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Wyniki wyszukiwania dla: AOPS
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ANTIOXIDANT POWER SERIES (APS) AS A TOOL FOR RATIONAL DESIGN AND ASSESSMENT OF HEALTH PROMOTING PROPERTIES OF FUNCTONAL FOODS BASED ON ANTIOXIDANT PHYTOCHEMICALS
PublikacjaOver past decades, plantborne antioxidants dominated so called "translational research" in the area of food, nutrition, and disease prevention. Among consumers and producers, such phytochemicals are synonyms of nutriceuticals. Popularity and commercial success of antioxidants stems from mechanistic studies suggesting the involvement of reactive oxygen species in etiology of chronic diseases. However, epidemiology failed to provide...
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Advanced oxidation processes for the removal of mono and polycyclic aromatic hydrocarbons – A review
PublikacjaAromatic hydrocarbons (AHs) are toxic environmental contaminants presented in most of the environmental matrices. Advanced oxidation processes (AOPs) for the removal of AHs in the account of complete mineralization from various environmental matrices have been reviewed in this paper. An in-depth discussion on various AOPs for mono (BTEX) and polyaromatic hydrocarbons (PAHs) and their derivatives is presented. Most of the AOPs were...
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Pharmaceuticals wastewater treatment via different advanced oxidation processes: Reaction mechanism, operational factors, toxicities, and cost evaluation – A review
PublikacjaPharmaceuticals comprises different drugs used for treating different infections in human being and animals. The huge quantities of pharmaceuticals used are found to discharge into different water resources and cause different health and environmental problems. The continuous and large-scale discharge of pharmaceuticals increases their persistency which can consequently make them more toxic. The different advanced oxidation processes...
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Advanced Oxidation Processes for Degradation of Water Pollutants—Ambivalent Impact of Carbonate Species: A Review
PublikacjaAdvanced oxidation processes (AOPs) hold great promise in the removal of organic contaminants. Reactive oxygen species (ROS) produced in AOPs react with target pollutants to initially form several intermediate compounds that finally undergo complete mineralization. Such observations are reported, especially for laboratory-scale experiments performed in pure water. On the other hand, while considering real contaminated wastewater...
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Polymer and graphitic carbon nitride based nanohybrids for the photocatalytic degradation of pharmaceuticals in wastewater treatment – A review
PublikacjaPharmaceuticals, including antibiotics and anti-inflammatory drugs, have been frequently detected in water reservoirs, in concentrations ranging from ng/L to μg/L, owing to their wide use in treatment of human and animal disease. Their uncontrolled use results in their increased release into the environment which is harmful for humans, animals, aquatic life and aquatic system. To remove these pollutants from water bodies, various...
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Effective method of treatment of industrial effluents under basic pH conditions using acoustic cavitation – a comprehensive comparison with hydrodynamic cavitation processes
PublikacjaThe use of acoustic cavitation in advanced oxidation processes (AOPs) is a promising trend in research for treatment of industrial effluents. The paper presents the results of investigations on the use of acoustic cavitation aided by additional oxidation processes (ozonation/H2O2 oxidation/Peroxone/UV-C) for the treatment of effluents from the production of bitumens. Under these conditions, the total contaminant load, expressed...
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Wastewater treatment by means of Advanced Oxidation Processes at basic pH conditions: A review
PublikacjaAdvanced oxidation processes (AOPs) have been used as an alternative and effective option for treatment of industrial wastewater, especially in the case of the non-biodegradable compounds. Despite of several well developed AOPs, the majority of them are effective only at acidic or neutral pH, namely Fenton related processes, making the list of available effective advanced oxidation technologies strongly limited. In many cases,...
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Treatment innovation using solar/UV In book: The Treatment of Pharmaceutical Wastewater: Innovative Technologies and the Adaptation of Treatment Systems
PublikacjaSince ancient times, sunlight irradiation has been widely used for water purification. Apart from solar water disinfection techniques, UV irradiation is of particular interest when considering the photodegradation of various classes of emerging pollutants. Pharmaceutically active compounds are one of the largest classes of micropollutants. The main sources of these contaminants in wastewater and aqueous environments are households,...
