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Wyniki wyszukiwania dla: SYNTHETIC DYES
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Photophysics of a Ruthenium 4H-Imidazole Panchromatic Dye in Interaction with Titanium Dioxide
PublikacjaThe photophysics of bis(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)[2-(4-carboxyphenyl)-4,5-bis(p-tolylimino-κN)imidazolato]ruthenium(II) hexafluorophosphate is investigated, both in solution and attached to a nanocrystalline TiO2 film. The studied substitution pattern of the 4H-imidazole ligand is observed to block a photoinduced structural reorganization pathway within the 4H-imidazole ligand that has been previously investigated....
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Chemical analysis of low carbon content coals and their applications as dye adsorbent
PublikacjaCoal is primarily a fuel material but lately it has been utilized as an adsorbent for removing toxic metal ions. However, its usage for removing organic pollutants is not well studied. We report here a systematic study on the use of coal samples of varying carbon contents as adsorbents for removing Basic Blue 41 as a model cationic dye. The coal samples were collected from coal mines and were thoroughly characterized. The concentrations...
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Does Mass Culture Mean a Crisis of Values? Dwight Macdonald's Position and the Issue of Its Topicality
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Does the Meeting Centre Support Programme decrease the experience of stigmatisation among people with cognitive deficits?
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The ChoCO-W prospective observational global study: Does COVID-19 increase gangrenous cholecystitis?
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Does social–economical transformation influence the incidence of type 1 diabetes mellitus? A Polish example
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Exploring the Role of Ownership in International Entrepreneurship: How does Ownership Affect Internationalisation of Polish Firms?
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Physics Comes to the Aid of Medicine—Clinically-Relevant Microorganisms through the Eyes of Atomic Force Microscope
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Does the chemical modification of Nystatin A1 affect the drug's ability to overcome the multidrug resistance of fungi?
PublikacjaAlthough the contemporary medicine keeps moving forward, disseminated infections caused by fungal pathogens are an emerging challenge. The dramatic rise of fungal diseases, especially the most life-threatening systemic mycoses is associated with a permanently growing number of immunodeficient patients. Undoubted difficulties in the treatment of fungal infections are caused by lack of highly effective and selective antifungal drugs,...
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Does one currency mean one price? An analysis of the euro effect on price dispersion and convergence
PublikacjaThis paper examines price differentials in the European Union to investigate whether the European Monetary Union has lowered the degree of price dispersion in the euro zone and increased the speed of price convergence. Both euro effects are evaluated using difference-in-difference methodology. Applied to the issue of introducing a single currency, the euro effects identified are the estimated differences in price dispersion and...
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Does system of local government subsidisation fulfil revenue equalisation function? Evidence from Poland
PublikacjaThe article will discuss functions that should pursue general grants. One of them is revenue equalization. To achieve it after applying the mechanism of subsidising revenues should be reduced. In addition, to be completed, the size of the support should be inversely proportional to achieved own revenues. Besides the theoretical analysis, which will present the general grants structure and the ability of fulfilling revenue equalisation...
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Impact of Clustering on a Synthetic Instance Generation in Imbalanced Data Streams Classification
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Biologically active compounds based on the carbazole scaffold - synthetic and mechanistic aspects
PublikacjaDoctoral dissertation is divided into three main parts: introduction, results and discussion and experimental. The introduction is divided into four main parts which describe: 5-hydroxytryptamine receptors, the most popular antidepressants, new compounds based on the carbazole structure with affinity for serotonin receptors, telomeres and telomerase with their functions, telomerase inhibition strategies, carbazoles approved in...
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Potential of Functionalized Polyolefins in a Sustainable Polymer Economy: Synthetic Strategies and Applications
PublikacjaPolymers play a crucial role in our modern life as no other material exists that is so versatile, moldable, and lightweight. Consequently, the demand for polymers will continue to grow with the human population, modernization, and technological developments. However, depleted fossil resources, increasing plastic waste production, ocean pollution, and related growing emission of greenhouse gases has led to a change in the way we...
