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Wyniki wyszukiwania dla: CYANIDE DETERMINATION
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Demand determination for electrical energy for trailing suction hopper dredgers
PublikacjaPrzedstawiono metodę określania obciążeń elektrowni w typowych stanach eksploatacji pogłębiarki ssącej nasiębiernej. Przedstawiono sposób określania średniego zapotrzebowania energii elektrycznej i jego odchylenia standardowego. Wykorzystano dane dokumentacji projektowych 10 pogłębiarek ssących nasiębiernych oraz wyniki badań eksploatacyjnych pogłębiarek zawarte w bazie danych DRAGA.
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Monosaccharides as internal probes for the determination of the absolute configuration of 2-butanol
PublikacjaD-dlukoza, D-mannoza i L-ramnoza zostały poddane reakcji z mieszaniną racemiczną 2-butanolu. Otrzymane w ten sposób glikozydy były analizowane za pomocą spektroskopii NMR, z wykorzystaniem eksperymentów COSY i NOESY. Analiza konformacyjna wiązania glikozydowego (dokonana w oparciu o modelowanie molekularne i heteronuklearne stałe sprzężenia) wraz z analizą sprzężeń dipolowych obserwowanych w widmie NOESY umożliwiła określenie konfiguracji...
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Determination of the width of the carrier recombination zone in organiclight emitting diodes.
PublikacjaW pracy mierzono kwantową wydajność elektroluminescencji w diodach dwuwarstwowych z różną grubością emitera w postaci warstwy hydroksychinolinowego kompleksu aluminium (Alq3). Stwierdzono, że szerokość strefy rekombinacji ładunku maleje ze wzrostem natężenia pola elektrycznego od 70 nm(dla E=0.75MV/cm do 40 nm (dla E=1.MV/cm).
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Determination of the shape of the CFGFT cylindrical column based on laboratory tests
PublikacjaAnalyses were carried out on glass-fibre-reinforced polymer tube columns with reference to laboratory tests. The angles of the glass fibre beams were 20◦, 55◦ and 85◦. The study employed non-classical operational calculus. Various modulated harmonic signal shapes were considered for columns and tubes at buckling. The buckling loads were assessed and compared for different models.
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Application of chromogenic dye in biogenic amines determination using spectrophotometry
PublikacjaBiogenic amines content can be the source of information in the field of freshness and suitability of certain foods for consumption. However, most analytical methods for their determination require complicated sample preparation and expert knowledge. Because of that, a novel approach based on chromogenic dye application was proposed. After the SN1 reaction of an amine with S 0378 dye, the absorbance of the solution was measured...
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Simple smartphone-based methods for the determination of bioactive compounds in wine
PublikacjaA set of simple smartphone-based methods of bioactive compounds determination were developed for wine analysis. Procedures for smartphone-based determination of the total content of phenolic compounds, flavonoids, anthocyanins and biogenic amines, as well as measurement of antioxidant activity were developed and fully validated. The experimental setup is based on smartphone and 3D-printed device, though it is very simple and can...
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Revision of Biological Methods for Determination of EDC Presence and Their Endocrine Potential
PublikacjaEndocrine-disrupting compounds (EDC) are chemicals responsible for disturbances in the hormonal balance of organisms. This group of chemicals includes both egzogenic and endogenic substances or their mixtures that impact functioning of natural hormones in organisms. In the available literature one can find information on the application of chromatographic and related techniques in the analysis of environmental samples for detection,...
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Sample preparation techniques for determination of pesticide residues in food samples
PublikacjaPesticides are very important in increasing the efficiency and quality of agricultural production. They are applied in many spheres of life, not only in agriculture, and their applications are expanding. Despite their numerous merits, pesticides are some of the most toxic substances contaminating our environment and have a negative impact on the human health. Properties of pesticides such as stability, ability to bioaccumulation...
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New methodology for determination cationic surfactants in liquid environmental samples
PublikacjaBecause of their specific physical and chemical properties (e.g. amphiphilicity, solubility in polar and nonpolar liquids, ability to form micelles, adsorption at phase boundaries, low toxicity) surfactants (surface-active compounds) are widely applied in industry and in the household. As their applications are on a very large scale, it has become necessary to acquire a more detailed understanding of their environmental fate. Mainly,...
