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Wyniki wyszukiwania dla: co2
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Wpływ redukcji emisji CO2 na funkcjonowanie sektorów biopaliw transportowych w Polsce ze szczególnym uwzględnieniem sektora bioetanolu
PublikacjaW artykule omówione zostały zagadnienia dotyczące produkcji bioetanolu w Polsce, w aspekcie wymogów unijnych. Artykuł prezentuje ponadto modele badawczo-decyzyjne, na podstawie których zostały zrealizowane badania wśród przedsiębiorstw produkujących bioetanol oraz model zalecany na przyszłość. Do zaprezentowanych przykładów przedsiębiorstw produkcyjnych bioetanol 1. generacji należy odnieść się w kontekście zmian techniczno-technologicznych...
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CO2 capture using steam ejector condenser under electro hydrodynamic actuator with non-condensable gas and cyclone separator: A numerical study
PublikacjaThe concept for condensation of steam and CO2 separation in a negative CO2 emission gas power plant involves the utilization of a steam ejector condenser (SEC) for direct-contact condensation of vapor with inert gas (CO2) on a spray of subcooled liquid, integrated with a separator to produce pure CO2. Due to the increasing diffusion resistance and reduced convective heat transfer between the steam and subcooled water phases...
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Influence of selected CO2 absorption promoters on the characteristics of calcium carbonate particles produced by carbonation of the post-distillation liquid from the Solvay process
PublikacjaThe aim of this work is to compare the effect of selected process parameters, gas flow rate, CO2 absorption promoter concentration and its pKa, on the precipitation of CaCO3 by the gas-liquid method using a model post-distillation liquid from the Solvay process. To ensure effective capture of CO2, the absorption promoters used were ammonia, triethanolamine and triethylamine. The Box-Behnken Design was applied to plan the experiments....
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Synergistic effects of a swirl generator and MXene/ water nanofluids used in a heat exchanger pipe of a negative CO2 emission gas power plant
Publikacjafocus on optimizing heat exchangers contributes to improved temperature control mechanisms, ensuring the sustainable operation of innovative power plants working towards negative CO2 emissions. In the realm of oxy-combustion within Negative CO2 Emission Power Plants (nCO2PP), the temperature of combustion products surpasses 3000 (K). Addressing this challenge, the imperative arises to reduce these elevated temperatures to a manageable...
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High-temperature Co-electrolysis of CO2/H2O and direct methanation over Co-impregnated SOEC. Bimetallic synergy between Co and Ni
PublikacjaTo study the synergy between the transition metals for enhancing the electrochemical and chemical activity, a series of SOECs were modified with a small amount of Co ions, namely 1.8, 3.6, and 5.4 wt% in the reduced state. The addition of βCD into the precursor solution allowed for extremely fine dispersion of Co species across the Ni-YSZ cermet structure. The sample containing 3.6 wt% Co reached an outstanding over 2.5-times-higher...
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An assessment of regulated emissions and CO2 emissions from a European light-duty CNG-fueled vehicle in the context of Euro 6 emissions regulations
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Exergy analysis of a negative CO2 emission gas power plant based on water oxy-combustion of syngas from sewage sludge gasification and CCS
PublikacjaA power cycle with water-injected oxy-combustion (water cycle) is investigated by exergy analysis. It is fueled with syngas (aka. producer gas) from gasification of sewage sludge. The cycle is equipped with a spray-ejector condenser (SEC). CO2 is separated and compressed for transportation and storage. The net delivered electric power is 31% of the fuel exergy. The task efficiency is 39% when the flue gas bleed to gasification...
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CO2 Capture by Virgin Ivy Plants Growing Up on the External Covers of Houses as a Rapid Complementary Route to Achieve Global GHG Reduction Targets
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Analiza procesu rozdrabniania biomateriałów w młynie walcowym z płytą międzywalcową w ujęciu emisji CO2. Cz. I. Składowe modelu
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Multifunctional nitrogen-doped nanoporous carbons derived from metal–organic frameworks for efficient CO2 storage and high-performance lithium-ion batteries
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An influence of molecular weight, deacetylation degree of chitosan xerogels on their antimicrobial activity and cytotoxicity. Comparison of chitosan materials obtained using lactic acid and CO2 saturation.
PublikacjaThis paper presents a comparison of the antimicrobial activity and cytotoxicity against L929 cells of chitosan xerogels prepared by dissolving the polymer in a solution of lactic acid (LA) or carbonic acid (CO2) and then freeze-drying. There was no simple relationship between the antimicrobial activity and cytotoxicity of the samples obtained using both techniques (LA and CO2). Chitosan materials obtained by the LA method in a...
