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Search results for: hard carbons
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Interatomic potential suitable for the modeling of penta-graphene: Molecular statics/molecular dynamics studies
PublicationWe test the potentials available for elemental carbon, with the scope to choose the potential suitable for the modeling of penta-graphene, the latest two dimensional carbon allotrope. By using molecular statics and molecular dynamics simulations we show that there is only one potential e namely the Tersoff-type potential proposed by Erhart and Albe in 2005 e which is able to correctly describe all the important features of penta-graphene....
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Anisotropic mechanical behavior and auxeticity of penta-graphene: Molecular statics/molecular dynamics studies
PublicationWe investigate the mechanical properties of penta-graphene (PG), a recently proposed two-dimensional carbon allotrope using atomistic simulation techniques combined with the empirical description of interatomic interactions. We report on the dependence of its three in-plane mechanical moduli (i.e. Young's modulus, Poisson's ratio and shear modulus) on the deformation direction, strain and temperature. We show that PG displays a...
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Nanocrystalline diamond sheets as protective coatings for fiber-optic measurement head
PublicationFiber-optic sensors find numerous applications in science and industry, but their full potential is limited because of the risk of damaging the measurement head, in particular, due to the vulnerability of unprotected tips of the fiber to mechanical damage and aggressive chemical agents. In this paper, we report the first use of a new nanocrystalline diamond structure in a fiber-optic measurement head as a protective coating of...
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Study on surface termination of boron-doped diamond electrodes under anodic polarization in H2SO4 by means of dynamic impedance technique
PublicationAnodic oxidation is a popular way to modify termination bonds at boron doped diamond electrodes altering their electrochemical and physicochemical properties. Our studies, performed with dynamic electrochemical impedance spectroscopy technique, supported with X-ray photoelectron spectroscopy and ellipsometry analysis prove its utility in continuous on-line monitoring of impedance changes on the electrode surface under polarization...
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Unraveling the role of boron dimers in the electrical anisotropy and superconductivity in boron-doped diamond
PublicationWe use quantum mechanics (QM) to determine the states formed by B dopants in diamond. We find that isolated B sites prefer to form BB dimers and that the dimers pair up to form tetramers (BBCBB) that prefer to aggregate parallel to the (111) surface in the <110> direction, one double layer below the H-terminated surface double layer. These tetramers lead to metallic character (Mott metal Insulator Transition) with holes in the...
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Enhanced electrochemical kinetics of highly-oriented (111)-textured boron-doped diamond electrodes induced by deuterium plasma chemistry
PublicationNovel highly-oriented (111)-textured boron-doped diamond electrodes (BDDD) featuring high electrochemical activity and electrode stability toward electrochemical analytics were fabricated by deuterium-rich microwave plasma CVD. The high flux deuterium plasma-induced preferential formation of (111)-faceted diamond as revealed by XRD. The highly-oriented diamond surface exhibited improved boron dopant incorporation and activation,...
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Low-strain sensor based on the flexible boron-doped diamond-polymer structures
PublicationA free-standing high boron-doped diamond nanosheet (BDDNS) has been fabricated for the development of a flexible BDDNS strain senor. High boron-doped diamond was initially grown on a tantalum substrate in a microwave plasma-assisted chemical vapor deposition method, and was then transferred to a Kapton polymer substrate to fabricate the flexible BDDNS/Kapton device. Before performing the transfer process, the thin BDDNS’s morphology...
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Nonlinearity shaping in nanostructured glass-diamond hybrid materials for optical fiber preforms
PublicationNanodiamond integration with optical fibers has proved a compelling methodology for magneto-optics. We reveal that the applicability of nanodiamonds in nonlinear optics goes beyond the previous demonstrations of frequency converters. Instead, we exploit the recently reported volumetric integration of nanodiamonds along the optical fiber core and show that the nonlinear response of glasses can be manipulated by nanodiamonds. By...
