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Search results for: fischer reaction
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Critical section maintenance in a distributed agent system
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Stability of an Innovative Cold-Formed GEB Section
PublicationThis paper is focused on the numerical analysis and experimental test of stability of the cold-formed profile with an innovative GEB cross-section. For the shell model of the axially compressed member, the linear buckling analysis and the nonlinear static analysis were carried out. In the numerical research, the buckling load and the limit load for variable section heights were obtained. Some of the results were compared with the...
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Geoinformation technologies in the identification of meandering section of the river
PublicationPublikacja traktuje o wykorzystaniu naziemnego skaningu laserowego dla potrzeb analiz przestrzennych w zakresie meandrowania rzeki.
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On Bayesian Tracking and Prediction of Radar Cross Section
PublicationWe consider the problem of Bayesian tracking of radar cross section. The adopted observation model employs the gamma family, which covers all Swerling cases in a unified framework. State dynamics are modeled using a nonstationary autoregressive gamma process. The principal component of the proposed solution is a nontrivial gamma approximation, applied during the time update recursion. The superior performance of the proposed approach...
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The inverse problem in a hyperbolic section radial compressor.
PublicationNa przykładzie wirnika sprężarki porównano wyniki rozwiązania zadania odwrotnego w ramach modelu 2D prowadzącego do kształtu wirnika, z zadaniem prostym, w ramach modelu 3D, dla skonstruowanego wirnika na bazie modelu 2D.Zasadniczym celem było uzyskanie równomiernych (bez oderwań) pól parametrów w obrębie wirnika sprężarki. Pokazano jak zmiana obrysu wirnika, z klasycznego kształtu stożkowego na hiperboliczny, wpłynąć może na...
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Micellar Route of the Synthesis of Alkyl Xylosides: An Unexpected Effect of Amphiphilic Imidazolium Ionic Liquids
PublicationThis manuscript presents results from the investigation on the synthesis of alkyl xylosides by the novel, very efficient and promising protocol of the Fischer synthesis from unprotected xylose and aliphatic alcohol. The use of 1-alkyl-3-methylimidazolium hydrogen sulfate ionic liquids as the catalysts with dual functionality (surfactant + acid catalyst) and micellar reaction system are the main novelty of described method. It has...
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Selective monoprotection of 1,4,7,10-tetraazacyclododecane via direct reactions with 4-nitrophenyl active esters
Publication1,4,7,10-tetraazacyklododekan jest cykliczną tetraaminą. Z chemicznego punktu widzenia wszystkie atomy azotu posiadają takie same właściwości fizykochemiczne. Jedyną różnicę stanowią ich właściwości kwasowo-zasadowe. Cyklen posiada dwa atomy azotu o obniżonej zasadowości. Właściwość ta z powodzeniem wykorzystywana jest w reakcjach jednoczesnej selektywnej substytucji dwóch atomów w pozycji 1 i 7. W przypadku bezpośredniej reakcji...
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Interaction of Acoustic and Thermal Modes in the Gas with Nonequilibrium Chemical Reactions: Possibilities of Acoustic Cooling
PublicationNonlinear generation of thermal mode during propagation of dominative sound in a chemically reacting gas is considered. The dynamic equation of excess temperature associated with the thermal mode is derived. It is instantaneous and includes quadratic nonlinear acoustic source reflecting the nonlinear character of interaction between acoustic and non-acoustic types of gas motion. Both periodic and aperiodic sound may be considered...
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Proton transfer reactions from NH acid to various N-bases in acetonitrile
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High catalytic performance of tungsten disulphide rodes in oxygen evolution reactions in alkaline solutions
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Monitoring of Caged Bluefin Tuna Reactions to Ship and Offshore Wind Farm Operational Noises
PublicationUnderwater noise has been identified as a relevant pollution affecting marine ecosystems in different ways. Despite the numerous studies performed over the last few decades regarding the adverse effect of underwater noise on marine life, a lack of knowledge and methodological procedures still exists, and results are often tentative or qualitative. A monitoring methodology for the behavioral response of bluefin tuna (Thunnus thynnus)...
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Place Attachment and Collective Action Tendency
PublicationThree studies were carried out to examine how place attachment and collective action tendency are related and what role self-expansion and social interactions play in this relationship. In the first study (N = 156) we found that a more active form of attachment – place discovered – is a significant predictor of tendency to engage in collective action in favor of one’s neighborhood. In the second study (N = 197), we focused on...
