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Wyniki wyszukiwania dla: COBALT HYDROXIDE
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Effect of pyridine extraction on the pyrolysis of a perhydrous coal based on in-situ FTIR analysis
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The origin and mobilization of deep brines to the aquifer system by considering the circulation systems existing on the polish western coast of the Baltic sea
PublikacjaW pracy przedstawiono stan wód podziemnych w przybrzeżnych warstwach wodonośnych polskiego wybrzeża Bałtyku. Obliczono czas przebywania wód odpływających do Bałtyku. Wiek wód i czas przebywania oszacowano również za pomocą izotopów środowiskowych.
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Impact of pollution derived from ship wrecks on the marine environment on the basis of s/s ''Stuttgart'' (Polish coast, Europe)
PublikacjaW 1943 roku niemiecki statek szpitalny, s/s Stuttgart (Lazaretschiff ''C'') został zatopiony w pobliżu portu w Gdyni. Doprowadziło to do zanieczyszczenia dna morskiego paliwem. Podczas badań przeprowadzonych w 2009 r. pobranych zostało 11 próbek osadów powierzchniowych i wody morskiej oraz 4 rdzenie. Próbki poddano analizie na zawartość zanieczyszczeń priorytetowych należących do grupy wielopierścieniowych węglowodorów aromatycznych...
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Enrichment of Bi-Be-Mo-Cd-Pb-Nb-Ga, REEs and Y in the Permian coals of the Huainan Coalfield, Anhui, China
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Kompleksy [CoCl(S2CNR2)(PR'3)] - synteza i właściwości
PublikacjaDitiokarbamianiany metali są związkami o znaczeniu przemysłowym, ale wciąż stanowią obiekt badań podstawowych. Właściwości tego typu kompleksów można korzystnie modyfikować stosując różnorodne dodatkowe ligandy, w tym P-donorowe. Stosunkowo dobrze poznano budowę układów [MCl(S2CNR2)(PR'3)] zwłaszcza dla M=Ni, gdzie dane strukturalne jednoznacznie pokazują płaską kwadratową geometrię rdzenia NiClS2P tworzących się kompleksów. Dla...
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Kompleksy [CoCl(S2CNR2)(PR'3)] - synteza i właściwości
PublikacjaDitiokarbamianiany metali są związkami o znaczeniu przemysłowym, ale wciąż stanowią obiekt badań podstawowych. Właściwości tego typu kompleksów można korzystnie modyfikować stosując różnorodne dodatkowe ligandy, w tym P-donorowe. Stosunkowo dobrze poznano budowę układów [MCl(S2CNR2)(PR'3)] zwłaszcza dla M=Ni, gdzie dane strukturalne jednoznacznie pokazują płaską kwadratową geometrię rdzenia NiClS2P tworzących się kompleksów. Dla...
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Age, frequency of volunteering, and Present-Hedonistic time perspective predict donating items to people in need, but not money to combat COVID-19 during lock-down
PublikacjaRestrictions due to COVID-19 necessitated staying at home, but in some cases, encouraged charitable behavior, e.g., donating items to people in need (e.g., clothes, food), or money to support combatting COVID-19. Drawing on the previous findings regarding helping during disastrous situations and roles of time perspective in helping behaviors, the study tested the predictive value of age, gender, previous volunteering, altruistic...
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The Evaluation of Quality of the Co-Firing Process of Glycerine Fraction with Coal in the High Power Boiler
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Large-scale Rowe cell experimental study on coefficient of consolidation of coal mine tailings
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Use of Bioluminescence for Monitoring Brown Coal Mine Waters from Deep and Surface Drainage
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State of the art in the field of emission reduction of sulphur dioxide produced during coal combustion
PublikacjaThe need for clean coal technologies to reduce the adverse environmental impact of coal combustion products has been grounded. The article deals with information concerning present and future technologies, directed towards the struggle against air pollution by SO2, produced during coal combustion. Their classification and critical rating from economical and technological points of views (including those developed by authors) have...
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Waste management in the mining industry of metals ores, coal, oil and natural gas - A review
PublikacjaWaste generated due to mining activity poses a serious issue due to the large amounts generated, even up to 65 billion tons per year, and is often associated with the risk posed by its storage and environmental management. This work aims to review waste management in the mining industry of metals ores, coal, oil and natural gas. It includes an analysis and discussion on the possibilities for reuse of certain types of wastes generated...
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Effect of slag coal ash and foamed glass on the mechanical properties of two-stage concrete
PublikacjaTwo-stage concrete (TSC) is known by various names such as colcrete, Polcrete, preplaced aggregate concrete and prepacked concrete. It is different from traditional concrete in two fundamental ways, namely method of construction and mix proportion. Two-stage concrete (TSC) is defined as firstly, coarse aggregates are placed into the formwork and grout is applied to fill in the between coarse aggregate particles voids. Secondly,...
