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Wyniki wyszukiwania dla: FT-IR SPECTRA
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Noise in biological Raman spectroscopy
PublikacjaRaman spectroscopy is a widely used method to investigate chemical molecules by analyzing their vibrational transitions. It utilizes inelastic scattering of the laser light irradiating the investigated object. The scattered light requires appropriate filtering to reduce dominant laser light and expose much weaker components having shifted wavelengths of a characteristic spectral pattern. These components are measured by dispersing...
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Luminescence properties of TeOx-Dy thin films annealing under an oxidizing atmosphere
Dane BadawczeThe DataSet contains the emission and excitation spectra of TeOx-Dy thin films. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. Next, the 5% mol of dysprosium ions were added, the nitrates were used as a source of rare-earth ions....
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Luminescence properties of TeOx-Tb thin films annealing under an oxidizing atmosphere
Dane BadawczeThe DataSet contains the emission and excitation spectra of TeOx-Tb thin films. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. Next, the 5% mol of terbium ions were added, the nitrates were used as a source of rare-earth ions. The...
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Luminescence properties of TeOx-Eu thin films annealing under an oxidizing atmosphere
Dane BadawczeThe DataSet contains the emission and excitation spectra of TeOx-Eu thin films. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. Next, the 5% mol of europium ions were added, the nitrates were used as a source of rare-earth ions. The...
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XPS studies of PDA-modified TiO2 nanotubes
Dane BadawczeThis dataset contains the XPS results (survey and high-resolution spectra) of the samples from TiO2 nanotubes modified with polydopamine. The studies were presented as a part of the research on "Band Gap Engineering toward Semimetallic Character of Quinone-Rich Polydopamine" (DOI: 10.1021/acs.jpcc.2c08804).
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Carbonized Metal-Organic Frameworks-based strucutres with aluminium, phosphorus and nitrogen
Dane BadawczeThe dataset includes Raman spectra of carbonized Metal-Organic Frameworks (MOF) [acquired on Renishaw] and electrochemical properties of the materials [acquired on EC Lab], which includes techniques such as Linear Sweep Voltammetry (LCV), Electrochemical Impedance Spectroscopy (EIS), Taffel slope and Chronopotentiometry (CP).
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XPS-Ni foam as received, after photocatalysis and after oxidation at 500_C.
Dane BadawczeThis dataset contains XPS spectra recorded for nickel foam as received from supplier, after photocatalytic process and after oxidation at 500C. Each set contains: survery spectrum, O1, C1s, Ni2p. The detailed equipment and measurement data was described in "readme XPS.txt" file
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Narrowband Transmission Quality in Presence of Modified IEEE 802.15.4a UWB Signal
PublikacjaThis paper presents results of measurement of narrowband transmission quality in presence of impulse radio UWB interference. In the first part of paper, unmodified IEEE 802.15.4a IR UWB signal is used. Then some modification of transmitted pulse sequence is proposed, which allow to reduce UWB power spectral density at frequency of narrowband transmission. Finally narrowband transmission quality in presence of modified ultrawideband...
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Application of the Fractional Fourier Transform for dispersion compensation in signals from a fiber-based Fabry-Perot interferometer
PublikacjaOptical methods of measurement do not require contact of a probe and the object under study, and thus have found use in a broad range of applications such as nondestructive testing (NDT), where noninvasive measurement is crucial. Measuring the refractive index of a material can give a valuable insight into its composition. Low‑coherence radiation sources enable measurement of the sample’s properties across a wide spectrum, while...
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On the electronic structure of methyl butyrate and methyl valerate
PublikacjaWe present novel results of the analysis of the electronic structure of two aliphatic esters: methyl butyrate and methyl valerate. High-resolution photoabsorption spectra were collected and analyzed over the energy range 4.0–10.8 eV and showed for both the molecules not only a clear band of the HOMO to LUMO transition, but also vibronic structure associated with the first Rydberg-valence transition. Photoelectron spectra recorded...