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Greencoin: a Proenvironmental Action-Reward System
PublicationThe massive destruction of the natural environment is rapidly eroding the world’s capacity to provide food and water, threatening the security of billions of people. In order to facilitate green lifestyles – understood in terms of both pro-environmental behaviors and green self-image on the one hand, and to build sustainable local and global communities, on the other, we put forward an idea of a novel action-reward system based...
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STATYSTYKA F ROZKŁADU FISHERA-SNEDECORA JAKO NARZĘDZIE DO OCENY ISTOTNOŚCI WPŁYWU MOCY SILNIKA O ZS NA WYBRANE MIARY DIAGNOSTYCZNE
Publicationniniejszym opracowaniu przedstawiono zastosowanie statystyki F rozkładu Fishera-Snedecora do oceny istotności wpływu obciążenia silnika o ZS, na obserwowany parametr diagnostyczny, wyznaczany na podstawie pomiarów szybkozmiennej temperatury spalin w kanale wylotowym, jakim jest entalpia właściwa strumienia spalin wylotowych w zakresie jednego cyklu pracy silnika. Przedstawiono plan badań eksperymentalnych przeprowadzonych na jednocylindrowym...
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Direct measurements of odorous volatile organic compounds present in biosolids cakes by Proton Transfer Reaction – Mass Spectrometry Technique
PublicationThis paper show the results of investigation of concentration of odorous chemical compounds emitted upon ageing of anaerobically stabilised biosolids that could contribute to the overall odour character of nuisance emissions. Biosolids samples from wastewater treatment plant were collected in spring time. Concentrations of volatile organic compounds using a US EPA flux hood and Proton Transfer Reaction-Time of Flight-Mass Spectrometry...
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The influence of thermal treatment on electrocatalytic properties of Mn-Co nanofilms on nickel foam toward oxygen evolution reaction activity
PublicationThis work evaluates electrodeposited and differently treated Mn-Co catalysts for their oxygen evolution reaction activity. Catalysts are evaluated in the as-deposited and heat treated state: after 350 C and 600 C. Results show that the highest electrochemical activity is obtained for the as-deposited Mn-Co oxyhydroxide, which possibly possess a layered double hydroxide structure. After the heat treatment process, especially after...
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Active Site Architecture and Reaction Mechanism Determination of Cold Adapted beta-D-galactosidase from Arthrobacter sp. 32cB
PublicationArthbetaDG is a dimeric, cold-adapted beta-D-galactosidase that exhibits high hydrolytic and transglycosylation activity. A series of crystal structures of its wild form, as well as its ArthbetaDG_E441Q mutein complexes with ligands were obtained in order to describe the mode of its action. The ArthbetaDG_E441Q mutein is an inactive form of the enzyme designed to enable observation of enzyme interaction with its substrate. The...
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Tuning of eg electron occupancy of MnCo2O4 spinel for oxygen evolution reaction by partial substitution of Co by Fe at octahedral sites
PublicationTo study the effect of partial Co substitution by Fe in the B site of MnCo2O4 spinel on its physicochemical and electrochemical properties, a series of MnCo2-xFexO4 powders (x=0.125; 0.250; 0.500; 0.750; 1.000) were synthesized by means of the sol-gel method. The produced powders were characterized by powder X ray diffraction (pXRD), scanning and transmission electron microscopy (SEM & TEM) coupled with energy dispersive spectroscopy...
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Online Volatile Compound Emissions Analysis Using a Microchamber/Thermal Extractor Coupled to Proton Transfer Reaction-Mass Spectrometry
PublicationIndoor air is a complex and dynamic mixture comprising manifold volatile organic compounds (VOCs) that may cause physiological and/or psychological discomfort, depending on the nature of exposure. This technical note presents a novel approach to analyze VOC emissions by coupling a microchamber/thermal extractor (μ-CTE) system to a proton transfer reaction-mass spectrometer (PTR-MS). This configuration provides an alternative to...
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On-line assessment of oil quality during deep frying using an electronic nose and proton transfer reaction mass spectrometry
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The suitability of DNA extracted from formalin-fixed, paraffin-embedded tissues for double differential polymerase chain reaction analysis
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Nanosecond pulsed electric fields (nsPEFs) impact and enhanced Photofrin II® delivery in photodynamic reaction in cancer and normal cells
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Surface-orientated platinum nanoparticles electrodeposited on a carbon substrate as a high performance electrocatalyst for glucose oxidation reaction in alkaline media
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APPLICABILITY OF PLUMS GROWN IN POLAND TO DRYING PROCESS IN TERMS OF CHANGES IN BIOACTIVE COMPOUNDS AND OF MAILLARD REACTION PRODUCTS BEING FORMED
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TiO2 with Tunable Anatase-to-Rutile Nanoparticles Ratios: How Does the Photoactivity Depend on the Phase Composition and the Nature of Photocatalytic Reaction?