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Some coatings of high cavitation resistance produced by CO2 laser beam. XIV International Symposium on Gas Flow, Chemical Lasers and High Power Lasers.
PublikacjaPrzedstawiono wyniki badań odporności kawitacyjnej stali 2H13, 45 i żelaza Armco po laserowym stopowaniu ich powierzchni różnymi kompozycjami proszków Co, Mo, Ni, Mn i Cr, Ti. Wykazano różne własności kawitacyjne otrzymanych warstw w zależności od otrzymanej mikrostruktury.
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Differing responses of the estuarine bivalve Limecola balthica to lowered water pH caused by potential CO2 leaks from a sub-seabed storage site in the Baltic Sea: An experimental study
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Comparative study of a combined heat and power plant retrofitted by CO2 capture during the combustion of syngas from sewage sludge gasification versus zero-emission combustion of hydrogen produced using renewables
PublikacjaWith ecological requirements aimed at limiting the production of CO2, it is necessary to produce all, or most of the energy from RES. During the transformation process, ecological and highly efficient combustion power plants will be needed. The classic cycle of combined heat and power (CCGT) with green improvements will continue to be one of the most suitable technologies for this task. This article presents the modernization of...
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Effect of selected ammonia escape inhibitors on carbon dioxide capture and utilization via calcium carbonate precipitation
PublikacjaCarbon dioxide was used to precipitate CaCO3 with CaCl2 solution in the presence of NH3 as a CO2 absorption promoter. Compounds that were previously indicated as inhibitors of ammonia escape during CO2 absorption were also added to the reaction mixture. Inorganic salts, i.e. ZnCl2, CuCl2, CoCl2, and organic substances, i.e. glycerol, ethylene glycol and triethanolamine were tested inhibitors in this work. A model post-distillation...
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O 1s excitation and ionization processes in the CO2molecule studied via detection of low-energy fluorescence emission
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Solid-Contact pH Sensor without CO2Interference with a Superhydrophobic PEDOT-C14as Solid Contact: The Ultimate “Water Layer” Test
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Coordination polymers of Fe(iii) and Al(iii) ions with TCA ligand: distinctive fluorescence, CO2uptake, redox-activity and oxygen evolution reaction
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Cement kiln dust
PublikacjaThe volume of cement production in the world has remained at the level of approxi mately 4.1 billion tons/year. The cement production process is energy intensive and is the world’s leading emitter of carbon dioxide. Therefore, the main activities cement plants are aimed at introducing technologies changes in production of clinkier.The construction industry is responsible for the majority of CO2 emissions to the atmosphere: the...
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Solubility of carbon dioxide in water: Some useful results for hydrate nucleation
PublikacjaIn this paper, the solubility of carbon dioxide (CO2) in water along the isobar of 400 bar is determined by computer simulations using the well-known TIP4P/Ice force field for water and the TraPPE model for CO2. In particular, the solubility of CO2 in water when in contact with the CO2 liquid phase and the solubility of CO2 in water when in contact with the hydrate have been determined. The solubility of CO2 in a liquid–liquid...
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Carbon dioxide sequestration by industrial wastes through mineral carbonation: Current status and perspectives
PublikacjaMineral carbonation using natural minerals or industrial wastes is a safe and promising strategy for CO2 sequestration. Application of industrial wastes for this purpose has significant ecological and environmental value, which is one of the key green technologies in the global carbon mitigation. This review summarizes the current research status of CO2 mineralization by industrial wastes. This work surveys the mechanisms and capacities...
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Wyznaczanie współczynników dyfuzji dwutlenku węgla przez membrany ciekłe wysycane cieczą jonową
PublikacjaZmniejszenie emisji związków węgla, głównie CO2, powstających w procesach przemysłowych, jest w chwili obecnej jednym z najważniejszych zagadnień ochrony środowiska. Ciecze jonowe odgrywają istotną rolę w projektowaniu technologii selektywnej separacji CO2 z mieszanin gazowych ze względu na wysoką zdolność do absorpcji CO2 przy jednoczesnej niskiej współabsorpcji innych gazów
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A method to monitor urinary carbon dioxide in patients with septic shock
PublikacjaSevere sepsis and septic shock are life-threatening conditions with mortality rates exceeding 31% (Levy et al., 2012) [1]. Septicemia was the most expensive US hospital condition in 2011 (Torio and Andrews, 2006)[2]. Urinary carbon dioxide may provide rapid, clinically useful information about a patient’s status, empowering physicians to intervene earlier and improve septic shock mortality. The objective of this paper is to validate...
