Filtry
wszystkich: 3172
wybranych: 2210
wyświetlamy 1000 najlepszych wyników Pomoc
Wyniki wyszukiwania dla: NITRATE REDUCTION REACTION
-
Problem of Clogging in Drainage Systems in the Examples of the Zur and Podgaje Dams
PublikacjaDrainage plays an extremely important role in hydraulic structures, such as earth dams. Observations of drainage in hydraulic structures under various soil conditions indicate that the phenomenon of clogging can lead to a radical reduction in the efficiency of drainage, making it non-functional within a few years after construction. This article describes the problems of drainage clogging by iron oxide in the examples of the Zur...
-
Investigation of the influence of capilary effect on operation of the loop heat pipe
PublikacjaIn the paper presented are studies on the inestigation of the capillary forces effect inducted in the porous structure of a loop heat pipe using water and ethanol ad test fluids. The potential application of such effects is for example in the evaporator of the domestic micro-CHP unit, where the reduction of pumping power could be obtained. Preliminary analysis of the results indicates water as having the best potential for developing...
-
Macromodels for Efficient Analysis of Open-Region Problems Using the Finite Element Method
PublikacjaThis paper presents a local model-order reduction, called macromodeling, applied to speed-up the simulations of open-region problems, analyzed by means of finite element method. This technique is illustrated by a numerical example, which deals with a dielectric resonator antenna (DRA). The obtained results show that the proposed approach is reliable and can significantly increase the standard finite element method efficiency.
-
Interconnection of the Customer-Side Resources Using Single Phase VAPF
PublikacjaThe paper introduces method for utilization of the customer-side generated energy using single phase voltage active power filter. Structure and control method of the power electronics converter has been described and some simulation results are shown to prove usefulness of this arrangements. Proposed application realizes the following functions: power quality improvement, uninterruptible supplying and energy costs reduction.
-
Reduced order models in computational electromagnetics (in memory of Ruediger Vahldieck)
PublikacjaThis paper reviews research of Ruediger Vahldieck's group and the group at the Gdansk University of Technology in the area of model order reduction techniques for accelerating full-wave simulations. The applications of reduced order models to filter design as well as of local and nested(multilevel) macromodels for solving 3D wave equations and wave-guiding problems using finite difference and finite element methods are discussed.
-
Hostility bias or sadness bias in excluded individuals: Does anodal transcranial direct current stimulation of right VLPFC vs. left DLPFC have a mitigating effect?
PublikacjaExclusion has multiple adverse effects on individual’s well-being. It induces anger and hostile cognitions leading to aggressive behavior. The purpose of this study was to test whether exclusion would affect recognition of anger on ambivalent faces of the excluders. We hypothesized that exclusion would elicit more anger encoding (hostility bias) than inclusion, but this effect would be mitigated by anodal tDCS of right VLPFC...
-
Toward Mechanosynthesis of Diamondoid Structures: X. Commercial Capped CNT SPM Tip as Nowadays Available C2 Dimer Placement Tool for Tip-Based Nanofabrication
PublikacjaAccording to Drexler, advanced mechanosynthesis will employ advanced nano-machines, but advanced nano-machines will themselves be products of advanced mechanosynthesis. This circular relationship must be broken via TBN technology development. In this article, the possibility of using easily available commercial CNT tips to assemble carbon-based intermediate generations of nano-devices is considered. Mechanosynthesis of a target...
-
Myrosinase activity in different plant samples; optimisation of measurement conditions for spectrophotometric and pH-stat methods
PublikacjaMyrosinase found in Brassicaceae plants, is the enzyme responsible for hydrolysis of glucosinolates. As a result a variety of biologically active metabolites are liberated, whose importance in crop protection and especially in cancer chemoprevention is rapidly gaining recognition. The growing practical application of glucosinolate degradation products requires that sensitive and reliable methods of myrosinase activity determination...
