Search results for: REDUCTIVE RADICAL SPECIES
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Reactive oxygen species (ROS) production in human peripheral blood neutrophils exposedin vitroto static magnetic field
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Attraction of Moths of Two Noctuidae Species to Field Traps Baited With a Mixture of two to three Homologous Acetates in Poland
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Species - specific detection of the toxic mushrooms Amanita virosa and Amanita verna by PCR amplification of the gpd gene fragment
PublicationZaprojektowano dwie pary starterów do reakcji PCR, które umożliwiają gatunkowo specyficzną amplifikację unikalnych fragmentów genów gpd dla dwóch grzybów kapeluszowych: muchomora wiosennego (Amanita verna) i muchomora jadowitego (Amanita virosa).
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Efficacy of rice husk biochar and compost amendments on the translocation, bioavailability, and heavy metals speciation in contaminated soil: Role of free radical production in maize (Zea mays L.)
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How to guide photocatalytic applications of titanium dioxide co-doped with nitrogen and carbon by modulating the production of reactive oxygen species
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Polybrominated diphenyl ethers (PBDEs) in raw milk from different animal species and in infant formula. Occurrence and risk assessment
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How the toxicity of nanomaterials towards different species could be simultaneously evaluated: a novel multi-nano-read-across approach
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Occurrence of fungi and cytotoxicity of the species: Aspergillus ochraceus, Aspergillus niger and Aspergillus flavus isolated from the air of hospital wards
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NUMERICAL ANALYSIS OF SPECIES DIFFUSION AND METHANOL DECOMPOSITION IN THERMOCATALYTIC REACTOR BASED ON THE INTERMETALLIC PHASE OF Ni3Al FOR LOW REYNOLDS NUMBERS
PublicationNumerical modelling of hydrogen production by means of methanol decomposition in a thermocatalytic reactor using corrugated foil made of the Ni3Al intermetallic phase is shown in the paper. Experimental results of the flow analysis of mixtures containing helium and methanol in a thermocatalytic reactor with microchannels were used for the initial calibration of the CFD calculations (calculations based on the Computational Fluid...
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MRM–MS of marker peptides and their abundance as a tool for authentication of meat species and meat cuts in single-cut meat products
PublicationThe abundance of protein markers in different types of meat cuts was explored in the context of authentication of raw meat (pork, beef and chicken) and processed meat products. Peptides originating from myoglobin (Mb) and myosin (My) were analyzed using multiple reaction monitoring mass spectrometry (MRM–MS). Analytical protocol was optimized for good repeatability (CV < 10%) and high sensitivity. The MS signal intensity of Mb...
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Methylmercury and total mercury content in soft tissues of two bird species wintering in the Baltic Sea near Gdansk, Poland
PublicationOf the various forms of Hg occurring in nature, (mono) methylmercury (MeHg) is an especially toxic form and practically all forms of Hg can be converted into MeHg as a result of natural processes. Total mercury (THg) and MeHg were determined in tissues of two piscivorous birds: razorbill Alca torda and black-throated loon Gavia arctica to provide baseline data on current mercury concentrations for liver, kidneys and pectoral muscle...
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Genetic identification of a non-native species introgression into wild population of the field cricket Gryllus campestris (Orthoptera: Gryllidae) in Central Europe
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Atmospheric Pressure Glow Discharges Generated in Contact with Flowing Liquid Cathode: Production of Active Species and Application in Wastewater Purification Processes
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Polymorphic microsatellite markers demonstrate hybridization and interspecific gene flow between lumbricid earthworm species, Eisenia andrei and E. fetida
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Prevalence of Closely Related Candida albicans Species among Patients with Vulvovaginal Candidiasis in Southern Poland Based on the hwp1 Gene Amplification
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Determination of Butyltin Species in Sea Water Samples Using Solid Phase Extraction Followed by Liquid Chromatography - Tandem Mass Spectrometry
PublicationReverse phase liquid chromatography (RP-HPLC)-electrospray ionization-tandem mass spectrometry (ESI-MS-MS) was evaluated for the analysis of TBT using solid phase extraction as sample preparation method. TBT was extracted from acidified water samples (spiked with tripropyltin as internal standard) using reversed phase polymeric Strata-X cartridges. Analytes were eluted from cartridges using acetonitrile-water mixture and the volume...
