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Diastereoselective formation of glucoluril dimers: isomerization mechanismand implications for cucurbit[n]uril synthesis
PublicationZaprezentowano syntezę pochodnych glikolurylu tworzących ściśle sprecyzowane dimeryczne struktury w roztworze wodnym. Opisano diastereoselektywną syntezę pochodnych o strukturze amfifilowej. Przedstawiono mechanizm reakcji oraz struktury krystalograficzne wybranych związków.
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Preparation of Ag/Cu-doped titanium (IV) oxide nanoparticles in W/O microemulsion
PublicationNanocząstki Cu-TiO2 oraz Ag/Cu-TiO2 otrzymano w mikroemulsji W/O. Właściwości fotokatalityczne zbadano w procesie degradacji fenolu (0,21mM) w zakresie światła widzialnego. Właściwości biobójcze zbadano poprzez wyznaczenie minimalnego stężenia zahamowania wzrostu (MIC) na szczepach bakterii E. coli, St. aureus oraz grzybów S. Cerevisiae i z rodziny Candida. Dla otrzymanych fotokatalizatorów określono wpływ stężenia domieszki metali...
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photocatalytic activity of silver doped tio2 in vis and uv light, prepared by microemulsion method
PublicationDitlenek tytanu otrzymany w wyniku hydrolizy izopropanolanu tytanu oraz komercyjny katalizator TiO-6 (Catalysis Society of Japan, rutyl, wielkość cząstek 15 nm) zmodyfikowano srebrem metodą mikroemulsyjną. Aktywność fotokatalityczna otrzymanych nanokompozytów Ag-TiO2 została zbadana dla fotodegradacji fenolu pod działaniem promieniowania ultrafioletowego oraz widzialnego. Zaobserwowano, że na efektywność fotorozkładu modelowego...
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Influence of Al3+co-doping on the spectral properties of europium doped Ca9Y(PO4)7
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Chromium(III)-Doped Fluoride Phosphors with Broadband Infrared Emission for Light-Emitting Diodes
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Evolution of the optical properties of chromium doped calcium tetraborate glass under high pressure
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High-pressure spectroscopy characterisation of LiSc(WO4)2 crystals doped with trivalent chromium
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Ultraviolet to near-infrared down-conversion in Bi3+–Yb3+ co-doped YAM phosphor
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Optical properties of pure and Ce3+ doped gadolinium gallium garnet crystals and epitaxial layers
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Nitrogen-doped porous carbon embedded with cobalt nanoparticles for excellent oxygen reduction reaction
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Influence of electropolymerization temperature on corrosion, morphological and electrical properties of PPy doped with salicylate on iron
PublicationIn this work, the influence of the electropolymerization temperature on corrosion, morphological and electrical properties of polypyrrole (PPy) film is studied. Polypyrrole is electrochemically synthesized on iron in the presence of sodium salicylate. The X-ray diffraction and scanning electron microscopy are performed in order to study the structure and morphology of electrodeposited PPy. The electroactive surface area, corrosion...
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Salt melt synthesis of curved nitrogen-doped carbon nanostructures: ORR kinetics boost
PublicationImplementing metal-free electrocatalysts for the oxygen reduction reaction (ORR) and revealing crucial chemical or topographical parameters driving their activity are vital for the development of power cells. The carbon-based catalysts are very often synthesized through carbonization of biopolymers, in particular, those one containing nitrogen groups such as chitosan. Unfortunately, the resulting carbonaceous materials usually...
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Bismuth-Doped Nano Zerovalent Iron: A Novel Catalyst for Chloramphenicol Degradation and Hydrogen Production
PublicationIn this study, we showed that doping bismuth (Bi) at the surface of Fe0 (Bi/Fe0, bimetallic iron system)—synthesized by a simple borohydride reduction method—can considerably accelerate the reductive degradation of chloramphenicol (CHP). At a reaction time of 12 min, 62, 68, 74, 95, and 82% degradation of CHP was achieved with Fe0, Bi/Fe0-1 [1% (w/w) of Bi], Bi/Fe0-3 [3% (w/w) of Bi], Bi/Fe0-5 [5% (w/w) of Bi], and Bi/Fe0-8 [8%...
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Optically transparent boron-doped nanocrystalline diamond films for spectroelectrochemical measurements on different substrates
PublicationFabrication process of optically transparent boron nanocrystalline diamond (BNCD) electrode on silicon and quartz substrate was shown. The B-NCD films were deposited on the substrates using Microwave Plasma Assisted Chemical Vapor Deposition (MWPACVD) at glass substrate temperature of 475 ºC. A homogenous, continuous and polycrystalline surface morphology with high sp3 content in B-NCD films and film thickness depending from substrate...
