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Ionic liquids for nano- and microstructures preparation. Part 1: Properties and multifunctional role
PublikacjaIonic liquids (ILs) are a broad group of organic salts of varying structure and properties, used in energy conversion and storage, chemical analysis, separation processes, as well as in the preparation of particles in nano- and microscale. In material engineering, ionic liquids are applied to synthesize mainly metal nanoparticles and 3D semiconductor microparticles. They could generally serve as a structuring agent or as a reaction...
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Selected issues related to the toxicity of ionic liquids and deep eutectic solvents—a review
PublikacjaGreen Chemistry plays a more and more important role in implementing rules of sustainable development to prevent environmental pollution caused by technological processes, while simultaneously increasing the production yield. Ionic liquids (ILs) and deep eutectic solvents (DESs) constitute a very broad group of substances. Apart from many imperfections, ILs and DESs have been the most promising discoveries in the world of Green...
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Comparison of different advanced oxidation processes for the degradation of room temperature ionic liquids
PublikacjaZbadano możliwość zastosowania wybranych zaawansowanych technologii utleniania (UV, UV/H2O2, UV/TiO2) do degradacji cieczy jonowych. Do degradacji wytypowano pięć związków: HHiM, BMiM, MiM, OMiM oraz EEiM.
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Determination of ionic conductivity in the Bi-Si-O and Pb-Si-O glasses
PublikacjaImpedance spectroscopy measurements in various gas atmospheres were carried out in order to explain the doubts about the type of carriers and the mechanism of electrical conductivity in Bi-Si-O and Pb-Si-O glasses. In bismuth silicate glass, a typical ionic conductivity with oxygen ions as charge carriers was observed. The level of electrical conductivity of the glass at 400 °C was 5 × 10−8 S·cm−1 , with the activation energy of...
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The domination of ionic conductivity in tetragonal phase of the organometal halide perovskite CH3NH3PbI3-xClx
PublikacjaOrganometal trihalide perovskites have recently gained extreme attention due to their high solar energy conversion in photovoltaic cells. Here, we investigate the contribution of iodide ions to a total conductivity of the mixed lead halide perovskite CH3NH3PbI3−xClx with a use of the modified DC Hebb–Wagner polarization method. It has been identified that an ionic conductivity dominates in tetragonal phase which is associated with room...
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Highly Active TiO2 Microspheres Formation in the Presence of Ethylammonium Nitrate Ionic Liquid
PublikacjaSpherical microparticles of TiO2 were synthesized by the ionic liquid-assisted solvothermal method at different reaction times (3, 6, 12, and 24 h). The properties of the prepared photocatalysts were investigated by means of UV-VIS diffuse-reflectance spectroscopy (DRS), Brunauer–Emmett–Teller (BET) surface area measurements, scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), and X-ray photoelectron spectroscopy...
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Analytical applications and physicochemical properties of ionic liquid-based hybrid materials: A review
PublikacjaIonic liquids with their unique properties found so far numerous analytical applications. Among them ionic liquids immobilized on the surface or within the pores of a solid support were successfully utilized in extraction techniques dedicated to preconcentration of the analytes from food, environmental and biological samples. In this review we focus on comprehensive summarizing of available literature data on the examples of ionic...
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Application of surface active amino acid ionic liquids as phase-transfer catalyst
PublikacjaFive structurally related morpholinium derived ionic liquids containing N-acetyl-glycinate anion were synthesized and their thermal stability, surface properties and activity as phase transfer catalysts investigated. The thermal properties were studied by differential scanning calorimetry, while the adsorption at the air/water interface and micellization behavior was analyzed by surface tension measurements, conductometry and isothermal...
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Use of pyridinium and pyrrolidinium ionic liquids for removal of toluene from gas streams
PublikacjaSeparation of toluene from a toluene/N2 gas mixture using supported liquid membranes based on a series of pyridinium (1-butylpyridinium- bis(trifluoromethylsulfonyl)imide - [C4Py][Tf2N], 1-hexylpyridinium trifluoromethanesulfone [C6Py][Tf2N]) and pyrrolidinium (1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide - [C4Pyrr][Tf2N], 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide - [C6Pyrr][Tf2N], 1-butyl-1-methylpyrrolidinium...