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Fiber-optic Fabry-Pérot sensors – modeling versus measurements results
PublikacjaThis paper describes how parameters of investigated substances and the fiber-optic Fabry-Pérot sensing interferometer affect the spectrum of the optical radiation at the output of the sensor. First, the modeling of the operation of the sensing interferometer was conducted. Most important parameters and effects that were taken into account are: dependences of the refractive indices of the core and the cladding, as well the mode...
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Effects of artificial lighting on bioactivity of sweet red pepper (Capsicum annuum L.)
PublikacjaRecent studies have shown that artificial light effectively promotes the growth and development of red peppers when light spectra, intensities and duration are controlled. Cited reports deal mostly with studies involving with the growth stages of pepper. Changes in the biochemical status of plants were not studied. Therefore, this study focuses on the changes in the content of some bioactive compounds (polyphenols, flavonoids,...
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SPECTRAL DYNAMIC ANALYSIS OF A STATIONARY JACK-UP PLATFORM
PublikacjaThe paper refers to the dynamic short-term response analysis of the Baltic steel drilling platform (see Fig.2) in a random sea-state represented by one-dimensional wave spectrum proposed by Striekalov and Massel and it is recommended for the Baltic Sea area. The Baltic drilling platform is a jack-up type platform for the exploration and exploitation of oil under the Baltic Sea. The analysis presented deals with the stationary...
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FIBRE-OPTIC SENSOR FOR SIMULTANEOUS MEASUREMENT OF THICKNESSAND REFRACTIVE INDEX OF LIQUID LAYERS
PublikacjaIn this paper, we present a fibre-optic sensor for simultaneous measurement of refractive index and thickness of liquid layers. We designed an experimental low-coherence setup with two broadband light sources and an extrinsic fibre-optic Fabry–Pérot interferometer acting as the sensing head. We examined how the refractive index of a liquid film and its thickness affect spectrum at the output of a fibre-optic interferometer. We...
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Fluctuation-Enhanced Sensing of Organic Vapors by Ink-Printed MoS2 Devices under UV Irradiation
PublikacjaThis work presents the results of fluctuationenhanced sensing (FES) of selected organic gases by MoS2 sensor fabricated via a simple ink printing method. We demonstrate that low-frequency noise measured under UV irradiation (275 nm) is more sensitive to different gases than measured in the dark. The noise at 1 Hz under UV light increased 3.3, 3.5, 1.6, and 2.9 times for chloroform, tetrahydrofuran, acetonitrile, and acetone ambiances, respectively....
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Dual role of oxygen-related defects in the luminescence kinetics of AlNMn2+
Dane BadawczeThis dataset presents the impact of temperature and pressure on AlN:Mn2+ luminescence kinetics. Unusual behavior of Mn2+ optical properties during UV excitation is observed, where a strong afterglow luminescence of Mn2+ occurs even at low temperatures. When the temperature increases, the contribution of the afterglow luminescence is further enhanced,...
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Internal electric fields in vacuum-evaporated films as studied by electroabsorption spectroscopy
PublikacjaMierzono sygnały elektroabsorpcji na I-szej harmonicznej częstości przykładanego sinusoidalnego pola elektrycznego w komórkach sandwiczowych Al/warstwa organiczna/Al. Wyznaczono elektryczne pola wewnętrzne (Fi) dla materiałów stosowanych w organicznych diodach elektroluminescencyjnych (TPD, TAPC, MTDATA, QAC, Alq3, Ir(ppy)3, PtOEP). Mechanizm powstawania pól Fi powiązano z pułapkowaniem ładunku w obszarach przyelektrodowych.
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Kontrola jakości materiałów polimerowych wytwarzanych metodą wytłaczania: stan obecny i perspektywy rozwoju
PublikacjaNiniejsza praca stanowi przegląd literaturowy metod kontroli jakości materiałów polimerowych wytwarzanych metodą wytłaczania. Scharakteryzowano możliwości kontroli efektywności procesu wytłaczania działających w układach "on-line" oraz "in-line", które polegają na przeprowadzeniu pomiarów w czasie trwania procesu. Opisano potencjał aplikacyjny technik spektroskopowych (IR, UV-VIS), pomiarów właściwości reologicznych, analizy morfologii...