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Influence of hydrothermal treatment on selenium emission-reduction and transformation from low-ranked coal
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Reply to “Enrichment of Bi-Be-Mo-Cd-Pb-Nb-Ga, REEs and Y in the Permian coals of the Huainan Coalfield, Anhui, China: Discussion”
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Establishment, Growth, and Yield Potential of the Perennial Grass Miscanthus × Giganteus on Degraded Coal Mine Soils
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Planning Recreation around Water Bodies in Two Hard Coal Post-Mining Areas in Southern Poland
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Identification of the featured-element in fine road dust of cities with coal contamination by geochemical investigation and isotopic monitoring
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The influence of thermal treatment on electrocatalytic properties of Mn-Co nanofilms on nickel foam toward oxygen evolution reaction activity
PublikacjaThis work evaluates electrodeposited and differently treated Mn-Co catalysts for their oxygen evolution reaction activity. Catalysts are evaluated in the as-deposited and heat treated state: after 350 C and 600 C. Results show that the highest electrochemical activity is obtained for the as-deposited Mn-Co oxyhydroxide, which possibly possess a layered double hydroxide structure. After the heat treatment process, especially after...
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Corrigendum to “Nonisothermal cure kinetics of epoxy/MnxFe3-xO4 nanocomposites” [Prog. Org. Coat. 140C (2020) 105505]
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The Balance of Outlays and Effects of Restructuring Hard Coal Mining Companies in Terms of Energy Policy of Poland PEP 2040
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Cost of Equity of Coal-Fired Power Generation Projects in Poland: Its Importance for the Management of Decision-Making Process
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Sustainable recovery of plant essential Nitrogen and Phosphorus from human urine using industrial coal fly ash
PublikacjaCoal-based thermal power plants play a pivotal role in meeting global energy demand. The amount of fly ash generated from these plants increases every year, and its successful use has posed a significant environmental risk in the last decade. In this study, coal fly ash was packed in a fixed-bed adsorption column to remove Urea–N from synthetic human urine. To assess the efficacy of fly ash in the removal of Nitrogen, various process...
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Generowanie planu zajęć z zastosowaniem algorytmów genetycznych
PublikacjaPrzedstawiono problem automatycznego generowania rozkładu zajęć. Do tego celu stworzono program, który przy wykorzystaniu algorytmów genetycznych w kilka minut potrafi sobie poradzić sobie ze średniej klasy problemem. Praca zawiera opis rdzenia programu oraz wyniki przeprowadzonych symulacji.
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Zastosowanie algorytmów genetycznych do automatycznego generowania planu zajęć
PublikacjaPrzedstawiono zastosowanie algorytmów genetycznych do automatycznego układania szkoklnego planu zajęć. Stworzono do tego celu odpowiedni program komputerowy - PLANIX, który w kilkanaście minut potrafi poradzić sobie ze średniej klasy problemem i nie wymaga praktycznie żadnej interwencji ze strony użytkownika. Zaprezentowano rdzeń tego programu, który zawiera implementację odp. algorytmu genetycznego. Opisano sposoby reprezentacji,...
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Zagadnienia osadzania elementów oraz kolejności podawania z uwzględnieniem ich wysokości
PublikacjaPrzedstawionom problem osadzania elementów sformułowany dla rzeczywistego procesu umieszczania elementów elektronicznych na płytasch drukowanych. Najpierw omówiono dokładnie sam problem osadzania elementów , własności technologiczne maszyny, parametry linii technologicznej oraz sformułowane cele do zrealizoweania. Następnie przedstawiono proponowane rozwiązanie tego problemu: omówiono wektory reprezentujące rozwiązanie, równania...
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Pale prefabrykowane
PublikacjaW artykule przedstawiono stan współczesnej technologii pali prefabrykowanych, drewnianych, stalowych, żelbetowych oraz zakres ich stosowania w budownictwie.
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Electric and magnetic properties of Lanthanum Barium Cobaltite
PublikacjaThe cubic Ba0.5La0.5CoO3‐δ was synthesized using solid state reaction. The structural properties were determined by the simultaneous refinement of Synchrotron Powder X‐ray Diffraction and Neutron Powder Diffraction data. Iodometric titration was used to examine the oxygen stoichiometry and average cobalt oxidation state. Low‐temperature magnetic studies show soft ferromagnetic character of fully oxidized material, with θP = 198(3)...