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Structural and catalytic properties of ceria layers doped with transition metals for SOFCs fueled by biogas
PublicationThe aim of this paper was to investigate an influence of the nanocrystalline Ce0.8A0.2O2-δ (A = Mn, Fe, Co, Ni, Cu) materials on the direct internal reforming of biogas in SOFC. Structural analysis of fabricated compounds has been done. An in-situ analysis of a composition of outlet gases from operating SOFC was performed using FTIR spectroscopy with simultaneous electrical tests. It was found out, that type of dopant strongly...
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Organic electroluminescent devices containing phosphorescent molecules in molecularly doped hole transporting layer.
PublicationW pracy opisano mechanizm świecenia diody dwuwarstwowej diody elektroluminescencyjnej (EL) o zewnętrznej kwantowej wydajności świecenia osiągającej 9% fot./elektron. Warstwę transportującą elektrony tworzyła pochodna osadiazolu (PBD) otrzymana metodąnaparowania próżniowego. Warstwę transportującą dziury uzyskano przez wylanie roztworu poliwęglanu(PC), dendrymeru aminowego m-MTDATAoraz fosforyzującego kompleksu irydu Ir(ppy)3 i...
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The microstructure effect on the electrical and optical properties of undoped and Sr-doped SmCoO3 thin films.
PublicationW pracy przedstawiono elektryczne i optyczne właściwości niedomieszkowanego i domieszkowanego Sr SmCoO3 cienkich filmów. Gęste i przezroczyste filmy o grubościach 80-100nm były przygotowane na szafirze metodą nanoszenia wirowego ciekłych polimerów. Filmy były syntezowane w temperaturach od 500 do 800C co umożliwiło otrzymanie różnych mikrostruktur. Elektryczne właściwości filmów były mierzone w funkcji temperatury. Domieszkowanie...
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Analysis of the grain boundary conductivity for nanocrystalline doped ceria using the brick layer model.
PublicationW pracy przedstawiono wyniki badań elektrycznych i mikrostrukturalnych ceru domieszkowanego itrem. Gęste i nanokrystaliczne filmy przygotowane zostały z użyciem prekursorów polimerowych na szafirze. Konduktancja elektryczna była badana w funkcji temperatury syntezy, która jest skorelowana z wielkością ziaren. Otrzymano mniejszą konduktancję nanokrystalicznego filmu ceru w porównaniu z próbkami ceramicznymi.
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Application of safirinium N-hydroxysuccinimide esters to derivatization of peptides for high-resolution mass spectrometry, tandem mass spectrometry, and fluorescent labeling of bacterial cells
PublicationMass spectrometry methods are commonly used in the identification of peptides and biomarkers. Due to a relatively low abundance of proteins in biological samples, there is a need for the development of novel derivatization methods that would improve MS detection limits. Hence, novel fluorescent N-hydroxysuccinimide esters of dihydro-[1,2,4]triazolo[4,3-a]pyridin-2-ium carboxylates (Safirinium P dyes) have been synthesized. The...
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Efficient Recovery of Noble Metal Ions (Pd2+, Ag+, Pt2+, and Au3+) from Aqueous Solutions Using N,N'-Bis(salicylidene)ethylenediamine (Salen) as an Extractant (Classic Solvent Extraction) and Carrier (Polymer Membranes)
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Surface quality of the plasma cermet coatings after grind finishing
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Synthesis and molecular structure of novel 2-(alkylthio)-4-chloro-N-(4,5-dihydro-5-oxo-1H-1,2,4-triazol-3-yl)-5-methylbenzenesulfonamideswith potential anticancer activity
PublicationOtrzymano 15 nowych związków: 2-(alkilotio)-4-chloro-N-(4,5-dihydro-5-oxo-1H-1,2,4-triazol-3-yl)-5-metylobenzenosulfonamidów, dla których opracowano nową metodę syntezy. Dla jednej pochodnej wyznaczono strukturę rentgenowską. Związek nr 36 wykazuje wysoką aktywność przeciwnowotworową w stosunku do 13 linii komórek nowotworowych o poziomie GI_50 w zakresie stężeń 1,9-3,0 μM.
