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Search results for: NITRATE REDUCTION REACTION
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Convenient Synthesis of Functionalized Unsymmetrical Vinyl Disulfides and Their Inverse Electron-Demand Hetero-Diels-Alder Reaction
PublicationThe simple, convenient, and efficient methods for the preparation of unsymmetrical vinyl disulfides with additional functional groups under mild conditions with moderate to high yields were designed. The developed methods include the reaction of S-vinyl phosphorodithioate with thiotosylates or S-vinyl thiotosylate with thiols. The designed methods allow for the synthesis of unsymmetrical vinyl disulfides with additional functionalities...
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Integration of the sulfate reduction and anammox processes for enhancing sustainable nitrogen removal in granular sludge reactors
PublicationThe Anammox and Sulfate Reduction Ammonium Oxidation processes were compared in two granular sequencing batch reactors operated for 160 days under anammox conditions. It was hypothesized that increasing the concentration of SO42− may positively influence the rate of N removal under anaerobic conditions and it was tested whether SO42− reduction and anammox occur independently or are related to each other. The cooperation of N-S...
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Study of the Effectiveness of Model Order Reduction Algorithms in the Finite Element Method Analysis of Multi-port Microwave Structures
PublicationThe purpose of this paper is to investigate the effectiveness of model order reduction algorithms in finite element method analysis of multi-port microwave structures. Consideration is given to state of the art algorithms, i.e. compact reduced-basis method (CRBM), second-order Arnoldi method for passive-order reduction (SAPOR), reduced-basis methods (RBM) and subspace-splitting moment-matching MOR (SSMM-MOR)
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Human awareness versus Autonomous Vehicles view: comparison of reaction times during emergencies
PublicationHuman safety is one of the most critical factors when a new technology is introduced to the everyday use. It was no different in the case of Autonomous Vehicles (AV), designed to replace generally available Conventional Vehicles (CV) in the future. AV rules, from the start, focus on guaranteeing safety for passengers and other road users, and these assumptions usually work during normal traffic conditions. However, there is still...
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Reduction in Errors in Roughness Evaluation with an Accurate Definition of the S-L Surface
PublicationCharacterization of surface topography, roughly divided into measurement and data analysis, can be valuable in the process of validation of the tribological performance of machined parts. Surface topography, especially the roughness, can respond straightly to the machining process and, in some cases, is defined as a fingerprint of the manufacturing. When considering the high precision of surface topography studies, the definition...
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Reduced-Cost Microwave Modeling Using Constrained Domains and Dimensionality Reduction
PublicationDevelopment of modern microwave devices largely exploits full-wave electromagnetic (EM) simulations. Yet, simulation-driven design may be problematic due to the incurred CPU expenses. Addressing the high-cost issues stimulated the development of surrogate modeling methods. Among them, data-driven techniques seem to be the most widespread owing to their flexibility and accessibility. Nonetheless, applicability of approximation-based...
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Compressed Projection Bases for Model-Order Reduction of Multiport Microwave Components Using FEM
PublicationThis paper presents a projection basis compression technique for generating compact reduced-order models (ROM) in the FE analysis of microwave devices. In this approach redundancy is removed from the projection basis by means of the proper orthogonal decomposition technique applied to the projected system of linear equations. Compression allows for keeping the size of a reduced-order model as small as possible without compromising...
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Low-Cost Method for Internal Surface Roughness Reduction of Additively Manufactured All-Metal Waveguide Components
PublicationIn this study, a novel low-cost polishing method for internal surface roughness reduction of additively manufactured components, developed for waveguide (WG) circuits operating in the millimeter frequency range is proposed. WG components fabricated using powder bed fusion (PBF) generally feature roughness of ten to fifty microns, which influences the increase of roughness-related conductor power losses having a major effect on...