-
Syntheses and Structures of Transition Metal Complexes with Phosphanylphosphinidene Chalcogenide Ligands
PublikacjaThe reactivity of the phosphanylphosphinidene complex [(DippN)2W(Cl)(η2-P-PtBu2)]− (1) toward chalcogens (Ch = Se, S) was studied. Reactions of stoichiometric amounts of 1 with chalcogens in DME yielded monomeric tungsten complexes with phosphanylphosphinidene chalcogenide ligands of the formula tBu2P−P−Ch (Ch = Se (in 2) and S (in 5)), which can be regarded as products of the addition of a chalcogen atom to a P=W bond in starting...
-
Dominant Pathways of Adenosyl Radical-Induced DNA Damage Revealed by QM/MM Metadynamics
PublikacjaBrominated nucleobases sensitize double stranded DNA to hydrated electrons, one of the dominant genotoxic species produced in hypoxic cancer cells during radiotherapy. Such radiosensitizers can therefore be administered locally to enhance treatment efficiency within the solid tumor while protecting the neighboring tissue. When a solvated electron attaches to 8-bromoadenosine, a potential sensitizer, the dissociation of bromide...
-
Poly(ε-Caprolactone)/Poly(Lactic Acid) Blends Compatibilized by Peroxide Initiators: Comparison of Two Strategies
PublikacjaPoly(ε-caprolactone) (PCL) and poly(lactic acid) (PLA) blends were compatibilized by reactive blending and by copolymers formed during reaction in the solution. The reactive blending of PCL/PLA was performed using di-(2-tert-butyl-peroxyisopropyl)benzene (BIB) or dicumyl peroxide (DCP) as radical initiator. PCL-g-PLA copolymers were prepared using 1.0 wt. % of DCP or BIB via reaction in solution, which was investigated through...
-
The Reactivity of Phosphanylphosphinidene Complexes of Transition Metals Toward Terminal Dihaloalkanes
PublikacjaThe reactivities of phosphanylphosphinidene complexes [(DippN)2W(Cl)(η2-P−PtBu2)]− (1), [(pTol3P)2Pt(η2- P=PtBu2)] (2), and [(dppe)Pt(η2-P=PtBu2)] (3) toward dihaloalkanes and methyl iodide were investigated. The reactions of the anionic tungsten complex (1) with stochiometric Br(CH2)nBr (n = 3, 4, 6) led to the formation of neutral complexes with a tBu2PP(CH2)3Br ligand or neutral dinuclear complexes with unusual tetradentate...
-
Investigations on the immunosuppressive activity of derivatives of mycophenolic acid in immature dendritic cell
PublikacjaThe main activity of mycophenolic acid (MPA) and its analogs is the inhibition of proliferation of T cells. Here, we hypothesized that MPA and its conjugates inhibits also the activity of antigen-presenting cells (APC) including dendritic cells (DCs). We tested the effect of novel amino acid derivatives of MPA and conjugates of MPA with acridines/acridones on DCs by flow cytometry, ELISA and MLR assay. Both acridines/acridone derivatives...
-
The Mechanism of a Retro-Diels–Alder Fragmentation of Luteolin: Theoretical Studies Supported by Electrospray Ionization Tandem Mass Spectrometry Results
PublikacjaThe mechanisms of retro-Diels–Alder fragmentation of luteolin are studied theoretically using the Density Functional Theory method (B3LYP hybrid functional) together with the 6-311++G(d,p) basis set and supported by electrospray ionization tandem mass spectrometry (ESI-MS) results. The reaction paths leading to the formation of 1,3A and 1,3B fragment ions observed as the main spectral features in the ESI-MS spectrum are described...
-
Surface and Trapping Energies as Predictors for the Photocatalytic Degradation of Aromatic Organic Pollutants
PublikacjaIn this study, anatase samples enclosed by the majority of three different crystal facets {0 0 1}, {1 0 0}, and {1 0 1} were successfully synthesized. These materials were further studied toward photocatalytic degradation of phenol and toluene as model organic pollutants in water and gas phases. The obtained results were analyzed concerning their surface structure, reaction type, and surface development. Moreover, the regression...
