Search results for: POLY(3,4-ETHYLENEDIOXYTHIOpHENE)

• Synthesis and electrochemical characterization of poly(3,4-ethylenedioxythiophene) modified by iron hexacyanocobaltate

  Publication

  • M. Wilamowska-Zawłocka
  • A. Lisowska-Oleksiak

  - SOLID STATE IONICS - Year 2010

  Praca dotyczy sposobu syntezy oraz elektrochemicznej charakterystyki materiału kompozytowego złożonego z poli(3,4-etylenodioksytiofenu) i heksacyjanokobaltanu(III) żelaza(II). Wybrany materiał badany był przy użyciu spektroskopii impedancyjnej, chronopotencjometrii oraz woltamperometrii cyklicznej w kontakcie z elektrolitem wodnym (KCl) oraz aprotycznym (LiPF6 w mieszaninie węglanu etylenu i węglanu propylenu). Materiał charakteryzuje...

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• Organic-inorganic composites consisted of poly(3,4-ethylenedioxythiophene)and Prussian Blue analogues

  Publication

  • A. Lisowska-Oleksiak
  • M. Wilamowska-Zawłocka
  • V. JASULAITIENé

  - ELECTROCHIMICA ACTA - Year 2011

  The organic-inorganic material consisted of poly(3,4-ethylenedioxythiophene) (pEDOT) and copper hexacyanoferrate (Cuhcf) was synthesized. The pEDOT film with Fe(CN)63−/4− as counter-ions potentiodynamically polarized in aqueous CuCl2 electrolyte brings about stable hybrid material (pEDOT/Cuhcf) performing single redox activity of FeII/III at a formal potential Ef = 0.61 V (vs. Ag/AgCl/0.1 M KCl) and less clearly shaped two redox...

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• Hetero-junction composed of poly(3,4-ethylenedioxythiophene) with poly(styrenesulphonate) and iodine doped titanium dioxide

  Publication

  • K. Siuzdak
  • A. Lisowska-Oleksiak

  - Functional Materials Letters - Year 2011

  Praca prezentuje nowe objętościowe heterozłacze typu p-n, gdzie domieszkowany jodem ditlenek tytanu (I-TiO2) pełni rolę elementu n, a poli(3,4-etylenodioksytiofen):poli(etylenosulfonian)(pEDOT:PSS)rolę elementu p. Heterozłącze zostało otrzymane na drodze potencjostatycznej polimeryzacji monomeru w obecnosci nanoproszku I-TiO2 zawieszonego w elektrolicie. Metoda pozwala na otrzymanie warstw hybrydowych, gdzie cząstki I-TiO2 są wbudowane...

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• Electrochemical activity of composite material poly(3,4-ethylenedioxythiophene) modified by silver hexacyanoferrate

  Publication

  • A. Nowak
  • A. Lisowska-Oleksiak

  - Functional Materials Letters - Year 2011

  W pracy przedstawiono sposób slektrochemicznj syntezy materiału składającego się z polimeru przewodzącego poli(3,4-etylenodioksytiofen) (pEDOT) i nieorganicznej sieci typu redox heksacyjanożelazianu srebra (Aghcf). Materiał otrzymano na drodze dwuetapowej. Etap pierwszy polega na galwanostatycznej redukcji srebra na elektrodzie z węgla szklistego. Etap drugi to roztwarzanie srebra z jednoczesną polimeryzacją monomeru. Otrzymany...

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• Spectroelectrochemical characteristics of poly(3,4-ethylenedioxythiophene) / iron hexacyanoferrate film-modified electrodes

  Publication

  • A. Nowak
  • A. Lisowska-Oleksiak
  • M. Wilamowska-Zawłocka

  - JOURNAL OF SOLID STATE ELECTROCHEMISTRY - Year 2010

  Praca dotyczy pomiarów spektroelektrochemicznych materiałów hybrydowych złożonych z polimeru elektroaktywnego poli(3,4-etylenodioksytiofenu) i Błękitu Pruskiego. Dla porównania badano również filmy polimerowe z wybranymi przeciwjonami: heksacyjanożelazowym (Fe(CN)63-/4-), chlorkowym (Cl-) i polistyrenosulfonowym (PSS-). Materiały w postaci cienkich filmów otrzymano na elektrodzie szklanej pokrytej tlenkiem indowo-cynowym. Widma...

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• Properties of electrodes modified with poly(3,4-ethylenedioxythiophene) and Pt particles-part II.

  Publication

  • S. Białłozór
  • A. Kupniewska

  - Year 2004

  Właściwości elektrokatalityczne elektrody Au/PEDT,PSS/Pt w reakcji utleniania kwasu mrówkowego, metanolu i etanolu określono za pomocą metody cyklowoltamperometrycznej i chronoamperometrycznej. Osiągnięto przyśpieszenie utleniania anodowego badanych reakcji. Ponadto ilościowe charakterystyki procesów wyznaczone metodą woltamperometryczną różnią się od charakterystyk przeprowadzonych metodą chronoamperometryczną.