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Fast Machine-Learning-Enabled Size Reduction of Microwave Components Using Response Features
PublicationAchieving compact size has emerged as a key consideration in modern microwave design. While structural miniaturization can be accomplished through judicious circuit architecture selection, precise parameter tuning is equally vital to minimize physical dimensions while meeting stringent performance requirements for electrical characteristics. Due to the intricate nature of compact structures, global optimization is recommended,...
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Real-Time Monnitoring of Vegetable Oils' Thermal Degradation Using Proton Transfer Reaction Mass Spectrometry
PublicationThe volatile aldehydes, which are generated during frying, can be harmful to human health, therefore the concentration of these compounds in frying fumes should be monitored. In addition, aldehydes are markers of oils’ quality, and so it is possible to determine shelf-life or suitability for frying of these oils. Commonly, in order to determine aldehydes concentration gas chromatography is performed, however it does not allow for...
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Experimental Study on the Effectiveness of Polyurethane Flexible Adhesive in Reduction of Structural Vibrations
PublicationThe aim of the present study is to consider the idea of using polyurethane flexible adhesive in to reduce the vibrations in structures exposed to dynamic loads and evaluate their damping properties in relation to large deformations. Firstly, two aluminium cantilever beams, simulating structural elements (without and with polyurethane layer in the form of tape), were analysed, in order to check the damping of the unconstrained polymer...
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Influence of the Square Wave Voltage on Dynamical Properties of a Flat Voltammetric Electrode in the Time Domain by the Electrochemical Reversible Reaction
PublicationIn this article there is a presentation of the analysis of the polarizing voltage shape influencing dynamic properties of voltammetric electrodes when on their surface reversible reaction takes place in the time domain. The electrode polarization with linearly increasing voltage and with a square component, was analyzed. The analysis that were conducted showed that the voltammetric electrode behaves like a first order transducer....
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Cobalt/Carbon Nanocomposite as Oxygen Evolution Reaction Electrocatalyst
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Action-reaction based synthesis of acoustic wavefield equations
PublicationThe analysis of acoustic fields is usually based on the well-known mathematics of second order partial differential equations called wave equations. The author explores the duality and symmetry of linear fluid mechanics and develops two distinct equations of acoustics on the basis of a causal approach to local small-scale phenomena. Wavefields that are solutions of these equations have different composition, the spherical pressure...
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Reaction of different microorganisms to novel graphene-based nanomaterials
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Mechanism of the reaction of Lawesson's reagent with N-alkylhydroxamic acids
PublicationIdentyfikacja fosforowych produktów powstających w reakcji kwasów hydroksamowych z odczynnikiem Lawessona pozwoliła ustalić mechanizm tytułowej reakcji. Wykorzystano w tym celu spektroskopię 31P NMR. Wzorce labilnych produktów otrzymano na niezależnej drodze syntetycznej lub przeprowadzono je w trwałe pochodne, które wyizolowano z mieszanin reakcyjnych. Produktem przejściowym badanej reakcji okazał się odpowiedni O-ditiofosfonylowany...
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Simulation-driven size-reduction-oriented design of multi-band antennas by means of response features
PublicationThis study addresses the problem of explicit size reduction of multi-band antennas by means of simulation-driven optimisation. The principal difficulty of electromagnetic (EM)-based miniaturisation of multi-band antennas is that several resonances have to be controlled independently (both in terms of their frequency allocation and depth) while attempting to reduce physical dimensions of the structure at hand. The design method...
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Experimental study on the effectiveness of polymer damper in damage reduction of temporary steel grandstand
PublicationA large number of accidents, involving collapses of temporary grandstands during different types of events, were observed in the past. If the synchronized movement of people is tuned with the natural frequency of the affected part of the structure, resonance might occur. It may lead to severe damages of grandstands, their collapse or panic among the spectators. The aim of the paper is to assess, through preliminary experimental...
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Experimental and numerical study on polymer element used for reduction of temporary steel grandstand vibrations
PublicationThe purpose of the paper is to analyse the effectiveness of a polymer damper in reduction of a temporary steel grandstand vibrations through the experimental and numerical study. The damper considered in the investigation is constructed out of two L-shape steel members bonded with polymer mass of high damping properties. The element has been installed as a diagonal one at the back part of the structure. The method has been compared...