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Luminescence properties of TeOx-2%Eu1.5%Tb1.5%Dy thin films annealing under an oxidizing atmosphere
Dane BadawczeThe DataSet contains the emission and excitation spectra of TeOx-2%Eu1.5%Tb1.5%Dy thin films. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. Next, the 5% mol of rare-earth ions were added, the nitrates were used as a source of rare-earth...
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Luminescence properties of TeOx-2%Eu1.5%Tb1.5%Tm thin films annealing under an oxidizing atmosphere
Dane BadawczeThe DataSet contains the emission and excitation spectra of TeOx-2%Eu1.5%Tb1.5%Tm thin films. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. Next, the 5% mol of rare-earth ions were added, the nitrates were used as a source of rare-earth...
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Luminescence properties of TeOx-1%Eu1.5%Tb2.5%Dy thin films annealing under an oxidizing atmosphere
Dane BadawczeThe DataSet contains the emission and excitation spectra of TeOx-1%Eu1.5%Tb2.5%Dy thin films. The material was obtained by the sol-gel method. The starting solution was prepared by mixing telluric acid (precursor) with thetraetylene glycol, water, and ethanol. Next, the 5% mol of rare-earth ions were added, the nitrates were used as a source of rare-earth...
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Photoelectron-photoabsorption (PePa) database
PublikacjaIn this paper a recently launched Photoelectron-Photoabsorption Database is presented. The database was developed in order to gather all the photoelectron and photoabsorption spectra measured by various collaborators over the years as well as to ease the access to the data to the potential users. In the paper the main features of the database were described and its outline explained.
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Cross-linked epoxy-isocyanate blends containing Epidian-6 modified by glycols
PublikacjaPolymeric films of cross-linked structure may be formed using epoxy-isocyanate blends composed of Epidian-5 epoxy resin, 4,4’-diphenylmethanediisocyanate (MDI), Z-1 polyamine hardener and Epidian-6 epoxy resin modified by glycols. The effect of the component natures and ratio, process temperature and time on the gel-fraction content, as well as film hardness, was examined. The chemistry of the film forming process was determined...
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Synthesis of Novel Polycationic Quaternary Di- and Trispirocyclic Benzenes
PublikacjaTreatment of hexakis(bromomethyl)benzene with a cyclic amine {morpholine, 1-methylpiperazine, 1-(2-hydroxyethyl)piperazine, isonipecotamide, 4-hydroxypiperidine, 4-[3-(4-piperidyl)propyl]-1-piperidineethanol} gave a range of di- and trispirocyclic ammonium salts in satisfactory yields (22-62%). Presumably, the electrostatic and repulsion forces play an important role in their formation. The structure in soln. and the protonation...
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Formation, crystal and molecular structures of heteroleptic zinc(II) tri-tert-butoxysilanethiolates with ZnNO2S2 and ZnN2S2 coordination pattern.
PublikacjaZsyntetyzowano pięć tri-tert-butoksysilanotiolanów cynku zawierających jako dodatkowe ligandy heterocykliczne, zasady azotowe. Wzór ogólny tych kompleksów to Zn(SSi(OBut)3)2L, gdzie L=alfa-pikolina, 2,4-lutydyna, N-metyloimidazol lub Zn(SSiOBut)3)2L2, gdzie L=N-metyloimidazol lub pirydyna. Określono strukturę krystaliczną otrzymanych związków oraz zmierzono widma IR i NMR.
