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Wyniki wyszukiwania dla: Titanium oxide film
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Electronic and ionic relaxations in oxide glasses
PublikacjaDokonano przeglądu procesów relaksacyjnych w szkłach wykazujących elektronowy i elektronowo-jonowy charakter przewodnictwa elektrycznego. Na podstawie badań impedancyjnych przedstawiono klasyfikację szkieł o mieszanym elektronowo-jonowym przewodnictwie. Wskazano na zalety metody tarcia wewnętrznego do badań procesów relaksacyjnych w szkłach tlenkowych.
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Anodized multi – component titanium alloys carrying antibacterial features
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Photocatalytic activity and surface properties of carbon-doped titanium dioxide
PublikacjaTiO2 domieszkowany węglem otrzymano poprzez hydrolizę izopropanolanu tytanu(IV) i kalcynację w 350ºC w atmosferze powietrza przez 2h. Przeprowadzone badania wykazały, że fenol (0.21 mM) jest efektywnie degradowany w fazie wodnej, w obecności otrzymanego fotokatalizatora oraz światła z zakresu widzialnego (λ>400 nm). Pole powierzchni właściwej otrzymanego C-TiO2 wynosiło około 127 m2/g, fotokatalizator absorbuje światło z zakresu...
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Modification of titanium dioxide with platinum ions and clusters: application in photocatalysis
PublikacjaW celu polepszenia właściwości fotokatalitycznych, TiO2 (komercyjny-P25 oraz syntezowany metoda zol-żel) był domieszkowany za pomocą jonów lub klasterów [Pt3(CO)6]62- platyny. Własności fizyczne fotokatalizatorów były badane za pomocą elektronowego mikroskopu transmisyjnego (TEM), dyfraktometru rentgenowskiego (XRD) oraz analizatora powierzchni właściwej (BET). Dyfuzyjna spektrometria odbiciowa (DRS) została zastosowana w celu...
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Preparation of the porous biomaterial based on titanium alloy for orthopaedic implants
PublikacjaObecnie tytan i jego stopy (Ti-6Al-4V lub Ti-13Nb-13Zr) są szeroko stosowane jako biomateriały dla implantów ortopedycznych. Stale prowadzone są badania nad ich najlepszą odpornością na korozję i zużycie ścierne oraz biozgodnością i bioaktywnością. Obecne badania również skoncentrowane są na projektowaniu, wytwarzaniu i właściwościach materiałów porowatych na podstawie na przykład stopu tytanu (Ti-13Nb-13Zr), które mogą być stosowane...
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Optimalization of titanium acaffold design using fuzzy reasoning approach
PublikacjaOpracowano metodę wnioskowania rozmytego do oszacowania geometrii scaffoldu Ti6Al4V, otrzymanego przy użyciu metody metalurgii proszków. Zaproponowana metoda umożliwia oszacowanie i optymalizację architektury scaffoldu poprzez dobór odpowiednich parametrów procesu. Zaprojektowano i przeprowadzono symulację działania sterownika rozmytego (FLC) za pomocą oprogramowania Matlab.
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Environmental degradation of titanium biomaterials: mechanisms, effects, testing and evaluation
PublikacjaPrzedyskutowano możliwe przyczyny oraz mechanizmy degradacji biomateriałów tytanowych, używanych jako długoterminowe implanty stawów. Dokonano przeglądu wpływu impalntów metalicznych w ludzkim ciele. Przedstawiono bieżące procedury badania oraz ich wady. Zaproponowano procedurę oszacowania biomateriałów na implanty.
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Preparation and photocatalytic activity of iron-modified titanium dioxide photocatalysts
PublikacjaTiO2 modyfikowany żelazem otrzymano dwiema metodami: metodą zol-żel oraz metodą impregnacji powierzchniowej. Fotokatalizatory kalcynowano w temperaturze 400C. Jako matrycę TiO2 zastosowano komercyjnie dostępne proszki ditlenku tytanu: P25 (Evonik, Niemcy, 50m2/g) oraz ST-01 (Ishihara Sangyo, Japonia, 300m2/g). Charakterystyka otrzymanych fotokatalizatorów obejmowała wyznaczenie właściwości absorpcyjnych, powierzchni właściwej BET...