• Electrochemical synthesis and characterization of nanocomposites based on poly(3,4-ethylenedioxythiophene) and functionalized carbon nanotubes

  Publication

  • A. D. Dettlaff
  • M. Wilamowska-Zawłocka

  - SYNTHETIC METALS - Year 2016

  This work is focused on new composite materials consisting of poly(3,4-ethylenedioxythiophene) (pEDOT) and functionalized multi-walled carbon nanotubes synthesized electrochemically. Three types of composites were synthesized: the first one containing carbon nanotubes with carboxyl groups (covalent functionalization), the second one containing oxidized carbon nanotubes ox-MWCNTs (with different oxygen-rich polar groups) (covalent...

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• Electrochemical activity and characterization of hybrid material consisted of poly(3,4- ethylenedioxythiophene) and silver hexacyanocobaltate

  Publication

  • A. Nowak
  • A. Lisowska-Oleksiak
  • J. Chojnacki

  - SOLID STATE IONICS - Year 2012

  Prac przedstawiono charakterystykę elektrochemiczną oraz powierzchniową materiału hybrydowego składającego się z polimeru przewodzącego, poli(3,4-etylenodioksytiofenu) oraz nieorganicznej sieci typu redoks, heksacyjanokobaltanu srebra. Materiał scharakteryzowano technikami jak AFM, SEM. Skład materiału oznaczono za pomocą mikroanalizy rentgenowskiej EDX. Analiza potwierdziła obecność sieci nieorganicznej w materiale. Proporcja...

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• Lithium ion insertion into poly(3,4-ethylenedioxythiophene) films from propylene carbonate electrolytes.

  Publication

  • A. Lisowska-Oleksiak
  • M. Graczyk

  - MOLECULAR PHYSICS - Year 2002

  Polimerowa matryca złożona z poli(3,4-etylenodioksytiofenu z poli(styrenosulfonianem) otrzymana została na drodze syntezy elektrochemicznej. Transport jonowy w matrycy polimerowej w kontakcie z węglanem propylenu zawierającym LiClO4 został scharakteryzowany za pomocą metody impedancji ac oraz chronowoltoamperometrii. Wyznaczono przewodność jonową matrycy oraz efektywne współczynniki dyfuzji dla kationu Li+. Wielkości te...

• Capacitance Enhancement by Incorporation of Functionalised Carbon Nanotubes into Poly(3,4-Ethylenedioxythiophene)/Graphene Oxide Composites

  Publication

  • A. Cymann-Sachajdak
  • M. Sawczak
  • J. Ryl
  • E. Klugmann-Radziemska
  • M. Wilamowska-Zawłocka

  - Materials - Year 2020

  This paper reports on the role of oxidised carbon nanotubes (oxMWCNTs) present in poly-3,4-ethylenedioxytiophene (PEDOT)/graphene oxide (GOx) composite. The final ternary composites (pEDOT/GOx/oxMWCNTs) are synthesised by an electrodeposition process from the suspension-containing monomer, oxidised carbon nanotubes and graphene oxide. Dissociated functional groups on the surface of graphene oxide play a role of counter-ions for the...

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• Ex situ XANES, XPS and Raman studies of poly(3,4-ethylenedioxythiophene) modified by iron hexacyanoferrate

  Publication

  • A. Lisowska-Oleksiak
  • A. Nowak
  • M. Wilamowska-Zawłocka
  • M. Sikora
  • W. Szczerba
  • C. Kapusta

  - SYNTHETIC METALS - Year 2010

  Praca dotyczy materiału hybrydowego złożonego z polimeru elektroaktywnego poli(3,4-etylenodioksytiofenu) i Błękitu Pruskiego. Wykonano pomiary spektroskopowe z użyciem technik: spektrometrii fotoelektronów wzbudzonych promieniami X (X-ray Photoelectron Spectroscopy (XPS)), spektroskopii absorpcyjnej struktury przykrawędziowej (X-ray Absorption Near Edge Structure (XANES)) oraz spektroskopii mikro-Ramana. Przeprowadzone badania...

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• Ex situ XANES, XPS and Raman studies of poly(3,4-ethylenedioxythiophene)modified by iron hexacyanoferrate

  Publication

  • A. Lisowska-Oleksiak
  • A. Nowak
  • M. Wilamowska-Zawłocka
  • M. Sikora
  • M. Szczerba
  • C. Kapusta

  - SYNTHETIC METALS - Year 2010

  Praca dotyczy badań XANES, XPS i Ramana polimeru przewodzącego poli(3,4-etylenodioksytiofenu) modyfikowanego heksacyjanożelazianem żelaza. Badania XANES potwierdziły oktaedryczne otoczenie atomu żelaza, którego najbliższymi sąsiadami są atomy węgla oraz atomy azotu. Badania XPS wykazały istnienie wiązań Fe-C, Fe-N oraz chemicznego oddziaływania między atomem siarki polimeru a atomem żelaza błękitu pruskiego. Obecność oddziaływań...

