Search results for: MAGNESIUM-AIDED CATALYSIS
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Characterization of CaTi0.9Fe0.1O3/La0.98Mg0.02NbO4 composite
PublicationA composite of CaTi0.9Fe0.1O3 and electrolyte material, i.e. magnesium doped La0.98Mg0.02NbO4 was prepared and studied. The phase content and the sample microstructure was examined by an X-ray diffraction method and scanning electron microscopy. EDS measurements were done both for composite samples and the diffusion couple. The electrical properties were studied by four terminal DC method. The Ahigh-temperature interaction between...
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Experimental and numerical evaluation of mechanical behaviour of composite structural insulated wall panels under edgewise compression
PublicationA composite structural insulated sandwich panel (CSIP) is a quite novel approach to the idea of sandwich structures. A series of natural-scale experimental test is required each time a change in panel’s geometry is planned and a reliable computational tool is required to precede actual laboratory testing with virtual simulations. An attempt of creating such a tool has been made with use of a commercial FEM code ABAQUS, in order...
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Functionalized polyolefins, synthesis application and industrial relevance
PublicationPolymers play a key role in our modern life full of technical advances and a continuous request for new materials with tailored properties for a low price. Their excellent mechanical properties, good processability, chemical stability and low price make polyolefins the polymers of choice for most commodity and some more specialized applications. As a result, polyolefins account for over 65% of the total world demand of plastic...
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Electrolytic corrosion of water pipeline system in the remote distance from stray currents– case study
PublicationCase study of corrosion failure of urban water supply system caused by the harmful effects of stray currents was presented. The failure occurred at a site distant from the sources of these currents namely the tramway and railway traction systems. Diagnosis revealed the stray currents flow to pipeline over a remote distance of 800 ÷ 1,000 meters from the point of failure. At the point of failure stray currents flowed from the pipeline...
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Ocena kształtu geometrycznego torów tramwajowych na podstawie pomiarów satelitarnych
PublicationW pracy przedstawiono ocenę możliwości wykorzystania dwusystemowych fazowych odbiorników GNSS (GPS/Glonass) dla realizacji pomiaru inwentaryzacyjnego linii tramwajowych. Opisano przebieg pomiarów przeprowadzonych na terenie Gdańska i uzyskane wyniki. Wykazano, że dla obszarów miejskich zastosowanie rozwiązań GNSS w oparciu o lokalną stację referencyjną może być alternatywnym podejściem względem pomiarów opartych o sieć ASG-EUPOS...
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CAD Introduction (2023/24)
e-Learning CoursesThe course aim is to demonstrate the application of Computer Aided Design in preparation of architectural drawings and project presentations. No previous CAD experience is necessary. Using hands-on exercises, students explore how to create project presentations using 2D drawings and 3D models created in AutoDesk AutoCAD and other programs.
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Bridging the gap between business process models and use-case models
PublicationToday's software development methodologies are equipped with a plethora of methods and techniques for business process engineering and Requirements Engineering. However, heavy investments in IT have not brought forth expected results. What seems to be lacking is a systematic approach that consolidates both disciplines to gain a synergistic effect. To address this challenge we extend Use-Case Driven Approach (UCDA) by binding use...
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Programowanie Obiektowe z Użyciem Adnotacji Semantycznych
PublicationW tym artykule przedstawiono jak przy udziale standardowych mechanizmów nowoczesnych języków obiektowych, osiągnięć z zakresu formalnej reprezentacji wiedzy oraz lingwistyki komputerowej wytworzyć zbiór narzędzi wzbogacających warsztat programisty o narzędzia semantyczne. Przedstawione tu Programowanie Obiektowe z Użyciem Adnotacji Semantycznych jest częścią rozwijanej przez autora referatu metodologii wytwarzania oprogramowania...