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Volumetric incorporation of NV diamond emitters in nanostructured F2 glass magneto-optical fiber probes
PublicationIntegration of optically-active diamond particles with glass fibers is a powerful method of scaling diamond's magnetic sensing functionality. We propose a novel approach for the integration of diamond particles containing nitrogen-vacancy centers directly into the fiber core. The core is fabricated by stacking the preform from 790 soft glass canes, drawn from a single rod dip-coated with submicron diamond particles suspended in...
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Changes on the Surface of the SiO2/C Composite, Leading to the Formation of Conductive Carbon Structures with Complex Nature of DC Conductivity
Open Research DataChanges on the Surface of the SiO2/C Composite, Leading to the Formation of Conductive Carbon Structures with Complex Nature of DC Conductivity
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Electrical and noise responses of carbon nanotube networks enhanced by UV light for detection of organic gases (ethanol, acetone)
Open Research DataCarbon nanotube networks of different optical transparencies were investigated via resistance and 1/f noise measurements for detection of ethanol and acetone. The sensor resistive and noise responses were collected for dark and UV-assisted conditions, revealing the improvement in sensor sensitivity and limit of detection after applying UV light (275...
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Raman spectra of PCMCA-X (potassium citrate derived porous carbon materials obtained at various temperatures of carbonization)
Open Research DataThese data contain Raman spectra of PCMCA-700 (potassium citrate derived porous carbon materials obtained at 700°C ), PCMCA-800 (potassium citrate derived porous carbon materials obtained at 800°C ), PCMCA-900 (potassium citrate derived porous carbon materials obtained at 900°C ). The D peak at 1340 cm−1 and the G peak at 1592 cm−1 can be seen in all...
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Volumes of N,N-dimethylacetamide solvated metal cations. Variation within the manganese(II) to zinc(II) series
PublicationDensities and apparent molar volumes for Mn(ClO4)2,Co(ClO4)2 , Ni(ClO4)2,Cu(ClO4)2 , and Zn(ClO4)2 in N, N -dimethylacetamide (DMA) solutions at T = 298.15 K are reported. Densities and apparent molar volumes of tetrabutylammonium tetraphenylborate...
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Preliminary Microbiological Tests of S-Carvone and Geraniol and Selected Derivatives of These Compounds That May Be Formed in the Processes of Isomerization and Oxidation
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O-substituted tetrahydroxamate derivatives of p-tert-butylcalix[4]arene as receptors for transition and heavy metal cations
PublicationTetrasubstituted O-hydroxamate derivatives of p-tert-butylcalix[4]arene were applied as active materials in ion-selective membrane electrodes and were tested towards Pb-selectivity. The electrodes gave near-Nernstian characteristics for Pb2+ cations. The selectivity coefficients were determined. The influence of plasticizer on the electrode behaviour was studied. The dependence of the chemical structure on selectivity coefficients...
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Solvation of ionic liquids based on N-methyl-N-alkyl morpholinium cations in dimethylsulfoxide – volumetric and compressibility studies
PublicationThe density and sound velocity of the solutions of ionic liquids based on N-alkyl-N-methyl-morpholinium cations, N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-butyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-methyl-N-octyl-morpholinium bis(trifluoromethanesulfonyl)imide and N-decyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide in dimethylsulfoxide were measured at T = (298.15 to 318.15)...
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DESIGN LOGICAL LINGUISTIC MODELS TO CALCULATE NECESSITY IN TRUCKS DURING AGRICULTURAL CARGOES LOGISTICS USING FUZZY LOGIC
Publication: The study is aimed to develop the logic-linguistic models to design a number of rules for the correct calculation of the vehicles needed, taking into account the technical, technological, and weather and climate conditions of the harvesting and transport complex. The article has shown that the construction of the design of logic-linguistic models was not performed earlier to solve the problem of the agro-industrial production...
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Rhamnolipid CMC Prediction
PublicationRelationships between the purity, pH, hydrophobicity (log Kow) of the carbon substrate, and the critical micelle concentration (CMC) of rhamnolipid type biosurfactants (RL) were investigated using a quantitative structure–property relationship (QSPR) approach and are presented here for the first time. Measured and literature CMC values of 97 RLs, representing biosurfactants at different stages of purification, were considered....