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• Impedance spectroscopy studies on hybrid materials consisting of poly(3,4-ethylenedioxythiophene) and iron, cobalt and nickel hexacyanoferrate

  Publication

  • A. Lisowska-Oleksiak
  • A. Nowak

  - SOLID STATE IONICS - Year 2008

  Badania warstw polimeru pEDOT modyfikowanego heksacyjanożelazianami żelaza, kobaltu i niklu przeprowadzono za pomocą spektroskopii impedancyjnej (SI). Wykazano, że materiały hybrydowe charakteryzują się dobrą stabilnością. Warstwy testowano w zakresie temperatur od 283 do 313K. w kontakcie z wodnym roztworem KCl. Wysokie współczynniki dyfuzji wskazują na możliwości wykorzystania układów jako przewodników jonowych.

• Thermal Transitions and Structural Characteristics of Poly(3,4-ethylenedioxythiophene/cucurbit[7]uril) Polypseudorotaxane and Polyrotaxane Thin Films

  Publication

  • B. Hajduk

  - Materials - Year 2024

  Herein, we report the thermal transitions and structural properties of poly(3,4-ethylenedioxythiophene/cucurbit[7]uril) pseudopolyrotaxane (PEDOT∙CB7-PS) and polyrotaxane (PEDOT∙CB7-PR) thin films compared with those of pristine PEDOT. The structural characteristics were investigated by using variable-temperature spectroscopic ellipsometry (VTSE), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and atomic force...

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• Electro oxidation of methanol and ethanol on poly(3,4-ethylenedioxythiophene) with dispersed Pt, Pt+Sn, and Pt+Pb particles.

  Publication

  • S. Białłozór
  • A. Kupniewska
  • V. Jasulajtiene

  - FUEL CELLS - Year 2003

  Wpływ mikrocząstek cyny i ołowiu na aktywność katalityczną platyny zdyspergowanej na podłożu polimerowym poli(3,4 etylenodioksytiofenu) w stosunku do reakcji elektrodowego utleniania alkoholu etylowego i metylowego określono za pomocą metody chronowoltamperometrycznej, spektroskopii fotoelektronów w zakresie promieniowania x (XPS) oraz mikrowagi elektrochemicznej. Wykazano,że zarówno cyna jak i ołów zwiększają szybkość procesu...

• Electrode materials for electrochemical capacitors based on poly(3,4-ethylenedioxythiophene) and functionalized multi-walled carbon nanotubes characterized in aqueous and aprotic electrolytes

  Publication

  • A. D. Dettlaff
  • P. R. Das
  • L. Komsiyska
  • O. Osters
  • J. Łuczak
  • M. Wilamowska-Zawłocka

  - SYNTHETIC METALS - Year 2018

  Within this work, we report a facile one-stage synthesis of nanocomposites based on functionalized carbon nanotubes (CNTs) and electroactive polymer poly(3,4-ethylenedioxythiophene). Three different composites are investigated as potential electrode materials for the electrochemical capacitors. Two of the composites contain carbon nanotubes (ox-CNTs), functionalized by acid oxidation process (65% HNO3, 120 °C). The third composite...

• Investigation of poly(3,4-ethylenedioxythiophene) deposition method influence on properties of ion-selective electrodes based on bis(benzo-15-crown-5) derivatives

  Publication

  • M. Jeszke
  • K. Trzciński
  • J. Karczewski
  • E. Luboch

  - ELECTROCHIMICA ACTA - Year 2017

  Glassy carbon electrodes modified by conductive polymers and membrane with derivatives of bis(benzo-15-crown-5) were tested as solid contact ion selective electrodes for K+ ions concentration determination. PEDOT with PSS, Cl- and ClO4- counter ions was electrochemically deposited onto glassy carbon substrates using four different electrochemical approaches (potentiostatic, galvanostatic, potentiodynamic and potentiostatic pulses)....

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• Transport of alkali metal cations in poly(3,4-ethylenethiophene) films.

  Publication

  • A. Lisowska-Oleksiak
  • A. Kupniewska

  - SOLID STATE IONICS - Year 2003

  Elektrochemicznie otrzymana warstwa kompozytowa złożona z poli(3,4-etyleno-dioksytiofenu) i poli(styrenosulfonianu) podczas polaryzacji ulega odwracalnemu procesowi sorpcji-desorpcji kationów z elektrolitu zewnętrznego. Transportowi jonowemu towarzyszą cząsteczki wody (rozpuszczalnika). Ilość cząsteczek wody przypadająca na jednostkowy kation metali alkalicznych została wyznaczona za pomocą metody elektrochemicznej mikrowagi...

• Properties of electrode modified with poly(3,4-ethylenedioxytiophene) and Pt particles.