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Determination of leakage inductances of multi-winding and single-phase transformer
PublikacjaThis paper presents the method for determination of leakage inductances of single-phase and multi-winding transformer. The matrix of leakage inductances takes into account leakage self and also leakage mutual magnetic couplings. It is assumed that there is a flux common to all windings and several leakage fluxes referred to a particular winding. The flux linkages of each coil needed fo calculation of leakage inductances was computed...
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DETERMINATION OF SURFACTANTS IN ENVIRONMENTAL SAMPLES. PART II. ANIONIC COMPOUNDS
PublikacjaSurfactants (SAA) with negative charge of polar group are named as anionic compounds. They are main constituent of most products containing synthetic surfactants. The linear alkylbenzene sulfonates (LAS), alkyl ethoxysulfates (AES) and alkyl sulfates (AS) are typically applied from this class of compounds. Those surfactants are ingredients of household detergents and cleaners, laundry detergents, cosmetic. Moreover they can be...
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Occurrence and Determination of Volatile Fatty Acids in Landfill Leachate and Gas
PublikacjaIn landfills containing biological matter volatile fatty acids (VFAs) are generated at high rate at the early stage of waste disposal and their content in leachate is high as compared to the leachate from old parts of landfill since they are converted to methane gas. Monitoring of the leachate for the content of VFAs can help determine the processes occurring in waste and possible effect of the leachate on the environment in the...
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Occurrence and Determination of Volatile Fatty Acids in Landfill Leachate and Gas
PublikacjaIn landfills containing biological matter volatile fatty acids (VFAs) are generated at high rate at the early stage of waste disposal and their content in leachate is high as compared to the leachate from old parts of landfill since they are converted to methane gas. Monitoring of the leachate for the content of VFAs can help determine the processes occurring in waste and possible effect of the leachate on the environment in the...
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Capillary Electrophoresis in Determination of Low Molecular Mass Organic Acids
PublikacjaThis paper presents overviews the capabilities of capillary electrophoretic techniques to determine low molecular mass organic acids in a variety of aqueous, gas and solid samples. It mainly focuses on short - chain carboxylic acids containing one or more carboxylic groups and possibly some other functional groups (hydroxyl, keto-, amino- etc.). Finally the procedures applied to the determine the acids in different matrices are...
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Determination of authenticity of brand perfume using electronic nose prototypes
PublikacjaThe paper presents practical application of an electronic nose technique for fast and efficient discrimination between authentic and fake perfume samples. Two self-built electronic nose prototypes equipped with a set of semiconductor sensors were employed for that purpose. Additionally 10 volunteers took part in sensory analysis. The following perfumes and their fake counterparts were analysed: Dior – Fahrenheit, Eisenberg – J’ose,...
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Determination of benzo(a)pyrene content in PM10 using regression methods
PublikacjaThe paper presents an attempt of application of multidimensional linear regression to estimation of an empirical model describing the factors influencing on B(a)P content in suspended dust PM10 in Olsztyn and Elbląg city regions between 2010 and 2013. During this period annual average concentration of B(a)P in PM10 exceeded the admissible level 1.5-3 times. Conducted investigations confirm that the reasons of B(a)P concentration...
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Analytical procedures for determination of cocaine and its metabolites in biological samples
PublikacjaThe dangerous effects and increased usage of illicit drugs have inspired the development of analytical methodologies. We based our review of analytical procedures for determination of cocaine (COC) and its metabolites on literature from the past two decades. Our main aim was to compare the capabilities of different analytical techniques. The diversity of matrices from which COC is determined (e.g., blood, hair, saliva, plasma,...
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Selection of derivatisation agents for chlorophenols determination with multicriteria decision analysis
PublikacjaThe paper shows very systematic method of selection of derivatisation agents for a given group of analytes. In this study 8 derivatisation agents are assessed for their capability to derivatise 8 chlorophenols. Multicriteria decision analysis is used to combine many objectives of derivatisation agents selection into single, easy to be interpreted numerical value. Three basic analyses were performed to obtain rankings with the aims...
