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Wyniki wyszukiwania dla: GREEN ANALYTICAL CHEMISTRY
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The evolution of education spaces - from plan as generator to regenerative architecture, virtual rooms and green campuses
PublikacjaThe study programmes are often considered the main formative factors in the process of educating future architects. Another highly influential component is the architectural characteristics of learning spaces, and consequently the impact of the physical built environment on the quality of education has been widely discussed. However, not often do we realise that the characteristics of education spaces correlate with the organisational...
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Green energy extraction for sustainable development: A novel MPPT technique for hybrid PV-TEG system
PublikacjaThe Photovoltaic (PV) module converts only a small portion of irradiance into electrical energy. Most of the solar energy is wasted as heat, resulting in a rise in PV cell temperature and a decrease in solar cell efficiency. One way to harvest this freely available solar thermal energy and improve PV cell efficiency is by integrating PV systems with thermoelectric generators (TEG). This cogeneration approach of the hybrid PV-TEG...
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Superhydrophobic sponges based on green deep eutectic solvents for spill oil removal from water
PublikacjaThe paper described a new method for crude oil-water separation by means of superhydrophobic melamine sponges impregnated by deep eutectic solvents (MS-DES). Due to the numerous potential of two-component DES formation, simple and quick screening of 156 non-ionic deep eutectic solvents using COSMO-RS (Conductor-like Screening Model for Real Solvents) computational model was used. DES which were characterized by high solubility...
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An Investigation of Polyamides Based on Isoidide-2,5-dimethyleneamine as a Green Rigid Building Block with Enhanced Reactivity
PublikacjaNovel, semicrystalline polyamides and copolyamides were synthesized from a new carbohydrate-based diamine, namely isoidide-2,5-dimethyleneamine (IIDMA). In combination with 1,6-hexamethylene diamine (1,6-HDA) as well as the biobased sebacic acid (SA) or brassylic acid (BrA), the desired copolyamides were obtained via melt polymerization of the nylon salts followed by a solid-state polycondensation (SSPC) process. Depending on the...
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A review of phosphorus recovery methods at various steps of wastewater treatment and sewage sludge management. The concept of “no solid waste generation” and analytical methods
PublikacjaPhosphorus deposits around the world are rapidly depleting, therefore phosphorus recovery methods are gaining more and more interest both in science and industry. This article presents the main methods of phosphorus recovery from sewage sludge. The described approaches are divided in two groups: phosphorus recovery from sewage sludge and leachate, and recovery of phosphorus from sewage sludge ashes. The latter seems to have more...
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Application of Box–Behnken design in the optimization of a simple graphene oxide/zinc oxide nanocomposite-based pipette tip micro-solid phase extraction for the determination of Rhodamine B and Malachite green in seawater samples by spectrophotometry
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Successive cytotoxicity control by evolutionary surface decorated electronic push-pull green ZnCr-LDH nanostructures: Drug delivery enlargement for targeted breast cancer chemotherapy
PublikacjaThe reason for the increasing bioavailability and biocompatibility of the porous nanomaterials in the presence of different (bio)molecules is still unknown. The role of difference functional groups and their interactions with the potential bioavailability and biocompatibility is of great importance. To investigate the potential contribution of the electronic effects (especially on the surface of the porous nanomaterials) on their...
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Understanding element composition of medicinal plants used in herbalism—A case study by analytical atomic spectrometry
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House dust as a source of analytical information on concentration of polybrominated diphenyl ethers (PBDEs) - first approach
PublikacjaPolybrominated diphenyl ethers (PBDEs), which are best recognized as flame retardants, were in 2001, by virtue of Stockholm Convention, listed in a group of Persistent Organic Compounds (POPs). Increasing concentration levels of PBDEs, reported in human tissues (e.g., blood, serum, breast milk, etc.) haverecently caught worldwide concern due to their potential tendency to disrupt thyroid hormones, neurobehavioral deficits and endocrine...
