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Search results for: POTASSIUM-SELECTIVE ELECTRODE
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Peptide-Based Rapid and Selective Detection of Mercury in Aqueous Samples with Micro-Volume Glass Capillary Fluorometer
PublicationMercury, a toxic heavy metal produced through both natural and anthropogenic processes, is found in all of Earth’s major systems. Mercury’s bioaccumulation characteristics in the human body have a significant impact on the liver, kidneys, brain, and muscles. In order to detect Hg2+ ions, a highly sensitive and specific fluorescent biosensor has been developed using a novel, modified seven amino acid peptide, FY7. The tyrosine ring...
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Properties of electrode modified with poly(3,4-ethylenedioxytiophene) and Pt particles.
PublicationWłaściwości warstw polimerowych poli(3,4-etylenodioksytiofenu)z cząstkami platyny zbadano pod względem zastosowania do reakcji utlenienia związków organicznych. Stwierdzono, bez wnikania w mechanizmy i kinetykę reakcji, że właściwości fizyczne jak i chemiczne (zdolność do katalizowania reakcji utlenienia alkoholi) zależą od materiału podłoża: Pt, węgiel szklisty, tytan, złoto.
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Dynamic electrochemical impedance spectroscopy of the first order electrode reaction
PublicationCiągłe transformaty STFT sinusoidalnego sygnału pobudzenia i odpowiedzi prądowej zostały wyznaczone dla reakcji elektrodowej pierwszego rzędu. Wyznaczono impedancję elektrody w łącznej dziedzinie czasu i częstotliwości. Wykonano pomiary dla reakcji redukcji Cd(II) na rtęciowej elektrodzie kroplowej w funkcji potencjału. Przedstawiono możliwość wyznaczenia chwilowych widm impedancyjnych. Opisano zależność rezystancji przeniesienia...
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Fast method for the determination of the charge transfer coefficient of an electrode reaction
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Paraxial parameters and aberration of seven-electrode axisymmetric cathodic lens
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Facile synthesis and characterization of graphene and N-doped graphene by CVD method from liquid precursors for promising electrode materials
PublicationIn this study, high-quality and few-layered graphene was synthesized using the chemical vapor deposition (CVD) method from liquid sources. Two different liquid carbon sources, pyridine, and benzene, were used and deposited on nickel foam under heat conditions using a bubbler in a quartz tube. X-ray diffraction (XRD) and Raman analysis confirmed the crystalline properties of graphene and N-doped graphene, demonstrating the high...
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Preparation and Characterization of Nanomaterial Consisting of Silica Aerogel & Carbon Tested as an Electrode in Non-Aqueous Media Containing Lithium Salt.
PublicationSilica aerogel (SiO2ag) was combined with carbonaceous material in the pyrolysis process of hydrocarbons. The obtained nanocomposite SiO2ag/C was amorphous, partially preserving the porous structure of SiO2ag. The specific surface area changes from 445.6 m2/g for pure SiO2ag to 205.52 m2/g SiO2ag/C. The 29Si MAS-NMR shows a three-dimensional matrix with silicon atoms connected to other silicon atoms by four...
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Solid-Contact Ion-Selective Electrodes with Highly Selective Thioamide Derivatives of p-tert-Butylcalix[4]arene for the Determination of Lead(II) in Environmental Samples
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Solid-contact lead(II) ion-selective electrodes for potentiometric determination of lead(II) in presence of high concentrations of Na(I), Cu(II), Cd(II), Zn(II), Ca(II) and Mg(II)
PublicationLead and its compounds are a serious threat to the environment. Monitoring of this toxic heavy metal is a driving force for the continuous development of novel lead(II) ionophores to be applied in ion-selective electrodes. In this work a highly selective lead(II) ionophore, namely 25,26,27,28-tetrakis(piperidinylthiocarbonylmethylene)-p-tert-butylcalix[4]arene, was used in solid-contact ion-selective electrodes for determination...
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Enhanced electrochemical performance of partially amorphous La0.6Sr0.4CoO3-δ oxygen electrode materials for low-temperature solid oxide cells operating at 400 °C
PublicationThis work evaluates partially amorphous La0.6Sr0.4CoO3-δ (LSC) as a potential oxygen electrode for lowtemperature solid oxide cells. LSC was deposited using the spin-coating technique onto Ce0.8Gd0.2O2-δ (CGO) substrates. The optimal oxygen electrode thickness was determined as 500 nm. The electrochemical impedance spectroscopy (EIS) study showed a significant improvement in oxygen reduction/oxidation reaction kinetics when annealing...
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Ionophores in polymeric membranes for selective ion recognition; impedance studies
PublicationBadania impedancyjne membran zawierających jonofory selektywne na kation Na+ (L1) i Cs+(L2) wykazały, ze stala dielektryczna materiału membrany zależy od typu uzytego plastyfikatora i zmienia się w zakresie od 28 do 60. Rezystancja membran zawierających ligand L1 i L2 wynosi 0.15 -1.4 Mohm w zależności od stężenia elektrolitu zewnnetrznego. Testowona dwa typy elektrod jonoselektywnych: elektrody typu ASS z polimerem przewodzącym...