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Sea spray as a secondary source of chlorinated persistent organic pollutants? - Conclusions from a comparison of seven fresh snowfall events in 2019 and 2021
PublikacjaSecondary sources of persistent organic pollutants (POPs) gain in importance worldwide as primary sources decline. In this work, we aim to determine whether sea spray may be a secondary source of chlorinated POPs to the terrestrial Arctic, since a similar mechanism was proposed there only for the more water-soluble POPs. To this end, we have determined polychlorinated biphenyls and organochlorine pesticides concentrations in fresh...
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Cavitation-Based Processes for Water and Wastewater Treatment
PublikacjaCavitation based on advanced oxidation processes (Cav-AOPs) is interesting alternatives for already implemented wastewater treatment technologies. Destructive and strongly undesirable phenomena in the industry, i.e., cavitation, revealed to be useful in a positive manner as a source of energy for chemical reactions. During the implosion of cavitation bubbles, focused energy and resulting high temperature and pressure allows to...
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Acid-aided epoxy-amine curing reaction as reflected in epoxy/Fe3O4 nanocomposites: Chemistry, mechanism, and fracture behavior
PublikacjaThis work seeks to answer the question whether or not the presence of acid functional groups accelerate epoxyamine curing reaction. Epoxy/Fe3O4 nanocomposite was considered as a case, where discussions are based on chemistry, mechanism behind curing reactions and fracture behavior influenced by acid assistance to crosslinking. Fe3O4 magnetic nanoparticles (MNPs) with nanosilica decorative layer (B-MNP) were synthesized and subsequently...
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First highly effective non-catalytic nitrobenzene reduction in UV/dithionite system with aniline production – Advanced reduction process (ARP) approach
PublikacjaAdvanced reduction processes (ARPs) are currently intensively investigated as an alternative to Advanced Oxidation Processes (AOPs). The study presents efficient reduction of nitrobenzene under non-catalytic conditions through reaction with free radicals having reductive potential. Effective conversion of nitrobenzene in a model wastewater solution, was obtained for sodium dithionite (SDT)/ dithionite (DTN). The developed process...
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Synergistic effect of TiO2 photocatalytic advanced oxidation processes in the treatment of refinery effluents
PublikacjaDifferent types of photolytic and photocatalytic advanced oxidation processes (AOPs) were used for treatment of refinery effluents from bitumen production. The treatment efficiency was evaluated by analyzing chemical oxygen demand (COD), biological oxygen demand (BOD5), volatile organic compounds (VOCs) and sulfide ions concentration. The studies revealed a synergistic effect of application of external oxidants (O3, H2O2, O3/H2O2)...
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Mechanochemically synthesized Mn3O4@β-cyclodextrin mediates efficient electron transfer process for peroxymonosulfate activation
PublikacjaThe rational surface engineering of heterogeneous catalysts is of great significance in advanced oxidation processes (AOPs) for eliminating refractory contaminants but remains challenging. In this study, β-cyclodextrin modified Mn3O4 (Mn3O4@β-CD) was prepared through a mechanochemical approach for peroxymonosulfate (PMS) activation, which achieved efficient bisphenol A (BPA) removal via electron transfer process (ETP). The reactive...
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Social learning in cluster initiatives
PublikacjaPurpose – The purpose of the paper is to portray social learning in cluster initiatives (CIs), namely: 1) to explore, with the lens of the communities of practice (CoPs) theory, in what ways social learning occurs in CIs; 2) to discover how various CoPs emerge and evolve in CIs to facilitate a collective journey in their learning process. Subsequently, the authors address the research questions: In what ways does social learning...
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Effective method of treatment of effluents from production of bitumens under basic pH conditions using hydrodynamic cavitation aided by external oxidants
PublikacjaUtilization of cavitation in advanced oxidation processes (AOPs) is a promising trend in research on treatment of industrial effluents. The paper presents the results of investigations on the use of hydrodynamic cavitation aided by additional oxidation processes (O3/H2O2/Peroxone) to reduce the total pollution load in the effluent from the production of bitumens. A detailed analysis of changes in content of volatile organic compounds...
