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Wyniki wyszukiwania dla: Organic–Inorganic Hybrid
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Kinetics of the Organic Compounds and Ammonium Nitrogen Electrochemical Oxidation in Landfill Leachates at Boron-Doped Diamond Anodes
PublikacjaElectrochemical oxidation (EO) of organic compounds and ammonium in the complex matrix of landfill leachates (LLs) was investigated using three different boron-doped diamond electrodes produced on silicon substrate (BDD/Si)(levels of boron doping [B]/[C] = 500, 10,000, and 15,000 ppm—0.5 k; 10 k, and 15 k, respectively) during 8-h tests. The LLs were collected from an old landfill in the Pomerania region (Northern Poland) and were...
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Influence of dispersed phase content on the mechanical properties of electroless nanocomposite Ni-P/Si3N4 and hybrid Ni-P/Si3N4/graphite layers deposited on the AW-7075 alloy.
PublikacjaThe article presents the results of mechanical testing of Ni-P/Si3N4 nanocomposite and hybrid Ni-P/Si3N4/graphite coatings deposited on AW-7075 aluminum alloy using the chemical reduction method. In terms of mechanical testing, microhardness was measured, and surface roughness and adhesion of the coatings to the aluminum substrate were determined using the “scratch test” method. The surface morphology of the deposited layers was...
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The influence of polarization of titania nanotubes modified by a hybrid system made of a conducting polymer PEDOT and Prussian Blue redox network on the Raman spectroscopy response and photoelectrochemical properties
PublikacjaIn this work we show the impact of applied potential on network vibrations and photoelectrochemical properties of a composite material containing hydrogenated titania nanotubes and poly (3,4-ethylenedioxythiophene) with iron hexacyanoferrate (H-TiO2/pEDOT:Fehcf) acting as a redox centre. For this purpose, Raman spectroscopy measurements under the working electrode (WE) polarization were carried out, allowing investigation of changes...
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Dissolved and colloidal organic nitrogen removal from WWTP effluents and reject waters using physical-chemical processes
PublikacjaFour physical-chemical processes were compared in terms of the efficiencies of dissolved and colloidal organic nitrogen (DON and CON) removal from the secondary effluents (SE) and reject water from full-scale biological nutrient removal activated sludge systems. Adsorption on activated carbon was most efficient and allowed to remove from the SE up to 80% and 100% of DON and CON, respectively. High efficiencies of DON removal from...
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Application of response surface methodology for optimization of metal–organic framework based pipette-tip solid phase extraction of organic dyes from seawater and their determination with HPLC
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Unconventional and user-friendly sampling techniques of semi-volatile organic compounds present in an indoor environment: An approach to human exposure assessment
PublikacjaThe commonly applied solutions used to assess the potential risk of human exposure to semi-volatile organic compounds (SVOCs) are based on the investigation of biological samples collected in an invasive or non-invasive manner. For SVOCs, which are typically introduced to humans through the respiratory system, dermal adsorption, or digestive system, sampling solutions generally used in the indoor environments are classified as...
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Elemental and water-insoluble organic carbon in Svalbard snow: a synthesis of observations during 2007–2018
PublikacjaLight-absorbing carbonaceous aerosols emitted by biomass or fossil fuel combustion can contribute to amplifying Arctic climate warming by lowering the albedo of snow. The Svalbard archipelago, being near to Europe and Russia, is particularly affected by these pollutants, and improved knowledge of their distribution in snow is needed to assess their impact. Here we present and synthesize new data obtained on Svalbard between 2007...
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Selection Of Optimal Working Fluid For Use With Hybrid Microchannel-Microjet Heat Exchanger
PublikacjaThe paper presents the investigation to find best suited working fluid for a microjet- microchannel cooling module. In which microjets are impinging into the microchannels and forming a liquid film on the impingement surface. This technology takes benefits from two very attractive heat removal techniques. When laminar jets are impinging on the surface have a very high kinetic energy at the stagnation point, also in microchannels...
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Current commutation process in a ultra-fast fuse-IGBT hybrid circuit breaker.