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Selective harvesting of regional digital libraries and national metadata aggregators
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Kinetic Description of the Membrane–Solution Interface for Ion-Selective Electrodes
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Human Obesity Is Characterized by a Selective Potentiation of Central Chemoreflex Sensitivity
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Selective Potentiation of Peripheral Chemoreflex Sensitivity in Obstructive Sleep Apnea
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Optimization of purification and selective burning of single-wall carbon nanotubes
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3-Substituted phenylalanines as selective AMPA- and kainate receptor ligands
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Selective Protection for All-Optical Physical Impairment Constrained Routing
PublicationW przypadku sieci optycznych, zauważalna jest obecnie tendencja dążenia do transmisji całowicie optycznej (tz. bez konwersji O/E/O w węzłach tranzytowych). Jednakże w niedalekiej przyszłości, z uwagi na techniczne ograniczenia, niemożliwa będzie obsługa całości ruchu wyłącznie w dziedzinie optycznej. Operatorzy będą więc zainteresowani oferowaniem rozwiązań przejściowych implikujących przełączanie w dziedzinie optycznej jedynie...
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Selective monitoring of noise emitted by vehicles involved in road traffic
PublicationAn acoustic intensity probe was developed measures the sound intensity in three orthogonal directions, making possible to calculate the azimuth and elevation angles, describing the sound source position. The acoustic sensor is made in the form of a cube with a side of 10 mm, on the inner surfaces of which the digital MEMS microphones are mounted. The algorithm works in two stages. The first stage is based on the analysis of sound...
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Study of oxygen electrode reactions on symmetrical porous SrTi0.30Fe0.70O3-δ electrodes on Ce0.8Gd0.2O1.9 electrolyte at 800 °C–500 °C
PublicationIron doped strontium titanates (SrTi1-xFexO3-δ) are an interesting mixed ionic-electronic conductor model used to study basic oxygen reduction/oxidation reactions. In this work, we performed an impedance spectroscopy study on symmetrical porous SrTi0.30Fe0.70O3-δ (STF70) electrodes on a ceriabased electrolyte. The sample was measured in varying oxygen concentration: from 0.3% to 100% in 800 °C - 500 °C temperature range. Low polarisation...
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Calcium, Potassium, Sodium, and Magnesium Concentrations in the Placenta, Umbilical Cord, and Fetal Membrane from Women with Multiple Pregnancies
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Release kinetics and antimicrobial properties of the potassium sorbate-loaded edible films made from pullulan, gelatin and their blends
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Molecularly imprinted polymers based on deep eutectic solvents as a greenest materials for selective extraction of emerging contaminants from complex samples
PublicationSome of the reagents applied in the synthesis of molecularly imprinted polymers (MIPs) may impact on health and the environment. Thus, a new generation of promising green chemicals are nowadays introduced and investigated, including deep eutectic solvents (DESs). DESs seems to be a reasonable choice as they are characterized as non-toxic, low cost, easy to prepare and biodegradable chemicals. This review presents the information...
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PARP inhibition potentiates the cytotoxic activity of C-1305, a selective inhibitor of topoisomerase II, in human BRCA1-positive breast cancer cells
PublicationTwo cellular proteins encoded by the breast and ovarian cancer type 1 susceptibility (BRCA1 and BRCA2) tumor suppressor genes are essential for DNA integrity and the maintenance of genomic stability.Approximately 5-10% of breast and ovarian cancers result from inherited alterations or mutations in these genes.Remarkably, BRCA1/BRCA2-deficient cells are hypersensitive to selective inhibition of poly(ADPribose) polymerase 1 (PARP-1),...
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Digital harmonic analysis of cadmium ion reduction on a dropping mercury electrode
PublicationBadano redukcję jonów kadmu na rtęciowej elektrodzie kroplowej. Jako pobudzenie zastosowano sinusoidalny sygnał napięciowy nałożony na liniowo zmieniający się potencjał dc. Przeprowadzono analizę czasowo-częstotliwościową prądu polarograficznego dla reakcji redukcji jonu kadmu na rtęciowej elektrodzie kroplowej. Klasyczna transformacja Fouriera prowadzi do dekompozycji prądu polarograficznego na składowe harmoniczne. Harmoniczne...
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Theoretical description of fundamental-harmonic impedance of a two-step electrode reaction
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Ellipsometry study of oxide formation on Cu electrode in 0.1 M NaOH
PublicationPrzedstawiono przykład zastosowania techniki elipsometrii monochromatycznej w celu określenia dynamiki wzrostu warstw tlenkowych i wodorotlenkowych na miedzi w środowisku 0.1M NaOH. Badania te stanowią część projektu skupiającego się na oznaczeniu fizycznych i elektrycznych własności tlenku miedzi (I) oraz tlenku miedzi (II) podczas procesu formowania się warstwy. Jednoczesne pomiary elipsometryczne i impedancyjne są nowatorskie...
