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Wyniki wyszukiwania dla: BIODEGRADABLE ALIPHATIC POLYESTERS
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Biodegradable Polymers in Biomedical Applications: A Review - Developments, Perspectives and Future Challenges
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Biodegradable macromolecular conjugates of citropin: Synthesis, characterization and in vitro efficiency study
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Biodegradable Poly(ester-urethane) Carriers Exhibiting Controlled Release of Epirubicin
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Preparation of Activated Carbon from the Biodegradable film for Co2 Capture Applications
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Thermal properties of terpoly(ester-b-ether-b-amide)s with aliphatic ester blocks
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Influence of e-beam irradiation on poly(aliphatic/aromatic-ester) multiblock copolymers used as biomaterials
PublikacjaThe use of polymers became more relevant in medical applications for the versatility in processing and enhanced material properties of polymers. In order to be suitable as a biomaterial, it is of medical importance that these polymers are biocompatible and do not elicit negative responses from the body after implantation. Furthermore during the course of usage under load-bearing conditions, these biomaterials must sustain dynamical...
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Enzymatic Polymerization of Cyclic Monomers in Ionic Liquids as a Prospective Synthesis Method for Polyesters Used in Drug Delivery Systems
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Tailoring the electrochemical degradation of iron protected with polypyrrole films for biodegradable cardiovascular stents
PublikacjaThe degradation of polypyrrole (PPy) coated iron is studied in phosphate buffer saline solution at 37 °C by odd random phase multisine electrochemical impedance spectroscopy (ORP-EIS). PPy is electropolymerized with anti-inflammatory salicylates incorporated in the film, as a drug release system. The modelling of EIS over time provides the quantitative description of the corrosion behaviour of the material. Thus, the reliable...
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Structure and Properties of Biodegradable Poly (Xylitol Sebacate-Co-Butylene Sebacate) Copolyester
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Response of inflammatory cells to biodegradable ultra-fine grained Mg-based composites
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Influence of cellulose fibers on physicochemical properties of biodegradable films based on polysaccharide derivatives
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The effect of slowly biodegradable substrate on the kinetics of biochemical processes in activated sludge bioreactors
PublikacjaCelem niniejszej rozprawy doktorskiej było określenie wpływu substratu wolnorozkładalnego (w postaci związków koloidalnych i zawiesinowych) na kinetykę wybranych procesów biochemicznych, zachodzących w komorach osadu czynnego (tj. denitryfikacja, uwalnianie i anoksyczny/tlenowy pobór fosforanów oraz pobór tlenu), opierając się na badaniach prowadzonych w dwóch dużych komunalnych oczyszczalniach ścieków "Wschód" w Gdańsku i "Dębogórze"...
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The effect of slowly biodegradable substrate on the kinetics of biochemical processes in activated sludge bioreactors
PublikacjaCelem niniejszej rozprawy doktorskiej było określenie wpływu substratu wolnorozkładalnego (w postaci związków koloidalnych i zawiesinowych) na kinetykę wybranych procesów biochemicznych, zachodzących w komorach osadu czynnego (tj. denitryfikacja, uwalnianie i anoksyczny/tlenowy pobór fosforanów oraz pobór tlenu), opierając się na badaniach prowadzonych w dwóch dużych komunalnych oczyszczalniach ścieków "Wschód" w Gdańsku i "Dębogórze"...
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Medical polyurethanes with different hard segments content obtained from polycaprolactone diol, aliphatic diisocyanates and butanediol.
PublikacjaW artykule opisano syntezę 3 serii segmentowych poliuretanów o przeznaczeniu medycznym otrzymanych z polikaprolaktonodiolu, alifatycznych diizocyjanianów: 1,6 heksametylenowego lub 4,4'-dicyklohesametylenowego oraz butanodiolu. Przedstawiono charakterystykę PU uzyskaną na podstawie badania pęcznienia w wodzie, oleju oraz soli fizjologicznej, właściwości powierzchniowych (kąt zwilżania i profilometria), a także badania IR i DSC....
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GC-FID determination of C2-C4 aliphatic monocarboxylic acids in aqueous samples preceded by solvent extraction
PublikacjaEkstrakcja za pomocą eteru metylo-tert-butylowego (MTBE) została wykorzystana do izolacji krótkołańcuchowych alkanowych kwasów monokarboksylowych (2-4 atomy węgla w cząsteczce) z próbek o matrycy wodnej. Całkowita wydajność dwukrotnej ekstrakcji z próbek wodnych kwasów: octowego, propionowego i masłowego wynosiła odpowiednio ok. 55% , ok. 90% i ponad 90%. Wydajności ekstrakcji są porównywalne z wartościami uzyskiwanymi w przypadku...