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Solubility of Carbon Dioxide in Deep Eutectic Solvents Based on 3-Amino-1-Propanol and Tetraalkylammonium Salts at Low Pressure
PublikacjaDeep eutectic solvents (DESs) became an object of a great interest as an alternative to ionic liquids (ILs) and commonly used in CO2 capture amine solutions. In the present study, five different DESs based on 3-amino-1-propanol as physical-chemical CO2 absorbents were used. The composition was chosen in order to estimate the effects of hydrogen bond acceptor:hydrogen bond donor (HBA:HBD) molar ratio, anion type and length of alkyl...
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Wyznaczanie współczynników dyfuzji tlenku węgla (IV) przez membrany wysycone cieczą jonową = Determination of carbon dioxide diffusion coefficients in supported ionic liquids membranes
PublikacjaWykazano możliwość zastosowania imidazoliowych cieczy jonowych osadzonych na nośnikach polimerowych SILM (supported ionic liquids membranes) do absorpcji CO2. W badaniach wykorzystano sole imidazoliowe posiadające w strukturze aniony fluoroalkilowe typu [Tf2N] i [TfO], które selektywnie separują tlenek węgla (IV). Wyznaczono współczynniki dyfuzji CO2 przez poszczególne SILM na podstawie ilości dyfundującego CO2 przez powierzchnię...
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Analysis of cyclone separator solutions depending on spray ejector condenser conditions
PublikacjaThe core design strategy for minimizing CO2 emissions in gas power plant entails combining a spray ejector condenser (SEC) and separator to accomplish steam condensation and CO2 purification. This innovative process involves direct-contact condensation of steam with CO2, facilitated by interaction with a subcooled water spray, along with a cyclone separator mechanism intended for generating pure CO2. The investigation of the SEC...
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
PublikacjaCu and Ag enhance the photocatalytic activities of metal–organic frameworks (MOFs) toward CO2 conversion because of their CO2 adsorption capacities and effects on the lowest unoccupied molecular orbital (LUMO) overpotentials of MOFs. However, to date, targeted introduction of metals into MOFs to achieve visible (Vis)- light-active photocatalysts for CO2 photoconversion has not been realized. Herein, a series of aminefunctionalized...
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Searching for Solvents with an Increased Carbon Dioxide Solubility Using Multivariate Statistics
PublikacjaIonic liquids (ILs) are used in various fields of chemistry. One of them is CO2 capture, a process that is quite well described. The solubility of CO2 in ILs can be used as a model to investigate gas absorption processes. The aim is to find the relationships between the solubility of CO2 and other variables—physicochemical properties and parameters related to greenness. In this study, 12 variables are used to describe a dataset...
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Influence of Ionic Liquid Structure on Supported Ionic Liquid Membranes Effectiveness in Carbon Dioxide/Methane Separation
PublikacjaThis paper indicates the possibility of application of imidazolium ionic liquids immobilized in polymeric supports—supported ionic liquid membranes—in CO2 separation from gaseous streams (e.g., biogas). Imidazolium salts containing alkyl fluoride anions, bis(trifluoromethylsulfonyl)imide and trifluoromethanesulfonate, selectively separating CO2 were used. The permeability of CO2 through membranes was investigated under gas pressure...
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Improving carbon dioxide capture in aqueous ammonia solutions by fine SiO2 particles
PublikacjaAmmonia solutions are considered to be effective solvents for carbon dioxide absorption. Despite the numerous advantages of these solvents, their high volatility is a significant technical and economic problem. Therefore, in this work, silica particles were used as additives to improve CO2 absorption and inhibit NH3 desorption. SiO2 microparticles and colloidal SiO2 particles in the concentration range of 0-0.15 wt.% were used...
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Analysis of cyclone separator solutions depending on SEC outlet conditions in nCO2PP
PublikacjaUtilization of spray ejector condenser in order to carry out direct-contact condensation of vapour with inert gas (CO2) on a spray of subcooled liquid integrated with separator (to make pure CO2) has been proposed for the task of condensation and CO2 separation in the negative CO2 emission gas power plant. Condensation and separation has a significant impact on the thermodynamic efficiency of the entire negative CO2 emission gas...