  Publication

  • S. Białłozór
  • A. Kupniewska
  • V. Jasulajtiene

  - Year 2004

  Właściwości warstw polimerowych poli(3,4-etylenodioksytiofenu)z cząstkami platyny zbadano pod względem zastosowania do reakcji utlenienia związków organicznych. Stwierdzono, bez wnikania w mechanizmy i kinetykę reakcji, że właściwości fizyczne jak i chemiczne (zdolność do katalizowania reakcji utlenienia alkoholi) zależą od materiału podłoża: Pt, węgiel szklisty, tytan, złoto.

• Poly(3,4-ethynenedioxythiophene)-Prussian Blue hybrid material evidence of direct chemical interaction betwenn PB andpEDOT

  Publication

  • A. Lisowska-Oleksiak
  • A. Nowak
  • V. Jasulajtiene

  - Year 2005

  Przedstawiono syntezę materiału złożonego z poli(3,4-etylenodioksytiofenu) oraz analogu błękitu pruskiego. Sieć struktury BP utworzona została wewnątrz matrycy polimerowej pEDOT-u za pomocą metody polaryzacji multicyklicznej. Chemiczne oddziaływania Fe z BP oraz siarki z pEDOT zostały potwierdzone metodą XPS. Obecność BP potwierdzono FTiR - stwierdzono obecność drgań rozciągających Fe-C oraz Fe-N. Metoda cyklowoltamperometryczna...

• The effect of PEDOT morphology on hexavalent chromium reduction over 2D TiO2/PEDOT photocatalyst under UV–vis light

  Publication

  • A. Sulowska
  • A. Fiszka Borzyszkowska
  • K. Cysewska
  • K. Siwińska-Ciesielczyk
  • K. Nikiforow
  • G. Trykowski
  • A. Zielińska-Jurek

  - MATERIALS CHEMISTRY AND PHYSICS - Year 2023

  The present study represents an approach to apply organic-inorganic hybrid materials for photocatalytic removal of heavy metals from the aqueous environment. The photocatalytic activity of the semiconductor modified with the conjugated polymer may depends on the conjugated polymer type, its amount and morphology. Therefore, in the present study the effect of poly (3, 4-ethylenedioxythiophene) (PEDOT) morphology on adsorption and photoreduction...

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• Synthesis and photoelectrochemical behaviour of hydrogenated titania nanotubes modified with conducting polymer infiltrated by redox active network

  Publication

  • K. Siuzdak
  • M. Szkoda
  • J. Karczewski
  • J. Ryl
  • A. Lisowska-Oleksiak

  - ELECTROCHIMICA ACTA - Year 2016

  In this work, we show preparation of ordered inorganic-organic composite electrode material where hydrogenated titania nanotubes H-TiO2 with tubularly developed surface modified with poly(3,4-ethylenedioxythiophene) matrix permeated by Prussian Blue (PB) inorganic redox network in order to reach highly photoactive heterojunction. The polymer deposition was realized via two subsequent processes covering: i) potentiostatic polymerization...

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• Electrochemical characterization of a composite comprising PEDOT/PSS and N doped TiO2 performed in aqueous and non-aqueous electrolytes

  Publication

  • K. Trzciński
  • A. Lisowska-Oleksiak

  - SYNTHETIC METALS - Year 2015

  Nitrogen doped titania (N-TiO2) was used as an inorganic component of composite electrodes containing poly(3,4-ethylenedioxythiophene) with poly(4-styrenesulphonate) PEDOT/PSS/N-TiO2. The composite materials were obtained by direct electrodeposition from an N-TiO2 suspension containing polyelectrolyte (NaPSS) and monomer EDOT. The electrodes were electrochemically tested in aqueous and non-aqueous electrolytes using cyclic voltammetry...

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• Investigation of sweet substances of different molecular structure by potentiometric taste sensor with all solid state electrodes

  Publication

  • E. Marjańska
  • M. Szpakowska

  - Year 2014

  A five channel potentiometric taste sensor consisting of an array of All Solid State Electrodes (ASSESs) with different lipid-polymer membranes has been developed. The electrodes are constructed of glassy carbon discs with electrochemically deposited poly(3,4-ethylenedioxythiophene) (PEDOT) acting as ion to electron transducer. The outer layer of the electrode is lipid-polymer membrane. Lipid substances immobilized in PVC membranes...

• Enhanced photoelectrochemical performance of inorganic-organic hybrid consisting of BiVO4 and PEDOT:PSS

  Publication

  • K. Trzciński
  • M. Szkoda
  • K. SiuzdaK
  • M. Sawczak
  • A. Lisowska-Oleksiak

  - APPLIED SURFACE SCIENCE - Year 2016

  The PEDOT:PSS (poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)) was electrodeposited on a thin layer of bismuth vanadate (BiVO 4 ) prepared using the pulsed laser deposition technique onto FTO. The inorganic-organic junction was characterized by Raman spectroscopy, UV-Vis spectroscopy and sc anning electron microscopy. Chronoamperometry curves, recorded under simulated solar light illumination,...