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Charge Transfer, Complexes Formation and Furan Fragmentation Induced by Collisions with Low-Energy Helium Cations
PublikacjaThe present work focuses on unraveling the collisional processes leading to the fragmentation of the gas-phase furan molecules under the He+ and He2+ cations impact in the energy range 5–2000 eV. The presence of different mechanisms was identified by the analysis of the optical fragmentation spectra measured using the collision-induced emission spectroscopy (CIES) in conjunction with the ab initio calculations. The measurements of...
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Comparability of Raman Spectroscopic Configurations: A Large Scale Cross-Laboratory Study
PublikacjaThe variable configuration of Raman spectroscopic platforms is one of the major obstacles in establishing Raman spectroscopy as a valuable physicochemical method within real-world scenarios such as clinical diagnostics. For such real world applications like diagnostic classification, the models should ideally be usable to predict data from different setups. Whether it is done by training a rugged model with data from many setups...
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A spline-based FE approach to modelling of high frequency dynamics of 1-D structures
PublikacjaIn this paper a computational methodology leading to the development of a new class of FEs, based on the application of continuous and smooth approximation polynomials, being splines, has been presented. Application of the splines as appropriately defined piecewise elemental shape functions led the authors to the formulation of a new approach for FEM, named as spFEM, where contrary to the well-known NURBS approach, the boundaries...
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Positron Scattering and Annihilation in Organic Molecules
PublikacjaIn this paper, we address the problem of connecting positron lifetimes in liquids with collision cross sections in gases. We present the analyses of annihilation lifetime spectra of positrons in the liquid benzene, c-hexane, n-hexane, methanol and ethanol and calculations of scattering cross sections of positrons with benzene and c-hexane in the gas phase.
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Spectroscopy properties of 1,8-diazafluoren-9-one (DFO) in PVA polymer for different concentrations
Dane BadawczeSpectroscopy properties: absorption and fluorescence spectra of 1,8-diazafluoren-9-one (DFO) in PVA film for different concentrations of dye.
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Smart city and fire detection using thermal imaging
PublikacjaIn this paper, we summarize the results obtained from fire experiments. The aim of the work was to develop new methods of fire detection using IR thermal imaging cameras and dedicated image processing. We conducted 4 experiments in different configurations and with the use of different objects. The conducted experiments have shown the great usefulness of infrared cameras for detecting the seeds of a fire. Even cheap low-resolution...
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Interactions between hydration spheres of two different solutes in solution: The least squares fitting with constraints as a tool to determine water properties in ternary systems
PublikacjaBiological systems are complex and the problem of their description lies in mutual interactions between their components. This paper is focused on model experiment-based studies which can reduce these difficulties. The ternary aqueous N-methylacetamide (NMA)–Na2HPO4 system has been studied by means of the FTIR spectroscopy. A novel difference spectra method aimed to extract the spectral contribution of water affected simultaneously...
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Two kinds of oxygen vacancies in lithium titaniate doped with copper as detected by EPR
PublikacjaLithium titanate (Li1+xTi2-xO4) doped with Cu2+ ions was synthesized by sol-gel processing method. The structure and morphology are characterized by X-ray Diffraction (XRD), X-ray Photoemission Spectroscopy (XPS), Scanning Electron Microscopy (SEM) and Electron Paramagnetic Resonance (EPR). Spin Hamiltonian parameters describing Zeeman and hyperfine interaction for 63Cu2+ ions were obtained from EPR spectra simulations. The spectra...
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Properties of Thermally Dewetted Thin Au Films on ITO-Coated Glass for Biosensing Applications
PublikacjaNoble metal nanostructures are object of great interest due to their unique optical and electronic properties exploited in nanotechnology, medicine, biochemistry, and surface-enhanced spectroscopies. In this work, the Au nanoparticle (NP) structures for application in biosensing obtained by dewetting are investigated in dependence on their preparation conditions. Structures are produced from thin Au films (5–30 nm) sputtered onto...