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Deodorization of model biogas by means of novel non-ionic deep eutectic solvent
PublikacjaThe paper presents new non-ionic deep eutectic solvent (DES) composed of natural and non-toxic components i.e. guaiacol, camphor and levulinic acid in 1:1:3 molar ratio as a promising absorbent for removal of selected volatile organic compounds (VOCs) including dichloromethane, toluene, hexamethyldisiloxane and propionaldehyde from model biogas. The affi nity of DES for VOCs was determined as vapour-liquid coeffi cients and the...
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Multiple Group Membership and Collective Action Intention
PublikacjaDatasets from two studies conducted in Poland on the relation between identity fusion, group identification, multiple group membership, perceived injustice, and collective action intention. The presented studies, in the context of protests against attempts to restrict abortion law, were conducted to examine the link between belonging to multiple groups, group efficacy & identification, perceived injustice and collective...
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Antifungal action of the oxathiolone-fused chalcone derivative
PublikacjaAMG-148, pochodna chalkonu z pierścieniem oksatiolonowym, wykazuje aktywność przeciwgrzybową in vitro wobec szczepów grzybowych patogennych dla człowieka, z wartościami minimalnych stężeń hamujących wzrost mieszczących się w zakresie 1-16 mikrogramów na mililitr, natomiast w wyższych stężeniach związek ten działa grzybobójczo. Obecność głównych białek oporności wielolekowej, Cdr1p, Cgr2p lub Mdr1p nie wpływa znacząco na aktywność...
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A sector-an industry? Definitional challenges in economic sciences
Publikacjathe aim of our paper is to present definitional challenges that we as scholars and teachers face while attempting to relate to a sector and an industry terms in economic analyses and from strategic management perspective. we employ secondary research and analyse the state of the academic discourse and common usages of the above terms. we argue that for an economic statistician classifications should be consistent and highlight...
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Concentration in ICTs sector - cross country analysis
PublikacjaIn the chapter below, the author present inequalities in sector of new information and communication technologies. Having in mind inequalities we can also discuss concentration issues, and the concentration itself is a problem to which the author refers on first place. The paper is organized as following: first basic measures of concentration are defined, after we can read a discussion referring to concentration in ICTs sector...
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Reflexion etique sur l´action ekonomique
PublikacjaPraca pokazuje ważność pytań z zakresu etyki, stawianych wszelkiej przedsię-biorczości, działalności ekonomicznej w ujęciu historycznym. Jednocześniepraca usiłuje znaleźć przyczynę roztraygnięć etycznych współczesności.
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Religious social action and its organizational profiles
PublikacjaPurpose Social action implemented by the Church via its affiliated entities, foundations and associations may be viewed as a uniform activity. In reality, however, several organizational profiles exist that depend on the origin of these organizations (lay or religious), the scope of their activities (local or general) and their dependence on resources (whether from public administration or civil society). The paper aims to discuss...
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Apple pectin complexes with whey protein isolate
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Knowledge Safety – Insights from the SME Sector
PublikacjaPurpose: This paper aims to explore the topic of knowledge safety, defined as the state of knowledge being safe from loss, leakage, attrition, oblivion, waste or theft. The paper first presents a theoretical background and review of previous studies on knowledge loss and ways of overcoming it, and then illustrates the topic of knowledge safety with ten case studies from the small and medium-sized enterprises (SMEs) sector. Methodology:...
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Innovativeness assessment of the SME sector in the Pomeranian region
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Longitudinal Motion Due to Action of Tunnel Thrusters
PublikacjaTunnel thrusters are propulsion and active control devises that provide a side force, or transverse thrust, to support mooring operations or position keeping. They shorten the time of manoeuvring, reduce the cost of towage and since inception, manoeuvrability specifically in ports has become a lot easier. Tunnel thrusters can either be operated manually or with the help of Dynamic Positioning systems which makes it even more efficient. Theoretically,...