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• Enhancing electrochemical properties of an ITO-coated lossy-mode resonance optical fiber sensor by electrodeposition of PEDOT:PSS

  Publication

  • M. Sobaszek
  • D. Burnat
  • P. Sezemsky
  • V. Stranak
  • R. Bogdanowicz
  • M. Koba
  • K. Siuzdak
  • M. Śmietana

  - Optical Materials Express - Year 2019

  A sensor working in multiple domains may offer enhanced information about the properties of an investigated analyte, including those containing biological species. It has already been shown that a dual-domain sensing capability, i.e., in optical and electrochemical domains, can be offered by lossy-mode resonance (LMR) sensors based on indium-tin-oxide (ITO) thin film. The spectral response of the LMR sensors depends on the refractive...

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• Influence of electropolymerization conditions on the morphological and electrical properties of PEDOT film

  Publication

  • K. Cysewska
  • J. Karczewski
  • P. Jasiński

  - ELECTROCHIMICA ACTA - Year 2015

  In this work the effects of electropolymerization conditions on the morphological properties and conductivity of poly(3,4-ethylenedioxythiophene) (PEDOT) film have been studied. PEDOT films were electrochemically synthesized in a one step process from acetonitrile solution containing 3,4-ethylenedioxythiophene (EDOT) and lithium perchlorate. Based on atomic force microscopy, scanning electron microscopy, cyclic voltammetry and...

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• Electrical Interface Parameters of PEDOT: PSS: Effect of Electrodeposition Charge Evaluated Under Body Conditions for Neural Electrode Applications

  Publication

  • M. T. Tourchi Moghadam
  • K. Cysewska

  - JOURNAL OF THE ELECTROCHEMICAL SOCIETY - Year 2024

  This study explores the influence of the deposition charge of poly(3,4-ethylenedioxythiophene) doped with polystyrene sulfonate (PEDOT:PSS) on its electrical interface parameters. For this purpose, PEDOT:PSS was fabricated by electrodeposition on commercial platinum electrodes with the time limited by different charges (1, 3, 6, 9 mC). Further, the electrodes were characterized regarding their electrical interface such as interfacial...

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• Nitrogen dioxide sensing properties of PEDOT polymer films

  Publication

  • K. Dunst
  • J. Karczewski
  • P. Jasiński

  - SENSORS AND ACTUATORS B-CHEMICAL - Year 2017

  This work presents a simple and fully electrochemical route for the polymerization of poly(3,4-ethylenedioxytiophene) (PEDOT) films for fabricating a NO2 gas sensor prepared by electropolymerization of 3,4-Ethylenedioxythiophene (EDOT) monomer in lithium perchlorate/acetonitrile solution. The main aim of this study is to determine the sensing properties of conductive polymer at elevated temperatures. The effects of the humidity,...

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• Solid-Contact Ion-Selective Electrodes with Highly SelectiveThioamide Derivatives of p-tert-Butylcalix[4]arene for theDetermination of Lead(II) in Environmental Samples

  Publication

  • M. Guziński
  • G. Lisak
  • T. Sokalski
  • J. Bobacka
  • A. Ivaska
  • M. Bochenska
  • A. Lewenstam

  - ANALYTICAL CHEMISTRY - Year 2013

  Thioamide derivatives of p-tert-butylcalix[4]arene were used as ionophores in the development of solid-contact ion-selective electrodes based on conducting polymer poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT/PSS) which was synthesized by electrodeposition on the glassy carbon electrodes. The typical ion-selective membranes with optionally two different plasticizers [bis(2-ethylhexyl)sebacate (DOS) and 2-nitrophenyl...

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• Improving the Performance of a Graphite Foil/Polyaniline Electrode Material by a Thin PEDOT:PSS Layer for Application in Flexible, High Power Supercapacitors

  Publication

  • Z. Zarach
  • K. Trzciński
  • M. S. Łapiński
  • A. Lisowska-Oleksiak
  • M. Szkoda

  - Materials - Year 2020

  In this study, we present a novel strategy for enhancing polyaniline stability and thus obtaining an electrode material with practical application in supercapacitors. A promising (graphite foil/polyaniline/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) GF/PANI/PEDOT:PSS) electrode material was characterized and used in the construction of a symmetric supercapacitor that provides an outstanding high power density. For this...

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• Highly stable organic–inorganic junction composed of hydrogenated titania nanotubes infiltrated by a conducting polymer

  Publication

  • K. Siuzdak
  • M. Szkoda
  • A. Lisowska-Oleksiak
  • J. Karczewski
  • J. Ryl

  - RSC Advances - Year 2016

  A poly(3,4-ethylenedioxythiophene) conducting polymer doped with poly(2-styrene sulfonate) (pEDOT:PSS) was efficiently electrodeposited on a layer composed of ordered titania nanotubes. TiO2 nanotubes were formed during an anodization process and, after calcinations, a layer was subjected to hydrogen plasma. Hydrogenation leads to Ti(III) formation, a decrease in resistance, and a huge increase of donor density when compared with...