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Gdansk 2020, Strzelecka (N) street - video data - pedestrian, bicycles, vehicles
Open Research DataThe data contain video traffic data (pedestrian, cyclists, vehicles) registered at Strzelecka street. Date 06.08.2020, 6:00-20:00. The video camera was installed around bicycle crossings and pedestrian crossings at Strzelecka - Nowe Ogrodycrossing. Camera was mounted on 7-meter-high mast.
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Etazene (N,N-diethyl-2-{[(4-ethoxyphenyl)methyl]-1H-benzimidazol-1-yl}-ethan-1-amine (dihydrochloride)): a novel benzimidazole opioid NPS identified in seized material: crystal structure and spectroscopic characterization
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Anion–cation interactions in a series of salts with substituted Hphen, Hbpy and H2bpy cations and [W(CN)8]4− anion: polymer with “super-short” N–H⋯N hydrogen bridges containing exclusively anions and H+
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Visnyk of V N Karazin Kharkiv National University-Series Geology Geography Ecology
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The von Neumann entanglement entropy for Wigner-crystal states in one dimensional N-particle systems
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Comparison of n-tetradecane/electrolyte emulsions properties stabilized by DPPC and DPPC vesicles in the electrolyte solution
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Effect of Temperature on n-Tetradecane Emulsion in the Presence of Phospholipid DPPC and Enzyme Lipase or Phospholipase A2
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Missing the sweet spot: one of the two N-glycans on human Gb3/CD77 synthase is expendable
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Aryl and N-arylamide carbon nanotubes for electrical coupling of laccase to electrodes in biofuel cells and biobatteries
PublicationSingle walled carbon nanotubes (SWCNTs) were equipped with aryl residues by chemical reactions. These insoluble materials were used to substitute classical soluble mediators, which help to transfer electrical charge between the conducting electrode and the redox active center of enzyme molecules. The effect of different aryl residues on the efficiency of the catalytic reduction of dioxygen in the presence of laccase was systematically...
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Fluorescent Submicron-Sized Poly(heptafluoro-n-butyl methacrylate) Particles with Long-Term Stability
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CLICK 'n' Sleep: Light-Switch Behavior of Triazole-Containing Tris(bipyridyl)ruthenium Complexes
PublicationA set of RuII complexes incorporating triazole subunits are presented. They show a solvent-dependent light-switch effect. Theoretical calculations revealed the excited states involved in the emission process. The findings are highly important for future design of light-switch sensors and suggest a severe restriction for functional photomolecular devices synthesized by CLICK chemistry.
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Monitoring of n-butanol vapors biofiltration process using an electronic nose combined with calibration models
PublicationMalodours, by definition, are generally unpleasant, nuisance smells that are a mixture of volatile chemical compounds which can be perceptible even at low concentrations. Due to the more frequent occurrence of odour nuisance associated with the odour sensations, and thus the need to remove them from the air, deodorization techniques are commonly used. Biofiltration is one of the methods of reducing odorants in the air stream. In...
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Dual-emission Eu-doped Ca2−xSrxPN3 nitridophosphate phosphors prepared by hot isostatic press
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Synthesis and luminescence characteristics of Dy3+ ions in silica xerogels doped with Ln2−xDyx(WO4)3
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Efficient removal of dyes and proteins by nitrogen-doped porous graphene blended polyethersulfone nanocomposite membranes
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Influence of attenuation on self-organized second-harmonic generation in a germanium-doped microstructured silica fiber
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Enhanced capacitance of composite TiO2 nanotube/boron-doped diamond electrodes studied by impedance spectroscopy
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Composite thermoluminescent detectors based on the Ce3+ doped LuAG/YAG and YAG/LuAG epitaxial structures
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The Superiority of TiO2 Supported on Nickel Foam over Ni-Doped TiO2 in the Photothermal Decomposition of Acetaldehyde
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Selectivity of Pb(II) transport across polymer inclusion membranes doped with imidazole azothiacrown ethers
PublicationMembrany wykonane z trioctanu celulozy zawierające jako jonofor 18 i 21-członowe azotiakorony z resztą imidazolu w makropierścieniu przebadano pod kątem transportu jonów Zn(II), Cd(II) i Pb(II) z wodnego roztworu soli (pH ~5.5, cMe = 0,001 M). W wyniku badań ustalono, że jon Pb(II) może być efektywnie wydzielony z roztworu mieszaniny jonów Pb(II), Zn(II), Co(II), Ni(II), Cu(II) i Cd(II).Sekwencja selektywności transportu dla 18-członowej...