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INFLUENCE OF BISMUTH CONTENT ON COMPLEX IMMITTANCE CHARACTERISTICS OF PRESSURELESS SINTERED BiNbO4 CERAMICS
PublikacjaGoal of the present research was to study immittance properties of BiNbO4 ceramics fabricated by the solid state reaction route followed by pressureless sintering. Four sets of samples were examined, namely the one fabricated from the stoichiometric mixture of oxides, viz. Bi2O3 and Nb2O5 as well as the ones with an excess of 3%, 5% and 10% by mole of Bi2O3. The immittance properties were studied by impedance spectroscopy. Measurements...
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Toward better understanding of phosphoryl transfer reaction: the use of phosphoroorganic biocides in research studies
PublikacjaZamierzeniem autora było nakreślenie potencjalnych kierunków rozwoju badań z wykorzystaniem biocydów fosforoorganicznych (BFO) i związanej z nimi reakcji przeniesienia grupy fosforylowej (reakcja FT). Projektowane są nowe, wysoce selektywne inhibitory enzymów, które w pełni wyjaśniają rolę enzymów w warunkach normalnego funkcjonowania i w procesach patologicznych. Pozwoli to w konsekwencji na wyselekcjonowanie nowych terapeutyków...
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Intelligent Decision Forest Models for Customer Churn Prediction
PublikacjaCustomer churn is a critical issue impacting enterprises and organizations, particularly in the emerging and highly competitive telecommunications industry. It is important to researchers and industry analysts interested in projecting customer behavior to separate churn from non‐churn consumers. The fundamental incentive is a firm’s intent desire to keep current consumers, along with the exorbitant expense of gaining new ones....
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Konzetrationslöschung durch Energieübertragung bei der Lumineszenz von Lösungen
PublikacjaThe absorption spectra and quantum yields of the fluorescence of rhodamine 6 G are investigated in two different water-glycerol mixtures as a function of the rhodamine concentration. The observed concentration quenching is attributed to the formation of rhodamine dimers and the decrease in quantum yield is compared with theoretical concepts about concentration quenching by energy transfer to the dimers.
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Opposite pressure impact on electron-phonon coupling in Eu2+ and Ce3+ doped AlN
Dane BadawczeThis data analyzes the influence of pressure on electron–lattice interactions in the 5d excited states of Ce3+ and Eu2+ in the AlN host based on pressure-dependent photoluminescence and photoluminescence excitation spectra. High-pressure measurements on AlN samples doped with Eu2+ and Ce3+ ions reveal that the Stokes shift increases with pressure for...
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Raman spectroscopy analysis of synthesized sol-gel silica coatings
Dane BadawczeThese data contains Raman spectra of silica coatings synthesized using sol-gel method A and B, which were described with publication associated with this dataset. Raman scattering was measured with a Renishaw microRaman spectrometer (830 nm).
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Thermal analysis of copper(II) complexes of general formula [Et4N]2[CuBrnCl4-n]
PublikacjaBadano dekompozycję termiczną związków składających sie z anionów: [CuBrnCl4-n]2- (n=0-4) i kationów tetrametyloamoniowych. Stosowano następujące metody badawcze: TG-FTIR, TG-MS, DTA i DTG. Pomiary przeprowadzono w atmosferze argonu i powietrza w zakresie temperatur od 293 K do 1073 K. Produkty dekompozycji identyfikowano metoda spektroskopii w podczerwieni (IR i FIR) oraz metodą dyfrakcji promieniowania rentgenowskiego.
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Medical polyurethanes with different hard segments content obtained from polycaprolactone diol, aliphatic diisocyanates and butanediol.
PublikacjaW artykule opisano syntezę 3 serii segmentowych poliuretanów o przeznaczeniu medycznym otrzymanych z polikaprolaktonodiolu, alifatycznych diizocyjanianów: 1,6 heksametylenowego lub 4,4'-dicyklohesametylenowego oraz butanodiolu. Przedstawiono charakterystykę PU uzyskaną na podstawie badania pęcznienia w wodzie, oleju oraz soli fizjologicznej, właściwości powierzchniowych (kąt zwilżania i profilometria), a także badania IR i DSC....