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Synthesis and application of oligomer with hydroxy groups based on peroxy derivative of ED-24 epoxy resin and POLYTHF-2000 oligoether
PublikacjaNew oligomer with peroxy, primary and secondary hydroxy groups has been synthesized on the basis of peroxy derivative of ED-24 epoxy resin (PO) and PolyTHF-2000 oligoether according to the developed procedure. The effect of the catalysts nature and amount, temperature and process time on the reaction rate has been studied. Benzyltriethylammonium chloride, potassium hydroxide,1,4-diazobicyclooctane and the mixture composed of benzyltriethylammonium...
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Conductivity and viscosity changes of imidazolium ionic liquids induced by H2O and CO2
PublikacjaSeveral solutions of ionic liquids based on 1-ethyl-3-methylimidazolium cation saturated and unsaturated with carbon dioxide were prepared and characterized by electrochemical impedance spectroscopy. The in fluence of ILs saturation on its electrical conductivity was determined. Additionally, the in fluence of the water presence and variations of temperature on electrical properties of ionic liquids were investigated. Changes of...
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OBTAINING OF COUMARONE-INDENE RESINS BASED ON LIGHT FRACTION OF COAL TAR 3. COUMARONE-INDENE RESINS WITH METHACRYLIC FRAGMENTS
PublikacjaThe method for obtaining coumarone-indene resins with methacrylic fragments (CIRM) was developed with the addition of methyl ethacrylate, using a light fraction of coal tar and its fraction boiling within 423–463 К. CIRM was obtained via radical cooligomerization using 2,2'-azobis (2-methyl-propionitrile) as the initiator. The effect of the initiator amount, temperature and reaction time on the yield, softening temperature and...
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Obtaining of coumarone-indene resins based on light fraction of coal tar.1. Coumarone-indene resins with carboxy groups
PublikacjaCoumarone-indene resins (CIR) with carboxy groups were synthesized via cooligomerization of unsaturated compounds presented in ligh fraction of coal tar and its fraction boiling out within 423-463 K with the addition of such industrial monomers as styrene, maleic anhydride, glycidyl methacrlate and methacryclic acid. 2,2-azobs 92-methylpropionitrile) in the form of 0,2 M solution in toluene was used as an initiator. The effect...
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Obtaining of coumarone-indene resins based on light fraction of coal tar 2. Coumarone-indene resins with epoxy groups
PublikacjaCoumarone-indene resins (CIR) with carboxy groups were synthesized via cooligomerization of unsaturated compounds presented in light fraction of coal tar and its fraction boiling out within 423–463 K with the addition of such industrial monomers as styrene, maleic anhydride, glycidyl methacrylate and methacrylic acid. 2,2`-Azobis(2-methylpropionitrile) in the form of 0.2 M solution in toluene was used as an initiator. The effect...
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Modelling Long‐Term Transition from Coal‐Reliant to Low‐Emission Power Grid and District Heating Systems in Poland
PublikacjaEnergy systems require technological changes towards climate neutrality. In Poland, where the power system is dominated by outdated coal-fired power plants, efforts to minimize the environmental impact are associated with high costs. Therefore, optimal paths for the development of the energy sector should be sought in order to achieve ambitious long-term strategic goals, while minimizing the negative impact on the consumers’ home...
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Combustion characteristics and retention-emission of selenium during co-firing of torrefied biomass and its blends with high ash coal
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Tri-tert-butoksysilanotiolanowe kompleksy cynku(II), kadmu(II) i kobaltu(II) jako modele koordynacji jonu cynku w miejscu aktywnym dehydrogenazy alkoholowej i niektórych innych enzymów
PublikacjaDehydrogenaza alkoholowa (ADH) katalizuje odwracalne utlenienie alkoholi do aldehydów przy użyciu NAD+ co można podsumować równaniem:R1R2CHOH + NAD+ = R1R2CO + NADH + H+. Geometria koordynacyjna cynku w miejscu aktywnym ADH opisywana jest na ogół jako tetraedryczna jednak istnieją również przesłanki wskazujące na poszerzanie sfery koordynacyjnej metalu w cyklu katalitycznym do LK=5. W pracy przeglądowej opisano badania nad syntetycznymi,...
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Effect of native air-formed oxidation on the corrosion behavior of AA7075 aluminum alloys
PublikacjaThe microstructure of aluminum alloys plays a key role in their corrosion resistance. In particular, the presence of intermetallic precipitates differing in the potential from the alloy matrix induces local corrosion. The study presents the effect of native air-formed oxidation on the corrosion behavior of AA 7075 aluminum alloy. Various microscopic and spectroscopic techniques were used to examine the changes occurring in the...
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The lanthanide influence on selected properties of BaLnCo2O6-δ
PublikacjaThe subject of research of this dissertation are cobalt oxides with a double perovskite structure with a general formula BaLnCo2O6-δ, where Ln stands for La, Pr, Nd, Sm, Gd, Tb, Dy. The aim of the study was to verify the ability of these materials to form the protonic defects, as well as to identify the factors determining this ability. As part of the work, materials from the proposed group were synthesised and characterized. To...