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Carbon dioxide emissions and fuel consumption from passenger cars tested over the NEDC and WLTC – an overview and experimental results from market-representative vehicles
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Spectrofluorometrical Determination of Vitamin B 1 in Different Matrices Using Box‐Behnken Designed Pipette Tip Solid Phase Extraction by a Carbon Nanotube Sorbent
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Determination of mefenamic acid in urine and pharmaceutical samples by HPLC after pipette-tip solid phase microextraction using zinc sulfide modified carbon nanotubes
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Electrocatalytic NADH Sensing using Electrodes Modified with 2‐[2‐(4‐Nitrophenoxy)ethoxy]ethylthio‐Substituted Porphyrazine/Single‐Walled Carbon Nanotube Hybrids
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
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Advanced oxidation (H2O2 and/or UV) of functionalized carbon nanotubes (CNT-OH and CNT-COOH) and its influence on the stabilization of CNTs in water and tannic acid solution
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Controllable Synthesis of 3D Hollow-Carbon-Spheres/Graphene-Flake Hybrid Nanostructures from Polymer Nanocomposite by Self-Assembly and Feasibility for Lithium-Ion Batteries
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Wyznaczanie współczynnika przejmowania ciepła podczas wrzenia w przepływie dwutlenku węgla (Prediction of flow boling heat transfer coefficient for carbon dioxide in minichannels)
PublicationW pracy przedstawiono wyniki obliczeń uzyskane za pomocą własnego modelu półemirycznego dla wybranych danych eksperymentalnych dla wrzenia w przepływie dwutlenku węgla. Metoda obliczeniowa została zweryfikowana z danymi eksperymentalnymi Docoulombiera i innych (2011) oraz Mastrullo i innych (2009). Badania eksperymentalne dotyczą pełnego zakresu zmienności stopnia suchości oraz zakresu prędkości masowej G=200-1200 kg/m2s. rozwijany...
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Leveraging food waste for electricity: A low-carbon approach in energy sector for mitigating climate change and achieving net zero emission in Hong Kong (China)
PublicationIn recent years, food waste has been a global concern that contributes to climate change. To deal with the rising impacts of climate change, in Hong Kong, food waste is converted into electricity in the framework of low-carbon approach. This work provides an overview of the conversion of food waste into electricity to achieve carbon neutrality. The production of methane and electricity from waste-to-energy (WTE) conversion are...
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Porous carbon derived from rice husks as sustainable bioresources: insights into the role of micro-/mesoporous hierarchy in hosting active species for lithium–sulphur batteries
PublicationThe exploration of natural resources as sustainable precursors affords a family of green materials. Exploring highly abundant and available biowaste precursors remaining from food processing throughout a scalable and cost-effective material synthesis path is highly important especially for new materials discovery in emerging energy storage technologies such as lithium–sulphur (Li–S) batteries. Herein, we have produced a series...
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Effect of copper and silver modification of NH2-MIL-125(Ti) on the photoreduction of carbon dioxide to formic acid over this framework under visible-light irradiation
PublicationCu and Ag enhance the photocatalytic activities of metal–organic frameworks (MOFs) toward CO2 conversion because of their CO2 adsorption capacities and effects on the lowest unoccupied molecular orbital (LUMO) overpotentials of MOFs. However, to date, targeted introduction of metals into MOFs to achieve visible (Vis)- light-active photocatalysts for CO2 photoconversion has not been realized. Herein, a series of aminefunctionalized...
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Activation of peroxymonosulfate using carbon black nano-spheres/calcium alginate hydrogel matrix for degradation of acetaminophen: Fe3O4 co-immobilization and microbial community response
PublicationHerein, we focused on the degradation of acetaminophen (ACT) drug in liquid phase by peroxymonosulfate (PMS) activated by carbon black nano-spheres (CBNS). The nanostructured activator was immobilized into calcium alginate hydrogel matrix (CAHM) to avoid the washout of the fine nanostructures. The Langmuir modeling showed an insignificant contribution to the adsorption process in the removal of ACT. The basic pH conditions favored...