-
Numerical simulation of temperature distribution of heat flow on reservoir tanks connected in a series
PublikacjaThe flow of temperature distribution through a medium in thermodynamic studies plays an important role in understanding physical phenomena in chemical science and petroleum engineering, while temperature distribution indicates the degree of reaction that must be undergone to obtain the final product. Therefore, this paper aims to present and apply the exponential matrix algorithm (EMA), differential transformation algorithm (DTA),...
-
Sustainable utilization of copper post-flotation waste in cement composites
PublikacjaThe current way of managing the copper ore flotation waste is by placing it in waste neutralization facilities. However, flotation waste has great potential in application in cement composites. The article presents the detailed characteristics of post-flotation waste (PFW) and three types of cements: CEM I, CEM II/B-V, and CEM III/A, 42.5 MPa class. The post-flotation waste added for 20% of the cement mass increase the water demand...
-
Beeswax And Palmitic Acid Utilization With Heat Pipes For Electronics Cooling
PublikacjaThis paper presents an experimental study of heat pipes supported by phase change materials (PCMs) coated at their adiabatic sections in application for electronics cooling. The PCMs investigated in this research were palmitic acid and beeswax, the latter being considered as a more cost-effective alternative. The study focused on three powers: 20W, 25W, and 30W. The experimental results revealed that the incorporation of palmitic...
-
Increasing the Seismic Resistance of Wood-frame Buildings by Applying PU Foam as Thermal Insulation
PublikacjaWood-frame buildings are very common in regions that are exposed to earthquakes. Most of residential buildings are constructed using this technology; therefore, the seismic resistance of them is really essential in order to prevent human losses and structural damage. The aim of the present article is to show the results of the detailed numerical FEM analysis focused on the seismic behaviour of the wood-frame house with different...
-
High catalytic performance of laccase wired to naphthylated multiwall carbon nanotubes
PublikacjaThe direct electrical connection of laccase on the electrode surface is a key feature in the design of efficient and stable biocathodes. However, laccases can perform a direct electron transfer only when they are in the preferable orientation toward the electrode. Here we report the investigation of the orientation of Laccase from Amano on multi-walled carbon nanotube surface modified with naphthalene group. Naphthylated multi...
-
Effect of interlayer bonding quality of asphalt layers on pavement performance
PublikacjaThe quality of interlayer bonding at the interfaces between the asphalt layers in flexible pavements affects the overall pavement performance. Lack or partial lack of interlayer bonding between asphalt layers can cause pavement's premature failures such as rutting, slippage of the wearing course, cracking or simply a reduction in the calculated fatigue life of the pavement structure. This paper shows the case studies of investigation...
-
Noise sources in Raman spectroscopy of biological objects
PublikacjaWe present an overview of noise sources deteriorating the quality of the recorded biological Raman spectra and the ability to determine the specimen composition. The acquired Raman spectra exhibit intense additive noise components or drifts because of low intensity of the scattered light. Therefore we have to apply expensive or bulky measurement setups to limit their inherent noise or to apply additional signal processing to reduce...
-
Graphene oxide, reduced graphene oxide and composite thin films NO2 sensing properties
PublikacjaA graphene oxide (GO), reduced graphene oxide (RGO) and poly(3,4-ethylenedioxytiophene)- reduced graphene oxide (PEDOT-RGO composite) gas sensors were successfully fabricated using an electrodeposition method. The electrodeposition was carried out in aqueous GO dispersions. In order to obtain RGO and PEDOT-RGO, the electrochemical reduction of GO and PEDOT-GO was carried out in 0.1 M KCl at constant potential of −0.85 V. The GO, RGO...
-
Experimental and numerical investigation of mercury removal from flue gas by sorbent polymer composite
PublikacjaThis paper presents an experimental and numerical investigation of the performance of a sorbent polymer composite (SPC) material used for removing mercury from the flue gases in a full-scale industrial installation. The investigated material is an attractive alternative to activated carbon, which is commonly used for this purpose. While the application of the SPC is characterized by high capital expenditures, this technology offers...
-
Hybrid Model of Axially Moving Continua
PublikacjaThe paper introduces the method of the model reduction of systems that experience a Coriolis acceleration component. It causes that system equations are non-self-adjoined. To avoid such problem modal, reduced model is built up for the system without Coriolis acceleration terms which are next included by application of any lumping technique. Hence, the final reduced model is a hybrid one, obtained by both lumping and modal methods...
