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Wyniki wyszukiwania dla: thermostable polymers
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Polymers (Polyvinylpyrrolidones) As Active Additives Modifying the Lubricating Properties of Water
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Theoretical Study of Polymerization Mechanism of p-Xylylene Based Polymers
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Progress in development of molecularly imprinted polymers as sorbents for sample preparation
PublikacjaSample preparation has been one of the most often investigated steps in analytical procedures.These investigations are focused on problems such as isolation of analytes from the sample matrix, matrix implification, analyte enrichment to the level above the detection limit of the instrumentation used, and the removal of interfering species to improve the final determination. Techniques based on solid (adsorption) and pseudo liquid...
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Theoretical study of polymerization mechanism of p-xylylene based polymers
PublikacjaObliczenia kwantowe mechanizmu polimeryzacji parylenów, opartych o cząsteczki p-ksylilenów. Praca zawiera wyniki szczegółowych obliczeń wszystkich etapów polimeryzacji, wnioski dotyczące znalezionych stanów kwantowych i energetyki poszczególnych etapów procesu.
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Analysis of structure and properties of DVB–GMA based porous polymers
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Sorption Properties of Polydivinylbenzene Polymers towards Phenolic Compounds and Pharmaceuticals
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The Role of Specific Side Groups and pH in Magnetization Transfer in Polymers
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Raman investigation of sol-gel-derived hybrid polymers for optoelectronics
PublikacjaPrzedstawiono wykorzystanie spektroskopii ramanowskiej do kompleksowej diagnostyki polimerów hybrydowych stosowanych w optoelektronice. Zbadano efektywność kolejnych etapów procesu technologicznego: od monomerów do etapu produktu finalnego - cienkich warstw.
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Photovoltaic bulk heterojunctions with interpenetrating network based on semiconducting polymers
PublikacjaPhotovoltaic cells are supposed to be the most common generators of useful electricity in the nearest future as they utilize inexhaustible carriers of renewable energy called photons. Despite the fact that 95% of worldwide applied photovoltaic devices are based on inorganic semiconductors the area of organic photovoltaics grows successively due to possibility of considerable reduction of manufacturing costs. Since the Heeger's...
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Molecularly imprinted polymers applied in capillary electrochromatography and electrophoresis techniques
PublikacjaMolecularly imprinted polymers (MIPs) are synthetic materials with predetermined selectivity for a particular analyte or group of structure-linked chemicals which make them an ideal separation component. The process of developing and applying new types of MIPs in the field of environmental analytical chemistry has been broadly discussedi n many scientific studies in recent years. The use of new types of MIP sorbents as unique sorption...
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Sustainable polymers targeted at the surgical and otolaryngological applications: Circularity and future
PublikacjaThe ongoing climate changes, high air and noise pollution have significant impact on humans’ health. This influence is especially visible in otolaryngology, which focuses on respiratory and hearing systems disfunctions. However, even though surgeries are done in response to diseases related to climate changes, they also have a negative impact on the environment, mostly connected with the inherence of single-use fossil fuel derived...
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HYDRODYNAMIC THRUST BEARINGS WITH POLYMER LINING
PublikacjaPolymeric linings of sliding surfaces of the hydrodynamic bearings have been used successfully for over 50 years. Despite of their long history of operation and research, they have not become wide spread in industrial applications. This fact may be surprising, considering th e conclusions that have been published concerning bearing operation and design. This paper summarizes the current...
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Interface analysis of compatibilized polymer blends
PublikacjaThis chapter seeks to address the interface location in the compatibilized polymer blends and paves the way for quantitative analysis of interface in terms of interfacial tension and interfacial adhesion to provide support for understanding the relationship between morphology and ultimate properties in the compatibilized polymer blends through the lens of interface. Since understanding and analysis of interfacial phenomena in the...
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Hybrid hydrophilic polymer/montmorillonite systems
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Recombinant !ermostable AP Exonuclease from Thermoanaerobacter tengcongensis: Cloning, Expression, Purification, Properties and PCR Application
PublikacjaApurinic/apyrimidinic (AP) sites in DNA are considered to be highly mutagenic and must be corrected to preserve genetic integrity, especially at high temperatures. !e gene encoding a homologue of AP exonuclease was cloned from the thermophilic anaerobic bacterium Thermoanaerobacter tengcongensis and transformed into Escherichia coli. The protein product showed high identity (80%) to human Ape1 nuclease, whereas to E. coli exonuclease...