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Electron Density from Balmer Series Hydrogen Lines and Ionization Temperatures in Inductively Coupled Argon Plasma Supplied by Aerosol and Volatile Species
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Folate-directed zinc (II) phthalocyanine loaded polymeric micelles engineered to generate reactive oxygen species for efficacious photodynamic therapy of cancer
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Antrakofilne gatunki Macromycetes w Lasach Oliwskich (Trójmiejski Park Krajobrazowy) = Anthracophilous species of Macromycetes in the Oliwskie Foresrs (Trójmiejski Ladscape Park)
PublicationW Lasach Oliwskich (Północna Polska), w miejscach wypalania drewna stwierdzono kilka gatunków macromycetes zaliczanych do grzybów antrakofilnych, np. Lyophyllum antracophilum, Faerberia carbonaria, Geopyxis carbonaria i in. Sprządzono krótką charakterystykę tych taksonów, podano położenie ich stanowisk.
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Texture or Linker? Competitive Patterning of Receptor Assembly toward Ultra-Sensitive Impedimetric Detection of Viral Species at Gold-Nanotextured Titanium Surfaces
PublicationIn this work, we study the electrodes with a periodic matrix of gold particles pattered by titanium dimples and modified by 3-mercaptopropionic acid (MPA) followed by CD147 receptor grafting for specific impedimetric detection of SARS-CoV-2 viral spike proteins. The synergistic DFT and MM/MD modeling revealed that MPA adsorption geometries on the Au–Ti surface have preferential and stronger binding patterns through the carboxyl...
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Method development and validation for optimized separation of quercetin derivatives in selected Potentilla species using high-performance thin-layer chromatography photodensitometry method
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New localities of rare species Kobayasiella okadae (Skvortzov) Lange-Bert. and K. tintinnus Buczkó, Wojtal & Jahn in Europe — morphological and ecological characteristics
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Bioaccumulation of alkaline soil metals (Ca, Mg) and heavy metals (Cd, Ni, Pb) patterns expressed by freshwater species of Ulva (Wielkopolska, Poland)
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The Impact of Adjacent Road on Vascular Plant Species Composition in Herbaceous Layers of Peucedano-Pinetum and Tilio-Carpinetum Urban Forests in the City of Warsaw (Poland)
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High efficiency protocol of DNA extraction from Micromys minutus mandibles from owl pellets: a tool for molecular research of cryptic mammal species
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The conversion of multinuclear μ-oxo titanium(IV) species in the reaction of Ti(OiBu)4 with branched organic acids; results of structural and spectroscopic studies
PublicationW reakcji tetraizobutoksylanu tytanu z rozgałęzionymi kwasami karboksylowymi otrzymano szereg wielordzeniowych związków kompleksowych tytanu(IV). Otrzymane produkty scharakteryzowano wykorzystując techniki spektroskopowe: FTIR, 1H i 13C NMR oraz rentgenowską analizę strukturalną. Zaproponowano ścieżki reakcji prowadzące do konwersji poszczególnych związków w coraz stabilniejsze formy.
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Seashore sediment and water chemistry at the Admiralty Bay (King George Island, Maritime Antarctica) – geochemical analysis and correlations between the concentrations of chemical species
PublicationThis study covers water and sediment chemical characteristics by the western shore of Admiralty Bay (King George Island, Antarctica) in 2016. Chemical processes between sediment and water have been described based on the determination of ions, metals, non-metals, and TOC concentrations. Rock weathering is an important source of Fe, Ni, Co, Al in the seashore area. The PCA shows the impact of acidification in the release metals...
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Labile and stable mercury in Harris mud crab (Rhithropanopeus harrisii) from the southern Baltic Sea – Considerations for a role of non-native species in the food web
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Porous carbon derived from rice husks as sustainable bioresources: insights into the role of micro-/mesoporous hierarchy in hosting active species for lithium–sulphur batteries
PublicationThe exploration of natural resources as sustainable precursors affords a family of green materials. Exploring highly abundant and available biowaste precursors remaining from food processing throughout a scalable and cost-effective material synthesis path is highly important especially for new materials discovery in emerging energy storage technologies such as lithium–sulphur (Li–S) batteries. Herein, we have produced a series...
