed steam turbine. This stage hase been based on assembling of a single blade to a rotating disk and increasing of rigidity of the system by using of a bandage. In the analysis will be nd a possiblity of resonance frequency, and mistuning by showing safety working ranges. The calculations have bean used the3D modal and harmonic analysis by the...
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Experimental methods in thermodynamic and kinetic studies on photocatalytic materials
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Victor Eremeev prof. dr hab.
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Which Curve Fits Best: Fitting ROC Curve Models to Empirical Credit-Scoring Data
PublicationIn the practice of credit-risk management, the models for receiver operating characteristic (ROC) curves are helpful in describing the shape of an ROC curve, estimating the discriminatory power of a scorecard, and generating ROC curves without underlying data. The primary purpose of this study is to review the ROC curve models proposed in the literature, primarily in biostatistics, and to fit them to actual credit-scoring ROC data...
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Decomposition of xenobiotics during visible light irradiation in the presence of immobilised photosensitisers: kinetics study
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Salt melt synthesis of curved nitrogen-doped carbon nanostructures: ORR kinetics boost
PublicationImplementing metal-free electrocatalysts for the oxygen reduction reaction (ORR) and revealing crucial chemical or topographical parameters driving their activity are vital for the development of power cells. The carbon-based catalysts are very often synthesized through carbonization of biopolymers, in particular, those one containing nitrogen groups such as chitosan. Unfortunately, the resulting carbonaceous materials usually...
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Thermal degradation kinetics of poly(propylene succinate) prepared with the use of natural origin monomers
PublicationLinear biobased polyester polyols were prepared with the use of succinic acid and 1,3-pro- panediol (both with natural origin). Tetraisopropyl orthotitanate (TPT) was used as a catalyst. In order to determine the effect of various synthesis temperature conditions on the thermal degradation kinet- ics, nine sequences of temperature conditions were used during two-step polycondensation reaction. Thermogravimetric analysis was conducted...
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Effects of the polyhistidine tag on kinetics and other properties of trehalose synthase from Deionococcus geothermalis
PublicationTwo recombinant trehalose synthases from Deinococcus geothermalis (DSMZ 11300) were compared. A significant influence of the artificial polyhistidine tag was observed in protein constitution. The recombinant trehalose synthase from D. geothermalis with His6 -tag has a higher K m value of 254 mM, in comparison with the wild-type trehalose synthase (K m 170 mM), and displayed a lower activity of maltose conversion when compared...
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Tb3+ ions in the presence of ZnS:Mn2+ nanocrystals incorporated into silica: Tb3+ and Mn2+ luminescence kinetics
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Fractional neutron point kinetics equations for nuclear reactor dynamics – Numerical solution investigations
PublicationThis paper presents results concerning numerical solutions to a fractional neutron point kinetics model for a nuclear reactor. The paper discusses and expands on results presented in (Espinosa-Paredes et al., 2011). The fractional neutron point kinetics model with six groups of delayed neutron precursors was developed and a numerical solution using the Edwards’ method was proposed (Edwards et al., 2002). The mathematical model...
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Thermodynamics and kinetics of amphotericin B self-association in aqueous solution characterized in molecular detail
PublicationAmphotericin B (AmB) is a potent but toxic drug commonly used to treat systemic mycoses. Its efficiency as a therapeutic agent depends on its ability to discriminate between mammalian and fungal cell membranes. The association of AmB monomers in an aqueous environment plays an important role in drug selectivity, as oligomers formed prior to membrane insertion – presumably dimers – are believed to act differently on fungal (ergosterol-rich)...
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Kinetics of Intermetallic Phase Precipitation in Manual Metal Arc Welded Duplex Stainless Steels
PublicationThe article presents the influence of heat treatment on the kinetics of transformations in lean duplex LDX2101 steel and a weld made of standard duplex 2209 material, which was welded by manual metal arc welding. Changes in the microstructure, hardness, and magnetic phase content were analyzed after heat treatment was conducted at a temperature of 800 °C for a period ranging from 15 to 1440 min. Light and scanning microscopy, Vickers...