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Reduction of the end-effect in surface texture analysis
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Model order reduction for subgridding in fdtd scheme
PublicationW artykule zaprezentowana została technika pozwalająca na uzyskanie wysokiej rozdzielczości w metodzie FDTD. Prezentowany algorytm jest połączeniem metod redukcji rzędu modelu i lokalnych zagęszczeń zaimplementowanych do FDTD. Pozwala to zmniejszyć liczbę użytych zmiennych stanu, a także skrócić krok czasowy, co skutkuje znacznie krótszym czasem symulacji, niż w przypadku klasycznej metody FDTD.
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Wow defect reduction based on interpolation techniques
PublicationW artykule przedstawiono wyniki badania różnych technik interpolacji wykorzystanych w redukcji kołysania dźwięku. W badaniach użyto: interpolację liniową, techniki interpolacji wielomianowej, i interpolację funkcją sink. Jakość rekonstrukcji zbadano wykorzystując sztucznie spreparowany sygnał foniczny, zrekonstruowany wymienionymi metodami interpolacji. Jakość rekonstrukcji oceniono wykorzystując standardowe deskryptory jakości...
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Data reduction and stacking for imbalanced data classification
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Reduction of Derivative pipeline effort in water turbine
PublicationThe paper presents an approach to evaluate and reduce the effort of the derivative pipeline in a water turbine of a hydrostatic power station in its vulnerable spots. Potential places of the biggest effort of the structure, as well as the coefficient of displacement and safety factor related to them were identified using FEM numerical method. Pipeline reinforcement was designed and made based on FEM analysis. Original technology...
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Digital techniques for noise reduction in CCD detectors
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Application of optical fibres in oxidation-reduction titrations
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Reduction of Inrush Current by Demagnetization of Magnetic Core
PublicationW artykule przedstawiono demagnetyzację rdzenia transformatora jako metodę ograniczania prądu załączeniowego. W zaproponowanej metodzie źródłem energii wykorzystywanej do rozmagnesowania jest kondensator. W przeprowadzonych obliczeniach symulacyjnych rozważono różne wartości pojemności kondensatora i wartości napięcia w celu określenia optymalnych wartości tych parametrów. Następnie obliczono strumienie szczątkowe, jakie ustalają...
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Metal salts reduction during parylenes polymerization
PublicationPublikacja o wynikach obliczeń kwantowych o możliwości redukcji niektórych soli metali przy pomocy rodników parylenu w czasie jego polimeryzacji.
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Reduction of pressure forces in turbine labyrinth seals
PublicationPrzedstawiono nową metodę zmniejszani sił samowzbudnych typu aerodynamicznego. zastosowano ją do różnych typów nadbandażowych uszczelnień labiryntowych. Efektywność rdukcji sił samowzbudnych wynosiła nawet ponad 60%. Potwierdzone rezultay obliczeniami i eksperymentalnie.
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Distributed Data Reduction through Agent Collaboration
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An Approach to Data Reduction and Integrated Machine Classification
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Wow defect reduction based on interpolation techniques
PublicationW referacie przedstawiono wyniki badania różnych technik interpolacji wykorzystanych w redukcji kołysania dźwięku. W badaniach użyto: interpolację liniową, dwie techniki interpolacji wielomianowej (Hermite i spline), i technikę sumowania okienkowanych funkcji sink. Jakość rekonstrukcji wykonano wykorzystując sztucznie spreparowany sygnał audio, rekonstruowany wymienionymi metodami interpolacji. Jakość rekonstrukcji oceniono wykorzystując...