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Estymacja położenia węzłów ruchomych w sieci UWB synchronizowanej emisją z węzła nieruchomego
PublikacjaW referacie przedstawiono wyniki testów możliwości wykorzystania modemów IR UWB (Impulse Radio Ultra-Wide Band) typu DWM1000 do budowy sieci radiolokalizacyjnej, w której położenie węzłów ruchomych jest estymowane na podstawie pomiarów różnic odległości metodą TDOA (Time Difference of Arrival). Opisana została struktura sieci i sposób synchronizacji pomiarów czasów w nieruchomych węzłach referencyjnych przez cykliczny odbiór sygnałów...
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Nadprzewodnictwo i magnetyzm w nowych związkach podwójnych R-Rh i R-Ir (R-ziemia rzadka)
ProjektyProjekt realizowany w Katedra Fizyki Ciała Stałego zgodnie z porozumieniem 0205/DIA/2017/46 z dnia 2017-08-29
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The Quantum Efficiency Roll-Off Effect in Near-Infrared Organic Electroluminescent Devices with Iridium Complexes Emitters
PublikacjaThe electroluminescence quantum efficiency roll-off in iridium(III)-based complexes, namely Ir(iqbt)2(dpm) and Ir(iqbt)3(iqbt=1 (benzo[b]thiophen-2-yl)-isoquinolinate, dpm=2,2,6,6-tetramethyl-3,5-heptanedionate) utilized as near-infrared emitters in organic light emitting diodes with remarkable external quantum efficiencies, up to circa 3%, 1.5% and 1%, are measured and analyzed. With a 5–6 weight % of emitters embedded...
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Optical transmission of the Niobium thin films
Dane BadawczeNiobium thin films with a thickness of 200nm were deposited n a Corning glass substrate by magnetron sputtering method. The optical transmission spectra in a visible light range were.recorded. Investigations showed a good optical transmission thru the layers for each samples, annealed at various temperatures. For measurements samples annealed at 500,...
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Tuning of the plasmon resonance location in Au nanostructures coated with a ultrathin film of Al2O3 – Optical measurements and FDTD simulations
PublikacjaThe Au nanostructures have been coated with an ultra-thin films of amorphous aluminium oxide. Optical absorption spectra show the influence of the thickness of Al2O3 on plasmon resonance wavelength. The observed red-shift of the resonance location with the increase of the thickness of the Al2O3 film, can be explained by the change in the dielectric function of this film. It allows control of the optical spectra of the coated particles....
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The role of Herzberg-Teller effects on the resonance Raman spectrum of trans-porphycene investigated by time dependent density functional theory.
PublikacjaThe S1 excited state properties as well as the associated absorption and resonance Raman (RR) spectra of trans-porphycene are investigated by means of time dependent density functional theory calculations. The relative magnitude of the Franck-Condon (FC) contribution and of the Herzberg-Teller (HT) effects is evaluated for both the absorption and RR intensities. The accuracy of the calculated spectra is assessed by employing different...
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The influence of dynamic load changes on temporary impedance in hydrogen fuel cells, selection and validation of the electrical equivalent circuit
PublikacjaTo achieve optimal performance of a fuel cell, a reliable monitoring and diagnostic method is required. The currently utilized methods give limited information or they are impossible to use under dynamic working conditions. To obtain comprehensive information about the fuel cell operation we utilized novel dynamic electrochemical impedance spectroscopy. Impedance measurements in dynamic mode were performed on a hydrogen fuel cell,...
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Novel Investigation of Higher Order Spectral Technologies for Fault Diagnosis of Motor-Based Rotating Machinery
PublikacjaIn the last decade, research centered around the fault diagnosis of rotating machinery using non-contact techniques has been significantly on the rise. For the first time worldwide, innovative techniques for the diagnosis of rotating machinery, based on electrical motors, including generic, nonlinear, higher-order cross-correlations of spectral moduli of the third and fourth order (CCSM3 and CCSM4, respectively), have been comprehensively...