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Application of the X-ray micro computed tomography to the analysis of the structure of polymeric materials
PublikacjaIn this paper the application of X-ray micro-computed tomography (micro-CT) as a non-destructive testing method of polymeric materials is presented. Increasing applicability of polymers in variedend-use industries such as automotive, building and construction, consumer goods, and packaging is propelling the growth of the global polymer processing market. However, controlling of the polymer structure is one of the most important...
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Flame-Retardant Polymer Materials Developed by Reactive Extrusion: Present Status and Future Perspectives
PublikacjaThe development of flame retardant polymer materials has two roots, one in materials design, and the other in materials processing. Over recent decades, different types and classes of flame retardant polymer materials have been commercialized to meet safety requirements in the construction, automotive, and coatings industries. In the vast majority of cases, the design and fabrication of new materials presenting low fire hazards...
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Unveiling of polymer/fullerene blend films morphology by ellipsometrically determined optical order within polymer and fullerene phases
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The use of fibre-reinforced polymers (FRP) in bridges as a favourable solution for the environment
PublikacjaThe purpose of this article is to show the modern engineering, in which sustainability and taking care of ecology play a significant role. The authors are focused on FRP composite materials and their applications in civil engineering. Case studies showing renovation and design of new bridges with the use of FRP are presented and discussed to clarify benefits, which this solution provides. Main advantages of FRP materials in comparison...
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A new concept of measuring the friction forces for cartilage and polymers with viscoelastic properties
PublikacjaReferat przedstawia nową koncepcję dotyczącą pomiaru niskich sił tarcia oraz właściwości materiałów lepkosprężystych. Zaprezentowano: ogólny zarys metody pomiaru, wskazania dotyczące projektowania i budowy urządzenia pomiarowego, model matematyczny oraz sposób identyfikacji parametrów modelu. Metoda ta jest szczególnie przydatna w przypadku analizy właściwości materiałowej polimerów oraz tkanki chrząstki stawowej człowieka, zarówno...
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Modelling of optical components made of liquid crystals and liquid crystalline polymers
PublikacjaW artykule przedstawiono koncepcję wykorzystania ciekłych kryształów i polimerów ciekłokrystalicznych do budowy dwójłomnych elementów optycznych - płytek opóźniających, pryzmatów Wollastona i Nomarskiego. Przedstawiono wyniki modelowania pryzmatów Nomarskiego wykonanych z polimerów ciekłokrystalicznych i dokonano porównania ich właściwości z właściwościami pryzmatów wykonanych z typowych materiałów dwójłomnych.
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The Application of Phenolic Acids in The Obtainment of Packaging Materials Based on Polymers—A Review
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Bringing a New Flexible Mercaptoacetic Acid Linker to the Design of Coordination Polymers
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Star Polymers vs. Dendrimers: Studies of the Synthesis Based on Computer Simulations
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AGREEMIP: The Analytical Greenness Assessment Tool for Molecularly Imprinted Polymers Synthesis
PublikacjaMolecular imprinting technology is well established in areas where a high selectivity is required, such as catalysis, sensing, and separations/sample preparation. However, according to the Principles of Green Chemistry, it is evident that the various steps required to obtain molecularly imprinted polymers (MIPs) are far from ideal. In this regard, greener alternatives to the synthesis of MIPs have been proposed in recent years....
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Fusion of DNA-binding domain of Pyrococcus furiosus ligase with TaqStoffel DNA polymerase as a useful tool in PCR with difficult targets
PublikacjaThe DNA coding sequence of TaqStoffel polymer- ase was fused with the DNA-binding domain of Pyrococcus furiosus ligase. The resulting novel recombinant gene was cloned and expressed in E. coli. The recombinant enzyme was purified and its enzymatic features were studied. The fusion protein (PfuDBDlig-TaqS) was found to have enhanced processivity as a result of the conversion of the Taq DNA polymerase from a relatively low processive...
