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Wyniki wyszukiwania dla: CHROMIUM-NICKEL ALLOY
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Bis(di-n-propylamine-κN)bis(tri-tert -butoxysilanethiolato-κS)chromium(II)
PublikacjaAtom chromu w tytułowym kompleksie jest czterokrotnie koordynowany: przez dwa atomy siarki grup tri-tert-butoksysilanotiolanowych oraz dwa atomy azotu z dwóch cząsteczek di-n-propyloaminy. Atom Cr leży w centrum inwersji w pozycji Wyckoffa a (1/2, 1/2, 1/2).
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Chromium Ion Pair Luminescence: A Strategy in Broadband Near-Infrared Light-Emitting Diode Design
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Reactions of NO2 with chromium(III) complexes with histamine and pyridoxamine ligands studied by the stopped-flow technique
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Enabling simultaneous redox transformation of toxic chromium(VI) and arsenic(III) in aqueous media—A review
PublikacjaSimultaneous conversion of most harmful As(III) and Cr(VI) to their less toxic counterparts is environmentally desirable and cost-effective. It has been confirmed that simultaneous oxidation of As(III) to As(V) and reduction of Cr(VI) to Cr(III) can occur via free radical or mediated electron transfer processes. While Cr(VI) is reduced by reacting with H•, eaq−, photoelectron directly or undergoing ligand exchange with H2O2 and...
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Selection of measurement frequency in Mott–Schottky analysis of passive layer on nickel
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The role of β-diketones in the extraction of cobalt (II) and nickel (II) ions
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Synergistic effect of nickel formate on the thermal and flame-retardant properties of polypropylene
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Oxidative Stress Level in the Testes of Mice and Rats during Nickel Intoxication
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Bonding interactions in oxydiacetate and thiodiacetate cobalt(II) and nickel(II) complexes
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Spectral dependences of photocurrent of the aluminium-nickel phthalocyanine-tetracene-aluminium heterojunction
PublikacjaAnalizowano charakterystyki spectralne fotoprądu płynącego przez heterozłącze tetracen-ftalocyjanina niklu. Obserwowany fotoprąd jest prądem dziurowym generowanym w trzech obszarach: w pobliżu obu elektrod Al i międzypowierzchni tetracen-ftalocyjanina niklu.
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Selection of measurement frequency in Mott-Schottky analysis of passive layer on nickel
PublikacjaPrzedstawiono zależności Mott'a - Schottky'ego dla różnych częstotliwości pomiarowych. Kształt uzyskanych zależności zależy od doboru tych częstotliwości. Związane jest to z tym, że stężenie defektów w warstwie pasywnej zależy od doboru częstotliwości. Metoda DEIS pozwala na uniknięcie tych niedogodności.
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Chlorido(ethyldiphenylphosphine-P)(1-pyrrolidinecarbodithioato-S,S)nickel(II)
PublikacjaPrzedmiotem publikacji jest struktura krystaliczna tytułowego [NiCl{S2CN(CH2)4}Cl(C14H15P)]. Atom niklu jest w tym przypadku skoordynowany przez S,S-chelatującą resztę ditiokarbaminianową, cząsteczkę fosfiny, zaś geometrię koordynacyjną dopełnia atom chloru.
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Powder metallurgy of the porous Ti-13Nb-13Zr alloy of different powder grain size
PublikacjaThe objective of the present project was to determine the effects of powder granulation (fraction of grain size) for the Ti-13Nb-13Zr alloy, produced by powder metallurgy, on its porosity, grain cohesion, compressive strength, and Young`s modulus. Two powder fractions, 45–105 µm, and 106–250 µm were applied. The 50 mass pct of NH4HCO3 was added as a space holder. The specimens were in compaction stage uniaxially pressed at pressure...
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The Chemical and Biological Properties of Nanohydroxyapatite Coatings with Antibacterial Nanometals, Obtained in the Electrophoretic Process on the Ti13Zr13Nb Alloy
PublikacjaThe risk of an early inflammation after implantation surgery of titanium implants has caused the development of different antimicrobial measures. The present research is aimed at characterizing the effects of nanosilver and nanocopper dispersed in the nanohydroxyapatite coatings, deposited on the Ti13Zr13Nb alloy, and on the chemical and biological properties of the coatings.The one-stage deposition process was performed by the...
