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Wyniki wyszukiwania dla: HYALURONIC ACID
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Amino Acid Based Antimicrobial Agents – Synthesis and Properties
PublikacjaStructures of several dozen of known antibacterial, antifungal or antiprotozoal agents are based on the amino acid scaffold. In most of them, the amino acid skeleton is of a crucial importance for their antimicrobial activity, since very often they are structural analogs of amino acid intermediates of different microbial biosynthetic pathways. Particularly, some aminophosphonate or aminoboronate analogs of protein amino acids are...
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Electron-impact ionization cross section of formic acid
PublikacjaExperimental electron-impact ionization cross sections of one of the simplest carboxylic acids, formic acid, are presented. The molecular target was studied in two independent experimental setups applying different methods: the total ion collection and the electron–impact mass spectrometry methods. Experimental data were taken at incident electron energies ranging from ionization threshold [11.31 eV; J.C. Traeger, Int. J. Mass...
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Structured triacylglicerols containing behenic acid: preparation and properties
PublikacjaNiskokaloryczne lipidy strukturyzowane otrzymano na drodze przeestryfikowania właściwego oleju oliwkowego całkowicie uwodornionym wysokoerukowym olejem rzepakowym (TAG/SLHE) oraz na drodze acydolizy oleju oliwkowego kwasem behenowym (TAG/SLB). Reakcje były katalizowane Lipozyme RM IM. Tłuszcz (TAG/SLHE) charakteryzował się wysoką temperaturą topnienia - 45,5 st. C, natomiast tłuszcz (TAG/SLB) miał temperaturę topnienia 37,5 st.C...
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Acid site concentrations of the MXenes samples
Dane BadawczeData contains the pH of 0.01M NaOH solution, before and after mixing with the MXenes samples.
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Analysis of carboxylic acid metabolites from the tricarboxylic acid cycle in Bacillus subtilis cell extract by capillary electrophoresis using an indirect photometric detection method
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The acid strength of the HClO4/n(AlF3) and HClO4/n(SbF5) (n = 1–3) Lewis–Brønsted superacids containing the excess of the Lewis acid component
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Microwave-assisted preparation of potato starch silicated with silicic acid
PublikacjaApplication of microwave irradiation for the silication of granular potato starch with silicic acid, and the properties of silicated starch were investigated. Potato starch was esterified on 20 min microwave irradiation of starch with silicic acid, applying the power of 450 or 800Wand, for comparison, on 120 min convectional heating of the reagent blend at 100 ◦C. The degree of esterification and the reaction efficiency did not...
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The Relationship between the Structure and Properties of Amino Acid Ionic Liquids
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Updates on Metabolism in Lactic Acid Bacteria in Light of “Omic” Technologies
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Phosphatidylcholine with conjugated linoleic acid in fabrication of novel lipid nanocarriers
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1,4,7,10-Tetraazacyclododecane incorporating salicyli acid moieties. Synthesis and properties
PublikacjaPochodne 1,4,7,10-tetraazacyklododekanu są związkami które znalazły szerokie zastosowanie w wielu dziedzinach: medycynie, chemii, farmacji, ochronie środowiska itd. Właściwości fizykochemiczne poszczególnych związków determinowane są przez pierścień makrocykliczny i podstawniki. Kwas salicylowy i salicylamid tworzą kompleksy chelatowe z kationami II grupy jak również z metalami przejściowymi. W reakcji acylowania cyklenu pochodnymi...
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An Improved Synthesis of Trisodium (R)-Homocitrate from Citric Acid
PublikacjaA method of synthesis of trisodium (R)-homocitrate starting from citric acid is reported. The procedure affords the final product of high optical purity with satisfactory yield.
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Application of Peracetic Acid for Biological Foam Elimination in the SBR Bioreactor
PublikacjaPrzedstawiono wyniki wstępnych badań nad zastosowaniem kwasu nadoctowego (PAA) do likwidacji piany biologicznej, spowodowanej przez bakterię nitkowatą Microthrix parvicella. Wykazano, że okresowe zraszanie powierzchni piany małymi dawkami kwasu nadoctowego (rzędu kilkudziesięciu ml 1% roztworu PAA/na 1 m2 piany o grubości 1 cm) powoduje niemal natychmiastwy zanik piany, wytworzonej na powierzchni osadu czynnego w bioreaktorze...
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Thermal properties of lanthanide(III) complexes with 2-aminoterephthalic ACID
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The influence of salt in solutions on hydrochloric acid recovery by membrane distillation
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Physicochemical and catalytic properties of ployaniline protonated with 12-molybdophosphoric acid
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Photophysics of 7-Hydroxytetrahydroisoquinoline-3-carboxylic Acid and Its Derivatives
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Chromogenic amides of pyridine-2,6-dicarboxylic acid as anion receptors
PublikacjaThe synthesis of simple, chromogenic pyridine-2,6-dicarboxylic acid amides, derivates of isomeric nitroanilines and aminonitrophenols, and their ion binding properties are described. The ligands' response to ionic species was examined by naked eye and was studied with the use of UV-Vis spectroscopy in DMSO and its mixture with water. The effect of the localisation and the type of the substituents in aromatic rings were discussed....