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Physicochemical and photocatalytic characterization of mesoporous carbon/titanium dioxide spheres
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Modification of titanium dioxide towards photocatalytic activity in visible light
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Sustainable energy system combined biogas-feedSolid Oxide Fuel Cell and Microalgae technology
PublikacjaIn the new frontier of energy and environmental safety, new efficient and clean safe energy conversion systems are required. In this sense, the present work is framed within the context of Circular Economy and proposes a multidisciplinary study for the development of more efficient, economically viable and non-polluting energy conversion systems, based on the synergetic combination of different technologies: fuel cells, biofuels,...
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Injectable poloxamer/graphene oxide hydrogels with well‐controlled mechanical and rheological properties
PublikacjaAlthough significant progress has been made in the design and application of injectable hydrogels for biomedical applications, concurrent control of rheological and mechanical properties of injectable hydrogels has remained as an open challenge to the researchers. In this work, we introduce and put into practice a photo‐curable poloxamer (also known as Pluronic)/graphene oxide (Plu/GO) injectable hydrogel with well‐controlled rheological...
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Iron doped manganese cobaltite spinel coatings produced by electrophoretic co-deposition on interconnects for solid oxide cells: Microstructural and electrical characterization
PublikacjaWe report a systematic microstructural and electrical characterization of iron doped Mn–Co spinel coatings processed by electrophoretic co-deposition of Mn1.5Co1.5O4 and Fe2O3 powders on Crofer 22 APU and AISI 441 steel substrates. Iron addition to Mn–Co spinel coating leads to a reduction of the area specific resistance on both substrates, after 3200 h at 750 °C. The Fe doped Mn–Co coating both leads to a thinner oxide scale and...
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Annealing of indium tin oxide (ITO) coated optical fibers for optical and electrochemical sensing purposes
PublikacjaGlass and fiber structures with Indium Tin Oxide (ITO) coating were subjected to annealing in order to identify impact of the thermal treatment on their optical and electrochemical properties. It is shown that the annealing process significantly modifies optical properties and thickness of the films, which are crucial for performance of optical fiber sensors. Moreover, it visibly improves electrochemical activity of ITO on glass...
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Investigation of functional layers of solid oxide fuel cell anodes for synthetic biogas reforming
PublikacjaSolid oxide fuel cells (SOFCs) are one of the most promising energy conversion devices due to their high efficiency, low pollution and fuel flexibility. Unfortunately, when hydrocarbons are used as a fuel, for example in the form of a biogas, solid carbon can deposit on the anode surface. This process leads to the degradation of the fuel cell performance. A possible solution to this problem is to apply an additional catalytic material,...
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Investigation of catalytic layers on anode for solid oxide fuel cells operating with synthetic biogas
PublikacjaIn this paper solid oxide fuel cells operating with dry synthetic biogas have been examined. In order to increase their stability the layers of CuO-CeO2, Cu1.3Mn1.7O4 and Y0.08Sr0.92Ti0.8Fe0.2O3 -δ have been deposited on the Ni-YSZ anode site. These layers should catalyze the internal biogas reforming and prevent the carbon deposition on the anode site. It has been found that CuO-CeO2 and Cu1.3Mn1.7O4 catalysts led to an increase...
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Spectroelectrochemical characteristics of poly(3,4-ethylenedioxythiophene) / iron hexacyanoferrate film-modified electrodes
PublikacjaPraca dotyczy pomiarów spektroelektrochemicznych materiałów hybrydowych złożonych z polimeru elektroaktywnego poli(3,4-etylenodioksytiofenu) i Błękitu Pruskiego. Dla porównania badano również filmy polimerowe z wybranymi przeciwjonami: heksacyjanożelazowym (Fe(CN)63-/4-), chlorkowym (Cl-) i polistyrenosulfonowym (PSS-). Materiały w postaci cienkich filmów otrzymano na elektrodzie szklanej pokrytej tlenkiem indowo-cynowym. Widma...