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Aromatic heptaene antibiotics as an alternative for synthetic triazole fungicides in plant protection
PublikacjaAn in vitro antifungal activity of candicidin and ascosin antibiotics (0,01-10 μg/mL) towards representative strains of phytopathogenic fungi was detd. Both compds. exhibited similar half max. effective concns. inhibiting growth of the fungi as that of tebuconazole used for comparison.
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Synthesis of 3-D Graphene via Combustion Synthesis of Magnesium and Calcium/Magnesium Oxalates
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Synthesis and properties of CaFe2As2single crystals
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Methods of ZnO nanoparticles synthesis
PublikacjaZinc oxide nanostructures are interesting nanomaterials with a wide range of applications. Since the physical and chemical properties of ZnO nanoparticles are influenced both by their shape and size, a control of morphology of ZnO structures is needed for their commercial usage. Different chemical, physical, and biological methods used to produce ZnO nanostructures can be found in the literature. The production of ZnO nanoparticles...
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The prns butterfly synthesis in the FPGA
Publikacjaw pracy przedstawiono sprzętową implementację elementarnych obliczeń, określanych jako obliczenia motylkowe, dla splotu realizowanego z użyciem wielomianowego systemu resztowego(ang. polynomial residue number system - prns). obliczenia są wykonywane z zastosowaniem reprezentacji systemu diminished-1. opisano syntezę układu realizującego obliczenie motylkowe w środowisku xilinx w układzie virtex 4. podano również wymaganą ilość...
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Synthesis and characterisation of starch cuprate
PublikacjaThe cupration of granular potato starch with ammonium tetrachlorocuprate(II) was performed by a 20 min lasting microwave-assisted process and by 40 min convectional heating. In both cases the degree of esterification (DE) did not exceed 0.0064. A higher dose of cuprate had a positive effect on DE, regardless of whether the microwave irradiation or the convectional heating was applied, and on the thermal stability of the starch...
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Silanethiolates - synthesis, properties and structures.
PublikacjaW pracy wskazano podstawowe drogi syntezy oraz podano zwięzłą charakterystykę silanotiolanów - w większości związków kompleksowych posiadających jako główny ligand grupę silanotiolanową, na ogół (t-BuO)3SiS. Przy pomocy odpowiednio dobranych przykładów zilustrowano właściwości tych związków - wskazano ciekawsze elementy struktury molekularnej oraz specyficzne cechy spektralne.
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Applications of Alkanethiols in Organic Synthesis
PublikacjaThis manuscript is an update to the earlier Science of Synthesis contribution describing methods for the synthesis of alkanethiols. Thiols can be converted into sulfonic, sulfinic, sulfenic acid and their derivatives, sulfides, disulfides, polysulfides, sulfonium salts, and thiiranes, etc. These transformations are accomplished by nucleophilic displacement or addition, oxidation, condensation, or coupling reactions involving thiol...
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Synthesis of Novel Arginine Building Blocks with Increased Lipophilicity Compatible with Solid-Phase Peptide Synthesis
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How does institutional and natural social support shape the beliefs about psychological help among policemen?
PublikacjaEffectiveness of social support mechanisms results from interacting subjective factors (beliefs about help from others) and context (social network available). Organized institutional support and perception of natural support reduce barriers in obtaining psychological help.
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Correcting a widespread error: Neuroprotectant N-acetyl-L-tryptophan does not bind to the neurokinin-1 receptor
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Does caffeine ingestion affect the lower-body post-activation performance enhancement in female volleyball players?
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Does being socially good save firms from bankruptcy? A systematic literature review and bibliometric analysis
PublikacjaThe purpose of the review was to find out, does being responsible saves firms from bank-ruptcy? What is the relationship between corporate social responsibility and default risk? What meth-ods and measures are used in the literature to evaluate this relationship? And what is the theoretical underpinning of the studies? Moreover, to explore what are the gaps for future work, Web of Science and Scopus databases were utilised to obtain...