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New Method for Determination of Adjustment Corrections for Crane Rail Axes
PublikacjaElectronic tacheometers are currently a standard instrument used in geodetic work, including also geodetic engineering measurements. One of the many applications of tacheometers in engineering geodesy are 3D control measurements of crane rail axes. This paper proposes a new method of computing adjustment corrections for crane rail axes based on 3D polar measurements performed with an electronic tacheometer. The intermediary method...
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State of the art and prospects of methods for determination of lipophilicity of chemical compounds
PublikacjaLipophilicity of the compounds is useful to (i) explain their distribution in biological systems, which is different in plant and in animal organisms, (ii) predict the possible pathways of pollutant transport in the environment, and (iii) support drug discovery process and select optimal composition in terms of bioactivity and bioavailability. The lipophilic properties can be determined by two main approaches, experimental, which...
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Application of analytical methods for the determination of bioactive compounds in some berries
PublikacjaFluorometry, ESI-MS, FTIR, and radical scavenging assays were used for characterization of bioactive compounds and the levels of their antioxidant activities. Polyphenols, flavonoids, anthocyanins, and ascorbic acid and the level of antioxidant activity of water extracts of “Murtilla-like” [Myrteola nummularia (Poiret) Berg.], and other widely consumed berries were determined and compared. The contents of bioactive compounds and...
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ThreSpect – A Program for the Determination of the Appearance Energies of Neutral and Ionized Species
PublikacjaCollisions of photons and charged particles with molecules lead to their excitation, ionization, and dissociation into neutral and ionized fragments. Accurately determining thresholds of the formation of particular products plays a vital role in analyzing processes occurring during these interactions. Therefore, we present a computer program, “ThreSpect,” that allows calculating threshold energies of various species generated in...
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Determination of representative volume element in concrete under tensile deformation
PublikacjaW artykule podano sposoby określenia elementu reprezentatywnej objętości w betonie podczas rozciągania. Obliczenia wykonano przy zastosowaniu izotropowego modelu degradacji sztywności rozszerzonego o długość charakterystyczną mikrostruktury w ramach teorii nielokalnej. Zaproponowano 2 różne metody wyznaczania elementu reprezentatywnej objętości niezależnego od warunków brzegowych.
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Determination of the Bending Properties of Wire Rope Used in Cable Barrier Systems
PublikacjaThis paper presents research on the bending properties of 3 × 7 19-mm wire rope commonly used in road cable barriers. A total of 19 experimental tests were conducted. In addition, two nonlinear 3D numerical models of the wire rope using beam and solid finite elements were developed. Based on these models, four numerical simulations were carried out. The numerical results were validated against the experimental ones and a very good...
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DETERMINATION OF SEAKEEPING PERFORMANCE FOR A CASE STUDY VESSEL BY THE STRIP THEORY METHOD
PublikacjaThe increase of seakeeping performance is of particular importance for car and passenger ferries, service ships in the gas and oil extraction industry and offshore wind power farm industry, as well as for special purpose ships (including military applications). In the water areas of the Baltic Sea, North Sea, and Mediterranean Sea, which are characterised by a short and steep wave, the hull shape has a substantial impact on the...
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Consideration of dynamic loads in the determination of axle load spectra for pavement design
PublikacjaAxle load spectra constitute a crucial part of the data for pavement design and pavement distress analysis. Typically, axle load spectra represent static load from vehicles and do not include dynamic loads generated by vehicles in motion. While dynamic loads can significantly contribute to faster pavement distress, this fact is mostly omitted in pavement design methods. The paper presents a methodology for consideration of dynamic...
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Detection, identification and determination of chiral pharmaceutical residues in wastewater: Problems and challenges
PublikacjaChiral pharmaceuticals (CPs) are widely used in different areas of human life, thus they are frequentlydetected in different ecosystems. However, before CPs reach the environment, wastewater is subjected todifferent treatment processes in order to remove them. Nevertheless, such processes may affect thechirality of CPs, thus it is very important to monitor CP levels during the wastewater treatment.This review addresses the present...
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Experimental determination of useful resistance value during pasta dough kneading
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Determination of the rigidity and deformation energy of the technological machine load-carrying systems
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Comparison of GC–MS and MEKC methods for caffeine determination in preworkout supplements
PublikacjaIn this study, GC–MS- and MEKC-based methods for determination of caffeine (CAF) in preworkout supplements were developed and validated. The proposed protocols utilized minimal sample preparation (simple dilution and syringe filtration). The developed methods achieved satisfactory validation parameters, i.e. good linearity (R2 0.9988 and R2 0.9985 for GC–MS- and MEKC-based method, respectively), satisfactory intraand interaccuracy...