-
Online Sound Restoration for Digital Library Applications
PublikacjaA system for sound restoration was conceived and engineered having the following features: no special sound restoration software is needed to perform audio restoration by the user, the process of restoration employs automatic reduction of noise, wow and impulse distortions performed in the online mode, no skills in digital signal processing from the user are needed. The principles of the created system and its features as well...
-
Influence of PWHT Parameters on the Mechanical Properties and Microstructural Behavior of Multi-Pass GTAW Joints of P92 Steel
PublikacjaThe 9% Cr steels were developed for ultra-supercritical (USC) power plants to meet the requirements of high operating temperature and pressure. These steels are produced to operate at high temperatures where impact toughness is not a concern; however, it becomes important for the welded joints to have good impact toughness at room temperature for manufacturing. The present work investigates the effect of the post-weld heat treatment...
-
Synthesis and application of oligomer with hydroxy groups based on peroxy derivative of ED-24 epoxy resin and POLYTHF-2000 oligoether
PublikacjaNew oligomer with peroxy, primary and secondary hydroxy groups has been synthesized on the basis of peroxy derivative of ED-24 epoxy resin (PO) and PolyTHF-2000 oligoether according to the developed procedure. The effect of the catalysts nature and amount, temperature and process time on the reaction rate has been studied. Benzyltriethylammonium chloride, potassium hydroxide,1,4-diazobicyclooctane and the mixture composed of benzyltriethylammonium...
-
Synthesis and structure determination of 2,3-diaryl-9,9-dioxo-1H-9-thia-1,4,4a,7,10-pentaazaphenanthrene-2-ols
Publikacja3-Amino-1,1-dioxopyrido[4,3-e]-1,4,2-dithiazine has been synthesized and applied to the synthesis of 3-amino-2-(4-thioxo-1,4-dihydropyridin-3-ylsulfonyl)guanidine. The reaction of the aminoguanidine with the appropriate 1,2-diarylethane-1,2-diones afforded 2,3-diaryl-9,9-dioxo-1H-9-thia-1,4,4a,7,10-pentaazaphenanthrene-2-ol derivatives. The structure of these compounds, which represent a novel heterocyclic ring system, was confirmed...
-
Syntheses and structures of the first terminal phosphanylphosphido complexes of molybdenum(IV)
PublikacjaThe reactions of R2P-P(SiMe3)Li (R = tBu, iPr2N) with [Cp2MoCl2] yield terminal phosphanylphosphido complexes formally via the insertion of the phosphinidene P-atom into the C - H bond of a cyclopentadienyl ring and the migration of the hydrogen atom or SiMe3 moiety to the molybdenum centre. Solid state structures of [Cp(C5H4P-PtBu2)MoH], [Cp(C5H4P-PtBu2)Mo(SiMe3)] and [Cp{C5H4P-P(NiPr2)2}Mo(SiMe3)] were established by single crystal...
-
Two-criteria optimisation problem for ventral hernia repair
PublikacjaTwo-criteria optimisation problem related to laparoscopic ventral hernia repair is formulated in this paper. An optimal implant from a given set and its orientation is sought. The implant is subjected to kinematic extortions due to a patient’s body movement and intra-abdominal pressure. The first criterion of the optimisation problem deals with the reaction force in the implant fastener, while the deflection of the implant constitutes...
-
Revalorisation of the Szewalski’s concept of the law of varying the last-stage blade retraction in a gas-steam turbine
PublikacjaThe article presents the implementations of the free vortex law to the blade of the last stage of a gas-steam turbine. First, a thermodynamic analysis was carried out, determining the parameters at the inlet, then the number of stages of the high and low-pressure part of the turbine was constructed, together with the kinematics and velocity vectors for subsequent stages of the axial turbine. The last step of article was to take...