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Nyelvtudomány (Acta Universitatis Szegediensis Sectio Linguistica)
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Annales Universitatis Scientiarum Budapestinensis. Sectio linguistica
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Analysis of free vibrations of cantilever bars with parabolically variable cross-sections using the Rayleigh’s method
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Measurements of absolute total cross sections for electron scattering fromtriatomic polar molecules: SO2 and H2S.
PublikacjaZmierzono całkowity przekrój czynny na rozproszenie elektronów na SO2 i H2S.Pomiary przeprowadzono na zmodyfikowanym spektrometrze elektronów pracującym w oparciu o metodę transmisyjną.
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Unveiling the electron-induced ionization cross sections and fragmentation mechanisms of 3,4-dihydro-2H-pyran
PublikacjaThe interactions of electrons with molecular systems under various conditions are essential to interdisciplinary research fields extending over the fundamental and applied sciences. In particular, investigating electron-induced ionization and dissociation of molecules may shed light on the radiation damage to living cells, the physicochemical processes in interstellar environments, and reaction mechanisms occurring in combustion...
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Differential cross sections for elastic electron scattering in xenon in the energy range from 5ev to 10ev
PublikacjaRóżniczkowe przekroje czynne na rozproszenie sprężyste elektronów na atomach ksenonu zmierzone zostały dla energii 5, 7.9 i 10eV w zakresie kątów rozproszenia 30°-180°. W pomiarach wykorzystano technikę lokalnego pola magnetycznego. Wyznaczono także całkowity przekrój czynny na rozproszenie sprężyste oraz przekrój czynny na przekazanie pędu poprzez scałkowanie zmierzonych różniczkowych przekrojów czynnych dla wybranych energii....
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Analiza wad powierzchni gorącowalcowanych wyrobów stalowych = Hot rolled sections surface defects analysis
PublikacjaZanalizowano hutnicze wady powierzchni dwuteowników walcowanych na gorąco, głebokość zdefektowanych obszarów i zmiany mikrostruktury w tych obszarach.
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ACTA CRYSTALLOGRAPHICA SECTION A
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A station strategy to deter backoff attacks in IEEE 802.11 LANs
PublikacjaDla konstrukcji strategii zapobiegającej atakom na mechanizm odczekania w sieciach lokalnych IEEE 802.11 zastosowano wybór konfiguracji MAC sterowany przez liczniki etapów gry z losowymi wartościami początkowymi. Wykazano, że przy pewnych warunkach nałożonych na rozkady prawdopodobieństwa liczników standardowe ustawienia parametrów MAC stają się punktem doskonałej równowagi strategicznej.
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Arylation of enelactams using TIPSOTf: reaction scope and mechanistic insight
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Analysis of tank safety with propane-butane on LPG distribution station
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Promotion of borophene/NiO-based electrocatalyst for oxygen evolution reaction
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The pharmacokinetics of propofol in ICU patients undergoing long-term sedation
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Auditory-model based robust feature selection for speech recognition
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Simple Selection Procedure to Distinguish between Static and Flexible Loops
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Problem of selection of reference plane with deep and wide valleys analysis
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Fast method for the determination of the charge transfer coefficient of an electrode reaction
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Multihomed Wireless Terminals: MAC Configuration and Network Selection Games
PublikacjaW artykule rozpatruje się rozdział pasma pomiędzy zbiór racjonalnych terminali bezprzewodowych dołączonych do wielu sieci lokalnych. Przy pomocy narzędzi analitycznych teorii gier pokazuje się, w jaki sposób można zniechęcać terminale do agresywnej konfiguracji protokołu MAC. Analizowana jest ilościowo rola prędkości generacji informacji zwrotnej z sieci w stosunku do częstości generacji żądań dostępu terminala do sieci. Wykazano,...
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Parameter selection of an adaptive PI state observer for an induction motor
PublikacjaThe paper discusses problems connected with the parameters selection of the proportional-integral observer, designed for recon- struction of magnetic fluxes and angular speed of an induction motor. The selection is performed in several stages that are focused on different criteria. The first stage consists in selecting observer’s gains and provides desired dynamical properties, taking into consideration immunity to disturbances and...