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Rapid and Green Separation of Mono- and Diesters of Monochloropropanediols by Ultrahigh Performance Supercritical Fluid Chromatography–Mass Spectrometry Using Neat Carbon Dioxide as a Mobile Phase
PublicationThis study demonstrates the effect of column selectivity and density of supercritical carbon dioxide (SC-CO2) on the separation of monochloropropanediol (MCPD) esters, known as food toxicants, using SC-CO2 without addition of cosolvent in ultrahigh performance supercritical fluid chromatography–mass spectrometry (UHPSFC-MS). This study shows that over 20 2-monochloropropanediol (2-MCPD) and 3-monochloropropanediol (3-MCPD) mono-...
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Original footbridge in Mikolajki, Poland
PublicationIn summer 2016, a new footbridge in the town of Mikołajki (Poland) was built, over a stream connecting two adjacent lakes – Talty and Mikołajki. Its modern construction, based on the shape of a DN ice-boat, makes it inique in Poland, and probably in the world as well. This novel and dynamic shape became a significant landmark associated not only with Mikołajki, but also with the whole region of Mazury, as well as with sailing...
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Research Platform for Monitoring, Control and Security of Critical Infrastructure Systems
PublicationSustainable operation of Critical Infrastructure Systems (CISs) is of a major concern to modern societies. Monitoring, control and security of such systems plays a key role in guaranteeing continuous, reliable and above all secure access to the resources provided by these systems. Development of adequate software and hardware structures, as well as algorithms to perform such functions cannot be done apart from the operational conditions...
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Functionalized nanodiamonds as a perspective green carbo-catalyst for removal of emerging organic pollutants
PublicationRapid industrial and urban development jointly with rising global population strongly affect the large-scale issues with drinking, groundwater, and surface water pollution. Concerns are not limited to environmental issues but also human health impact becoming serious global aspect. Organic pollution becomes a primarily serious hazard, therefore, the novel sophisticated approaches to treat them are thoroughly investigated. Among...
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Electrochemical Characterization of Gelatine Derived Ceramics
PublicationNew materials obtained by pyrolysis of gelatine (G) and poly(1,2-dimethylsilazane) (PSN) (weight ratio: G/PSN 70/30) at temperatures 700 and 900 °C were characterized by SEM and Raman spectroscopy. The presence of ceramics influences on the cluster size of the materials. Electrochemical tests were performed by cyclic voltammetry and galvanostatic cyclic polarization. The capacity of G/PSN was 464 and 527 mAh/g for materials pyrolysed...
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ECG measurement from the hand with elbows in the air - Woman 27 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows in the air - Man 29 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows to the body - Man 29 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows to the body - Woman 27 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows to the body - Woman 49 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows in the air - Woman 49 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows to the body - Man 53 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows in the air - Woman 30 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows in the air - Man 53 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows in the air - Man 30 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows to the body - Man 30 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows to the body - Woman 24 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows to the body - Woman 30 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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ECG measurement from the hand with elbows in the air - Woman 24 age
Open Research DataThe data set shows the measurements of the ECG signal from the hand made with the use of the proprietary measuring system, based on the AD8232 and STM32 chips. Thanks to such a constructed device, it is possible to measure the ECG signal in a non-standard way - from the hand. The results show the ECG signal for a specific hand and forearm position relative...
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Performance of Haemophilus influenzae impedimetric biosensors based on screen-printed carbon electrodes (SPCE) with boron-doped diamond foils
Open Research DataThis dataset contains electrochemical impedance spectroscopy studies of SPCE electrodes containing boron-doped diamond BDD foils and functionalized towards detection of Protein D and Haemophilus influenzae.