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Formulation and In Vitro Characterization of Bioactive Mesoporous Silica with Doxorubicin and Metronidazole Intended for Bone Treatment and Regeneration
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Quantification of Compatibility Between Polymeric Excipients and Atenolol Using Principal Component Analysis and Hierarchical Cluster Analysis
PublikacjaAn important challenge to overcome in the solid dosage forms technology is the selection of the most biopharmaceutically efficient polymeric excipients. The excipients can be selected, among others, by compatibility studies since incompatibilities between ingredients of the drug formulations adversely affect their bioavailability, stability, efficacy, and safety. Therefore, new, fast, and reliable methods for detecting incompatibility...
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Catalysts for advanced oxidation processes: Deep eutectic solvents-assisted synthesis – A review
PublikacjaNew catalyst synthesis techniques, including green materials, are extensively studied for heterogeneous photocatalytic advanced oxidation processes (AOPs) on spotlight of sustainable development. Deep eutectic solvents (DESs) started to be used in this field as environmentally friendly alternative to ionic liquids (ILs). During the catalyst synthesis, DESs can act as stabilizers, capping agents, structure directing agents, templates,...
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Impacts on human health in the Arctic owing to climate-induced changes in contaminant cycling – The EU ArcRisk project policy outcome
PublikacjaResults of the EU ArcRisk project on human health impacts in the Arctic owing to climate-induced changes in contaminant cycling are summarized in the context of their policy application. The question on how will climate change affect the transport of selected persistent organic pollutants (POPs) and mercury, both to and within the Arctic has been addressed, as well as the issue of human health impacts of these pollutants in the...
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Selected organophosphorus compounds with biological activity. Applications in medicine
PublikacjaThe purpose of this article is to provide an overview of the latest applications of organophosphorus compounds (OPs) that exhibit biological activity. A large family of OPs have become popular in recent years. The practical application of OPs in modern medicine has been attributed to their unique properties. In this article, the methods used to select these compounds will be emphasized. This paper will first outline the findings...
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Sequential treatment of landfill leachate by electrocoagulation/aeration, PMS/ZVI/UV and electro-Fenton: Performance, biodegradability and toxicity studies
PublikacjaThis study presents a systematic study on sequential treatment of highly resistant landfill leachate by electrocoagulation (EC)/aeration, sulfate radical advanced oxidation process (SR-AOP) and electro-Fenton (EF). In case of SR-AOP, peroxymonosulfate (PMS) catalyzed by zero valent iron (ZVI) and ultraviolet irradiation (UV) system was developed. Treatment process was optimized in respect to COD removal. Analysis of results revealed...
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Mechanism of antifreeze protein functioning and the “anchored clathrate water” concept
PublikacjaIn liquid water, there is a natural tendency to form aggregates that consist of water molecules linked by hydrogen bonds. Such spontaneously formed aggregates are surrounded by a "sea" of disordered water molecules, with both forms remaining in equilibrium. The process of creating water aggregates also takes place in the solvation water of proteins, but in this case the interactions of water molecules with the protein surface shift...
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Wastewater treatment by means of advanced oxidation processes based on cavitation – A review
PublikacjaHydrodynamic and acoustic cavitation combined with advanced oxidation processes (AOPs), including, among others, the Fenton process, is a promising alternative to the technologies of wastewater treatment technologies in use today. The present review discusses processes based on cavitation combined with AOPs and evaluates their effectiveness in oxidation of organic contaminants. Complete degradation of, among others, p-nitrotoluene,...
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Exploring perceptions of pro environmental educational mobile applications based on semantic field analysis
PublikacjaThe paper aims to identify multidimensional perceptions of mobile apps by their users. Special attention has been paid to pro-environmental educational apps. Semantic field analysis and measurement of emotional temperatures were performed to achieve this goal. Transcripts from seven focus group interviews were used as research material. The results indicate that functionality based on a reward or benefit system reinforces environmentally...