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In-situ FTIR study of reaction mechanism and chemical kinetics of a Xundian lignite during non-isothermal low temperature pyrolysis
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Red phosphorus as self-template to hierarchical nanoporous nickel phosphides toward enhanced electrocatalytic activity for oxygen evolution reaction
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Solvent effects for proton transfer reaction from dimethyl(4-nitrophenyl)malonate to cis 1,2-bis(diethylaminomethyl)cyclohexane
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The reaction of substituted N-phenacyl-pyridinium bromides in the pyridine ring with DABCO and DBU in water and DMSO. Kinetics and DFT studies
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Robust and highly efficient electrocatalyst based on ZIF-67 and Ni2+ dimers for oxygen evolution reaction: In situ mechanistic insight
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Monitoring of odors emitted from stabilized dewatered sludge subjected to aging using proton transfer reaction–mass spectrometry
PublicationOne of the potential emission sources of odorous compounds from wastewater treatment plants is sludge processing. The odorous compounds released from dewatered sludge can result in odor nuisance. This study concerns the use of flux hood chamber combined with proton transfer reaction—time of flight—mass spectrometry (PTR-MS) technique for periodical monitoring of odorous compounds emitted from aged, stabilized dewatered sludge samples...
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Non-Coaxially Rotating Motion in Casson Martial along with Temperature and Concentration Gradients via First-Order Chemical Reaction
PublicationThe effect of non-coaxial rotation on the transport of mass subjected to first-order chemical reaction is studied analytically. The effects of thermal radiation, buoyancy, constructive and destructive chemical reactions along with Casson fluid in rotating frame are discussed. Time evolution of primary and secondary velocities, energy and solute particles are analyzed. The behavior of flow under the variation of intensity of magnetic...
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Solvent Impact on the Diversity of Products in the Reaction of Lithium Diphenylphosphide and a Ti(III) Complex Supported by a tBu2P–P(SiMe3) Ligand
PublicationWe present two important trends in the reactivity ofthe titanium complex [MeNacNacTi(Cl){η2-P(SiMe3)-PtBu2}](MeNacNac− = [Ar]NC(Me)CHC(Me)N[Ar]; Ar = 2,6-iPr2Ph)with nucleophilic reagents RLi (R = Ph2P,tBuO, (Me3Si)2N, andtBu2N) depending on the reaction medium. Reaction in nonpolarsolvent (toluene) leads to three main products: via an autoredoxprocess and nucleophilic substitution at the Ti-atom to afford theTi(IV) complex [MeNacNacTi(R){η2-P-PtBu2}]...
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On-line assessment of oil quality during deep frying using an electronic nose and proton transfer reaction mass spectrometry
PublicationWe describe a novel method for the quality assessment of oil utilized for deep frying. The method is based on the analysis of frying fumes using a custom electronic nose. The quality score could be obtained after less than 3 min of analysis and without interrupting the frying process or sampling the oil directly. The obtained results were correlated with the peroxide value using a multivariate linear regression model. The most...
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The Effect of Cobalt Incorporation into Nickel–Iron Oxide/(oxy)hydroxide Catalyst on Electrocatalytic Performance Toward Oxygen Evolution Reaction
PublicationThis work presents a study on the influence of the addition of cobalt into state-of-the-art nickel–iron (NiFe) mixed oxides/hydroxides/(oxy)hydroxides on their structural and morphological properties, and oxygen evolution reaction (OER) catalytic activity. A one-step electrodeposition process is performed without any additives to fabricate NiFe and x cobalt-doped nickel/iron (xCoNiFe) layer-double-hydroxide catalysts directly on...
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Chemical investigation on the mechanism and kinetics of the atmospheric degradation reaction of Trichlorofluoroethene by OH⋅ and Its subsequent fate in the presence of O2/NOx
PublicationThe M06-2X/6-311++G(d,p) level of theory was used to examine the degradation of Trichlorofluoroethene (TCFE) initiated by OH⋅ radicals. Additionally, the coupled-cluster single-double with triple perturbative [CCSD(T)] method was employed to refine the single-point energies using the complete basis set extrapolation approach. The results indicated that OH-addition is the dominant pathway. OH⋅ adds to both the C1 and C2 carbons,...