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Microstructure and mechanical properties of laser surface-treated Ti13nb13zr alloy with MWCNTs coatings
PublikacjaLaser surface modification of titanium alloys is one of the main methods of improving the properties of titanium alloys used in implantology. This study investigates the microstructural morphology of a laser-modified surface layer on a Ti13Nb13Zr alloy with and without a carbon nanotube coating deposited by electrophoretic deposition. Laser modification was performed for samples with and without carbon nanotube coating for two...
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Tracking of the Multimodal Ordering Process in FePd Alloy
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Internal friction in FePd alloy during ordering
PublikacjaStwierdzono występowanie wysokiego poziomu tarcia wewnętrznego w zahartowanym stopie FePd (50% at. Pd). Zbadano proces uporządkowania atomowego w korelacji ze zmianami tarcia wewnętrznego defektu modułu i relaksacji magnetycznej stopu porządkującego się podczas nagrzewania do 900 K. Zaobserwowano efekt prędkości nagrzewania na punkt Curie.
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Phase investigations of copper based CuZn38Al2MnFe alloy
PublikacjaW pracy przedstawiono analizę fazową mosiądzu CuZn38Al2MnFe. Wykazano, że obecność fazy Fe4Mn77Si19 powoduje kruchość stopu w teście zginania próbek.
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Elasto-viscoplastic properties of AA2017 aluminium alloy
PublikacjaArtykuł opisuje procedurę identyfikacji parmetrów materiałowych dla sprężysto-lepkoplastycznego modelu Bodnera-Partoma. Prezentowane są symulacje numeryczne testów jednoosiowego rozciągania z różnymi prędkościmi odkształcenia, które porównane są z wynikami eksperymantalnymi.
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Induction Assisted Hybrid Friction Stir Welding of Dissimilar Materials AA5052 Aluminium Alloy and X12Cr13 Stainless Steel
PublikacjaThis research aimed to study the induction in-situ heated hybrid friction stir welding (IAFSW) method to join AA5052 aluminium alloy with X12Cr13 stainless steel (SS) to enhance joint strength. The potency of this method on the mechanical properties and microstructural characterizations were also investigated. The results show that the transverse tensile strength gained was 94% of the AA5052 base metal that is 229.5 MPa. This superior...
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The Influence of Tool Shape and Process Parameters on the Mechanical Properties of AW-3004 Aluminium Alloy Friction Stir Welded Joints
PublikacjaThe purpose of the following study was to compare the effect of the shape of a tool onthe joint and to obtain the values of Friction Stir Welding (FSW) parameters that provide the bestpossible joint quality. The material used was an aluminium alloy, EN AW-3004 (AlMn1Mg1). To theauthors’ best knowledge, no investigations of this alloy during FSW have been presented earlier. Fivebutt joints were made with a self-developed, cylindrical,...
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Pressure effects on the electronic structure and superconductivity of (TaNb)0.67(HfZrTi)0.33 high entropy alloy
PublikacjaEffects of pressure on the electronic structure, electron-phonon interaction, and superconductivity of the high entropy alloy ( TaNb ) 0.67 ( HfZrTi ) 0.33 are studied in the pressure range 0–100 GPa. The electronic structure is calculated using the Korringa-Kohn-Rostoker method with the coherent potential approximation. Effects of pressure on the lattice dynamics are simulated using the Debye-Grüneisen model and the Grüneisen...
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Bis(3,5-dimethylpyridine-kN)bis(tri-tert-butoxysilanethiolato-kS)chromium(II)toluene solvate
PublikacjaW tytułowym związku atom chromu jest czterokrotnie koordynowany: przez dwa atomy siarki grup tri-tert-butoksysilanotiolanowych oraz dwa atomy azotu z dwóch cząsteczek 3,5-dimetylopirydyny. Geometria ligandów wokół centrum metalicznego jest płaska kwadratowa. Cząsteczka leży na dwukrotnej osi symetrii przechodzącej przez atom N 3,5-dimetylopirydyny. Dodatkowo w krysztale na jedną cząsteczkę kompleksu przypada jedna cząsteczka toluenu.
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The influence of welding heat input on the quality and properties of high strength low-alloy dissimilar steel butt joints
PublikacjaThe paper presents the results of non-destructive and destructive tests of dissimilar highstrength low-alloy S460ML and S460N steel butt joints. These steels are characterized by similar mechanical properties, but their carbon equivalent CeIIW values are much different. The joints were made using different values of heat input for each welding bead. They were tested by non-destructive methods: visual, penetrant, radiographic and...