PublikacjaUkład hybrydowy bezpiecznika topikowego i tranzystora IGBT umożliwia bardzo szybkie włączenie do obwodu zwarciowego impedancji ograniczającej wartość prądu. Po eksplozji krótkiego topika bezpiecznika wywołanej narastającym prądem zwarciowym wywołuje w czasie poniżej 2 ms wzrost napięcia na topiku do wartości ok.20 - 25V, po czym prąd jest komutowany do gałęzi z przyrządem półprzewodnikowym typu GTO lub IGBT. Ostateczne wyłączenie...
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Improving the performance of the 3-dB microstrip hybrid-ring based power dividers
PublikacjaW pracy przedstawiono wyniki teoretycznych i eksperymentalnych badań zintegrowanych układów mikropaskowych 3-dB dzielników mocy wykorzystującch strukturę pierścieniową. Zaproponowano modyfikację geometrii układu prowadzącą do poprawy jego charakterystyk transmisyjnych.
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Cascaded Buck Hybrid Interlink Converter for Multiple-Input / Multiple-Output Operation
PublikacjaThe provision of isolated- and non-isolated DC output voltages by Power electronics power-conditioning devices in the recent ‘green-energy-revolution’ era is on course. In this paper, a structure for multi-input multi-output(MIMO) DC–DC buck converter is proposed to generate output voltages of varying levels with fewer component-count. The DC output voltage of each of the constituting buck converters can be used independently or...
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Application of Hybrid FEM-DIC Method for Assessment of Low Cost Building Structures
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Hybrid Process Equipment: Improving the Efficiency of the Integrated Metalworking Machines Initial Designing
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Operational analysis of threats to the security of NATO’s eastern flank. Context of hybrid activities
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CHITOSAN-DERIVATIVES IN COMBINATIONS WITH SELECTED PORPHYRINOIDS AS NOVEL HYBRID MATERIALS FOR MEDICINE AND PHARMACY
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Internal heat recuperation in vapor compression and hybrid desiccant air conditioning systems
PublikacjaPraca przedstawia badania prowadzone w Katedrze Techniki Cieplnej Politechniki Gdańskiej nad wewnętrznym odzyskiem ciepła w parowo-spreżarkowych oraz adsorpcyjnych hybrydowych urządzeniach klimatyzacyjnych. Zaprezentowano wyniki analizy psychrometrycznej procesów realizowanych w urządzeniach, stanowiska badawcze urządzeń oraz uzyskane wyniki eksperymentalne.
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Biobased Polyethylene Hybrid Composites with Natural Fiber: Mechanical, Thermal Properties, and Micromechanics
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<title>HOST: hybrid optoelectronic versatile telemetric system for local community</title>
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Synthesis and thermal characterization of luminescent hybrid composites based on bisphenol A diacrylate and NVP
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Toward a hybrid model of ship performance in ice suitable for route planning purpose
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A compact seven-section rat-race hybrid coupler incorporating pbg cells
PublikacjaA conventional rat-race coupler has been doubly miniaturized: (i) characteristic impedances and electrical lengths of microstrip sections have been adequately modified as the first step of size reduction and (ii) T-shaped PBG cells have been implemented to diminish strip section length as the second step of circuit rat-race couplerminiaturization. The experimental results show good agreement with theoretical characteristics. Furthermore,...
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Influence of the method of the control of the hybrid contactless short-circuit limiter on power quality
PublikacjaW artykule przedstawiono wpływ sterowania bezstykowego ogranicznika prądów zwarciowych na ograniczanie zapadów napięcia. Scharakteryzowano podstawowe własności ogranicznika oraz układu sterowania jego pracą. Ponieważ prąd zwarciowy jest detekowany przez dedykowany superkrótki bezpiecznik sterowanie musi być dostosowane do czasu przedrukowego i łukowego topika, które zależą od aktualnej wartości prądu i aktualnej konfiguracji obwodu....
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Application of hybrid radiation modes of microstrip line in rectangular patch antenna design
PublikacjaW pracy przedstawiono metodę wykorzystania hybrydowych rodzajów promieniujących linii mikropaskowej do projektowania anten mikropaskowych. Pokazano,że pojedynczy rodzaj promieniujący można wykorzystać do przybliżonego opisu pola promieniowania anteny mikropaskowej. Zamieszczono wyniki symulacji potwierdzające zadowalającą dokładność przybliżenia w przypadku obliczeń częstotliwości środkowych pracy anteny oraz rezystancji promieniowania...