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The influence of UV-irradiation on the poly(vinyl alcohol)/hyaluronic acid film properties
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2D numerical simulation of tear film dynamics: Effects of shear-thinning properties
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On the Effect of Non-Thermal Atmospheric Pressure Plasma Treatment on the Properties of PET Film
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Spectroscopic studies of sol-gel derived thin film structures for integrated optics
PublikacjaPrzedstawiono wyniki badania struktur cienkowarstwowych wykonywanych dla zastosowań w optyce zintegrowanej z polimerów hybrydowych (np. w postaci ścieżek śwaitłowodów planarnych). Jakość i jednorodność stuktur badano za pomocą mikroskopii ramanowskiej, mikroskopii optycznej i profilometrii światła białego. Wykonano porównanie wyników uzyskanych tymi trzema metodami.
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Resistance noise in tio2-based thin film gas sensors underultraviolet irradiation
PublikacjaBadano możliwości wykorzystania fluktuacji rezystancji w cienkich warstwach TiO2 do wykrywania gazów. Pomiary przeprowadzono, gdy próbka była oświetlona promieniowaniem ultrafioletowym o długości 370nm, w obecności gazu H2S. Stwierdzono, że fluktuacje rezystancji są indukowane promieniowaniem ultrafioletowym i pozwalają na wykrycie obecności H2S w stężeniu do 1.5 ppm.
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Magnetization Reversal Mechanism in Exchange-Biased Spring-like Thin-Film Composite
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Application of BDD thin film electrode for electrochemical decomposition of heterogeneous aromatic compounds
PublikacjaThe aim of the presented study is to investigate the applicability of electrochemical oxidation of aromatic compounds containing heteroatoms, e.g. waste from production of pesticides or pharmaceutics, at a borondoped diamond (BDD) electrode. The BDD electrodes were synthesized by microwave plasma enhanced chemical vapour deposition (MW PE CVD). Investigation of the electrode surface by optical microscopy and scanning electron microscopy...
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CGO as a barrier layer between LSCF electrodes and YSZ electrolyte fabricated by spray pyrolysis for solid oxide fuel cells
PublikacjaPerovskite La0.6Sr0.4Co0.2Fe0.8O3 − δ (LSCF) is often used as a cathode material for solid oxide fuel cells (SOFC) due to high mixed ionic and electronic conductivity and good catalytic activity. Unfortunately, sintering of the LSCF cathode together with the yttria stabilized zirconia (YSZ) electrolyte, leads to formation of the La2Zr2O7 and SrZrO3 phases in the interface. These phases increase the resistance of the cell. To avoid...
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Biological properties of chitosan/Eudragit E 100 and chitosan/poly(4-vinylpyridine) coatings electrophoretically deposited on AgNPs-decorated titanium substrate
PublikacjaThe objective of the study was the determination of the response, in contact with human osteoblast-like MG-63 cells, of electrophoretically deposited coatings composed of chitosan (CS), Eudragit E 100 (EE100), or poly(4- vinylpyridine) (P4VP) on a silver nanoparticle (AgNPs)-decorated titanium substrate. Before deposition, the substrate was coated with silver by electro-reduction of silver nitrate. The coatings deposition was carried...
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Electrophoretic deposition and characterization of composite chitosan/Eudragit E 100 or poly(4-vinylpyridine)/mesoporous bioactive glass nanoparticles coatings on pre-treated titanium for implant applications
PublikacjaTitanium implants are surface-modified to achieve bioactivity and often antibacterial properties. Such surface coatings may increase corrosion degradation and be weakly attached to the substrate. In the present research, biodegradable composite coatings, investigated so far as smart environment-sensitive, slowly releasing silver to the implant neighborhood, were produced as a combination of chitosan (CS) with Eudragit E 100 (EE100)...