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Spectacular Oxygen Evolution Reaction Enhancement through Laser Processing of the Nickel‐Decorated Titania Nanotubes
PublicationThe selective, laser‐induced modification of the nickel‐decorated titania nanotubes provides remarkable enhancement toward oxygen evolution reaction. Particularly, the irradiation of the laterally spaced crystalline TiO2 nanotubes, results in the formation of the tight closure over irradiated end, preserving their hollow interior. The shape of the absorbance spectra is modulated along with applied energy, and the new absorption...
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Spectacular Oxygen Evolution Reaction Enhancement Through Laser Processing of the Nickel-Decorated Titania Nanotubes
PublicationThe selective, laser-induced modification of the nickel-decorated titania nanotubes provides remarkable enhancement toward oxygen evolution reaction. Particularly, the irradiation of the laterally spaced crystalline TiO2 nanotubes, results in the formation of the tight closure over irradiated end, preserving their hollow interior. The shape of the absorbance spectra is modulated along with applied energy, and the new absorption...
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Voltage variations and their reduction in a rural low-voltage network with PV sources of energy
PublicationRenewable sources of energy (RES), especially photovoltaic (PV) micro-sources, are very popular in many countries. This way of clean power production is applied on a wide scale in Poland as well. The Polish legal regulations and tariffs specify that every prosumer in a low-voltage network may feed this network with a power not higher than the maximum declared consumed power. In power networks with RES, the voltage level changes...
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Short-term Price Reaction to Involuntary Bankruptcies Filed in Bad Faith: Empirical Evidence from Poland
PublicationPurpose: Assessing the reaction of the prices of shares of companies listed in the Warsaw Stock Exchange to the public disclosure of information about the filing a bankruptcy petition in bad faith by creditors. Design/Methodology/Approach: Event study analysis. Findings: It can therefore be assumed that the filing of an unfounded bankruptcy petition does not, in the short term, have a statistically significant negative impact on...
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Greedy Multipoint Model-Order Reduction Technique for Fast Computation of Scattering Parameters of Electromagnetic Systems
PublicationThis paper attempts to develop a new automated multipoint model-order reduction (MOR) technique, based on matching moments of the system input–output function, which would be suited for fast and accurate computation of scattering parameters for electromagnetic (EM) systems over a wide frequency band. To this end, two questions are addressed. Firstly, the cost of the wideband reduced model generation is optimized by automating a...
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Modeling of a Quasi-Resonant DC Link Inverter Dedicated to Common-Mode Voltage and Ground Current Reduction
PublicationIn this paper, the modeling methodology of the AC drive system with a Parallel Quasi-Resonant DC Link Inverter (PQRDCLI) is described. A presented modeling approach is an attractive tool used for the effective evaluation of a common-mode (CM) voltage and grounds current reduction methods. Designed models of inverter, induction machine (IM), and cable are simple, thus the methods for parameter extraction are not complicated. Verification...
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The influence of thermal treatment on electrocatalytic properties of Mn-Co nanofilms on nickel foam toward oxygen evolution reaction activity
PublicationThis work evaluates electrodeposited and differently treated Mn-Co catalysts for their oxygen evolution reaction activity. Catalysts are evaluated in the as-deposited and heat treated state: after 350 C and 600 C. Results show that the highest electrochemical activity is obtained for the as-deposited Mn-Co oxyhydroxide, which possibly possess a layered double hydroxide structure. After the heat treatment process, especially after...
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Acid-aided epoxy-amine curing reaction as reflected in epoxy/Fe3O4 nanocomposites: Chemistry, mechanism, and fracture behavior
PublicationThis work seeks to answer the question whether or not the presence of acid functional groups accelerate epoxyamine curing reaction. Epoxy/Fe3O4 nanocomposite was considered as a case, where discussions are based on chemistry, mechanism behind curing reactions and fracture behavior influenced by acid assistance to crosslinking. Fe3O4 magnetic nanoparticles (MNPs) with nanosilica decorative layer (B-MNP) were synthesized and subsequently...