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Special techniques and future perspectives: Simultaneous macro- and micro-electrode recordings
PublicationThere are many approaches to studying the inner workings of the brain and its highly interconnected circuits. One can look at the global activity in different brain structures using non-invasive technologies like positron emission tomography (PET) or functional magnetic resonance imaging (fMRI), which measure physiological changes, e.g. in the glucose uptake or blood flow. These can be very effectively used to localize active patches...
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Collection efficiency in narrow electrostatic precipitators with a longitudinal or transverse wire electrode
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Ellipsometric study of oxide formation on Cu electrode in 0.1 M NaOH
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Effect of electrode waterproof coating on quality of underwater wet welded joints
PublicationIn this paper, the effects of different hydrophobic coatings on the surface of covered electrodes on the quality of wet welded carbon steel joints were discussed. Commonly available hydrophobic substances used in industrial applications were selected for the research. The aim of using waterproof coatings was to check the possibility to decreasing the susceptibility of highstrength low-alloy S460N steel to cold cracking. During...
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Method of selective fading as a educational tool to study the behaviour of prestressed concrete elements under excess loading
PublicationPrestressed structures are a key to realization of the boldest architectural ideas, characteristic feature of prestressed structure is better use of concrete material properties by insertion of internal forces. Learning about pre-stressed reinforced concrete structures is an integral part of Graduate Studies Program in construction engineering. Know-how of geometry change patterns in prestressed concrete elements under certain...
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Beer as a potential source of macroelements in a diet: the analysis of calcium, chlorine, potassium, and phosphorus content in a popular low-alcoholic drink
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Effect of Cobalt on the Activity of CuO/CeO2 Catalyst for the Selective Oxidation of CO
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Salicylaldimine-based receptor as a material for iron(III) selective optical sensing
Publicationα,α-Bis(salicylimino)-m-xylene (L) was prepared using both conventional and microwave-assisted procedure. The compound exhibits ability to colorimetric recognition of iron(III) ions in aqueous environment, what is shown by significant color change from yellow to purple. In DMSO : water (9:1 v/v) solvent system receptor creates with iron(III) cations complexes of 2:1 stoichiometry (L:Fe3+) with stability constant (log K) 7.54±0.21....
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Computer-aided design and selective laser melting of porous biomimetic materials
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Porous Selective Laser Melted Ti and Ti6Al4V Materials for Medical Applications
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Multiaxial fatigue behaviour of maraging steel produced by selective laser melting
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Comparison of Vacuum Sintered and Selective Laser Melted Steel AISI 316L
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Design of selective substrates of proteinase 3 using combinatorial chemistry methods
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Studies on the separation of some transition metals using trialkylimidazole as selective extractant
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Reduced diameter distribution of single-wall carbon nanotubes by selective oxidation
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Discovery of the First Highly Selective Antagonist of the GluK3 Kainate Receptor Subtype
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Chinifur, a Selective Inhibitor and "Subversive Substrate" for Trypanosoma congolense Trypanothione Reductase
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Standard and Fast Selective Catalytic Reduction of NO with NH3on Zeolites Fe-BEA
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Surface engineering of graphene oxide membranes for selective separation of perfluorooctanoic acids
PublicationPerfluoroalkyl compounds (PFCs) are environmental toxicants and their widespread detection and accumulation in the environment can be detrimental to the ecosystem. In this study, surface charge of GO membranes was engineered to enhance selectivity of graphene oxide (GO) membranes and for the removal of perfluorooctanoic acid (PFOA ∼400 Da) in real concentration ranges in wastewater streams. The structure and physicochemical properties...
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Influence of the analyzing window on electrode impedance measurement by thecontinuous freqency scanning method
PublicationPrzeprowadzono pomiary impedancyjne modelowego układu elektrycznego RC techniką ciągłego skanowania częstotliwościowego. Wyznaczono impedancję modelowego układu dla różnych okien analizujących oraz ich różnych wielkości. Wyznaczone dla różnych okien analizujących wartości R i C porównywano z wartościami rzeczywistymi. Stwierdzono wpływ rodzaju okna analizującego oraz jego długość na dokładność otrzymywanych wyników.
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Influence of the analyzing window on electrode impedance measurement by the continuous frequency scanning method
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Performance and Stability in H2S of SrFe0.75Mo0.25O3-δ as Electrode in Proton Ceramic Fuel Cells
PublicationThe H2S-tolerance of SrFe0.75Mo0.25O3-δ (SFM) electrodes has been investigated in symmetric proton ceramic fuel cells (PCFC) with BaZr0.8Ce0.1Y0.1O3-δ (BZCY81) electrolyte. The ionic conductivity of the electrolyte under wet reducing conditions was found to be insignificantly affected in the presence of up to 5000 ppm H2S. The fuel cell exhibited an OCV of about 0.9 V at 700 °C, which dropped to about 0.6 V and 0.4 V upon exposure...
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Solid-phase microextraction and ion chromatographic analysis of anions based on polypyrrole electrode
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