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Thermal and mechanical properties of polyurethanes modified with L-ascorbic acid
PublikacjaIn this study we report the thermal and mechanical properties of polyurethanes modified with ascorbic acid (AA). Ascorbic acid was used as a modifier at concentration of 1 or 2 mass%. The antioxidative properties of AA may improve the biocompatibility of the obtained materials, which were designed for biomedical applications. In this paper we describe characterization of obtained unmodified and ascorbic acid modified polyurethanes...
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Characterization of fatty acid composition in Eurasian badger (Meles meles)
PublikacjaPolyunsaturated fatty acids (PUFAs, LA and ALA) are not synthesized in mammals in the absence of their essential fatty acid precursors. However, hibernating animals and animals sleeping through the winter need sufficiently high amounts of these acids. The Eurasian badger does not hibernate, but sleeps over winter. In the autumn the body weight of adult badgers increases even twofold, since they put on fat before the winter. Fat...
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Thermal energy storage using stearic acid as PCM material
PublikacjaThis work presents an experimental study of thermal energy storage by use of PCM. The aim of the study was to establish the influence of different inlet temperature of heat transfer fluid (HTF) and different Reynolds number of HTF on intensity of charging process. The PCM used in this study was stearic acid and water was used as HTF. A copper helical coil mounted in cylindrical container served as a heat transfer surface.
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Raman spectroscopy study on concentrated acid treated carbon nanotubes
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Dissociation of furan-2-carboxylic acid by low energy electrons
PublikacjaElectron attachment to molecular target can lead to a variety of negative fragment ions. We experi- mentally probe the main dissociative electron attachment channels in furan-2-carboxylic acid (C3H3O2 − COOH) - a molecular target composed of two important structural units: a furan ring and a carboxylic group. In our studies we utilise nearly mono-energetic electrons at electron energies from 0 eV up to 15 eV. Our detection setup...
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Molecular targets for antifungals in amino acid and protein biosynthetic pathways
PublikacjaFungi cause death of over 1.5 million people every year, while cutaneous mycoses are among the most common infections in the world. Mycoses vary greatly in severity, there are long-term skin (ringworm), nail or hair infections (tinea capitis), recurrent like vaginal candidiasis or severe, life-threatening systemic, multiorgan infections. In the last few years, increasing importance is attached to the health and economic problems...
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Atom-economic thiophosphoroselenenylations of C–H acid esters and amides
PublikacjaThree improved thiophosphoroselenenylation procedures of CHacids, including derivatives of malonic and acetyl-, phosphono-, 4-nitrophenyl- and 3-pyridylacetic acids, have been described and compared to previously reported thiophosphoroselenylation of diethyl malonate using bis(disopropoxyphosphinothioyl)diselenide alone or with the aid of methyl iodide. The use of iodine makes it possible to utilize both equivalents of the selenenylating...
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Dissociative electron attachment and anion-induced dimerization in pyruvic acid
PublikacjaWe report partial cross sections for the dissociative electron attachment to pyruvic acid. A rich fragmentation dynamics is observed. Electronic structure calculations facilitate the identification of complex rearrangement reactions that occur during the dissociation. Furthermore, a number of fragment anions produced at electron energies close to 0 eV are observed, that cannot originate from single electron-molecule collisions....
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Photoresponsive, amide-based derivative of embonic acid for anion recognition
PublikacjaThe synthesis and ion-binding properties of amide-based derivative of embonic acid andp-aminoazobenzenewere described. The new compound was characterized by X-ray structural analysis and spectroscopic methods.Ligand interacts in acetonitrile with Y-shaped anions (benzoates and acetates) and dihydrogen phosphatesforming complexes of 1:1 stoichiometry. In more polar DMSO the complexes stoichiometry changes to 2:1(L:anion). Light-inducedtranstocisisomerization...
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The electrochemical deposition of nickel from electrolytes containing malonic acid
PublikacjaZbadano proces elektrolitycznego osadzania niklu z roztworów siarczanowych zawierających kwas malonowy lub winowy jako bufor zamiast kwasu borowego. Badano wpływ gęstości prądu katodowego, pH roztworu i temperaturę. Określono pojemność buforową i wgłębność kąpieli. Wyznaczono wydajności prądowe, twardość oraz połysk powłok niklowych otrzymanych z badanych kąpieli. Określono optymalne warunki pracy kąpieli i wykazano jej zalety...
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Synthesis of polyglycerol esters of fatty acid with defined hydrophilic properties
PublikacjaOtrzymane w odrębnej reakcji mieszaniny poligliceroli poddano estryfikacji kwasami tłuszczowymi oktadekanowym i izooktadekanowym, w obecności odpowiednich mydeł sodu powstających in situ. Zaobserwowano wpływ stężenia karboksylanów sodu oraz budowy kwasu tłuszczowego na przebieg estryfikacji mieszaniny polioli. Stwierdzono, że zastosowany sposób prowadzenia reakcji pozwala zsyntetyzować efektywne emulgatory emulsji O/W, o wartościach...