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Physical effects of radiation processes in poly(aliphatic/aromatic-ester)s modified with e-beam radiation
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Gas chromatographic determination of volatile aliphatic and selected aromatic amines, without derivatization: solid phase microextraction
PublikacjaW pracy opisano wykorzystanie techniki chromatografii gazowej do oznaczania śladowych stężeń lotnych amin alifatycznych i wybranych amin aromatycznych w próbkach o różnym składzie matrycy. W tym przypadku aminy nie podlegają procesowi derywatyzacji przed etapem końcowym a na etapie pobierania próbek analitów jest wykorzystana technika mikroekstrakcji do fazy stacjonarnej (SPME).
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Tailoring the Physico-Chemical Properties of Poly(xylitol-dicarboxylate-co-butylene dicarboxylate) Polyesters by Adjusting the Cross-Linking Time
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THE INFLUENCE OF DIFFERENT VEGETABLE DISPERSION PHASES ON THE ROLLING CONTACT FATIGUE OF BIODEGRADABLE LUBRICATING GREASES
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One dimensional coordination polymers generated from Cd(II) tri-tert-butoxysilanethiolates and flexible aliphatic diamines.
PublikacjaPraca ta dotyczy chemii koordynacyjnej tri-tert-butoksysilanotiolanu kadmu(II) z diaminami alifatycznymi. Reakcja dwucentowego [Cd{SSi(OtBu)3}2]2 z poszczególnymi diaminami pozwala otrzymać pięć nowych obojętnych jednowymiarowych polimerów koordynacyjnych o różnej topologii łańcuchów [Cd{SSi(OtBu)3}2(μ-C4H12N2)(CH3OH)]n (1), [Cd{SSi(OtBu)3}2(μ-C5H14N2)(CH3OH)]n (2) [Cd{SSi(OtBu)3}2(μ-C6H16N2)(CH3OH)]n (3), [Cd{SSi(OtBu)3}2(μ-C7H18N2)]n...
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Influence of e-beam irradiation on the chemical and crystal structure of poly(aliphatic/aromatic-ester) multiblock thermoplastic elastomers
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Synthesis, physical properties and preliminary investigation of hemocompa-tibility of polyurethanes from aliphatic resources with castor oil participation
PublikacjaWykonano syntezy PUR z oligoeterodiolu, dioli małocząsteczkowych, oleju rycynowego i 4,4´diizocyjanianudicykloheksylometanu. Oznaczono właściwości mechaniczne PUR, kąty zwilżania i napięcie powierzchniowe. Opisano wstępne badania zgodności PUR z ludzką krwią oraz kalcyfikacji powierzchni PUR w warunkach statycznych in vitro. Napięcie powierzchniowe otrzymanych PUR jest zbliżone do napięcia powierzchniowego naturalnych powierzchni...
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The role of slowly biodegradable substrate in a full-scale biological nutrient removal activated sludge systems
PublikacjaThis paper contains futher results obtained at ''Wschod'' WWTP in Gdańsk under transient conditions (spring season) and comparation of similar experiments carried out at a recently upgraded ''Debogorze'' WWTP in Gdynia. The removal of colloidal and particulate fractions resulted in similar effects (reduced process rates) at both plants. For example, the initial denitrification rates (NUR1) were up to 30% lower during the ''conventional''...
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Novel Biodegradable Potato Starch-based Compositions as Candidates in Packaging Industry, Safe for Marine Environment
PublikacjaAbout 70 % of our planet’s surface is covered by seas and oceans to which even 10 million tons of waste go every year. It makes these places the largest global landfills, containing up to 90 % of plastic waste. In this article we present the results of research on novel starch-based compositions expected to be more safe for the marine environment. For these purpose biopolymers such as, thermoplastic starch (TPS), polylactide (PLA)...
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Modeling hydrolysis of slowly biodegradable organic compounds in biological nutrient removal activated sludge systems
PublikacjaHydrolysis is an important process in biological wastewater treatment and has been known as the rate limiting step in organic carbon removal from municipal or industrial wastewater. The biodegradation of XS is initiated by hydrolysis which is an integral part of activated sludge models, such as the Activated Sludge Model no. 2d (ASM2d). The aim of this study was to evaluate different concepts of modeling the hydrolysis process...
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Influence of e-beam irradiation on the dynamic creep and fatigue properties of poly(aliphatic/aromatic-ester) copolymers for biomedical applications
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Determination of volatile aliphatic amines in air by solid phase microex traction coupled with gas chromatography with flame ionization detection.
PublikacjaOpisano nową metodę oznaczania lotnych amin alifatycznych w powietrzu. Metodyka oparta jest na zastosowaniu techniki mikroekstrakcji do fazy stacjonarnej na etapie pobierania próbek oraz zestawu GC-FID do rozdzielania i oznaczania poszczególnych analitów.Badaniom poddano nowe typy faz stacjonarnych.Zbadano wpływ wilgotności powietrza na proces pobierania próbek analitów z powietrza.