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A highly-efficient technique for evaluating bond-orientational order parameters
PublikacjaWe propose a novel, highly-efficient approach for the evaluation of bond-orientational order parameters (BOPs). Our approach exploits the properties of spherical harmonics and Wigner 3jj-symbols to reduce the number of terms in the expressions for BOPs, and employs simultaneous interpolation of normalised associated Legendre polynomials and trigonometric functions to dramatically reduce the total number of arithmetic operations....
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Raport dotyczący wyników badań w zakresie diagnozy ekonomii społecznej w mieście Gdynia. Od ekonomii społecznej do przedsiębiorczości społecznej.
PublikacjaEkspertyza jest dotyczy wyników badań wykonanych na zlecenie MOPS w Gdyni, na temat ekonomii społecznej i przedsiębiorczości społecznej w mieście Gdynia.
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Greening procedures and analytical parameters. The polychlorinated naphthalenes analysis in complex matrices as proof of concept
PublikacjaDue to the complexity of analytical procedures employed for the determination of wide spectrum of persistent organic pollutants (POPs), it is important to consider the green character of the applied protocols and propose the greenest solutions. In this review, the green aspects of several analytical procedures used for the determination of polychlorinated naphthalenes (PCNs) (as a representatives of POPs) in different types of...
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Application of multicriteria decision analysis to assess the greenness of molecularly imprinted polymers synthesis components
PublikacjaThe study applies multicriteria decision analysis (MCDA) to rank the components of molecularly imprinted polymers (MIPs) synthesis according to their greenness. The components are taken from papers that are describing synthesis of MIPs for persistent organic pollutants (POPs) sorbents. Functional monomers (n = 14), target/surrogate molecules (n = 10), porogens (n = 8), cross-linking agents (n = 8) and initiators (n = 4) are described...
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Isotope-labeled substances in analysis of persistent organicpollutants in environmental samples
PublikacjaUltratrace analysis of persistent organic pollutants (POPs) in environmental samples requires very sophisticated methods for both sample preparation and instrumental analysis. The complex matrix requires a multi-stage procedure. Each stage is a potential source of error, as a consequence of which the final result of analysis could be a source of misinformation rather than information. The individual stages and the procedure as...
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Hydroxyl and sulfate radical-based degradation of ciprofloxacin using UV-C and/or Fe2+-catalyzed peroxymonosulfate: Effects of process parameters and toxicity evaluation
PublikacjaCiprofloxacin (CIP) is a valuable antibiotic and discharged in huge quantities in aquatic environment. Different •OH and SO4•−-based advanced oxidation technologies (AOTs), e.g., Fe2+/PMS, UV-C/PMS, and UV-C/Fe2+/PMS are developed for treatment of CIP. The removal of CIP by Fe2+/PMS, UV-C/PMS and UV-C/Fe2+/PMS was 63, 77, and 87 %, respectively, under identical conditions which showed better performance of UV-C/Fe2+/PMS. The UV-C/Fe2+/PMS...
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Removal efficiency of phenol by ozonation process with calcium peroxide from aqueous solutions
PublikacjaPhenol has been introduced as a priority pollutant by the US Environmental Protection Agency. Advanced oxidation processes (AOPs) are one of the most efcient methods for removal of non-degradable organic pollutants in aqueous solutions. The removal efciencies of phenol and COD under optimal conditions pH=3, phenol concentration=5 mg/L, CaO2 concentration=0.025 mg/L, temperature 25 °C, 1 g/min ozonation rate and contact time=90...
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Do online reviews reveal mobile application usability and user experience? The case of WhatsApp
PublikacjaThe variety of hardware devices and the diversity of their users imposes new requirements and expectations on designers and developers of mobile applications (apps). While the Internet has enabled new forms of communication platform, online stores provide the ability to review apps. These informal online app reviews have become a viral form of electronic wordof-mouth (eWOM), covering a plethora of issues. In our study, we set ourselves...