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Aspects of Tests and Assessment of Filtering Materials Used for Respiratory Protection Against Bioaerosols. Part I: Type of Active Substance, Contact Time, Microorganism Species
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Chronione i zagrożone grzyby wielkoowocnikowe (macromycetes) Trójmiejskiego Parku Krajobrazowego (Pomorze Gdańskie) = Threatened and procected by law species of macromycetes in Trójmiejski Landscape Park (Gdańskie Pomerania)
PublicationArtykuł zawiera opis rzadkich gatunków grzybów wielkoowocnikowych, stwierdzonych w TPK, które znajdują się na "czerwonej liście makrogrzybów" oraz otrzymały status organizmów pod ochroną ścisłą i częściową. Wyszczególniono łącznie 61 gatunków, spośród których 1 gatunek jest traktowany jako wymarły w Polsce (Ex), 7 jest wymierających (E), 18 narażonych na wymarcie (V), 20 rzadkich (R), a 15 posiada nieokreślony status zagrożenia....
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Spectroscopic evaluation of a low power atmospheric pressure mixed argon–helium microwave induced plasma combined with the chemical generation of volatile species for the optical emission spectrometric determination of arsenic, antimony and mercury
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Convenient identification of desulfoglucosinolates on the basis of mass spectra obtained during liquid chromatography-diode array-electrospray ionisation mass spectrometry analysis: Method verification for sprouts of different Brassicaceae species extracts
PublicationOver the past decade, glucosinolates (GLs) present in different tissues of Brassicaceae and their breakdown products, especially isothiocyanates formed after myrosinase catalyzed hydrolysis, have been regarded as not only environment friendly biopesticides for controlling soilborne pathogens, but most importantly as promising anticarcinogenic compounds. For these reasons, the identification and quantitative determination of the...
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In-situ generation of Ag, Cd, Hg, In, Pb, Tl and Zn volatile species by flowing liquid anode atmospheric pressure glow discharge operated in gaseous jet mode – Evaluation of excitation processes and analytical performance
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Chromatographic analysis of extracts isolated from different poplar species as potential inhibitors of enzymatic hydrolysis Analiza chromatograficzna substancji ekstrakcyjnych pozyskanych z różnych odmian topoli jako potencjalnych inhibitorów hydrolizy enzymatycznej
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abiotic degradation of chlorinated ethanes and ethenes in water
PublicationIntroduction Chlorinated ethanes and ethenes are among themost frequently detected organic pollutants of water. Theirphysicochemical properties are such that they can contaminateaquifers for decades. In favourable conditions, they canundergo degradation. In anaerobic conditions, chlorinatedsolvents can undergo reductive dechlorination.Degradation pathways Abiotic dechlorination is usuallyslower than microbial but abiotic dechlorination...
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Phytotoxic Metabolites from Three Neofusicoccum Species Causal Agents of Botryosphaeria Dieback in Australia, Luteopyroxin, Neoanthraquinone, and Luteoxepinone, a Disubstituted Furo-α-pyrone, a Hexasubstituted Anthraquinone, and a Trisubstituted Oxepi-2-one from Neofusicoccum luteum
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Isolation and structure of a covalent cross-link adduct between mitomycin C and DNA
PublicationA DNA cross-link adduct of the antitumor agent mitomycin C (MC) to DNA has been isolated and characterized; the results provide direct proof for bifunctional alkylation of DNA by MC. Exposure of MC to Micrococcus luteus DNA under reductive conditions and subsequent nuclease digestion yielded adducts formed between MC and deoxyguanosine residues. In addition to the two known monoadducts, a bisadduct was obtained. Reductive MC activation...
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Cyanobacterial occurence in the Gulf of Gdańsk (2008-2009)
Open Research DataEN: This dataset includes information about cyanobacterial occurrence in the Gulf of Gdansk (Southern Baltic) in 2008 and 2009. The presented data concern the basic physicochemical and biological parameters of the sampled waters (temperature, PSU, Chla), occurrence of diazotrophic cyanobacterial species from Nodularia, Aphanizomenon and Dolichospermum...
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Azo and azoxythiacrown ethers: synthesis and properties
PublicationA series of 16- and 18-membered azo- and azoxythiacrown ethers have been synthesized by reductive macrocyclization of the respective bis(nitrophenoxy)oxaalkanes. The aromatic residues located in the polyether region of the molecule were introduced to macrocyclic skeletons and their affinities toward different groups of metal cations in ion-selective electrodes were described. X-ray structures for one dinitropodand and one azoxybenzothiacrown...