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Approximate analytical boundary conditions for efficient finite difference frequency domain simulations in cylindrical coordinates
PublikacjaW artykule zaprezentowano prostą technikę analizy rezonatora otwartego. Algorytm łączy w sobie metodę różnic skończonych i rozwinięć funkcyjnych , umożliwiając implementację warunków brzegowych symulujących otwartą przestrzeń. Metoda testowana była w analizie rezonatorów o różnych wymiarach,a otrzymane wyniki dobrze zgadzały się z rezultatami innych metod.
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Application of sublation and two phase titration methods for analytical of surfactants in AFFF fire-fighting foams
PublikacjaCelem badań była próba opracowania odpowiedniej metody izolacji ze ścieków fluorowanych związków powierzchniowo czynnych FZPC do celów analitycznych, a także metody ich ilościowego oznaczania. W badaniach polegających na oznaczaniu stężenia FZPC w oparciu o miareczkowanie w układzie dwufazowym: woda/chloroform użyto Hyaminy 1622, jako titranta oraz błękitu metylenowego, jako wskaźnika. Kolejnym etapem badań była izolacja ZPC z...
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Analytical-numerical approach to solve the transport equation for steady gradually varied flow in open channel
PublikacjaW pracy przedstawiono metodę rozwiązania równania transportu adwekcyjno-dyfuzyjnego w przypadku ustalonego niejednostajnego przepływu w kanałach otwartych. Metoda wykorzystuje technikę dekompozycji. Do rozwiązania równania adwekcji-dyfuzji zastosowano analityczne rozwiązanie w postaci odpowiedzi impulsowej liniowego równania adwekcji-dyfuzji. Dokonano adaptacji metody dla przypadku ze zmiennymi parametrami. Do rozwiązania drugiej...
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Analytical and experimental determination of parameters for the non-linear viscoelastic model of earthquake-induced structural pounding
PublikacjaNieliniowy model lepko-sprężysty umożliwia dokładną symulację siły zderzenia w czasie oraz symulację odpowiedzi konstrukcji podatnej na zderzanie podczas trzęsień ziemi. Jednym z celów niniejszego artykułu jest wyprowadzenie wzoru na zależność pomiędzy liczbą tłumienia zderzenia (parametr wspomnianego modelu), a współczynnikiem odbicia. Kolejnym celem jest wyznaczenie zakresu wartości współczynników odbicia oraz współczynników...
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Experimental and analytical analysis of punching shear in flat slabs supported on column topped with concrete head
PublikacjaAn experimental laboraatory test of the two series of slab-column elements topped with drop panels of varying sizes is described in this paper. The scope of the paper is to investigate the influence of the drop panel size and stiffness on the behaviour of the connection between the flat slab and the column topped by the concrete head. The impact of the head size and stiffness is analysed analytically and experimentally. The experimental...
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Analytical comparison between capacitor assisted and diode assisted cascaded quasi-z-source inverters
PublikacjaQuasi-Z falownik z prostym obwodem impedancyjnym jest bardzo interesującym rozwiązaniem topologicznym ze względu na unikalną możliwość jednostopniowego przekształcanie DC/AC w połączeniu z funkcjami obniżania i podwyższania napięcia. W niektórych aplikacjach jego właściwości podwyższające są jednak niewystarczające. Wyższe napięcie wejściowe można uzyskać w wyniku zastosowania w quasi-Z-falownikach kaskadowych obwodów impedancyjnych....
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Development of an orbital shaker-assisted fatty acid-based switchable solvent microextraction procedure for rapid and green extraction of amoxicillin from complex matrices: Central composite design
PublikacjaIn this study, a cheap, fast and simple orbital shaker-assisted fatty acid-based switchable solvent microextraction (OS-FASS-ME) procedure was developed for the extraction of amoxicillin (AMOX) in dairy products, pharmaceutical samples and wastewater prior to its spectrophotometric analysis. Fatty acid-based switchable solvents were investigated for extracting AMOX. The key factors of the OS-FASS-ME procedure were optimized using...
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Chemometrics and Statistics | Multicriteria Decision Making
PublikacjaThis contribution describes the application of Multicriteria Decision Making tools in analytical chemistry. The general scheme of MCDM is presented to show its general steps. The most frequently applied in analytical sciences MCDM techniques – AHP, ELECTRE, PROMETHEE and TOPSIS – are briefly described and their advantages and disadvantages are discussed. The applications in analytical chemistry are selection of an appropriate...