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Zjawisko kawitacji hydrodynamicznej i akustycznej w połączeniu z zaawansowanymi procesami utleniania, jako skuteczne metody oczyszczania ścieków z produkcji asfaltów
PublikacjaW pracy doktorskiej przedstawiono wyniki badań nad zastosowaniem kawitacji hydrodynamicznej oraz akustycznej, wspomaganych zewnętrznymi odczynnikami utleniającymi (ozonem; nadtlenkiem wodoru; oraz ich mieszaniną – tzw. odczynnikiem peroxone) do obniżenia ładunku zanieczyszczeń ścieków rzeczywistych z produkcji asfaltów. Przeprowadzono szczegółową analizę zmian zawartości lotnych związków organicznych tlenu i siarki oraz porównano...
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Integrated Photocatalytic Advanced Oxidation System (TiO2/UV/O3/H2O2) for Degradation of Volatile Organic Compounds
PublikacjaSeveral advanced oxidation processes (AOPs) including photocatalytic processes were studied for effective treatment of complex model wastewater containing a wide variety of VOCs. The studies revealed synergistic effects of TiO2 based processes for improved degradation of the VOCs. A peroxone combined with TiO2/UV system (TiO2/UV/O3/H2O2) with a ratio between the oxygen source from the oxidant to chemical oxygen demand (COD) of...
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Interspecific and intraspecific variation in organochlorine pesticides and polychlorinated biphenyls using non-destructive samples from Pygoscelis penguins
PublikacjaAs humans are present in Antarctica only for scientific and tourism-related purposes, it is often described as a pristine region. However, studies have identified measurable levels of Persistent Organic Pollutants (POPs), such as organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs), in the Antarctic region. These are highly toxic anthropogenic compounds with tendency to travel long distances and reach remote environments, where...
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Review of Diameter protocol implementations for realization of communication in NGN networks
PublikacjaIn the paper Diameter protocol as well as its applications in the context of Next Generation Network (NGN) are described. Diameter message content and Attribute-Value Pairs (AVPs) concept are presented. Critical review of open source Diameter implementations is carried out. The performed analysis takes into consideration programming language, availability, support and documentation aspects. Basing on the review project fulfilling...
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Using Fast Frequency Hopping Technique to Improve Reliability of Underwater Communication System
PublikacjaAcoustic underwater communication systems designed to work reliably in shallow coastal waters must overcome major limitations such as multipath propagation and the Doppler effect. These restrictions are the reason for the complexity of receivers being built, whose task is to decode a symbol on the basis of the received signal. Additional complications are caused by the low propagation speed of the acoustic wave in the water and...
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Green energy extraction for sustainable development: A novel MPPT technique for hybrid PV-TEG system
PublikacjaThe Photovoltaic (PV) module converts only a small portion of irradiance into electrical energy. Most of the solar energy is wasted as heat, resulting in a rise in PV cell temperature and a decrease in solar cell efficiency. One way to harvest this freely available solar thermal energy and improve PV cell efficiency is by integrating PV systems with thermoelectric generators (TEG). This cogeneration approach of the hybrid PV-TEG...
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Pulsowo-różnicowa woltamperometria jako narzędzie pozwalające na wyznaczenie wartości mocy przeciwutleniającej
PublikacjaStandardowy potencjał redukcji (E0) jako parametr określający zdolność przeciwutleniaczy, jak np. flawan-3-oli do przyjmowania elektronów wykazywał wysoką korelację z ich aktywnością biologiczną. Jednak, w przypadku oceny całkowitej aktywności przeciwutleniającej mieszanin tych związków, parametr ten może okazać się być niewystarczającym. Bowiem do określenia tzw. mocy przeciwutleniającej ang. antioxidant power (AOP) powinny być...
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The Research of the Contamination Levels present in Samples of Precipitation and Surface Waters Collected from the Catchment Area Fuglebekken (Hornsund, Svalbard Archipelago)
PublikacjaPersistent organic pollutants (POPs) are contaminants that may appear in polar regions. In present work surface water was collected from the main stream water in the Fuglebekken basin. The precipitationsamples was collected from the near area by Polish Polar Station in Hornsund. The present investigationreveals the results of the analysis of these samples for their total phenols, formaldehyde, TOC, PAHs and PCBs content. The...