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How Much Does an e-Vote Cost? Cost Comparison per Vote in Multichannel Elections in Estonia
PublikacjaWe are presenting the results of the CoDE project in this paper, where we investigate the costs per vote of different voting channels in Estonian Local Elections (2017). The elections analyzed involve different processes for casting a vote: Early Voting at County Centers, Advance Voting at County Centers, Advance Voting at Ordinary Voting District Committees, Electronic Voting, Election Day Voting, and Home Voting. Our analysis...
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Shape memory thin films of Polyurethane: Does graphene content affect the recovery behavior of Polyurethane nanocomposites?
PublikacjaThin nanocomposite films of polyurethane have received remarkable attention due to their shape memory properties. As most of the reports focus on the beneficial aspects of the presence of nanofillers such as graphene nanoplatelets (GNPs) introduced into shape memory polymers, some research results reveal the opposite trend. The polyether/polyester-based polyurethane was synthesized through a condensation polymerization and the...
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How does stakeholder pressure influence CSR-practices? A construction industry model based on a European sample
PublikacjaThe stakeholder pressure is one of the most vital powers which determines CSR implementation and can provide organizations with the motivation to adopt corporate social responsibility (CSR) strategy, as the stakeholder theory claims. The current investigation replications Kowalczyk’s (2019) study, who examined the same structure of relations based on the Polish sample. The essence of this replication is to find out whether CSR-...
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Descriptors to Predict Dye‐Sensitized Semiconductor Based Photocatalyst for Hydrogen Evolution Reaction
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Examination of the Effect of Selected Factors on the Photovoltaic Response of Dye-Sensitized Solar Cells
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Rekonstruktion des Baudenkmals ''Das grune Tor'' in Danzing nach einem Teileinsturz.
PublikacjaW pracy przedstawiono opis konstrukcyjny zabytkowej ''Zielonej Bramy'' w Gdańsku, która jako kilkukondygnacyjny obiekt murowany została wzniesiona w XVI wieku nad brzegiem Motławy. Podczas prowadzenia prac rmontowych w styczniu 2002r uległ zawaleniu fragment sklepienia wraz z podpierającą go kamienną kolumną. Dokładny przegląd całej konstrukcji wykazał, że bardzo zły stan także innych elementów konstrukcji nośnej tego obiektu....
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Spray deposited carbon nanotubes counter electrodes for dye-sensitized solar cells
PublikacjaCarbon nanotubes due to their catalytic properties are a promising alternative to platinum counter electrodes (CE) for dye-sensitized solar cells (DSSC). In this study, counter electrodes were made from double-walled carbon nanotube (DWCNT) ink using the spray printing technique and afterwards thermally treated at temperatures ranging from 120 to 300 °C. Morphology and structure was studied using scanning electron microscopy and...
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Spray-deposited carbon-nanotube counter-electrodes for dye-sensitized solar cells
PublikacjaCarbon nanotubes due to their catalytic properties are a promising alternative to platinum counter electrodes (CE) for dye-sensitized solar cells (DSSC). In this study, counter electrodes were made from double-walled carbon nanotube (DWCNT) ink using the spray printing technique and afterwards they were thermally treated at temperatures ranging from 120 to 300 °C. Morphology and structure was studied using scanning electron microscopy...
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Patterns of synthetic cathinones use and their impact on depressive symptoms and parafunctional oral behaviors
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The Influence of Synthetic Oxygenates on Euro IV Diesel Passenger Car Exhaust Emissions
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Synthetic Principles Determining Local Organization of Copolyesters Prepared from Lactones and Macrolactones
PublikacjaA highly effective and facile technique for catalytic ring-opening copolymerization (cROP) of lactones viz. ε- caprolactone and ε-decalactone with ω-pentadecalactone is being described. The reactions were mediated by Zn- and Cabased tridentate Schiff base complexes and benzyl alcohol as initiator. The catalysts were successfully employed for the preparation of numerous block and random copolymers. To unravel the composition of...