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A new hybrid method for analysis of scattering from arbitrary configuration of cylindrical objects
PublikacjaArtykuł opisuje nową hybrydową metodę analizy rozpraszania fali elektromagnetycznej od obiektów cylindrycznych o dowolnym przekroju poprzecznym. W prezentowanym podejściu każdy obiekt jest traktowany jako efektywny cylinder o przekroju kołowym, opisany przez macierz impedancyjną. W celu uzyskania owej macierzy zastosowano połączenie metod różnic skończonych w dziedzinie częstotliwości (FDFD) i dopasowania rodzajów (MM). W celu...
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Hybrid materials comprising trimethylglycinamide groups: immobilization consequences for anion binding affinities
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Hybrid Numerical-Analytical Approach for Force Prediction in End Milling of 42CrMo4 Steel
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Investigation on microstructure, mechanical, and tribological performance of Cu base hybrid composite materials
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Improving signal quality of a speech codec using hybrid perceptual-parametric algorithm
PublikacjaW artykule zaprezentowano hybrydową architekturę parametryczno-perceptualną kodeka mowy. Jego podstawę stanowi kodek CELP, który wspomagany jest kodekiem perceptualnym. Celem zastosowania proponowanej metody jest uzyskanie poprawy jakości kodowania sygnału mowy. Badaniom poddano dwie architektury, z których w jednej dźwięczne części sygnału rezydualnego kodeka CELP kodowane są perceptualnie. Drugi z proponowanych kodeków dokonuje...
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Hybrid electrodes composed of electroactive polymer and metal hexacyanoferrates in non-aqueous electrolytes
PublikacjaMateriały hybrydowe złożone z polimeru elektroaktywnego poli(3,4-etylenodioksytiofenu) (pEDOT) i heksacyjanożelazianów wybranych metali Mehcf (Me = Fe, Co, Ni) zostały poddane testom w elektrolitach niewodnych składających się z mieszaniny rozpuszczalników węglan etylenu (EC) : węglan propylenu (PC) w stosunku objętościowym 1:1 oraz wybranych soli: KPF6 i LiPF6. Właściwości elektrochemiczne materiałów badane były metodami woltamperometrii...
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Hybrid technique for the analysis of scattering from periodic structures composed of irregular objects
PublikacjaW pracy zaproponowano nową metodę hybrydową do badania zjawiska rozpraszania fali elektromagnetycznej na strukturach periodycznych złożonych z obiektów rozpraszających o nieregularnym kształcie. Zaprezentowana metoda została wykorzystana do badania własności nowych struktur falowych. Uzyskane wyniki numeryczne zostały zweryfikowane eksperymentalnie.
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Field Tests on Hydrodynamic and Hybrid Operation of a Bidirectional Thrust Bearing of a Pump-Turbine
PublikacjaIn vertical shaft pump turbines operating in pumped storage power plants an important role is played by a thrust bearing. Due to the bidirectional character of operation, thrust bearing tilting pads have to be supported symmetrically, which is known to be unfavourable from the point of view of their performance. Large thrust bearings have to be carefully designed so as to minimise excessive thermo-elastic pad deformations. The...
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INFLUENCE OF THE HULL SHAPE ON THE ENERGY DEMAND OF A SMALL INLAND VESSEL WITH HYBRID PROPULSION
PublikacjaRecently, there has been a significant development of ecological propulsion systems, which is in line with the general trend of environmentally friendly “green shipping”. The main aim is to build a safe, low-energy passenger ship with a highly efficient, emission-free propulsion system. This can be achieved in a variety of ways. The article presents the main problems encountered by designers and constructors already at the stage...
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Nonlinearity shaping in nanostructured glass-diamond hybrid materials for optical fiber preforms
PublikacjaNanodiamond integration with optical fibers has proved a compelling methodology for magneto-optics. We reveal that the applicability of nanodiamonds in nonlinear optics goes beyond the previous demonstrations of frequency converters. Instead, we exploit the recently reported volumetric integration of nanodiamonds along the optical fiber core and show that the nonlinear response of glasses can be manipulated by nanodiamonds. By...