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Kinetics of Cross-Linking Reaction of Epoxy Resin with Hydroxyapatite-Functionalized Layered Double Hydroxides
PublicationThe cure kinetics analysis of thermoset polymer composites gives useful information about their properties. In this work, two types of layered double hydroxide (LDH) consisting of Mg2+ and Zn2+ as divalent metal ions and CO32− as an anion intercalating agent were synthesized and functionalized with hydroxyapatite (HA) to make a potential thermal resistant nanocomposite. The curing potential of the synthesized nanoplatelets in the...
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A Three-Step Approach to Estimation of Reduction Potentials of Natural Mixtures of Antioxidants Based on DPPH Test; Illustration for Catechins and Cocoa
PublicationThe aim of this study is to propose a methodology to assess electrochemical properties of complex mixtures of antioxidants, such as plant extracts, based on the results of simple and popular DPPH test. The first, most difficult step, involves determinations of standard reduction potentials (E0) for the series of purified compounds (here catechins). The next step is the calculation of stoichiometric values (n10) based on the results...
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A Subspace-Splitting Moment-Matching Model-Order Reduction Technique for Fast Wideband FEM Simulations of Microwave Structures
PublicationThis article describes a novel model-order reduction (MOR) approach for efficient wide frequency band finite-element method (FEM) simulations of microwave components. It relies on the splitting of the system transfer function into two components: a singular one that accounts for the in-band system poles and a regular part that has no in-band poles. In order to perform this splitting during the reduction process, the projection...
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Crystal structure, DFT-study and NLO properties of the novel copper(I) nitrate π,σ-coordination compound based on 1-allyl-3-norbornan-thiourea
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Comparison of hydrogen bonds and diverse weak interactions of the nitro group in 2-methyl-4-nitroanilinium nitrate, bisulfate and two hexafluoridosilicates: elementary graph-set approach
PublicationCrystal structures of (H2m4na)NO3 (1), (H2m4na)HSO4 (2), (H2m4na)2SiF6 (3) and (H2m4na)2SiF6*2H2O (4), where 2m4na = 2-methyl-4-nitroaniline, are presented. Two layers of interactions occur in the structures, N—H...O/F hydrogen bonds and interactions with the nitro group. Although diverse, hydrogen-bonding patterns are compared with each other by means of interrelations among elementary graph-set descriptors and descriptors of hydrogen-bonding...
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Fast EM-driven size reduction of antenna structures by means of adjoint sensitivities and trust regions
PublicationIn this letter, a simple yet robust and computationally efficient optimization technique for explicit size reduction of antenna structures is presented. Our approach directly handles the antenna size as the main design objective, while ensuring satisfactory electrical performance by means of suitably defined penalty functions. For the sake of accuracy, the antenna structure is evaluated using high-fidelity EM simulation. In order...
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Synthesis of compounds with C-P-P and C=P-P bond systems based on the phospha-Wittig reaction
PublicationA reactivity study of a β-diketiminate titanium(III) phosphanylphosphido complex [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}] (1) towards ketones such as benzophenone, 9-fluorenone, acetophenone, cyclopentanone, cyclohexanone and cycloheptanone is reported. The reactions of 1 with aromatic ketones (without α-protons) directly lead to the Ti(III) complex [MeNacNacTi(μ2-Cl)(OSiMe3)] (5) as well as Ti(IV) complexes with the pinacol condensation...
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Denitrification Process Enhancement and Diversity of the Denitrifying Community in the Full Scale Activated Sludge System after Adaptation to Fusel Oil
PublicationImplementation of anaerobic digestion of primary sludge in modern wastewater treatment plants (WWTPs) limits the availability of organic carbon for denitrification in conventional nitrification-denitrification (N/DN) systems. In order to ensure efficient denitrification, dosage of the external carbon source is commonly undertaken. However, application of commercial products, such us ethanol or acetate, greatly increases operational...
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Fast method for the determination of the charge transfer coefficient of an electrode reaction
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The overabundance of excited hydrogen atoms produced in the H2++ furan reaction
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