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• Electrodes consisting of PEDOT modified by Prussian Blue analogues deposited onto titania nanotubes – Their highly improved capacitance

  Publication

  • M. Szkoda
  • K. Trzciński
  • J. Rysz
  • M. Gazda
  • K. Siuzdak
  • A. Lisowska-Oleksiak

  - SOLID STATE IONICS - Year 2017

  In this work we present the outstanding energy storage of prepared inorganic-organic heterojunction where hydrogenated ordered titania nanotubes (H-TiO2NT) were modified by the hybrid made of poly(3,4-ethylenedioxythiophene) (pEDOT) and iron hexacyanoferrate centres (Fehcf, Prussian Blue). The material TiO2NT/pEDOT:Fechf was obtained electrochemically by means of: anodization, hydrogenation and finally, electropolymerization of...

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• Fabrication and photoactivity of organic-inorganic systems based on titania nanotubes and PEDOT containing redox centres formed by different Prussian Blue analogues

  Publication

  • M. Szkoda
  • J. Rysz
  • J. Ryl
  • A. Lisowska-Oleksiak
  • K. Siuzdak

  - JOURNAL OF ALLOYS AND COMPOUNDS - Year 2017

  Herein, the heterojunction composed of an inorganic substrate: ordered hydrogenated titania nanotubes (H-TiO2NTs) and a deposited organic film: poly(3,4-ethylenedioxythiophene) (PEDOT) is reported. The conducting polymer is modified with different transition metal haxacyanoferrates (Mehcf), wherein as metal: copper, iron, cobalt and nickel are introduced. The presence of various metal centres provides characteristic redox activity...

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• Flexible dye-sensitized solar cells based on Ti/TiO2 nanotubes photoanode and Pt-free and TCO-free counter electrode system

  Publication

  • M. Klein
  • M. Szkoda
  • M. Sawczak
  • A. Cenian
  • A. Lisowska-Oleksiak
  • K. Siuzdak

  - SOLID STATE IONICS - Year 2017

  Flexible dye-sensitized solar cells (DSSCs) are getting more attention compared to standard glass covered DSSCs due to their unique commercial applications (e.g. tents or sail surfaces) and the possibility of rolling up into a small, portable device. In this work, titania nanotubes (TiO2 NT) modified with titania nanoparticles (TiO2 NP) were photoelectrochemically characterized as an anode for flexible dye-sensitized solar cells....

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• Understanding the capacitance of thin composite films based on conducting polymer and carbon nanostructures in aqueous electrolytes

  Publication

  • A. Cymann-Sachajdak
  • M. Graczyk-Zajac
  • G. Trykowski
  • M. Wilamowska-Zawłocka

  - ELECTROCHIMICA ACTA - Year 2021

  In this work electrochemical performance of thin composite films consisted of poly(3,4-ethylenedioxythiophene) (PEDOT), graphene oxide (GOx) and oxidized multiwalled carbon nanotubes (oxMWCNTs) is investigated in various sulphates (Li2SO4, Na2SO4, K2SO4, MgSO4) and acidic (H2SO4) electrolytes. Capacitance values, rate capability and cycling stability achieved for the composite layers are correlated with the electrolytes’ properties...

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• Laser patterned platform with PEDOT–graphene composite film for NO2 sensing

  Publication

  • K. Dunst
  • D. Jurków
  • P. Jasiński

  - SENSORS AND ACTUATORS B-CHEMICAL - Year 2016

  This work presents a simple and fully electrochemical route used for fabricating of a NO2 gas sensor made of reduced-graphene-oxide-poly(3,4-ethylenedioxythiophene) composite film. The sensing platform was fabricated from alumina substrate and equipped with gold interdigitated electrodes and built-in heater.The temperature distribution on the surface of interdigitated electrodes was investigated by a thermalimaging camera and compared...

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• Synthesis, structure characterization and thermal propertiesof [Zr₆(μ₃-O)₄(μ₃-OH)₄(OOCCH₂^tBu)₉(μ₂-OH)₃]₂

  Publication

  • P. Piszczek
  • A. Bradtke
  • A. Wojtczak
  • T. Muzioł
  • J. Chojnacki

  - POLYHEDRON - Year 2009

  Tytułowy związek otrzymano w reakcji Zr(OiPr)4 z nadmiarem kwasu 3,3-dimetylobutyrowego. Rentgenowska analiza strukturalna została wykonana w temperaturze 103 i 153K. Struktury zawierają dimery podjednostek o wzorze: [Zr6(μ3-O)4(μ3-OH)4-(OOCCH2tBu)9] połączonych 6 mostkującymi grupami μ2-OH. Analiza zmiennotemperaturowych...