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Application of case based reasoning to hybrid expert system for electronic filter design
PublikacjaPrzedstawiono koncepcję i przykład praktycznej realizacji obiektowo zorientowanego hybrydowego systemu ekspertowego wykorzystującego rozumowanie sytuacyjne. System wykorzystuje algorytmy najbliższego sąsiada i sztuczne sieci neuronowe. System został przetestowany jako klasyfikator decyzyjny w projektowaniu filtrów elektronicznych. W budowie systemu został wykorzystany obiektowy system CLIPS, rozszerzony o wiele dodatkowych funkcji...
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Retention of selected heavy metals: Cd, Cu, Pb in a hybrid wetland system
PublikacjaWykonano bilans wybranych metali ciężkich Cd2+, Pb2+, Cu2+ dla pilotowej oczyszczalni hydrofitowej w Przywidzu k. Gdańska. Wykazano m.i. że sorpcja była głównym mechanizmem odpowiedzialnym za usuwanie tych pierwiastków ze ścieków.
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Post-impact moisture absorption in hybrid glass, aramid, carbon/epoxy composites
PublikacjaZbadano chłonność wody i własności po udarze i absorpcji wody w laminatach hybrydowych aramidowo-szklano-węglowych. Badania porównawcze dla laminatów szklano-epoksydowych wykazały 18% i 33% spadek wytrzymałości na ściskanie odpowiednio w wyniku udaru o energii 10J oraz udaru i absorpcji wody.
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A possibility of vibration surveillance of the hybrid systems by the optimal control at energy performance index.
PublikacjaPraca poświęcona jest nadzorowaniu drgań niestacjonarnych układów mechanicznych modelowanych metodą elementów skończonych. W celu redukcji poziomu drgań wprowadzono zewnętrzne sygnały sterujące. Zdefiniowano uzmienniony w czasie energetyczny wskaźnik jakości. Uwzględnienie założenia o możliwości podziału układu na podukład modalny, podukład strukturalny oraz podukład łączący umożliwiło opis układu sterowanego we współrzędnych hybrydowych....
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Determination of volatile organic compounds in water samples using membrane-solid phase microextraction (M-SPME) (headspace version)
PublikacjaThe results of a study on the use of membrane-solid phase microextraction (M-SPME) for sampling volatile organic compounds (VOCs) from the headspace above the liquid medium are presented. The sampled VOCs were subsequently quantified by gas chromatography (GC). Two systems were compared in this study, i.e. a novel two-phase sorption system (M-SPME), and a commercial fibre. Headspace sampling using SPME was optimized with respect...
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Comparison of traditional district heating with low temperature district heating systems featuring organic Rankine cycle and heat pump
PublikacjaPaper presents a comparison between a traditional district heating system with conventional boilers as a source of heat and electricity purchases from power utilities and a low temperature DH system incorporating the CHP with organic Rankine Cycle providing electricity and local heat pump raising the temperature of the DH fluid to the required temperature in the dwelling, meaning that both heat and electricity are produced within...
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Vibrational Sum-Frequency Generation Activity of a 2,4-Dinitrophenyl Phospholipid Hybrid Bilayer: Retrieving Orientational Parameters from a DFT Analysis of Experimental Data
PublikacjaThe vibrational nonlinear activity of films of 2,4-dinitrophenyl phospholipid (DNP) at the solid interface is measured by sum-frequency generation spectroscopy (SFG). Hybrid bilayers are formed by a LangmuirSchaefer approach in which the lipid layer is physisorbed on top of a self-assembled monolayer of dodecanethiol on Pt with the polar heads pointing out from the surface. The SFG response is investigated in two vibrational frequency...
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Evaluation of polycaprolactone as a new sorbent coating for determination of polar organic compounds in water samples using membrane–SPME
PublikacjaCommercially available solid-phase microextraction fibers used for isolation of polar analytes are based on the adsorption phenomenon. In consequence, typical limitations bonded with analytes displacement and matrix effects are very frequent. In the present study, alternative solution is described. Polycaprolactone (PCL) was used for the first time as sorbent to isolate polar organic compounds from water samples using the membrane–solid-phase...
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Different design aspects of an Organic Rankine Cycle turbine for electricity production using a geothermal binary power plant
PublikacjaIn recent years, pressure has been growing to increase the share of renewable energy sources in electricity generation, which may offer opportunities for the development of geothermal energy in regions that have been so far considered unprofitable in this respect. One such country currently undergoing an energy transition is Poland in which low-temperature geothermal resources are currently used for district heating and recreation...