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LaNi1-xCoxO3-δ(x=0.4 to 0.7) cathodes for solid oxide fuel cells by infiltration
PublikacjaPerformance of LaNi 1-x Co x O 3−δ (LNC) (x=0.4 to 0.7) as a cathode in solid oxide fuel cell (SOFC) is evaluated. Symmetrical cathode/electrolyte/cathode cells for electrochemical testing are prepared by infiltration of yttria stabilized zirconia (YSZ) backbone with LNC solutions. It is showed that the cathode infiltrated with LaNi 0.5 Co 0.5 O 3−δ (LNC155) has the lowest polarization resistance and activation energy, 197 mΩ cm...
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Edgewise Compressive Behavior of Composite Structural Insulated Panels with Magnesium Oxide Board Facings
PublikacjaEdgewise compression response of a composite structural insulated panel (CSIP) with magnesium oxide board facings was investigated. The discussed CSIP is a novel multifunctional sandwich panel introduced to the housing industry as a part of the wall, floor, and roof assemblies. The study aims to propose a computational tool for reliable prediction of failure modes of CSIPs subjected to concentric and eccentric axial loads. An advanced...
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Structure and thermoelectric properties of Bi–Te alloys obtained by novel method of oxide substrates reduction
PublikacjaA novel method of thermoelectric materials fabrication has been developed. Oxide reagents have been melted at high temperature in air, quenched, milled to powder and reduced in hydrogen to form Bi–Te alloys. Structural and thermoelectric properties of samples have been investigated depending on initial composition and temperature of reduction process. Sample 25Bi2O3–75TeO2 reduced at 340 °C for 10 h has been found to be a p-type...
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Development of iron doped strontium titanates as oxygen electrode for solid oxide fuel cells
PublikacjaProducing efficient solid oxide fuel cells (SOFC) without the use of harmful elements is one of the current challenges. Increasing the safety of people and reducing production costs is possible, among others, thanks to the use of iron doped strontium titanates as porous oxygen electrodes. In this thesis, the results of research on iron doped strontium titanates as potential oxygen electrodes for SOFC are presented. The research...
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X-ray diffraction (XRD) and particle size distribution (PSD) data of iron oxide (Fe3O4) - magnetite particles
Dane BadawczeDataset presenting X-ray diffractogram and particle size distribution of nanomagnetite (Fe3O4) iron oxide particles purchased from Sigma Aldrich (637106).X-ray diffraction study was performed with a PRO X-ray diffractometer (X’Pert PRO Philips diffractometer, Co. Ka radiation, Almelo, Holland), while PSD was determined using laser diffraction technique...
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Recent advances on spinel-based protective coatings for solid oxide cell metallic interconnects produced by electrophoretic deposition
PublikacjaThe application of ceramic protective coatings to the metallic interconnects in solid oxide cells (SOCs) is a viable and effective method to limit interconnect degradation issues. This featured letter provides a critical overview of the main outcomes of current research on the use of the electrophoretic deposition (EPD) technique to produce protective coatings for SOC metallic interconnects, specifically focusing on different approaches...
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Trimethylamine N-oxide and the reverse cholesterol transport in cardiovascular disease: a cross-sectional study
PublikacjaThe early atherosclerotic lesions develop by the accumulation of arterial foam cells derived mainly from cholesterol-loaded macrophages. Therefore, cholesterol and cholesteryl ester transfer protein (CETP) have been considered as causative in atherosclerosis. Moreover, recent studies indicate the role of trimethylamine N-oxide (TMAO) in development of cardiovascular disease (CVD). The current study aimed to investigate the association...