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Superconductivity and appearance of negative magnetocaloric effect in Ba1–xKxBiO3 perovskites, doped by Y, La and Pr
PublicationRecently, substantial attention is given to the bismuth-based perovskites for variety of electronic applications. The perovskites are used for quantum dots displays (QLED), photovoltaic systems and superconducting (HTS) devices. In this paper comprehensive studies of Ba1–xKxBi1–yREyO3 bismuth perovskites (REBKBO, RE = Y , La or Pr) are reported. Apart from structural anomalous behavior at low temperatures, the electronic properties...
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DC and AC Conductivity, Biosolubility and Thermal Properties of Mg-Doped Na2O–CaO–P2O5 Glasses
PublicationBioactive glasses have recently been extensively used to replace, regenerate, and repair hard tissues in the human body because of their ability to bond with living tissue. In this work, the effects of replacing Na2O with MgO on the electrical, biosolubility, and thermal properties of the target glass 10Na2O–60P2O5–30CaO (in mol%) were investigated. The electrical properties of the glasses were studied with the impedance spectroscopy...
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Heat treatment effect on Eu3+ doped TeO2-BaO-Bi2O3 glass systems with Ag nanoparticles.
PublicationGlass systems of 73TeO2-4BaO-3Bi2O3-2Eu2O3-xAg ( in molar ratio where x= 0, 1, 2, 3) compositions have been successfully synthesized. Silver nanoparticles were obtained with the employment of heat treatment (HT) procedure executed at 350 °C. Glass transition temperatures of different compositions have been determined through DSC measurements. XRD measurement results presented characteristic amorphous halo indicating lack of long...
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Synthesis, thermal, structural and electrical properties of vanadium-doped lithium-manganese-borate glass and nanocomposites
PublicationA glassy sample with a nominal formula LiMn1−3x/2VxBO3 (where x = 0.05) was synthesised using the melt-quenching method. Material was characterised by differential thermal analysis (DTA), X-ray diffactometry (XRD) at room temperature and as a function of temperature (HT-XRD), X-ray photoelectron spectroscopy (XPS), impedance spectroscopy (IS) and scanning electron microscopy (SEM). Dependences of glass transition and crystallisation...
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Preparation of DNA films for studies under vacuum conditions. The influence of cations in buffer solutions
PublicationBadania zostały przeprowadzone w celu określenia optymalnych warunków wymaganych do przygotowania jednolitych filmów superskręconego plazmidowego DNA do wykorzystania w doświadczeniach napromieniowania w warunkach wysokiej próżni. Badania pokazują, że znaczne szkody w DNA powstają w wyniku odpompowywania filmów DNA z roztworów zawierających jedynie czysta wodę.
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(2-Ethylimidazole-κN)bis(tri-tert-butoxysilanethiolato-κ2O,S)zinc(II) propan-2-ol solvate
PublicationW publikowanym związku [Zn(C12H27O3SSi)2(C5H8N2)]*C3H8O, atom Zn(II) jest koordynowany przez atom azotu 2-etyloimidazolu, dwa atomy siarki i dwa atomy tlenu pochodzące od reszt tri-tert-butoksysilanotiolanowych, a geometria na atomie cynku(II) jest typu trygonalnej bipiramidy. Grupa hydroksylowa cząsteczki rozpuszczalnika 2-propanolu tworzy dwa wiązania wodorowe typu N-H - O i O-H - S z sąsiednią czasteczkĄ kompleksu, przez co...
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Structure-based design and evaluation of novel N-phenyl-1H-indol-2-amine derivatives for fat mass and obesity-associated (FTO) protein inhibition
PublicationFat mass and obesity-associated (FTO) protein contributes to non-syndromic human obesity which refers to excessive fat accumulation in human body and results in health risk. FTO protein has become a promising target for anti-obesity medicines as there is an immense need for the rational design of potent inhibitors to treat obesity. In our study, a new scaffold N-phenyl-1H-indol-2-amine was selected as a base for FTO protein inhibitors...
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Heteroleptic tri-tert-butoxysilanethiolate complexes of manganese(II) - thermal studies
PublicationThe thermal behavior of Mn(II) silanethiolate series [Mn(SR)2L(MeOH)n], where R=SSi(OBut)3, L=heterocyclic nitrogen base and n=0, 1 or 2 has been comparatively investigated using differential scanning calorimetry (DSC), thermogravimetry (TG) and TG-infrared spectoscopy (IR) techniques. The TG curves indicate the differences in the thermal decomposition due to presence of distinct N-donor ligands and labile MeOH molecules coordinated...