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Photoconversion of carbon dioxide to methane and light hydrocarbons
PublikacjaFotokonwersja ditlenku węgla do lekkich węglowodorów jest czystym i przyjaznym dla środowiska procesem, pozwalającym na obniżenie emisji CO2 przy jednoczesnym generowaniu paliwa. Badanie efektywności procesu fotokonwersji CO2 prowadzono w obecności promieniowania UV-Vis, pary wodnej oraz fotokatalizatorów Ag-TiO2, Au-TiO2, Ag/Au-TiO2 otrzymanych w mikroemulsji woda/AOT/cykloheksan. Najwyższą aktywność w procesie fotoredukcji...
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Free volume in physical absorption of carbon dioxide in ionic liquids: Molecular dynamics supported modeling
PublikacjaUnderstanding the mechanisms underlying the carbon dioxide (CO2) absorption in ionic liquids (ILs) is the key to their efficient utilization in industrial flue gas treatment. One of the parameters considered substantially important in the process is the Free Volume. In this study, the Fractional Free Volume (FFV) of 73 ILs was calculated using Molecular Dynamics (MD). A quantitative Structure-Property Relationship (QSPR) study...
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In situ study of a composition of outlet gases from biogas fuelled Solid Oxide Fuel Cell performed by the Fourier Transform Infrared Spectroscopy
PublikacjaThe purpose of this study was to develop a method and software based on the Fourier Transform Infrared Spectroscopy for the in-situ, quantitative analysis of the composition of outlet gases from Solid Oxide Fuel Cell (SOFC). The calibration procedure performed at the beginning of the experiment indicated a polynomial dependence between the concentration of a calibrating gas (CO, CO2, CH4) and the corresponding integrated absorbance in...
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Methane formation over TiO2–based photocatalysts: reaction pathways
PublikacjaThe effects of organic impurities adsorbed or incorporated into semiconductors structure on the photocatalytic products are noteworthy. For this purpose, the as-prepared Ag, Au and Pdmodified TiO2 samples were exposed to UV-vis irradiation in various gas atmospheres (CO2, N2, 600 ppm CO2 in N2, and 13CO2) in order to clarify the route of CH4 formation in the process of photocatalytic CO2 reduction. In the presented research it...
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Advanced local energy planning using the ALEP-PL computer software
PublikacjaPrzedstawiono autorski system komputerowy ALEP-PL do gromadzenia i agregacji danych o lokalnych obiektach energetycznych. System pozwala na analizy senariuszowe poprzez bilanse zapotrzebowania na paliwa i energie oraz poprzez wskaźnikowe wyznaczanie wilekości emisji CO2. Dodatkowo, dzięki wybudowanemu w system ALEP-PL zestawowi technologii modernizacyjnych, aplikacja umożliwia opracowywanie strategii redukcji emisji CO2, poprawy...
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Solvent dependency of carbon dioxide Henry's constant in aqueous solutions of choline chloride-ethylene glycol based deep eutectic solvent
PublikacjaThe Henry's constants of carbon dioxide absorbed in aqueous solutions of ethaline (choline chloride-ethylene glycol) were determined for temperatures ranging from 303.15 to 323.15 K based on solubility measurement at CO2 pressure ranging from 0 to 6 bar (0.6 MPa). These studies revealed that the Henry's constant increased with the increase of temperature. Data indicated the highest capacity of CO2 absorption is obtained for ethaline...
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Modelling long-term technological transition of Polish power system using MARKAL: Emission trade impact
PublikacjaThe need for technological transition of electricity production becomes a global problem. However, in coal-dominated Polish power system this need is even more crucial than anywhere, since technical lifetime of the most domestic power plants is ending. In this paper, the impact of the EU Emission Trading Scheme (EU ETS) for CO2 combined with sulfur dioxide (SO2) and nitrogen oxides (NOx) emission trading mechanism on power technology...
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Impact of trajectory simplification methods on modeling carbon dioxide emissions from ships
PublikacjaModels of ship fuel consumption and emissions play an essential role in estimating global shipping’s greenhouse gas emissions. They are also widely used for verification of reported CO2 emissions for systems like EU MRV (Monitoring, Reporting and Verification) or IMO DCS (Data Collection System). Such models achieve high accuracy using historical spatiotemporal information about each ship from AIS data. However, this approach requires substantial...