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Hydrogen evolution on the reduced TiO2 under simulated solar lamp
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Methylene blue decomposition on TiO2/reduced graphene oxide hybrid photocatalysts obtained by a two-step hydrothermal and calcination synthesis
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Photocatalytic Removal of Phenol Under UV Irradiation on WO x –TiO2 Prepared by Sol–Gel Method
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TiO2 Nanoparticles with High Photocatalytic Activity Under Visible Light
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A new method for preparation of rutile phase titania photoactive under visible light
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Spectroelectrochemical analysis of TiO 2 electronic states – Implications for the photocatalytic activity of anatase and rutile
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On Oxygen Activation at Rutile- and Anatase-TiO2
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Carbon catalysts from pine cones – Synthesis and testing of their activities
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The studies on the limonene oxidation over the microporous TS-1 catalyst
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Influence of Technological Parameters on the Isomerization of Geraniol Using Sepiolite
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Application of photoactive electrospun nanofiber materials with immobilized meso-tetraphenylporphyrin for parabens photodegradation
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Formation of 2-chloroallyl alcohol oligomers using a new crystalline dipicolinate complex of Cr(III) as a catalyst
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Photodegradation and advanced oxidation of endocrine disruptors in aqueous solutions
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A Reaction of Thioamides with Zinc Ammoniates Leading to Simple Amidines. Discovery of a New Zwitterionic Monomethylamidine
PublicationThe reaction of thioamides with the R1R2N-ZnCl ammoniates leads to N-mono-, N,N'-di-, N,N-disubstituted, and unsubstituted amidines with high concns. of amines in abs. ethanol. The efficient direct formation of the N,N'-dimethylamidine can be explained by a greater reactivity of methylamine compared with dimethylamine. Discovery of a new zwitterion (induced by a carbonyl oxygen) suggests that the stabilization in the thymine...
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Operando EPR Study of Radical Formation in Anion-Exchange Membrane Fuel Cells
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H3PMo12O40-doped polyacetylene as a catalyst for ethyl alcohol conversion
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Ag/Pt-modified TiO2 nanoparticles for toluene photooxidation in the gas phase
PublicationAg/Pt-modified TiO2nanocomposites were synthesized using the sol–gel method. The effect of metal typeand amount as well as synthesis route on the photocatalytic activity in reaction of toluene removal, usedas a model volatile organic compound, was investigated. Toluene, at the concentration of about 200 ppm,was irradiated over modified TiO2using light-emitting diodes (LEDs, max= 415 nm). The results showedthat toluene could be...
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Preparation and characterization of Pt/Pd-modified titanium dioxidenanoparticles for visible light irradiation
PublicationSeries of Pt/Pd–TiO2photocatalysts were obtained using the sol–gel method. The Pt/Pd–TiO2nanocom-posites showed significant visible light photoactivity. X-ray diffraction, STEM microscopy, UV–visspectroscopy and BET characterization allowed to conclude that the photocatalysts at the best perfor-mance had the anatase structure, 91 m2/g specific surface area, Pt/Pd alloy structure and 1–4 nm particlesize. The photocatalytic activity...
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Mono- and bi-metallic plasmonic photocatalysts for degradation of organic compounds under UV and visible light irradiation
PublicationTitania powders were surface modified with gold and/or silver nanoparticles (NPs) by photodeposition method. Gold modified titania exhibited much higher photocatalytic activity during methanol dehydrogenation under UV irradiation than titania modified with monometallic silver and bimetallic Au–Ag NPs. Bimetallic photocatalysts exhibited either enhanced or reduced visible light activity, depending on properties of noble metal NPs,...
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Catalytic activity of Ni-MgAl2O4 modified with transition metal (Ti, Mo, W) carbides as potential catalysts for resource recovery via dry reforming of waste plastics
PublicationThe growing amounts of plastic waste and CO2 emissions are two environmental threats that require urgent attention. Pyrolysis combined with dry reforming (PCDR) is a technology that allows both CO2 utilization and resource recovery from waste plastic. New catalysts for PCDR are crucial for developing efficient and stable processes that can be widely implemented in the industry. In this study, Ni/MgAl2O4 catalysts modified using different...
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Quantum chemical modelling of the process of lithium insertion into WO3 films
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Engineering a de Novo Transport Tunnel
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New type of repeated Si–C-podand catalysts for solid–liquid phase transfer reactions
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Fe-promoted CuO/CeO2 catalyst
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Surface properties of wustite based iron-cobalt catalysts for ammonia synthesis reaction
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The application of titanium dioxide for deactivation of bioparticulates: An overview
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Fused FeCo catalysts for hydrogen production by means of the ammonia decomposition reaction
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Study of the Kinetics of Ammonia Synthesis and Decomposition on Iron and Cobalt Catalysts
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Kinetics studies of recrystallization process of metallic catalysts for ammonia synthesis
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Ethanol production in membrane distillation bioreactor
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Synthesis of 2-Propanoyl-5-Norbornene in Pyridinium Ionic Liquids Catalyzed by Yttrium Salts
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Wustite based iron-cobalt catalyst for ammonia synthesis
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Application of nanofiltration for production of 1,3-propanediol in membrane bioreactor
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Effect of Cobalt on the Activity of CuO/CeO2 Catalyst for the Selective Oxidation of CO
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Silver-modified titania with enhanced photocatalytic and antimicrobial properties under UV and visible light irradiation
PublicationCommercial titania photocatalysts were modified with 2 wt% of silver by photodeposition. The properties of the samples were characterized by DRS, XPS, XRD, FE-SEM and STEM. The modified samples exhibited activity under visible light and enhanced activity under UV irradiation for 2-propanol and acetic acid oxidation, respectively. The time-resolved microwave conductivity (TRMC) analysis indicated that enhanced activity (2.5–8-fold...