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Polyglycerol esters of lauric acid with defined hydrophile-lipophile properties.
PublikacjaZsyntetyzowano estrowe pochodne poligliceroli i kwasu laurynowego w obecności laurynianu sodu powstającego in situ. Przeanalizowano wpływ temperatury, stężenia katalizatora oraz czasu reakcji na postęp reakcji polimeryzacji glicerolu, a także wpływ stężenia karboksylanu i czasu reakcji na reakcję estryfikacji uzyskanej mieszaniny polioli kwasem laurynowym. Zauważono, że zastosowana metoda syntezy estrów poligliceroli prowadzi do...
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Beeswax And Palmitic Acid Utilization With Heat Pipes For Electronics Cooling
PublikacjaThis paper presents an experimental study of heat pipes supported by phase change materials (PCMs) coated at their adiabatic sections in application for electronics cooling. The PCMs investigated in this research were palmitic acid and beeswax, the latter being considered as a more cost-effective alternative. The study focused on three powers: 20W, 25W, and 30W. The experimental results revealed that the incorporation of palmitic...
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Maternal smoking Modulates Fatty Acid Profile of Breast Milk
PublikacjaAIM: We hypothesized that the fatty acid composition of breast milk can be affected by a smoking habit in the mother. Consequently, this study verified whether maternal smoking modulates, and if so to what extent, the breast milk fatty acid profile. METHODS: The study included 20 postpartum women who declared smoking more than five cigarettes daily throughout a period of pregnancy and lactation, and 136 non-smoking postpartum women....
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Photodynamic therapy with 5-aminolevulinic acid and diamino acid derivatives of protoporphyrin IX reduces papillomas in mice without eliminating transformation into squamous cell carcinoma of the skin
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NUCLEOSIDES NUCLEOTIDES & NUCLEIC ACIDS
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Fatty Acid-Binding Protein 7 (FABP-7), Glutamic Acid and Neurofilament Light Chain (NFL) as Potential Markers of Neurodegenerative Disorders in Psoriatic Patients—A Pilot Study
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PROSTAGLANDINS LEUKOTRIENES AND ESSENTIAL FATTY ACIDS
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Effect of Ion and Binding Site on the Conformation of Chosen Glycosaminoglycans at the Albumin Surface
PublikacjaAlbumin is one of the major components of synovial fluid. Due to its negative surface charge, it plays an essential role in many physiological processes, including the ability to form molecular complexes. In addition, glycosaminoglycans such as hyaluronic acid and chondroitin sulfate are crucial components of synovial fluid involved in the boundary lubrication regime. This study presents the influence of Na+, Mg2+ and Ca2+ ions...
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Is the Fatty Acids Profile in Blood a Good Predictor of Liver Changes? Correlation of Fatty Acids Profile with Fatty Acids Content in the Liver
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The Chemistry of Mycophenolic Acid-Synthesis and Modifictions Towards Desired Biological Activity
PublikacjaDokonano przeglądu literatury chemicznej na temat metod syntezy kwasu mykofenolowego oraz jego pochodnych, a także zależności pomiędzy ich strukturą i aktywnością biologiczną.
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Spectroscopic Studies of Amino Acid Ionic Liquid-Supported Schiff Bases
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Modulation of TET2 Activity By Ascorbic Acid and Factors Affecting Lysine Acetylation
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Spectroscopic insight into supramolecular assemblies of boric acid derivatives and β-cyclodextrin
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Effect of renal replacement therapy on selected arachidonic acid derivatives concentration
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Molecular self-assembly and optical activity of chiral thionooxalamic acid esters
PublikacjaZsyntezowano kilka optycznie czynnych estrów dietylowych kwasu bis(tiooksamowego). Związki te, z powodu ich zdolności do tworzenia ze sobą komplementarnych cyklicznych wiązań wodorowych, są potencjalnie użytecznym materiałem budulcowym większych układów supramolekularnych. Odpowiednie układy modelowe otrzymano z optycznie czynnych 1,2-diamin, które poddano acylowaniu chlorooksooctanem etylu, a następnie otrzymane półprodukty tionowano...
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Thermal properties of rare earth elements complexes with 1,3,5-benzenetricarboxylic acid
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Bringing a New Flexible Mercaptoacetic Acid Linker to the Design of Coordination Polymers
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Some properties of Nd and Er complexes with 1,2,3,4,5,6-benzenehexacarboxylic (mellitic) acid
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Serum Fatty Acid-Binding Protein 4 is Increased in Patients with Psoriasis
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Recovery of hydrochloric acid from metal pickling solutions by membrane distillation
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Thermal degradation of butyl acrylate-methyl acrylate-acrylic acid-copolymers
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