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Scaling of numbers in residue arithmetic with the flexible selection of scaling factor
PublikacjaA scaling technique of numbers in resudue arithmetic with the flexible selection of the scaling factor is presented. The required scaling factor can be selected from the set of moduli products of the Residue Number System (RNS) base. By permutation of moduli of the number system base it is possible to create many auxilliary Mixed-Radix Systems associated with the given RNS with respect to the base, but they have different sets...
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Genetic Programming with Negative Selection for Volunteer Computing System Optimization
PublikacjaVolunteer computing systems like BOINC or Comcute are strongly supported by a great number of volunteers who contribute resources of their computers via the Web. So, the high efficiency of such grid system is required, and that is why we have formulated a multi-criterion optimization problem for a volunteer grid system design. In that dilemma, both the cost of the host system and workload of a bottleneck host are minimized. On...
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Methane formation over TiO2–based photocatalysts: reaction pathways
PublikacjaThe effects of organic impurities adsorbed or incorporated into semiconductors structure on the photocatalytic products are noteworthy. For this purpose, the as-prepared Ag, Au and Pdmodified TiO2 samples were exposed to UV-vis irradiation in various gas atmospheres (CO2, N2, 600 ppm CO2 in N2, and 13CO2) in order to clarify the route of CH4 formation in the process of photocatalytic CO2 reduction. In the presented research it...
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Photochemical and thermal reaction of intermediates in the phenylnitrene rearangment inside a hemicarcerand
PublikacjaBroadband irradiation (λ > 320 nm) of hemicarceplex H1 between −74 °C and −84 °C, produces encapsulated didehydroazepine (2), triplet phenylnitrene (3PN), 2-azabicyclo[3.2.0]hepta-1,3,6-triene (6), and 4-azaspiro[2.4]hepta-1,4,6-triene (7). The highly strained anti-Bredt imine 6 is formed from 2 via a photochemical four-electron electrocyclization. Under the irradiation conditions, 6 rearranges further to azaspirene 7. In addition,...
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Feature type and size selection for adaboost face detection algorithm
PublikacjaThe article presents different sets of Haar-like features defined for adaptive boosting (AdaBoost) algorithm for face detection. Apart from a simple set of pixel intensity differences between horizontally or vertically neighboring rectangles, the features based on rotated rectangles are considered. Additional parameter that limits the area on which the features are calculated is also introduced. The experiments carried out on...
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Carbon Nanohorns as Reaction Nanochambers – a Systematic Monte Carlo Study
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The overabundance of excited hydrogen atoms produced in the H2++ furan reaction
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Objective selection of minimum acceptable mesh refinement for EMC simulations
PublikacjaOptimization of computational electromagnetics (CEM) simulation models can be costly in both time and computing resources. Mesh refinement is a key parameter in determining the number of unknowns to be processed. In turn, this controls the time and memory required for a simulation. Hence, it is important to use only a mesh that is good enough for the objectives of the simulation, whether for direct handling of high-fidelity EM...
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A solvent selection guide based on chemometrics and multicriteria decision analysis
PublikacjaThe selection of suitable solvents is a crucially important subject in a wide range of chemical processes. This study presents a solvent selection guide where 151 solvents were assessed, including a significant number of recently reported bio-based solvents. The assessment procedure involves grouping of solvents according to their physicochemical parameters and ranking within clusters according to their toxicological and hazard...
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Project of hip joint endoprothesis for an individual patient with materials selection
PublikacjaThis work includes the hip replacement design, based on the patient's medical records, the description of creation process and materials used for individual components.
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Frequency distribution of chemical oscillations in the closed Belousov Zhabotinsky reaction.
PublikacjaW publikacji przedstawiono wykorzystanie metody STFT (krótkoczasowej transformaty Fouriera) do analizy oscylacji chemicznych. Badano rejestry potencjałowe reakcji Biełousowa Żabotyńskiego. Wykazano niestacjonarność analizowanych przebiegów. Wykazano liniową zależność pomiędzy częstotliwością oscylacji a stężeniem jednego z komponentów reakcji (bromian potasu). Udowodniono przydatność analizy czasowo-częstotliwościowej do analizy...