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Electric and magnetic dipole shielding constans for the ground state of the relativistic hydrogen-like atom: Application of the Sturmian expansion of the generalized Dirac-Coulomb Green function
PublikacjaStosując rozwinięcie sturmowskie funkcji Greena-Diraca-Coulomba, znaleziono wyrażenie analityczne dla stałych ekranowania elektrycznego i magnetycznego relatywistycznego atomu wodoropodobnego w stanie podstawowym.
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Investigation on environmental chemistry changes in the Antarctic Special Management Area (ASMA 1): King George Island, South Shetlands Islands
PublikacjaThe doctoral dissertation included a review of the scientific literature that resulted in the selection of the research area, type of samples and chemical species that were marked. The published series of articles contains an in-depth description of the results of chemical analyses of surface water, sediment and snow samples from the Antarctic Specially Managed Area (ASMA 1) – King George Island. In addition, studies have been...
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Thermo-oxidative exfoliation of carbon black from ground tire rubber as potential reinforcement in green tires
PublikacjaConsidering the balance between rapidly growing global tire demand and scarcity of natural resources, recycling and reclaiming techniques of tire rubber have become the state of the art. Herein, we set out to implement a self-designed thermo-oxidative reactor for the exfoliation of carbon black (CB) from ground tire rubber, which is efficiently functioned under a thermo-oxidative reclaiming condition without any additive. The exfoliation...
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Chemical Profile and Antioxidant Activity of the Kombucha Beverage Derived from White, Green, Black and Red Tea
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Evaluation of Fluoride and Selected Chemical Parameters in Kombucha Derived from White, Green, Black and Red Tea
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Green synthesis and application of GO nanoparticles to augment growth parameters and yield in mungbean (Vigna radiata L.)
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Phytotoxic activity of diclofenac: Evaluation using a model green alga Chlamydomonas reinhardtii with atrazine as a reference substance
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Green`s function methods for Mathematical modeling of unidirectional diffusion process in isothermal metals bonding process
PublikacjaPodano wykorzystanie funkcji Greena w rozwiązaniu matematycznego modelu dyfuzji jednowymiarowej podczas izotermicznego łączenia metali.
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The Economic Dimension of Using the Integration of Highway Sound Screens with Solar Panels in the Process of Generating Green Energy
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Noise level arrangement in determined zones of homogenous development of green areas on the example of the spa park in Inowrocław
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A green route for high-performance bio-based polyurethanes synthesized from modified bio-based isocyanates
PublikacjaThe need for sustainability and a circular economy leads to the development of innovative greener materials and technologies. This paper is focused on a novel class of bio-based polyurethanes (PUs) synthesized with the use of bio-monomers including bio-based isocyanates. The novelty of this work is related to the usage of bio-based modified isocyanate via a two-step solvent-free synthesis of novel cast bio-based poly(ester-urethanes)...
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Sulfuric acid modified clinoptilolite as a solid green catalyst for solvent-free α-pinene isomerization process
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Density functional theory-based simulations of sum frequency generation spectra involving methyl stretching vibrations: effect of the molecular model on the deduced molecular orientation and comparison with an analytical approach
PublikacjaThe knowledge of the first hyperpolarizability tensor elements of molecular groups is crucial for a quantitative interpretation of the sum frequency generation (SFG) activity of thin organic films at interfaces. Here, the SFG response of the terminal methyl group of a dodecanethiol (DDT) monolayer has been interpreted on the basis of calculations performed at the density functional theory (DFT) level of approximation. In particular,...