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Biological and antibacterial properties of chitosan-based coatings with AgNPs and CuNPs obtained on oxidized Ti13Zr13Nb titanium alloy
PublikacjaDespite numerous studies, the antibacterial efficiency and cytotoxicity of chitosan-based coatings with nanometals need further studies. The purpose of this research was to determine the biological properties of chitosan coatings implemented with either silver nanoparticles (AgNPs) or copper nanoparticles (CuNPs), that were electrophoretically deposited on electrochemically oxidized Ti13Zr13Nb alloy. The SEM tests were used to...
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Microstructure and Properties of Electroless Ni-P/Si3N4 Nanocomposite Coatings Deposited on the AW-7075 Aluminum Alloy
PublikacjaThe article presents the results of mechanical and tribological tests of Ni-P/Si3N4 nanocomposite coatings deposited on the AW-7075 aluminum alloy using the chemical reduction method. The influence of the chemical composition on the Vickers microhardness determined by the DSI method was examined. The nanocomposite layers were made of Si3N4 silicon nitride in a polydisperse powder with a particle size ranging from 20 to 25 nm. The...
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Redetermination of bis(O,O′-diethyl dithiophosphato-κ2S,S′)nickel(II)
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Enhanced Degradation of Ethylene in Thermo-Photocatalytic Process Using TiO2/Nickel Foam
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The effect of temperature during soybean oil hydrogenation on nickel catalyst poisoning by phospholipids.
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Chlorido(1-pyrrolidinecarbodithioato-k2S,S')(triphenylphosphine)nickel(II)chloroform hemisolvate
PublikacjaTytułowy kompleks chloro(1-pirolidynoditiokarbaminiano-S,S')(trifenylofosfina)-nikiel(II), będący hemisolwatem chloroformu zawiera płaski rdzeń o składzie NiClS2P. Molekuły chloroformu oddziałują z kompleksem poprzez słabe wiązania C-H...S.
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Novel sugar-based nickel-tungsten carbide catalysts for dry reforming of hydrocarbons
PublikacjaThe search for new materials for dry reforming of hydrocarbons with high activity, stability, and ease of synthesis is still one of the main directions of research in the field of heterogeneous catalysis. Traditional methods of carbide synthesis require the use of combustible gases of petrochemical origin. The search for new catalysts based on renewable and safe carbon sources is highly demanded. Therefore, we report WC and Ni-WC...
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3D mesoporous α-Co(OH)2 nanosheets electrodeposited on nickel foam: A new generation of macroscopic cobalt-based hybrid for peroxymonosulfate activation
PublikacjaCobalt-based catalysts with high stability and facile recovery for heterogeneous peroxymonosulfate (PMS) activation are still rather sparse and therefore highly desirable. Herein, 3D mesoporous α-Co(OH)2 nanosheets was created on robust nickel foam (NF) via facile electrodeposition approach at 6 mA/cm2 for only 400 s. Almost complete removal of phenol can be achieved within 7 min with a degradation rate of 0.39 min−1, 2 times higher...
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The Effect of Sodium Tetrafluoroborate on the Properties of Conversion Coatings Formed on the AZ91D Magnesium Alloy by Plasma Electrolytic Oxidation
PublikacjaMagnesium and its alloys are widely used in many areas because of their light weight, excellent dimensional stability, and high strength-to-weight ratio. However, the material exhibits poor wear and corrosion resistance, which limits its use. Plasma electrolytic oxidation (PEO) is an effective surface modification method for producing ceramic oxide layers on Mg and their alloys. The influence of the additions of sodium tetrafluoroborate...
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Effect of hybrid modification by ceramic layer formation in MAO process and laser remelting on the structure of titanium bio-alloy Ti13Nb13Zr
PublikacjaTo improve the biological properties of titanium alloy Ti13Nb13Zr, hybrid modifications involving micro-arc oxidation (MAO) and Nd: YAG laser remelting were carried out in two combinations. The first consisted of laser modification before the production of the ceramic layer by the micro-arc oxidation process, and the second combination involved Nd: YAG laser modification after the MAO process. The creation of developed surface...
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Exsolution of Ni nanoparticles on the surface of cerium and nickel co-doped lanthanum strontium titanate as a new anodic layer for DIR-SOFC. Anti-coking potential and H2S poisoning resistance of the prepared material
PublikacjaThe aim of this study was to evaluate a new catalytic material for biogas fueled DIR-SOFC. This material was a perovskite-type SrTiO3 doped with La, Ce and Ni of a general formula La0.27Sr0.54Ce0.09Ni0.1Ti0.9O3-σ (LSCNT). Additional preparation steps were undertaken to promote a nickel exsolution process. Heat post-treatment of powders in a humidified H2 resulted in an intensive growth of nickel nanoparticles (NPs) while the temperature...