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Investigations of a new humidity sensor with polymer film
PublikacjaPrzedstawiono wyniki badań impedancyjnych nowego czujnika wilgotności z filmem polimerowym. Jako polimer wykorzystano chemicznie modyfikowaną polietylenoiminę.
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Mechanism for sonocoating a polymer surface with nano-hydroxyapatite
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Manufacturing of metal-polymer composites for medical applications
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Biodegradable polymer packaging materials - influence on environment
PublikacjaAwareness of the waste problem and its impact on the environment has awakened new interest in the area of biodegradable polymers. Biodegradation of various polymers have been studied under diverse environments like in soil, in sewage sludge, in compost conditions and in sea water by different research groups. The aim of this paper is to present the research methods on the biodegradation of the commercially available biodegradable...
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Electrical properties of polymer coatings modified with nanoadditives
PublikacjaW pracy przedstawiono właściwości elektryczne (antystatyczne, rezystancję powierzchniową) polimerowych powłok. Pokazano wpływ różnych domieszek na czasy rozładowania się warstwy oraz na jej rezystancję powierzchniową.
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Review: synthetic polymer hydrogels for biomedical applications
PublikacjaSynthetic polymer hydrogels constitute a group of biomaterials, used in numerous biomedical disciplines, and are still developing for new promising applications. The aim of this study is to review information about well known and the newest hydrogels, show the importance of water uptake and cross-linking type and classify them in accordance with their chemical structure.
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Some kind of joints in composite polymer bridges
PublikacjaContemporary, polymer composites bridge structures are of two types: truss or arch structures(with many joints along the length) and beam structures with limited number of joints. Both of them have special types of composite polymer decks. An ideal solution is to join advantages of two types of structuresdescribed below and create long span FRP beam bridge structure system using joints along the length. Theproblem is to find the...
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Raman investigation of hybrid polymer thin films
PublikacjaPrzestawiono problemy diagnostyki ramanowskiej transparentnych struktur cienkowarstwowych wykonanych metodą zol-żel z polimerów hybrydowych. Analizowano możliwości badania struktury molekularnej i grubości, a także określania jakości wykonania struktur falowodowych. Przedstawiono wyniki badań wykonanych mikroskopem ramanowskim dla polimerowych struktur cienkowarstwowych osadzonych na podłożach szklanych i krzemowych.
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Conducting Polymer Microelectrodes Anchored to Hydrogel Films
PublikacjaArtykuł prezentuje wytwarzanie organicznych hydrożeli z mikroelektrodami poli(3,4-ethylenedioxythiophene, PEDOT), które wykazują obniżoną rezystywność 100 Ω/□. Proces przygotowania rozpoczyna się elektroosadzania przewodzącego PEDOT (ok. 20 S/cm) na mikroelektrodach Pt. Elektrolityczne wiąże się film PEDOT z hydrożelem. Tak wytworzona struktura jest odrywana elektrycznie pd podłoża.
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Study on polymer modified road asphalt mixture
PublikacjaThe formulation of ternary asphalt-additives blend composed of crumb rubber : low-density polyethylene (CR : LDPE) and crumb rubber : textile fiber (CR : TF) couples, and quaternary asphalt additives-blend composed of (CR : LDPE : TF) triplets on the virgin asphalt to optimize the asphalt basic and rheological properties and to use the extrusion process of two or three additives to obtain composite materials of them, as well as...
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Inhibition of Polymer Photodegradation by Incorporation of Coffee Silverskin
PublikacjaOver the last years, the trend associated with the incorporation of materials from renewable resources into polymer technology is getting significantly more vital. Researchers are trying to transfer the properties of natural raw materials into the polymer world. Therefore, different natural materials are more often investigated as potential additives for polymers. Such an effect is noted for the coffee industry by-products, such...
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Biodegradable Polymer Packaging Materials in Seawater Environment
PublikacjaIn this chapter, our interest is directed into dea/ocean/lakes biodegradable environment for polymer packaging materials from two different points of view.
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Green Polymer Nanocomposites for Skin Tissue Engineering
PublikacjaFabrication of an appropriate skin scaffold needs to meet several standards related to the mechanical and biological properties. Fully natural/green scaffolds with acceptable biodegradability, biocompatibility, and physiological properties quite often suffer from poor mechanical properties. Therefore, for appropriate skin tissue engineering and to mimic the real functions, we need to use synthetic polymers and/or additives as complements...