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Simultaneous elimination of Malachite Green, Rhodamine B and Cresol Red from aqueous sample with Sistan sand, optimized by Taguchi L16 and Plackett–Burman experiment design methods
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Ceramic atmospheric pressure micro glow discharge device with evaporating liquid flowing cathode for analytical purposes
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Advancement of Non-Newtonian Fluid with Hybrid Nanoparticles in a Convective Channel and Prabhakar’s Fractional Derivative—Analytical Solution
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Targeted metabolomics in bladder cancer: From analytical methods development and validation towards application to clinical samples
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Selection of peptomeric inhibitors of bovine α-chymotrypsin and cathepsin G based on trypsin inhibitor SFTI-1 using a combinatorial chemistry approach
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Simple Physics-Based Analytical Formulas for the Potentials of Mean Force for the Interaction of Amino Acid Side Chains in Water. IV. Pairs of Different Hydrophobic Side Chains
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Incidence trends for childhood type 1 diabetes in Europe during 1989–2003 and predicted new cases 2005–20: a multicentre prospective registration study
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Effect of bio-based components on the chemical structure, thermal stability and mechanical properties of green thermoplastic polyurethane elastomers
PublikacjaIt seems to be obvious that conditions changes during polyols synthesis have impact on the polyols properties. Even the chemical formula is the same or similar, physicochemical properties and also molecular weight of polyols might be different and are significant in term of future polyurethanes properties and processing. In this work, fully bio-based poly(propylene succinate)s synthesized at different temperature conditions were...
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Mixture toxicity of six sulfonamides and their two transformation products to green algae Scenedesmus vacuolatus and duckweed Lemna minor
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Green alga Chlamydomonas reinhardtii can effectively remove diclofenac from the water environment – A new perspective on biotransformation
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Application of ionic liquid-based microwave-assisted extraction of malachite green and crystal violet from water samples
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Influence of Abiotic Stress Factors on the Antioxidant Properties and Polyphenols Profile Composition of Green Barley (Hordeum vulgare L.)
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Current View on Green Tea Catechins Formulations, Their Interactions with Selected Drugs, and Prospective Applications for Various Health Conditions
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Enhanced Light-Induced Biosynthesis of Fatty Acids Suitable for Biodiesel Production by the Yellow-Green Alga Eustigmatos magnus
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Magnetizability of the relativistic hydrogen-like atom: applicayion of the Sturmian expansion of the first-order Dirac-Coulomb Green function
PublikacjaStosując rozwinięcie sturmowskie funkcji Greena-Diraca-Coulomba, znaleziono wyrażenie analityczne dla magnetyzowalności relatywistycznego atomu wodoro-podobnego w stanie podstawowym.
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Green Physical Activity Indicator: Health, Physical Activity and Spending Time Outdoors Related to Residents Preference for Greenery
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Evaluation of inhibition of cancer cell proliferation in vitro with different berries and correlation with their antioxidant level by advanced analytical methods
PublikacjaW pracy opisano wyniki badań:- właściwości przeciwutleniających ekstraktów rozpuszczalnikowych (DMSO) uzyskanych z różnych gatunków owoców jagodowych- zdolność do infibizacji proliferacji komórek rakowych.W badaniach wykorzystano testy (DPPH) oraz zaawansowane techniki analityczne (spektroskopia FTIR oraz fluoroscencja 3D)Wyniki badań wskazują, że spożywanie owoców jagodowych może zredukować zagrożenie procesu proliferacji komórek...
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Analytical expression between the impact damping ratio and the coefficient of restitution in the non-linear viscoelastic model of structural pounding
PublikacjaWyniki wcześniejszych badań pokazują, iż nieliniowy model lepko-sprężysty zderzeń konstrukcji budowlanych podczas trzęsień ziemi najdokładniej symuluje siłę zderzenia w czasie kontaktu oraz odpowiedź konstrukcji. Celem niniejszego artykułu jest wyprowadzenie wzoru na zależność pomiędzy liczbą tłumienia zderzenia (parametr wspomnianego modelu) a współczynnikiem odbicia, który jest parametrem często stosowanym i analizowanym w literaturze....
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The metabolic profiles of pterin compounds as potential biomarkers of bladder cancer—Integration of analytical-based approach with biostatistical methodology
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Analytical Buckling of FG Nanobeams on The Basis of A New One Variable First-Order Shear Deformation Beam Theory
PublikacjaIn this work, buckling analysis of functionally graded (FG) nanobeams based on a new refined beam theory has been analyzed. The beam is modeled as an elastic beam subjected to unidirectional compressive loads. To achieve this aim, the new obtained beam theory has only one variable which leads to one equation similar to the Euler beam theory and also is free of any shear correction factor. The equilibrium equation has been...