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Physical Effects of Radiation Modification of Biodegradable Xylitol-Based Materials Synthesized Using a Combination of Different Monomers
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Experimental and numerical investigation on shell and coil storage unit with biodegradable PCM for modular thermal battery applications
PublikacjaThermal energy storage (TES) in automotive applications is currently growing in importance. TES can visibly reduce primary energy consumptions, decrease CO2 emission, and improve thermal comfort in electric as well as hybrid vehicles. However, to meet the new ambitious target (15% reduction of CO2 emissions in the new cars until 2025) it is required to use plug-in electric vehicles. For this reason, this paper focuses on the optimization...
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A Simple Replica Method as the Way to Obtain a Morphologically and Mechanically Bone-like Iron-Based Biodegradable Material
PublikacjaPorous iron-based scaffolds were prepared by the simple replica method using polyurethane foam as a template and applying the sintering process in a tube furnace. Their surface morphology was characterized using scanning electron microscopy (SEM) and phase homogeneity was confirmed using X-ray diffraction (XRD). Corrosion behavior was determined using immersion and potentiodynamic polarization methods in phosphate buffered saline...
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The potential of the application of biodegradable and non‐toxic base oils for the formulation of gear oils — model and component scuffing tests
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Amphiphilic core-shell nanoparticles with dimer fatty acid-based aliphatic polyester core and zwitterionic poly(sulfobetaine) shell for controlled delivery of curcumin
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Coordination polymers based on octacyanometalates(iv,v) (M = Mo, W) and aliphatic polyamine copper(ii) tectons with [N3] donor atom sets
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Influence of the electrosynthesis conditions on the spontaneous release of anti-inflammatory salicylate during degradation of polypyrrole coated iron for biodegradable cardiovascular stent
PublikacjaIn this work, the spontaneous release of anti-inflammatory salicylate from polypyrrole (PPy) coated iron has been studied during degradation of the material in phosphate buffer saline at 37 C. The sodium salicylate was incorporated into PPy in a one-step electropolymerization process. The influence of the synthesis conditions such as sodium salicylate concentration, pyrrole concentration and deposition charge on drug release profile...
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Experimental and theoretical study of a vertical tube in shell storage unit with biodegradable PCM for low temperature thermal energy storage applications
PublikacjaThis article presents the experimental investigations of the coconut oil-based TES module for HVAC applications in the ambient and-sub ambient temperature range. To properly study this problem modular experimental module and test loop were developed. Special attention has been paid to study the physical mechanism of the melting/solidification process for natural substance (coconut oil) which has perspectives to be used in thermal...
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Use of Silybum marianum Extract and Bio-Ferment for Biodegradable Cosmetic Formulations to Enhance Antioxidant Potential and Effect of the Type of Vehicle on the Percutaneous Absorption and Skin Retention of Silybin and Taxifolin
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Marcin Wekwejt dr inż.
OsobyMarcin Wekwejt, absolwent studiów inżynierskich w inż. biomedycznej (2016; Politechnika Bydgoska im. J. i J. Śniadeckich & Collegium Medicum im. L. Rydygiera), studiów magisterskich w inż. mechaniczno-medycznej (2018; Politechnika Gdańska & Gdański Uniwersytet Medyczny) oraz studiów doktoranckich w dyscyplinie inż. materiałowej (2021, Politechnika Gdańska). Uzyskał z wyróżnieniem stopień naukowy doktora nauk inżynieryjno-technicznych...
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Przydatność białka rybiego w postaci kolagenu lub żelatyny oraz polisacharydu - kapa-karagenu do wytwarzania aktywnych opakowań biodegradowalnych = Usefulness of fish collagen, gelatin and carrageenan for preparation of active biodegradable packages
PublikacjaSummary - The possibility of use of protein films made of fish collagen or gelatin as well as polysaccharide carrageenan films as carriers of enzymes (lysozyme or lysostaphyne), for preparation of microbiologically active packages, was investigated. It was found that crosslinking of such systems with N-[3(dimethylamino)propyl]-N'-ethylcarboimide (EDC) does not influence the activity of lysozyme immobilized in the films (Table 1)....
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Structure-property relationships in peroxide-assisted blends of poly(ε-caprolactone) and poly(3-hydroxybutyrate)
PublikacjaPoly(ε-caprolactone) and poly(3-hydroxybutyrate) (PCL/PHB) blends in two weight ratios (75/25 and 50/50) were reactively compatibilized in the presence of di-(2-tert-butyl-peroxyisopropyl)-benzene and dicumyl peroxide as free radical initiators. Rheological, mechanical, thermal properties and morphological features, as well as the chemical structure of PCL/PHB blends were investigated. It was found that regardless of PCL/PHB blend...