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Experimental determination of H2 mass stopping powers for low-energy electrons
PublikacjaWe present experimental mass stopping powers of electrons in gaseous H2 obtained with an electron time- of-flight spectrometer, for the incident electron energy range of 11 to 25 eV. In our procedure, the average energy loss is derived from conversion of the measured electron time-of-flight spectra into equivalent electron energy-loss spectra. Our present results are compared with the only available experimental measurement and...
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Microencapsulation of fish oil – determination of optimal wall material and encapsulation methodology
PublikacjaFor the first time, we present a meta-analysis of experimental and literature data to determine which microencapsulation methodology, and which wall material are best suited to protect fish oil. Our analysis covered a period of several decades of research (1984–2018). The analysis was conducted on 196 literature data-points, and 16 data-points determined experimentally for this publication. PLS regression was used to determine...
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Determination of Hydroxy Groups in the Modified Epoxy Oligomers Using IR-Spectroscopy
PublikacjaThe use of IR-spectroscopy has been proposed to determine the content of hydroxy groups in the modified functional oligomers based on bisphenol A diglycidyl ether. Apart from hydroxy groups the investigated oligomers contain epoxy or peroxy, carboxy or acrylic groups.
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Application of GC-MS/MS technique for the determination of benzodiazepines in blood samples
PublikacjaAbstract Benzodiazepines (BZD) are widely used as pharmaceuticals in medicine. However, due to psychostimulatory effect of BZD, in the last decade, they are more and more often used as drugs of abuse. These compounds produce similar effects to classical illicit drugs and are sold as “legal” alternatives to them as new psychoactive substances (NPS). Currently new BZD, named designer benzodiazepines (DBZD), are synthesized each year...
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Application of TOPSIS for Selection and Assessment of Analytical Procedures for Ibuprofen Determination in Wastewater
PublikacjaThis paper describes the possible implementation of the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) as green analytical chemistry metrics tools. TOPSIS is one of the multi-criteria decision analysis (MCDA) tools that is applied in the selection of the best alternative from many possible. In this case we have applied it to assess the nineteen analytical procedures for ibuprofen determination in wastewater...
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Comparison of Two Methods for the Determination of Selected Pesticides in Honey and Honeybee Samples
PublikacjaDeveloped and validated analytical methods for the determination of a wide spectrum of pesticide residues in honey and honeybee samples after the modification of QuEChERS extraction in combination with gas chromatography–tandem quadrupole mass spectrometry (GC-MS/MS) and liquid chromatography–tandem quadrupole mass spectrometry (LC-MS/MS) were discussed and compared. The developed methods were evaluated regarding the utilized equipment...
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Determination of grain shape of laser-irradiated FePdCu thin alloy films
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Determination of bisphenol A in size fractions of indoor dust from several microenvironments
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Determination of norflurazon concentration in wheat leaves using a modified QuEChERS method
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Postmortem Determination of Short-Term Markers of Hyperglycemia for the Purposes of Medicolegal Opinions
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Validation of the HS-GC-FID method for the determination of ethanol residue in tablets
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Quality problems in determination of organic compounds in environmental samples, such as PAHs and PCBs
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Procedure of determination of volatile trihalomethanes in human urine with pervaporation and gas chromatography
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The simultaneous determination of hydrophobicity and dissociation constant by liquid chromatography–mass spectrometry
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Determination of the Stereostructure of Pyrimidine Nucleoside Derivatives with a Combination of Various Chiroptical Methods
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Determination of Stent Load Conditions in New Zealand White Rabbit Urethra
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Determination of the Content of Promoters in Magnetite and Wustite Phases in the Fused Iron Catalyst
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Experimental based determination of SCOP coefficient for ground-water heat pump
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Determination of Flavonoids in Selected Scleranthus Species and Their Anti-Collagenase and Antioxidant Potential
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Determination of Flavonoids, Tannins and Ellagic acid in leaves fromRubus L. species
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