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Wpływ fazy nagrzewania silnika samochodowego na zużycie paliwa
PublikacjaW referacie przedstawiono wybrane problemy wpływu parametrów rozgrzewania silnika na zużycie paliwa. Wymieniono przewidywane ograniczenia prawne Unii Europejskiej co do emisji CO2.
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Badania naprężeń własnych laserowo przetapianej stali C45.
PublikacjaPraca prezentuje badania wpływu parametrów laserowego przetapiania stali C45 za pomocą wiązki lasera CO2 o mocy 6 kW na wielkość naprężeń własnych.
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Synteza bio-cyklicznych węglanów z wykorzystaniem oligoeteroli różniących się masą molową
PublikacjaCykliczne węglany mogą być otrzymywane w wyniku cykloaddycji CO2 do eterów glicydylowych. Biorąc pod uwagę stopniowe wyczerpywanie się, a co za tym idzie, zauważalny wzrost cen substratów ropopochodnych należy wziąć pod uwagę zastąpienie surowców petrochemicznych przez związki pochodzenia naturalnego. Ponadto, wykorzystanie CO2 przyczynić się może do rozwoju perspektyw utylizacji tego gazu w syntezach organicznych. Otrzymanie węglanów...
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Możliwość redukcji emisji C02 dzięki zastosowaniu geosyntetyków
PublikacjaZastosowanie geosystemów jako rozwiązania zamiennego do konstrukcji klasycznych. Wybór geosystemu - względy techniczne, ekonomiczne i środowiskowe. Metodologia obliczania emisji CO2. Geosyntetyki wsparciem zrównoważonego rozwoju
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Measurements of electron drift velocity in OCS
PublikacjaWykonano pomiary prędkości dryfu elektronów w funkcji zredukowanego pola elektrycznego E/N. Wyniki tych pomiarów porównano z wynikami pomiarów w CO2 i N2O.
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Utilization of ionic liquids for the enrichment of biogas
PublikacjaThis article discusses the dependence of biogas composition on organic feed material. High amounts of CO2 decrease the calorific value of biogas. Several technologies are reviewed which can be used to increase the calorific value. Special emphasis is laid on ionic liquids as a new absorbing material. ILs have a number of advantages due to their unique properties such as: low melting point, high thermal conductivity, no flammability,...
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A novel concept of enhanced direct-contact condensation of vapour- inert gas mixture in a spray ejector condenser
PublikacjaAn analytical model of direct steam condensation (DCC) in the novel idea of spray ejector condenser (SEC) in the presence of inert gas has been developed. It is based on continuity, momentum and energy equations for the steam-carbon dioxide mixture and direct contact condensation mechanisms due to heat transfer and concentration. Crucial in the process of DCC is atomisation of the motive fluid in the ejector. The effect of atomised...
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Wpływ podatku węglowego na efektywność pracy elektrociepłowni.
PublikacjaArtykuł prezentuje metodę wprowadzania podatku węglowego z progiem emisji dopuszczalnej, zwolnionej od podatku i jedną z metod podziału emisji CO2 między energią elektryczną i ciepło wytwarzane w elektrociepłowni.
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Diphosphinoboranes as Intramolecular Frustrated Lewis Pairs: P–B–P Bond Systems for the Activation of Dihydrogen, Carbon Dioxide, and Phenyl Isocyanate
PublikacjaHerein, we present the first example of the activation of small molecules by P-B-P bond systems. The reactivity study involves reactions of two selected diphosphinoboranes, (tBu2P)2BPh (1’) and (Cy2P)2BNiPr2 (2), that differ in terms of their structural and electronic properties for the activation of dihydrogen, carbon dioxide, and phenyl isocyanate. Diphosphinoborane 1’ activates H2 under very mild conditions in the absence of...
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Odporność kawitacyjna stali 2H13 przetapianej wiązką lasera i stopowanej niobem
PublikacjaPrzedstawiono badania odporności kawitacyjnej stali 2H13 po dwóch wariantach obróbki laserowej. W pierwszym wariancie powierzchnie stali przetapiano wiązką lasera CO2, a w drugim powierzchnie wzbogacano Nb w ilości 5% masowego.
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Photocatalysts for Solar Energy Conversion
PublikacjaPhotocatalytic oxidation over suspended solid photocatalysts (e.g., titanium dioxide) has been proposed as a sustainable process for treatment and purification of water and wastewater as well as the process for photoconversion of solar energy to hydrogen, methane, and other low hydrocarbons. Solar radiation could be used to drive heterogeneous electrochemical reactions at the surface of an optically active photocatalyst (e.g.,...