-
Hybrid model of moving or rotating continua
PublikacjaThe paper introduces the method of the model reduction of systems that experience a Coriolis acceleration or gyroscopic effect component. In such causes that corresponding system equations are non-self-adjoined. Modal reduced model is built up for the system without Coriolis or gyroscopic effect terms. These phenomena are next included by application of any lumping technique. Hence, the final reduced model is a hybrid one, obtained...
-
The Method of Finding the Optimal Spindle Speed When Milling Flexible Details
PublikacjaThe paper presents a new method of vibration reduction during milling of flexible details. The method consists in selecting the optimal spindle speed, based on the natural frequency of the workpiece. For this purpose, an original method was created, which is based on minimizing the work of cutting forces in the direction of the depth of cutting. The effectiveness of the method has been proved by comparing the RMS values of vibration...
-
Degradation of electrical performance of a crystalline photovoltaic module due to dust deposition in northern Poland
PublikacjaThe reduction in power output caused by the accumulation of dust on the photovoltaic module surface is an important problem and should receive much more attention in the literature. This study was an evaluation of the performance degradation of crystalline photovoltaic modules due to natural and simulated dust deposition. Dust is created from powdered grains of sand and particles of different bodies. Dust originates from different...
-
Investigation and operation problems of metal tanks in Poland
PublikacjaThe paper consists of three parts concerned with steel cylindrical, vertical tank for liquid fuel. In the first part the present trends in tank design and building in Poland are described. The main are: · reduction of environment contamination danger caused by tank leakage and hydrocarbons evaporation, · increasing capacity of new tanks (100000 m3 and more) due to economic factor - reduction of steel amount per m3 of storage capacity....
-
Refining of Secondary Pb with Retention of Sn Using Al and Ca Additions
PublikacjaLead grid from spent lead-acid batteries contains significant amounts of tin and antimony. In classical pyro-refining processes of lead, tin oxidizes and is transferred to dross, making its recovery problematic and expensive. This paper presents an innovative method of pyro-refining lead using metallic aluminum and calcium to purify the lead from contaminants while retaining a higher amount of tin than in the traditional process....
-
Mitigating the Energy Consumption and the Carbon Emission in the Building Structures by Optimization of the Construction Processes
PublikacjaFor decades, among other industries, the construction sector has accounted for high energy consumption and emissions. As the energy crisis and climate change have become a growing concern, mitigating energy usage is a significant issue. The operational and end of life phases are all included in the building life cycle stages. Although the operation stage accounts for more energy consumption with higher carbon emissions, the...
-
Experimentally Aided Operational Virtual Prototyping to Predict Best Clamping Conditions for Face Milling of Large-Size Structures
PublikacjaVibrations occurring during milling operations are one of the main issues disturbing the pursuit of better efficiency of milling operations and product quality. Even in the case of a stable cutting process, vibration reduction is still an important goal. One of the possible solutions to obtain it is selection of the favorable conditions for clamping the workpiece to the machine table. In this paper, a method for predicting and...
-
Triangulation-based Constrained Surrogate Modeling of Antennas
PublikacjaDesign of contemporary antenna structures is heavily based on full-wave electromagnetic (EM) simulation tools. They provide accuracy but are CPU-intensive. Reduction of EM-driven design procedure cost can be achieved by using fast replacement models (surrogates). Unfortunately, standard modeling techniques are unable to ensure sufficient predictive power for real-world antenna structures (multiple parameters, wide parameter ranges,...
-
Structural and electrical properties of Cr-doped SrTiO 3 porous materials
PublikacjaSeries of single-phase materials with assumed formula SrTi1−xCrxO3 (where x = 0, 1, 4, 6 mol.%) were obtained by sol-gel method. The structure and microstructure of materials were characterised by X-ray diffraction and scanning electron microscopy methods. Moreover, the study of electrical properties and evaluation of chemical stability in CO2/H2O atmosphere was performed by electrochemical impedance spectroscopy and thermogravimery...
-
Poroelastic Road Surface – a Promising Road Traffic Noise Abatement Solution
PublikacjaRoad surfaces have a direct impact on the generation of noise by rolling tyres, the main and dominant source of noise of moving vehicles, as well as may affect propagation of noise emitted by all noise sources of a vehicle. Thus there is no doubt that pavement should be considered as one of the major potential road traffic noise abatement measure. Low noise pavements of existing types may in new conditions provide up to 8 dB of...