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• The first manganese trialkoxysilanethiolates: formation, properties and structure of solvent ligated complexes - [Mn{SSi(OBut)3}2(MeCN)] and [Mn{SSi(OBut)3}2(MeOH)4]

  Publication

  • A. Mietlarek-Kropidłowska
  • J. Chojnacki
  • B. Becker

  - INORGANIC CHEMISTRY COMMUNICATIONS - Year 2006

  W pracy przedstawiono otrzymywanie i strukturę pierwszych trialkoksysilanotiolanowych kompleksów manganu(II). Syntezy prowadzone były reakcji 2≡SiSH+ MnCl2 + 2Et3N = (≡SiS)2Mn + 2Et3N.HCl doprowadziły do otrzymania nowych kompleksów: [Mn{SSi(OBut)3}2(MeOH)4] (gdy jako rozpuszczalnik zastosowano MeOH) oraz [Mn{SSi(OBut)3}2(NCCH3)], gdy w badaniach posłużono się acetonitrylem.

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• Crystal structures of (E)-3-(4-hydroxybenzylidene)chroman-4-one and (E)-3-(3-hydroxybenzylidene)-2-phenylchroman-4-one

  Publication

  • K. Suchojad
  • A. Dołęga
  • A. Adamus-Grabicka
  • E. Budzisz
  • M. Małecka

  - Acta Crystallographica Section E CRYSTALLOGRAPHIC COMMUNICATIONS - Year 2019

  The synthesis and crystal structures of (E)-3-(4-hydroxybenzylidene)chroman-4-one, C16H12O3,I, and (E)-3-(3-hydroxybenzylidene)-2-phenylchroman-4-one,C22H16O3,II, are reported. These compounds are of interest with respect to biological activity. Both structures display intermolecular C—H---O and O—H---O hydrogen bonding, forming layers in the crystal lattice. The crystal structure of compound I is consolidated...

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• The influence of polarization of titania nanotubes modified by a hybrid system made of a conducting polymer PEDOT and Prussian Blue redox network on the Raman spectroscopy response and photoelectrochemical properties

  Publication

  • M. Szkoda
  • G. Nowaczyk
  • A. Lisowska-Oleksiak
  • K. Siuzdak

  - ELECTROCHIMICA ACTA - Year 2018

  In this work we show the impact of applied potential on network vibrations and photoelectrochemical properties of a composite material containing hydrogenated titania nanotubes and poly (3,4-ethylenedioxythiophene) with iron hexacyanoferrate (H-TiO2/pEDOT:Fehcf) acting as a redox centre. For this purpose, Raman spectroscopy measurements under the working electrode (WE) polarization were carried out, allowing investigation of changes...

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• Structure-property relationships in peroxide-assisted blends of poly(ε-caprolactone) and poly(3-hydroxybutyrate)

  Publication

  • M. Przybysz-Romatowska
  • Ł. Zedler
  • M. Saeb
  • K. Formela

  - REACTIVE & FUNCTIONAL POLYMERS - Year 2018

  Poly(ε-caprolactone) and poly(3-hydroxybutyrate) (PCL/PHB) blends in two weight ratios (75/25 and 50/50) were reactively compatibilized in the presence of di-(2-tert-butyl-peroxyisopropyl)-benzene and dicumyl peroxide as free radical initiators. Rheological, mechanical, thermal properties and morphological features, as well as the chemical structure of PCL/PHB blends were investigated. It was found that regardless of PCL/PHB blend...

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• Preparation and evaluation of 1,3-alternate 25,27-bis[p-nitrobenzyloxy]-26,28-bis[3-propyloxy]-calix[4]arene-bonded silica gel stationary phase for LC

  Publication

  • K. Jaszczołt
  • M. Śliwka-Kaszyńska

  - CHROMATOGRAPHIA - Year 2007

  Przeprowadzono syntezę nowej fazy stacjonarnej na bazie sililowej pochodnej 25,27-bis[p-nitrobenzyloksy]-26,28-bis-[3-propyloksy]kaliks[4]arenu zablokowanego w konformacji 1,3-naprzemianległej. Zbadano selektywność i sprawność fazy w stosunku do szeregu klas związków organicznych techniką wysokosprawnej chromatografii cieczowej.

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• Preparation and HPLC evaluation of a new 1,3-alternate 25,27-bis-[p-chlorobenzyloksy]26,28-bis-[3-propyloxy]-calix[4]arene silica bonded stationary phase

  Publication

  • M. Śliwka-Kaszyńska
  • S. Karaszewski

  - JOURNAL OF SEPARATION SCIENCE - Year 2008

  Przeprowadzono syntezę nowej fazy stacjonarnej HPLC na bazie pochodnej 25,27-bis-[p-chlorobenzyloksy]26,28-bis-[3-propyloksy]-kaliks[4]arenu zablokowanego w konformacji 1,3-naprzemianległej. Zbadano selektywność i sprawność fazy w stosunku do aromatycznych izomerów pozycyjnych, alkilobenzenów, WWA, sulfonamidów i niesterydowych leków przeciwbólowych.