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Ichtiofauna seasonal changes in Redłowo area
Open Research DataSallow water areas of the Baltic Sea are very important feeding, spawning, and nursery grounds for many fish species. The dataset includes data from fish mass analysis and detailed analysis. The mass analysis includes total abundance and a total weight of fish species caught during sampling. Detailed analysis includes individual fish total length, weight,...
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The reactivity of 1,1-dichloro-2,2-di-tert-butyldiphosphane towards lithiated metal carbonyls: a new entry to phosphanylphosphinidene dimers
PublicationReactions of [Cp*(OC)3M]Li (Cp* = C5Me5, M = Mo, W) towards t-Bu2P–PCl2 lead to the formation of phosphanylphosphinidene dimers [Cp*(OC)3M(η2-t-Bu2P–P)]2 in fairly good yields. The formation of a tetraphosphorus ligand proceeds via reductive dimerization of t-Bu2P–P units. NMR, X-ray investigations and DFT calculations show that the resulting tetraphosphorus ligand has a structure of dication t-Bu2P+=P–P=P+t-Bu2.
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The effect of roasting beetroot and chicory on the anti-oxidative activity of their extracts
Open Research DataThe eThe data set presents the results of the assessment of the impact of roasting raw materials in the form of beetroot and chicory on their antioxidant activity measured by the standard ABTS and DPPH radical tests. The numerical results were compared with the visual assessment of the roasted raw materials. The obtained results confirmed the increase...
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XRD diffraction patterns for strontium ferrite molybdate-based compounds: as-prepared, reduced and reoxidized
Open Research DataThe dataset contains the XRD diffractograms collected at room temperature for SFM, LSFM and SFMNb in 3 different oxidation states, namely: as-prepared, reduced and reoxidized.
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Cyanobacterial occurrence in 6 lakes in the Pomorskie Province (2005-2006)
Open Research DataEN: This dataset includes information about cyanobacterial occurrence in 6 lakes in the Pomorskie Province (northern Poland) in 2005 and 2006. Presented data concern basic physicochemical and biological parameters of sampled waters (temperature, pH, Chl a), occurence of potentially toxic cyanobacterial species and the type and concentration of toxins...
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Phytoplankton in the Kashubian Lakes – microscopic photo archive
Open Research DataPhytoplankton is a group of microscopic plant organisms passively floating in water. The organisms included in the phytoplankton of lakes include the following main taxonomic groups: cyanobacteria (Cyanobacteria), green algae (Chlorophyta), dinoflagellates (Dinophyta), diatoms (Bacillariophyceae), cryptophytes (Cryptophyta), chrysophytes (Chrysophyceae)...
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Cytotoxic and Antioxidant Activities of Benzohydroxamic Acid Analogues
Publication20 benzohydroxamic acid analogues were synthesized and evaluated for their in vitro cytotoxicities against mouse mammary tumor cells as well as antioxidant activities against DPPH radical and superoxide anion. It was found that benzothiohydroxamic acids exhibit greater cytotoxicities than benzohydroxamic acids and N-isopropyl derivatives are more active than N-methyl ones. On the other hand, benzothiohydroxamic acids show more...
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A first-principles study of electron attachment to the fully hydrated bromonucleobases
PublicationDegradation mechanism of four brominated nucleobases (BrX), potential DNA radiosensitizers, is studied in explicit water solution, using ab initio molecular dynamics. Several fs long dynamics is needed to localize an electron on the nucleobase. Produced by electron attachment BrX anion radical degrades through the bromide anion abstraction, barrier-free (purines) or with low barrier (pyrimidines), to a reactive nucleobase radical....
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Piotr Konieczka prof. dr hab. inż.
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Sławomir Milewski prof. dr hab. inż.
PeopleSławomir Milewski, born in 1955 in Puck, Poland, graduated in 1979 in Chemistry from the Faculty of Chemistry, Gdańsk University of Technology (GUT). In 1984 was employed at the Department of Pharmaceutical Technology and Biochemistry. In 1985 he got his PhD, in 1994 became a DSc (habilitation) and in 2002 got the professorship in chemical sciences. Currently he is a full professor and Head of the Department of Pharmaceutical Technology...