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Stabilization of the titanium vibration damping wires in the steam turbine blades system
PublikacjaPrzedstawiono metody stabilizacji drutów tłumiących w systemie łopatkowym turbin parowych. Na podstawie badań eksperymentalnych mikrostruktury i własności mechanicznych wykazano przydatność metody stabilizacji na gorąco drutów tłumiących wykonywanych ze stopu tytanu WT3-1.
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The Use of 3D Titanium Miniplates in Surgical Treatment of Patients with Condylar Fractures
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The oxidation of limonene at raised pressure and over the various titanium-silicate catalysts
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Characterisation of the interfacial heat transfer coefficient in hot stamping of titanium alloys
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Ammonium Hydroxide Mediated Hydrothermal Crystallization of Hydroxyapatite Coatings on Titanium Substrate
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Characterization and photocatalytic activity of rare earth metal-doped titanium dioxide
PublikacjaW publikacji została przedstawiona metoda otrzymywania fotokatalizatorów na bazie TiO2 modyfikowanego erbem i iterbem. Otrzymane nanocząstki zostały scharakteryzowane za pomocą powierzchni właściwej BET, objętości porów. Zostały przedstawione widma absorpcyjne UV-Vis oraz właściwości fluorescencyjne otrzymanych nanoproszków. Dokonano również przedstawienia wyników pomiaru aktywności fotokatalitycznej pod wpływem promieniowania...
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Modification of Titanium (IV) Dioxide with Small Silver Nanoparticles: Application in Photocatalysis
PublikacjaThe surface of commercial TiO2 compounds (P25 and ST01) has been modified with Ag nanoparticles induced by radiolysis. On P25, the Ag nanoclusters are very small (1−2 nm) and homogeneous in size while on ST01, two populations of nanoparticles are obtained, small nanoparticles (1−2 nm) and larger ones (mean diameter 7 to 12 nm depending on the silver loading). The photocatalytic properties of Ag-modified TiO2 have been studied for...
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Actions of a nitric oxide donor on prostaglandin production and angiogenic activity in the equine endometrium
PublikacjaNitric oxide (NO) plays an important role in prostaglandin secretion and angiogenesis in the reproductive system. In the present study, the roles of the NO donor spermine NONOate and tumour necrosis factor-alpha (TNF; as a positive control) in prostaglandin production and angiogenic activity of equine endometria during the oestrous cycle were evaluated. In addition, the correlation between NO production...
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Preparation of Hydrogen Electrodes of Solid Oxide Cells by Infiltration: Effects of the Preparation Procedure on the Resulting Microstructure
PublikacjaIn this work, the infiltration technique was used to produce hydrogen electrodes for solid oxide cells. Different infiltration methodologies were tested in order to try to shorten the infiltration cycle time. The porous scaffolds used for infiltration were based on highly porous yttria-stabilized zirconia (YSZ) obtained by etching the reduced nickel from the Ni-YSZ cermet in HNO3 acid. The support had a complex structure which...
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The Historical Journal of Film, Radio and Television
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Film Studies (Manchester U. Press)
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New Review of Film and Television Studies
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Studies in South Asian Film and Media
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International Journal of Film and Media Arts
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Fabrication of Bi6Fe2Ti3O18 Ceramics by Mixed Oxide Method
PublikacjaIn the present study Bi6Fe2Ti3O18 (BFTO) ceramics has been fabricated by solid state reaction from the mixture of simple oxides viz. Bi2O3, TiO2 and Fe2O3. Stoichiometric mixture of the powders was thermally analyzed so parameters of the thermal treatment were determined. The EDS measurements have shown conservation of the chemical composition of the ceramic powder after calcination. Hot-pressing method was used for final densification...
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9 - Solid oxide fuel and electrolysis cells
PublikacjaIn this chapter, the fundamental reactions, the geometrical designs, the material requirements, and the status of SOFCs and SOECs are presented. In the following seven chapters, the most important components of an SOC are described and the chapter ends with a summary and outlook. The described components are: (i) oxygen-ion conductors (electrolyte), (ii) anode materials for SOFCs (cathode in SOEC mode), (iii) cathode materials...