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Magnetic properties of α-KCoPO4 compound with a chiral polar crystal structure
PublikacjaWe have obtained polycrystalline samples of a metastable α variant of KCoPO4 by low temperature (350–400 °C) solid state metathesis reaction of potassium oxalate and ammonium cobalt orthophosphate. The material crystallizes in a polar chiral structure (sg. P63, no. 173). Measurements of magnetic properties reveal antiferromagnetic interactions and no ordering observed down to T = 1.9 K, well below the Weiss temperature |Θcw| =...
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Mass transfer in Spinning Fluids Reactor — Measurement and prediction
PublikacjaSpecific mass transfer area (a) and overall volumetric mass transfer coefficient (kLa) are mass transfer parameters commonly used in the description and comparison of various chemical reactors’ constructions. Determination of these was performed for Spinning Fluids Reactor (SFR). Sodium sulfite oxidation in the presence of cobalt ion catalyst was used for the determination of a and kLa. The a and kLa were successful predicted....
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Systematic investigation on combustion characteristics and emission-reduction mechanism of potentially toxic elements in biomass- and biochar-coal co-combustion systems
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Tri-tert-butoksysilanotiolany kobaltu.**2003, 109 s. 43 rys. 12 tab. bib-liogr. 123 poz. maszyn. Rozprawa doktorska /05.03.2003/ Wydz. Chem. Promotor: dr hab. inż. B. Becker.
Publikacja.
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Failure analysis of the exhaust valve face in diesel marine engine
PublikacjaThe exhaust valve from marine diesel engine which was damaged after 2000 hours of service was investigated. In order to prolong the service time the valve face was cladded with cobalt base alloy using laser technique. After failure microstructural and chemical analyses reviled that cladding process was conducted improperly. The chemical composition of the clad layer was far from the designed one and what more completely inhomogeneous....
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Fe-modified Mn2CuO4 spinel oxides: coatings based on abundant elements for solid oxide cell interconnects
PublikacjaThe current state of the art steel interconnect coating materials are based on critical raw material - Co-oxide spinels. Replacing Co-oxide spinels with alternative, abundant materials can reduce the dependence on the critical raw materials. Cobalt-free coatings with the general formula Mn2-xCuFexO4, where x = 0, 0.1, 0.3, were electrophoretically deposited on a ferritic stainless-steel support and evaluated. Prior to deposition,...
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Multilayer coatings based on cerium oxide and manganese cobaltite spinel for Crofer22APU SOC interconnects
PublikacjaThe current state of the art steel interconnect coating materials are based on critical raw material - Co-oxide spinels. Replacing Co-oxide spinels with alternative, abundant materials can reduce the dependence on the critical raw materials. Cobalt-free coatings with the general formula Mn2-xCuFexO4, where x = 0, 0.1, 0.3, were electrophoretically deposited on a ferritic stainless-steel support and evaluated. Prior to deposition,...
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Enhanced electrochemical performance of partially amorphous La0.6Sr0.4CoO3-δ oxygen electrode materials for low-temperature solid oxide cells operating at 400 °C
PublikacjaThis work evaluates partially amorphous La0.6Sr0.4CoO3-δ (LSC) as a potential oxygen electrode for lowtemperature solid oxide cells. LSC was deposited using the spin-coating technique onto Ce0.8Gd0.2O2-δ (CGO) substrates. The optimal oxygen electrode thickness was determined as 500 nm. The electrochemical impedance spectroscopy (EIS) study showed a significant improvement in oxygen reduction/oxidation reaction kinetics when annealing...
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Contrasting effects of biochar and hydrothermally treated coal gangue on leachability, bioavailability, speciation and accumulation of heavy metals by rapeseed in copper mine tailings
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Emission characterization and δ13C values of parent PAHs and nitro-PAHs in size-segregated particulate matters from coal-fired power plants
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Emission characteristics for gaseous- and size-segregated particulate PAHs in coal combustion flue gas from circulating fluidized bed (CFB) boiler
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Regeneracja zaworów silników okrętowych metodą napawania plazmowego
PublikacjaW artykule przedstawiono zastosowanie procesu napawania plazmowego (PTA) do regeneracji zużytych przylgni zaworów wylotowych okrętowych silników Diesla. Zużyte zawory, po odpowiedniej selekcji, poddano obróbce skrawaniem w celu nadania odpowiedniego kształtu powierzchni przylgni, a następnie poddano procesowi napawania plazmowego z wykorzystaniem trzech rodzajów proszków na bazie kobaltu. Wybrane proszki charakteryzowały się wysoką...