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Results of wettability evaluation of acrylic bone cements incorporating various components
Dane BadawczeThe database contains the images of the contact angle measurements of modified bone cements using the optical tensiometer. The following modifications were evaluated: the addition of biodegradable components (including chitosan, cellulose, tricalcium phosphate, polydioxanone or magnesium), the addition of bioactive components (bioglasses) or the addition...
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Results of microhardness measurements of acrylic bone cements incorporating various components
Dane BadawczeThe database contains the images of microhardness measurements of modified bone cements using the Vickers Hardness Tester. The following modifications were evaluated: the addition of biodegradable components (including chitosan, cellulose, tricalcium phosphate, polydioxanone or magnesium), the addition of bioactive components (bioglasses) or the addition...
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Results of SEM examination of acrylic bone cements incorporating various components
Dane BadawczeThe database contains the images of the microstructure of modified bone cements observed with the scanning electron microscope (SEM). The following modifications were evaluated: the addition of biodegradable components (including chitosan, cellulose, tricalcium phosphate, polydioxanone or magnesium), the addition of bioactive components (bioglasses)...
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Results of OM examination of acrylic bone cements incorporating various components
Dane BadawczeThe database contains the images of the microstructure of modified bone cements observed on the cross-section with the optical microscope (OM). The following modifications were evaluated: the addition of biodegradable components (including chitosan, cellulose, tricalcium phosphate, polydioxanone or magnesium), the addition of bioactive components (bioglasses)...
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Results of AFM examination of acrylic bone cements incorporating various components
Dane BadawczeThe database contains the images of the surface topography of modified bone cements observed with the atomic force microscopy (AFM). The following modifications were evaluated: the addition of biodegradable components (including chitosan, cellulose, tricalcium phosphate, polydioxanone or magnesium), the addition of bioactive components (bioglasses)...
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Linear and branched polyester resins based on dimethyl-2,5-furandicarboxylate for coating applications
PublikacjaIn this study, novel bio-based hydroxyl-functional (co)polyesters from dimethyl-2, 5-furandicarboxylate (DMF), 2,3-butanediol, and a variety of comonomers viz. glycerol, pentaerythritol or trimethylolpropane are prepared using a solvent-free, bulk polycondensation technique. Extensive molecular and thermal characterization was performed to elucidate the properties of these materials. The materials showed suitable properties for solvent-borne...
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Influence of chemical structure on physicochemical properties and thermal decomposition of the fully bio-based poly(propylene succinate-co-butylene succinate)s
PublikacjaIn this work, two polyesters and four copolyesters were studied. All materials were synthesized to obtain the monomers dedicated for thermoplastic polyurethane elastomers. For this type of PUR, the monomers should characterize by appropriate selected physicochemical properties and macromolecular structure distribution, which depends on synthesis conditions. The study of chemical structure with extensive and knowledgeable analysis...
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Wpływ ścieków przemysłowych na energochłonność i efektywność procesów technologicznych w komunalnej oczyszczalni ścieków
PublikacjaW artykule skupiono się na przedstawieniu wpływu jakości i ilości ścieków przemysłowych wprowadzanych do sieci kanalizacyjnej PEWIK GDYNIA Sp. z o. o. na stabilność procesów technologicznych. Określono również wpływ ścieków przemysłowych na energochłonność i efektywność oraz na wzrost kosztów oczyszczania ścieków komunalnych w Grupowej Oczyszczalni Ścieków „Dębogórze” w latach 2012-2015.
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Wpływ dodatku odcieków składowiskowych do oczyszczanych ścieków komunalnych na wielkość frakcji ChZT
PublikacjaManaging landfill leachate is one of the most important problems with maintaining landfills. The aim of this study was to determine the influence on COD fraction of landfill leachate addition from 0,5% to 5% to raw wastewater. The results of this study show that soluble inert COD in wastewater and mixture wastewater with landfill leachate constituted the smallest percentage of total COD. Nonetheless this fraction (soluble inert...
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Degradibility in vitro of polyurethanes based on synthetic atactic poly[)R,S)-3-hydroxybutyrate
PublikacjaThe aim of the paper was to determine the degradibility of aliphatic polyurethanes in hydrolytic and oxidative solutions. DSC, GPC, density, polymer surface morphology were studied.
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The role of particulate and colloidal substrate in biological nutrient removal activated sludge systems
PublikacjaThe authors investigated COD fractionation according to the physical state (soluble/colloidal/particulate) in four wastewater treatment plants (WWTPs) in northern Poland. It was found that particulate and colloidal organic compounds constituted up to 70% of total COD. On the other hand, according to literature data, municipal wastewater contains readily and slowly biodegradable substrates in the amount of approximately 10-30% and...