-
Multi-fidelity EM simulations and constrained surrogate modelling for low-cost multi-objective design optimisation of antennas
PublikacjaIn this study, a technique for low-cost multi-objective design optimisation of antenna structures has been proposed. The proposed approach is an enhancement of a recently reported surrogate-assisted technique exploiting variable-fidelity electromagnetic (EM) simulations and auxiliary kriging interpolation surrogate, the latter utilised to produce the initial approximation of the Pareto set. A bottleneck of the procedure for higher-dimensional...
-
In Vitro and In Vivo Imaging-Based Evaluation of Doxorubicin Anticancer Treatment in Combination with the Herbal Medicine Black Cohosh
PublikacjaAs a substitution for hormone replacement therapy, many breast cancer patients use black cohosh (BC) extracts in combination with doxorubicin (DOX)-based chemotherapy. In this study, we evaluated the viability and survival of BC- and DOX-treated MCF-7 cells. A preclinical model of MCF-7 xenografts was used to determine the influence of BC and DOX administration on tumor growth and metabolism. The number of apoptotic cells after...
-
The Influence of Global Corrosion Degradation on Localized Damage Detection Using Guided Waves
PublikacjaThis paper presents the results of a numerical analysis of the influence of corrosion degradation of metal plates on the wave propagation phenomenon. There are several different corrosion types, but general and pitting corrosion are the most common. General corrosion is more or less uniformly distributed over the entire exposed surface of the metal while pitting corrosion takes the form of localized cracks. Because the general...
-
The influence of moderate pressure and subzero temperature on the shelf life of minced cod, salmon, pork and beef meat
PublikacjaThe effect of moderate pressure at subzero temperature on natural microflora of minced cod, salmony, pork and beef meat was studied. Pressure of 193 MPa at –20 °C caused reduction of total bacterial count in pork and beef meat by 1.1 and 0.6 log cycles, respectively, and by about 1.5 log cycles in fish meat. Under these conditions the psychrophilic and psychrotophic bacteria were below the detection limit (<10CFU/g of sample) in...
-
Online sound restoration system for digital library applications
PublikacjaAudio signal processing algorithms were introduced to the new online non-commercial service for audio restoration intended to enhance the content of digitized audio repositories. Missing or distorted audio samples are predicted using neural networks and a specific implementation of the Jannsen interpolation method based on the autoregressive model (AR) combined with the iterative restoring of missing signal samples. Since the distortion...
-
Experimental Research on the Energy Efficiency of a Parallel Hybrid Drive for an Inland Ship
PublikacjaThe growing requirements for limiting the negative impact of all modes of transport on the natural environment mean that clean technologies are becoming more and more important. The global trend of e-mobility also applies to sea and inland water transport. This article presents the results of experimental tests carried out on a life-size, parallel diesel-electric hybrid propulsion system. The eciency of the propulsion system was...
-
Further development of the poroelastic road surface within the new Polish project SEPOR
PublikacjaRoad surfaces have a direct impact on noise generated by rolling tyres, the main and dominant source of noise of moving vehicles. Road surface texture, porosity and stiffness/elasticity govern the pavement contribution to tyre/road noise the most. An experimental PoroElastic Road Surface (PERS) is a wearing course with a high content of interconnected voids (pores) and with an elastic behavior due to the use of small particles...
-
Experimental and DFT insights into an eco-friendly photocatalytic system toward environmental remediation and hydrogen generation based on AgInS2 quantum dots embedded on Bi2WO6
PublikacjaBismuth tungstate (Bi2WO6) can work as a photocatalyst but suffers from rapid recombination of photogenerated charge carriers. Herein, density functional theory (DFT) simulations revealed that the formation of a thermodynamically stable AgInS2(112)/Bi2WO6(010) heterojunction could promote charge separation and enhance the photoactivity of Bi2WO6. To confirm these theoretical predictions, a new type of photocatalysts in the form...