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Upscaling biomass production of rosmarinic acid-rich hairy root cultures of Agastache rugosa (Fisch. & C.A.Mey.) Kuntze
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Reclaimed rubber in-situ grafted with soybean oil as a novel green reactive plasticizer in SBR/silica compounds
PublicationPolymer recycling and biodegradable polymeric materials are two major routes towards the sustainable development of polymer materials which contributes to the management of waste. In this regard, an eco-friendly approach is presented wherein high reclaiming degree of ground tire rubber (GTR) was achieved by low-temperature oxidation under swollen action of soybean oil. In-situ reclaimed GTR with soybean oil was cured into reactive...
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The reduction of auxiliaries power demand: The challenge for electromobility in public transportation
PublicationAn important role in the consumption of electric energy in urban transport are non-traction needs (auxiliaries), the main part of which is heating and air condition (HVAC). Auxiliaries are responsible for almost half of total energy consumption (normal weather conditions) and in the winter (or hot summer) it reaches up to 70% in daily scale. The reduction of energy used for non-traction needs is currently the main challenge related...
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Spurious Modes in Model Order Reduction in Variational Problems in Electromagnetics
PublicationIn this work, we address an everlasting issue in 2 model order reduction (MOR) in electromagnetics that has 3 remained unnoticed until now. Contrary to what has been 4 previously done, we identify for the very first time spurious 5 modes in MOR for time-harmonic Maxwell’s equations and 6 propose a methodology to remove their negative influence on the 7 reduced order model (ROM) response. These spurious modes 8 have nonzero resonance...
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An orthogonality relation for the Whittaker functions of the second kind of imaginary order
PublicationPrzeprowadzono dowód ortogonalności funkcji Whittakera drugiego rodzaju rzędu urojonego. Użyto metody analogicznej do tej, którą zaprezentowano we wcześniejszej pracy tych samych autorów [J. Math. Anal. Appl. 365 (2010) 195-197], poświęconej funkcjom Macdonalda rzędu urojonego.
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Alcohol craving in relation to coping with stress and satisfaction with life in the addicted
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Modeling of Ozonation of Reactive Black 5 Through a Kinetic Approach
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Influence of the improved reduction technique on superconductivity in Nd1.85Ce0.15Cu1+_yO4-z
PublicationW pracy opisano zmodyfikowany proces redukcji próbek ceramicznych NCCO oraz jego wpływ na właściwości nadprzewodzące związku. Uzyskano dobre właściwości nadprzewodzące dla próbek z 2% niedoborem Cu oraz bardzo dobre wyniki dla próbek z 2% nadmiarem Cu.
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Drift, wow and flutter measurement and reduction in shrunken movie soundtracks
PublicationReferat przedstawia metodę i algorytmy do oceny i redukcji dryfu, kołysania i drżenia w skurczonych taśmach filmowych. Przedstawione algorytmy działają w oparciu o przetwarzaniu obrazu taśmy filmowej w celu wyznaczenia jej lokalnego skurczu, który jest jednym z powodów powstawania dryfu, kołysania i drżenia. Lokalny skurcz taśmy można wyznaczyć dzięki analizie wysokości: ramki obrazu, perforacji, lub innego, standaryzowanego elementu...
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Putative Biological Mechanisms of Efficiency of Substrate Reduction Therapies for Mucopolysaccharidoses
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Destructive Consequences of PWM Inverter Feeding for Traction AC Motors
PublicationThe electric traction drives with an AC motor fed by a frequency converter are used more and more often nowadays. The most significant side effects, of a converter's output voltage forming PWM method for AC motor windings, are steep voltage changes, which can initiate several destructive phenomena. The paper presents the adverse influence of a converter common mode voltage on the motor windings' increased voltage exposure and the...
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The Method of reduction of aerodynamic forces generated in turbine blade seals
PublicationThe distibution of pressure in the seal gaps does not only affect the so called '' leakage losses'' and the turbine stage overall efficiency but also plays an important role in the generation of aerodynamic forces which may cause self-excited rotor vibrations. The paper describes a chamber seal applied for the reduction of the aerodynamic forces created in shroud seals. This kind of turbine seal was patented and tested.
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Moderately Reactive Molecules Forming Stable Ionic Compounds with Superhalogens
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The origin of luminescence accompanying electrochemical reduction or chemical decomposition of peroxydisulfates
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