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• The structure of novel polyurethanes containing synthetic poly[(R,S)-3-hydroxybutyrate]

  Publication

  • J. Brzeska
  • P. Dacko
  • K. Gębarowska
  • H. Janik
  • B. Kaczmarczyk
  • J. Kasperczyk
  • M. Kowalczuk
  • M. Rutkowska

  - JOURNAL OF APPLIED POLYMER SCIENCE - Year 2012

  The aim of this study was to estimate the structure of new polyurethanes with the potential to be used in medicine. Atactic poly[(R,S)-3-hydroxybutyrate], obtained via a ring-opening polymerization, and polycaprolactonediol or polyoxytetramethylenediol were used to built the soft segments. 4,4'-methylene dicyclohexyl diisocyanate and 1,4-butanediol were the components to form hard segments. Polyurethanes with low-molecular weight...

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• Chitosan/poly(4-vinylpyridine) coatings formed on AgNPs-decorated titanium

  Publication

  • Ł. Pawłowski
  • M. Bartmański
  • A. D. Mielewczyk-Gryń
  • A. Zieliński

  - MATERIALS LETTERS - Year 2022

  Electrophoretic deposition (EPD) of chitosan/poly(4-vinylpyridine) (chit/P4VP) coatings on titanium substrates previously decorated with silver nanoparticles (AgNPs) was performed at different content of P4VP in the suspension and different voltage values. The results revealed that the composite coatings were formed, well-adjacent to the titanium substrate, of suitable roughness, hydrophilicity, and corrosion resistance. The voltage...

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• 3 d 3 system – Comparison of Mn 4+ and Cr 3+ in different lattices

  Publication

  • M. Grinberg
  • T. Lesniewski
  • S. Mahlik
  • R. Liu

  - OPTICAL MATERIALS - Year 2017

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• Preparation and evaluation of 1,3-alternate 25,27-dibenzyloxy-26,28-bis-[3-propyloxy]-calix[4]arene - bonded silica stationary phase for high performance liquid chromatography

  Publication

  • M. Śliwka-Kaszyńska
  • K. Jaszczołt
  • A. Hoczyk
  • J. Rachoń

  - CHEMIA ANALITYCZNA - Year 2006

  Otrzymano nową fazę stacjonarną na bazie dibenzyloksy pochodnej kaliks[4]arenu w konformacji 1,3-naprzemianległej, chemicznie związaną z żelem krzemionkowym. Przeprowadzano badania selektywności i sprawności tej fazy w rozdzielaniu izomerów konstytucyjnych benzenu i pochodnych fenoli. Zaprezentowano wyniki badania wpływu pH fazy ruchomej oraz stężenia metanolu na zdolność rozdzielczą nowej fazy stacjonarnej.

• Curing behavior of epoxy/Fe 3 O 4 nanocomposites: A comparison between the effects of bare Fe 3 O 4 , Fe 3 O 4 /SiO 2 /chitosan and Fe 3 O 4 /SiO 2 /chitosan/imide/phenylalanine-modified nanofillers

  Publication

  • M. Jouyandeh
  • S. Paran
  • M. Shabanian
  • S. Ghiyasi
  • H. Vahabi
  • M. Badawi
  • K. Formela
  • D. Puglia
  • M. Saeb

  - PROGRESS IN ORGANIC COATINGS - Year 2018

  In this study, Fe3O4 magnetic nanoparticles (MNPs) were synthesized (B-MNP) and then modified with SiO2 to form Fe3O4/SiO2 core/shell MNPs. The Fe3O4/SiO2 MNPs were chemically functionalized with chitosan so as to gain Fe3O4/SiO2/Chitosan (CH-MNP). The CH-MNP was functionalized with a macromolecule containing imide and phenylalanine precursors to gain Fe3O4/SiO2/Chitosan/imide/phenylalanine based MNPs (CH-IM-MNP). The differences...

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• Synthesis and steroid sulfatase inhibitory activities of N-phosphorylated 3-(4-aminophenyl)-coumarin-7-O-sulfamates

  Publication

  • M. Daśko
  • M. Masłyk
  • K. Kubiński
  • J. Aszyk
  • J. Rachoń
  • S. Demkowicz

  - MedChemComm - Year 2016

  In the present work, we report convenient methods for the synthesis and biological evaluation of N-phosphorylated derivatives of 3-(4-aminophenyl)-coumarin-7-O-sulfamate as potential steroid sulfatase (STS) inhibitors. Their binding modes were modeled using docking techniques. The inhibitory effects of the synthesized compounds were tested on STS isolated from human placenta. All of the newly synthesised coumarin derivatives were...

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