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Structural and spectroscopic investigation of new luminescent hybrid materials based on calix[4]arene-tetracarboxylate and Ln 3+ ions (Ln = Gd, Tb or Eu)
PublikacjaLanthanide-calixarene hybrid materials are of particular interest due to the combination of the interesting properties of the ligand cavity-like structure and the luminescent features of lanthanides. The aim of this study was to synthesize and investigate the photophysical properties of Eu3+, Tb3+ and Gd3+ hybrids based on calix[4]arene-tetracarboxylate. The preparation of two structurally different...
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Ground Tire Rubber Modified by Ethylene-Vinyl Acetate Copolymer: Processing, Physico-Mechanical Properties, Volatile Organic Compounds Emission and Recycling Possibility
PublikacjaGround tire rubber (GTR) was reclaimed and modified with 10 phr of ethylene-vinyl acetate copolymer via low-temperature extrusion process. Processing, physico-mechanical properties, volatile organic compounds emission, and recycling possibility were investigated. In order to better understand the impact of used modifiers, their efficiency was compared with transpolyoctenamer, which is an additive that is commercially dedicated...
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Pendant Proton-Relays Systematically Tune the Rate and Selectivity of Electrocatalytic Ammonia Generation in a Fe-Porphyrin Based Metal-Organic Framework
PublikacjaElectrocatalytic nitrite reduction (eNO2RR) is a promising alternative route to produce ammonia (NH3). Until now, several molecular catalysts have shown capability to homogeneously reduce nitrite to NH3, while taking advantage of added secondary-sphere functionalities to direct catalytic performance. Yet, realizing such control over heterogeneous electrocatalytic surfaces remains a challenge. Herein, we demonstrate that heterogenization...
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Electric transport in organic system with planar DBP/F16ZnPc junction on the basis of direct current and small signal admittance spectra analysis
PublikacjaThe objective of this work was to determine electric transport in the organic device based on a planar junction of electron donor and electron acceptor materials, namely ITO/MoO3/DBP/F16ZnPc/BCP/Ag. The analysis reported herein was based on direct current-voltage measurements and small-signal admittance spectra in the dark and under illumination. Such analysis may provide information on potential barriers, parasitic resistances...
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Massively parallel linear-scaling Hartree–Fock exchange and hybrid exchange–correlation functionals with plane wave basis set accuracy
PublikacjaWe extend our linear-scaling approach for the calculation of Hartree–Fock exchange energy using localized in situ optimized orbitals [Dziedzic et al., J. Chem. Phys. 139, 214103 (2013)] to leverage massive parallelism. Our approach has been implemented in the ONETEP (Order-N Electronic Total Energy Package) density functional theory framework, which employs a basis of non-orthogonal generalized Wannier functions (NGWFs) to achieve...
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Theoretical designing of selenium heterocyclic non-fullerene acceptors with enhanced power conversion efficiency for organic solar cells: a DFT/TD-DFT-based prediction and understanding
PublikacjaIn this study, we have designed and explored a new series of non-fullerene acceptors for possible applications in organic solar cells. We have designed four molecules named as APH1 to APH4 after end-capped modification of recently synthesized Y6-Se-4Cl molecule. Density functional theory and time dependent-density functional theory have been employed for computing geometric and photovoltaic parameters of the designed molecules....
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Numerical modeling of PFAS movement through the vadose zone: Influence of plant water uptake and soil organic carbon distribution
PublikacjaIn this study, we investigated the effects of soil organic carbon (SOC) distribution and water uptake by plant roots on PFAS movement in the vadose zone with a deep groundwater table under temperate, humid climate conditions. Two series of numerical simulations were performed with the HYDRUS computer code, representing the leaching of historical PFOS contamination and the infiltration of water contaminated with PFOA, respectively. We...
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Organic pollutants photodegradation increment with use of TiO2 nanotubes decorated with transition metals after pulsed laser treatment
PublikacjaAmong various titanium(IV) oxide (TiO2, titania) structures, 1D nanotubes (TiO2 NTs) produced during the two-electrode anodization process, are extensively utilized in sensors or supercapacitors as well as in photo(electro)catalytic water splitting. However, due to wide bandgap and fast electron-hole recombination additional modifications, mostly concerned on materials surface, are required. According to the recent research, TiO2...