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CeCu2O4 as a functional layer on solid oxide fuel cells for synthetic biogas reforming
PublikacjaSolid Oxide Fuel Cells (SOFC) are one of the most promising electrochemical devices, which can convert chemical energy to the electrical energy these days. Their ability to work with different kind of fuel makes them noteworthy. SOFC can work with biogas. The problem arises when solid carbon starts to be deposited in anode. That leads to degradation of fuel cell. Simple solution is to apply catalytic functional layer, which is...
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The structure of novel polyurethanes containing synthetic poly[(R,S)-3-hydroxybutyrate]
PublikacjaThe aim of this study was to estimate the structure of new polyurethanes with the potential to be used in medicine. Atactic poly[(R,S)-3-hydroxybutyrate], obtained via a ring-opening polymerization, and polycaprolactonediol or polyoxytetramethylenediol were used to built the soft segments. 4,4'-methylene dicyclohexyl diisocyanate and 1,4-butanediol were the components to form hard segments. Polyurethanes with low-molecular weight...
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Preeclampsia Risk Prediction Using Machine Learning Methods Trained on Synthetic Data
PublikacjaThis paper describes a research study that investigates the use of machine learning algorithms on synthetic data to classify the risk of developing preeclampsia by pregnant women. Synthetic datasets were generated based on parameter distributions from three real patient studies. Four models were compared: XGBoost, Support Vector Machine (SVM), Random Forest, and Explainable Boosting Machines (EBM). The study found that the XGBoost...
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Hydrogen assisted cracking of 2205 duplex stainless steel in synthetic sea water
PublikacjaThe cracking behavior of 2205 duplex stainless steels (DSSs) in synthetic sea water under cathodic polarization condition was investigated. (SSRT) method was employed in aim to evaluate the susceptibility to hydrogen assisted cracking. The results showed that the reduction in the uniform elongation (UEL) and the reduction of area (RA) varied with the applied cathodic current density. Significant reductions in ductility were found,...
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Synthetic strategies in construction of organic low molecular-weight carrier-drug conjugates
PublikacjaInefficient transportation of polar metabolic inhibitors through cell membranes of eukaryotic and prokaryotic cells precludes their direct use as drug candidates in chemotherapy. One of the possible solutions to this problem is application of the ‘Trojan horse’ strategy, i.e. conjugation of an active substance with a molecular carrier of organic or inorganic nature, facilitating membrane penetration. In this work, the synthetic...
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Wetting properties of biosurfactant (rhamnolipid) with synthetic surfactants mixtures in the context of soil remediation
PublikacjaWetting properties of synthetic surfactant Rokanol NL6, biosurfactant JBR 425 and their mixture have been investigated.The results show that synthetic surfactant addition worsens physicochemical properties of pure biosurfactant but exhibits much higher oil removal efficiency than biosurfactant does.
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COMPLEXITY OF INNOVATIVE FINANCIAL PRODUCTS: THE CASE OF SYNTHETIC EXCHANGE TRADED FUNDS IN EUROPE
PublikacjaThe aim of the text is the presentation of the most important categories of exchange traded funds (ETFs) – physical and synthetic ones. A theoretical part of the text includes an overview of the main features of ETFs, the presentation of differences between physical and synthetic funds and the main risks posed by both types to their users and the whole financial systems. An empirical part focuses on the European market. Time span...
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Serendipitous synthesis of trimetallic porphyrazine triads
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A General Synthesis of Diaryl Cyclic Diamidines
PublikacjaA convenient and general method has been developed for directly converting bis-nitriles, e.g., I, to cyclic diamidines, e.g., II, using reagents derived from diaminoalkanes, e.g., H2NCH2CH2NH2, satd. with hydrogen sulfide. A 1:1 mixt. of a diaminoalkane and Et alc. (or without) was effective in most cases (72-88%). The synthetic utility of this methodol. in the prepn. of tetrakis(cyclic amidino)pyrenes III (R = H, Me) from 1,3,6,8-tetracyanopyrene...
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Synthesis of the zeolites on the lightweight aluminosilicate fillers
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Hydrothermal and mechanochemical synthesis of crystalline CaCO3
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Widely parameterizable high-level synthesis
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