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KTaO3-based nanocomposites for air treatment
PublicationA series of single semiconductors and their nanocomposites combination (such as KTaO3 + CdSe + SrTiO3; KTaO3 + CdS +WO3; KTaO3 + CdS + MoS2) were prepared using hydrothermal route. Photocatalytic activity of as-prepared nanocomposites was estimated by photocatalytic degradation of toluene in the gas phase using light-emitting diodes (LEDs, 375 nm) in four subsequent cycles. The nanocomposites were characterized by scanning electron...
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Photocatalytically Active TiO2/Ag2O Nanotube Arrays Interlaced with Silver Nanoparticles Obtained from the One-Step Anodic Oxidation of Ti–Ag Alloys
PublicationThe development of a photocatalyst with remarkable activity to degrade pollutants in aqueous and gas phase requires visible lightresponsive stable materials, easily organized in the form of a thin layer (to exclude the highly expensive separation step). In this work, we present a one-step strategy for synthesizing material in the form of a self-organized TiO2/Ag2O nanotube (NT) array interlaced with silver nanoparticles (as in a...
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Effect of irradiation intensity and initial pollutant concentration on gas phase photocatalytic activity of TiO2 nanotube arrays
PublicationWell-organized TiO2 nanotube arrays were fabricated via one-step anodization process. The as-prepared TiO2 nanotubes were characterized by X-ray powder diffractometry (XRD), X-ray photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy (DRS) and scanning electron microscopy (SEM). Photocatalytic activity of obtained photocatalyst was studied in reaction of toluene degradation in the gas phase using low powered and low...
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Monometallic nanoparticles decorated and rare earth ions doped KTaO3/K2Ta2O6 photocatalysts with enhanced pollutant decomposition and improved H2 generation
PublicationNew, monometallic nanoparticles (MNPs) decorated surface and rare earth (RE) ions doped lattice of perovskite-type (KTaO3)/pyrochlore-type (K2Ta2O6) photocatalysts were successfully prepared by facile hydrothermal incorporation of RE ions into KTaO3/K2Ta2O6 lattices followed by photodeposition of MNPs. The impact of noble metal type (MNPs = Au, Pt, Rh) and rare earth dopant type (RE = Er, Pr) on the physicochemical properties correlated...
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Visible light photocatalysis employing TiO2/SrTiO3-BiOI composites: Surface properties and photoexcitation mechanism
PublicationA series of binary TiO2/SrTiO3 and ternary TiO2/SrTiO3_BiOI composites have been synthesized using multistep preparation method. Characterization of the obtained photocatalysts covered complex analysis including morphology + y (SEM), BET specific surface area, porosity, optical properties (DRS), chemical composition of surface (XPS), crystal structure and crystal size (XRD). UV–vis and Vis ligh induced photocatalytic activity was...
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Mechanism of reaction of RNA-dependent RNA polymerase from SARS-CoV-2
PublicationWe combine molecular dynamics, statistical mechanics, and hybrid quantum mechanics/molecular mechanics simulations to describe mechanistically the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) RNA-dependent RNA polymerase (RdRp). Our study analyzes the binding mode of both natural triphosphate substrates as well as remdesivir triphosphate (the active form of drug), which is bound preferentially over ATP by RdRp while...
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Non-toxic fluorine-doped TiO2 nanocrystals from TiOF2 for facet-dependent naproxen degradation
PublicationIn the present study, the photocatalytic degradation of naproxen (NPX), which is a nonsteroidal anti-inflammatory drug (NSAID), frequently detected in drinking water, was investigated. The F-doped TiO2 with defined morphology was successfully obtained from TiOF2 and applied for photocatalytic degradation under UV-vis and visible light. All samples were characterised by X-ray diffraction, scanning electron microscopy, X-ray photoelectron...