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Elimination of impulsive disturbances from archive audio files – comparison of three noise pulse detection schemes
PublikacjaThe problem of elimination of impulsive disturbances (such as clicks, pops, ticks, crackles, and record scratches) from archive audio recordings is considered and solved using autoregressive modeling. Three classical noise pulse detection schemes are examined and compared: the approach based on open-loop multi-step-ahead signal prediction, the approach based on decision-feedback signal prediction, and the double threshold approach,...
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Sparse vector autoregressive modeling of audio signals and its application to the elimination of impulsive disturbances
PublikacjaArchive audio files are often corrupted by impulsive disturbances, such as clicks, pops and record scratches. This paper presents a new method for elimination of impulsive disturbances from stereo audio signals. The proposed approach is based on a sparse vector autoregressive signal model, made up of two components: one taking care of short-term signal correlations, and the other one taking care of long-term correlations. The method...
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Tereny polarne - interesującym obszarem do badań Cz. II - Analityka próbek abiotycznych w Arktyce
PublikacjaW pracy ujęto problematykę zanieczyszczeń obszarów polarnych. Zwrócono szczególną uwagę na trwałe związki organiczne obecne w rejonie Arktyki w elementach przyrody nieożywionej. TZO pochodzenia antropogenicznego mogą pojawiać się na terenach polarnych za sprawą transportu na duże odległości z obszarów Euroazji i Ameryki Północnej. Badania poziomów zanieczyszczeń obecnych w próbkach abiotycznych na obszarze Arktyki stanowią fundament...
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Application of gas chromatographic data and 2D molecular descriptors for accurate global mobility potential prediction
PublikacjaMobility is a key feature affecting the environmental fate, which is of particular importance in the case of persistent organic pollutants (POPs) and emerging pollutants (EPs). In this study, the global mobility classification artificial neural networks-based models employing GC retention times (RT) and 2D molecular descriptors were constructed and validated. The high usability of RT was confirmed based on the feature selection...
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Application of persulfate-based oxidation processes to address diverse sustainability challenges: A critical review
PublikacjaOver the past years, persulfate (PS) is widely applied due to their high versatility and efficacy in decontamination and sterilization. While treatment of organic chemicals, remediation of soil and groundwater, sludge treatment, disinfection on pathogen microorganisms have been covered by most published reviews, there are no comprehensive and specific reviews on its application to address diverse sustainability challenges, including...
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Correlations between the wear of car brake friction materials and airborne wear particle emissions
PublikacjaAirborne wear particles emitted from transport vehicle brakes are one of the main sources of toxic metals in inhalable particulate matter. Prediction of wear particle emissions may become more accurate if the relationship between the wear and particle emission characteristics is known. An experimental study was performed to investigate proportional correlations between the mass wear, 0.01–0.42 μm particle emission measured by a NanoScan...
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New semi-causal and noncausal techniques for detection of impulsive disturbances in multivariate signals with audio applications
PublikacjaThis paper deals with the problem of localization of impulsive disturbances in nonstationary multivariate signals. Both unidirectional and bidirectional (noncausal) detection schemes are proposed. It is shown that the strengthened pulse detection rule, which combines analysis of one-step-ahead signal prediction errors with critical evaluation of leave-one-out signal interpolation errors, allows one to noticeably improve detection results...
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Some Artificial Intelligence Driven Algorithms For Mobile Edge Computing in Smart City
PublikacjaSmart mobile devices can share computing workload with the computer cloud that is important when artificial intelligence tools support computer systems in a smart city. This concept brings computing on the edge of the cloud, closer to citizens and it can shorten latency. Edge computing removes a crucial drawback of the smart city computing because city services are usually far away from citizens, physically. Besides, we introduced...
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Ball milling treatment of Mn3O4 regulates electron transfer pathway for peroxymonosulfate activation
PublikacjaHeterogeneous metal catalysts have attracted considerable interest in advanced oxidation processes (AOPs) for wastewater treatment by activating peroxymonosulfate (PMS). However, it remains challenging to the rational design of efficient reaction pathway for high-performance contaminants removal by regulating the inherent structure of metal oxides. Herein, a high-energy ball milling method was employed to modulate the electronic...