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THERMOPLASTIC POLYMER MACHINE GUARDS – EXPLOITATION SAFETY
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Effect of modified soybeen oil amount on rheological characteriza-tion of polyurethane pre-polymers
PublikacjaPolyurethanes (Pu’s) are the polymeric materials which have got urethane groups in the structure. The properties of Pu’s depend both on the method of preparation and monomers used. Polyurethanes are produced by two methods known as one step or two step method called as “pre-polymers method”, especially for the case of segmented polyurethanes (SPU’s). These materials are thermoplastic block copolymers of the (AB)n type consisting...
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Hydrothermal reactions: From the synthesis of ligand to new lanthanide 3D-coordination polymers
PublikacjaThe organic ligand 2,5-piperazinedione-1,4-diaceticacid (H2PDA) was synthesized under hydrothermal conditions starting from the iminodiacetic acid and catalyzed by oxalic acid. The X-ray powder diffraction data indicates that the compound crystallizes in the P21/c space group as reported in the literature. The ligand was also characterized by elemental analysis, magnetic nuclear resonance, infrared spectroscopy and thermogravimetric...
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Application of Microextraction Techniques Including SPME and MESI to the Thermal Degradation of Polymers: A Review
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Molecularly Imprinted Polymers for Stir Bar Sorptive Extraction: Synthesis, Characterization, and Application
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From phosphanylphosphaalkenes to coordination copper and silver polymers containing P–P bonds
PublikacjaThis study was focused on the activation of the C[double bond, length as m-dash]P bond via reactions of Ph2C[double bond, length as m-dash]P-PtBu2 (1) with 1,6-hexanediol and selected dithiols (1,4-butanedithiol, 1,4-benzenedithiol and 1,4-benzenedimethanethiol). These reactions proceed according to a 1,2-addition mechanism, providing new compounds with formulas {(Ph)2(H)C-P-PtBu2}{μ2-(O-(CH2)6-O)}{tBu2P-P-C(H)(Ph)2} (2), {(Ph)2(H)C-P-PtBu2}{μ2-(S-(CH2)4-S)}{tBu2P-P-C(H)(Ph)2}...
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Interfacial properties of PET and PET/starch polymers developed by air plasma processing
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Recent advancements in molecularly imprinted polymers for the removal of heavy metal ions and dyes
PublikacjaContamination set off by highly toxic metal ions and dyes is a big threat to the environment and living beings. Various industries like metal plating, mining, pesticides, battery manufacturing, and dyeing release metal ions and toxic dyes directly into the water. It is necessary to remove these toxic substances from the environment. Molecular imprinting technology (MIT) got a lot of attention in the last two decades because of...
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Pilot study of the influence of thermoplastic starch based polymer packaging material on the growth of diatom population in sea water environment
PublikacjaNovel polymeric packaging materials susceptible to environmentally friendly decomposition appeared on the global market. The paper is devoted to an investigation of the impact of degradable polymer packaging on marine life. The chosen polymer was a commercial packaging based on thermoplastic starch (TPS over 85%). The microorganism chosen was Phaeodactylum tricornutum diatom (identified in many aquatic reservoirs, with a tendency...
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Polymer based thick films - material quality and interface resistance evaluation
PublikacjaThe properties of polymer based thick film layers mede using different resistive pastes and dipping silvers have been studied. The composite of carbon and graphite (C/Gr) conducting particles suspended in different polymer vehicles were used for preparation resistive layers. Interface resistance Rc created between dipping silver (DiAg) contact layer and resistive layer was determined from the surface potential distribution measurements...
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Nitrogen dioxide sensing properties of PEDOT polymer films
PublikacjaThis work presents a simple and fully electrochemical route for the polymerization of poly(3,4-ethylenedioxytiophene) (PEDOT) films for fabricating a NO2 gas sensor prepared by electropolymerization of 3,4-Ethylenedioxythiophene (EDOT) monomer in lithium perchlorate/acetonitrile solution. The main aim of this study is to determine the sensing properties of conductive polymer at elevated temperatures. The effects of the humidity,...