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Screening stability, thermochemistry, and chemical kinetics of 3-hydroxybutanoic acid as a bifunctional biodiesel additive
PublicationThe thermo-kinetic aspects of 3-hydroxybutyric acid (3-HBA) pyrolysis in the gas phase were investigated using density functional theory (DFT), specifically the M06-2X theoretical level in conjunction with the cc-pVTZ basis set. The obtained data were compared with benchmark CBS-QB3 results. The degradation mechanism was divided into 16 pathways, comprising 6 complex fissions and 10 barrierless reactions. Energy profiles were calculated...
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Understanding the kinetics and atmospheric degradation mechanism of chlorotrifluoroethylene (CF2=CFCl) initiated by OH radicals
PublicationThe atmospheric degradation of chlorotrifluoroethylene (CTFE) by OH˙ was investigated using density functional theory (DFT). The potential energy surfaces were also defined in terms of single-point energies derived from the linked cluster CCSD(T) theory. With an energy barrier of −2.62 to −0.99 kcal mol−1 using the M06-2x method, the negative temperature dependence was determined. The OH˙ attack on Cα and Cβ atoms (labeled pathways...
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The application of Monod equation to denitrification kinetics description in the moving bed biofilm reactor (MBBR)
PublicationIn this paper, the kinetic constants Vmax and KCOD occurring in the Monod equation, which describe the denitrification process in the moving bed, are determined. For this purpose, a laboratory moving bed biofilm reactor (MBBR) was used. The filling of the reactor consisted of EvU Perl carriers. The experiment was carried out with an excess of nitrate, and denitrification rate was dependent on the concentration of external organic...
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Kinetics of Cross-Linking Reaction of Epoxy Resin with Hydroxyapatite-Functionalized Layered Double Hydroxides
PublicationThe cure kinetics analysis of thermoset polymer composites gives useful information about their properties. In this work, two types of layered double hydroxide (LDH) consisting of Mg2+ and Zn2+ as divalent metal ions and CO32− as an anion intercalating agent were synthesized and functionalized with hydroxyapatite (HA) to make a potential thermal resistant nanocomposite. The curing potential of the synthesized nanoplatelets in the...
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The level of spiritual care competence of Polish nurses and the psychometric properties of the spiritual care competence scale (SCCS)
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Grinding of cemented carbides with planetary kinematics
PublicationW pracy przeprowadzono wyniki badań szlifowania z wykorzystaniem nowoczesnej szlifierki planetarnej DLM 505 HS. Zastosowano jednolite narzędzie wykonane z ziarna diamentowego D107. W artykule wyprowadzono podstawowe równania ruchu w układzie planetarnym. Przedstawiono również wartości parametrów chropowatości, ubytku materiałowego i płasko-równoległości po szlifowaniu przedmiotów wykonanych z węglików spiekanych - HF10, D10x8 mm.
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Microgrinding with single-disk lapping kinematics.
PublicationGrinding operations are carried out with a variety of tool-workpiece configurations. The selection of a grinding process for a particular application depends on part shape, part size, ease of fixture, requirements concerning the acceptable shape errors. It is evident that lapping is very effective in eliminating the waviness while surface grinding is not. Dual disk machines for the double face grinding with planetary kinematics...
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Quality improvement in health care services
PublicationW niniejszym rozdziale zaprezentowano podstawowe formy doskonalenia jakości w usługach medycznych. Zaprezentowano kluczowe metody jakie mogą być stosowane przez zakłady opieki zdrowotnej, zarówno w tzw. "leczeniu zamkniętym" - szpitale, jak i "leczeniu otwartym" - przychodnie. Dokonano również analizy podejścia systemowego do doskonalenia jakości usług medycznych wiążącego się z reformami projakościowymi w ogólnonarodowych systemach...