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Cyclic Behavior of Masonry Shear Walls Retrofitted with Engineered Cementitious Composite and Pseudoelastic Shape Memory Alloy
PublikacjaThe behavior of masonry shear walls reinforced with pseudoelastic Ni–Ti shape memory alloy (SMA) strips and engineered cementitious composite (ECC) sheets is the main focus of this paper. The walls were subjected to quasi-static cyclic in-plane loads and evaluated by using Abaqus. Eight cases of strengthening of masonry walls were investigated. Three masonry walls were strengthened with different thicknesses of ECC sheets using...
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High-Temperature Tensile Behaviour of GTAW Joints of P92 Steel and Alloy 617 for Two Different Fillers
PublikacjaThis study explores the high-temperature (HT) tensile rupture characteristics of a dissimilar gas-tungsten-arc-welded (GTAW) joint between P92 steel and Alloy 617, fabricated using ER62SB9 and ERNiCrCoMo-1 fillers. The high-temperature tensile tests were performed at elevated temperatures of 550 ◦C and 650 ◦C. An optical microscope (OM) and a field emission scanning electron microscope (FESEM) were utilized to characterize the...
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Effects of electrophoretic deposition times and nanotubular oxide surfaces on properties of the nanohydroxyapatite/nanocopper coating on the Ti13Zr13Nb alloy
PublikacjaLoad-bearing implants are developed with a particular emphasis placed on an application of ceramic hydroxyapatite coatings in order, to enhance the bioactivity of titanium implants and to shorten the healing time. Therefore, thin, fully crystalline coatings that are, highly adhesive, hydrophilic and demonstrating antibacterial properties are ly looked for. The aim of this research was to develop and characterize the properties...
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Experimental and theoretical study on high-temperature creep of VT6 titanium alloy under multi-axial loading conditions
PublikacjaIn the framework of damage mechanics, we discuss a new mathematical model that describes the kinetics of the stress–strain state and damage accumulation during material degradation by the mechanism of long-term strength under complex multiaxial stress state. An experimental and theoretical technique is proposed for determination of material parameters and scalar constitutive functions for damaged media based on specially set experiments...
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A new complex compound of chromium(III) with 5-aminopyridine-2-carboxylate anions – Structure, physicochemical and catalytic properties
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EXPERIMENTAL EVALUATION OF THE EMISSIVITY OF A NITI SHAPE MEMORY ALLOY
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Special Issue “Corrosion Resistance of Alloy and Coating Materials”
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Underwater robot actuated by shape memory alloy wires
PublikacjaW pracy przedstawiono koncepcję projektu robota podwodnego z napędem wykorzystującym materiały SMA ze stopów z pamięcią kształtu. Rozpatrywany układ ma budowę modułową złożoną z segmentów na podobieństwo do anatomicznej budowy dżdżownicy. Pojedyńczy segment składa się z dwóch okrągłych tarcz, pomiędzy którymi umieszczono balon wypełniony wodą. Wielkość balonu jest dopasowana w taki sposób do rozmiarów tarcz oraz długości sprężyn...
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Influence of the heat treatment on corrosion characteristics of the Superston alloy
PublikacjaW artykule przedstawiono wpływ hartowania i odpuszczania na twardość i właściwości korozyjne stopu Superston, stosowanego na śruby okrętowe. Stwierdzono, iż hartowanie z temperatury 900 st.C i odpuszczanie w temperaturze 550 st.C znacząco podwyższa odporność na korozję stopu Superston w 3% roztworze NaCl w porownaniu ze stanem odlanym.
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Surface treatment of porous Ti13Nb13Zr alloy for biomedical applications
PublikacjaPrzeprowadzono badania materiału porowatego, przeznaczonego na implanty ortopedyczne, wytworzonego metodą metalurgii proszków ze stopu Ti13Nb13Zr. Proszki z badanego stopu uzyskano metodą rozpylania plazmowego. Otrzymano próbki o otwartej porowatej strukturze, stopniu porowatości do 68% i średniej wielkości porów w przedziale 30-150 mikrometrów. Obróbka próbek porowatych - utlenianie termiczne, chemiczne i/lub elektrochemiczne...
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High temperature corrosion resistance of porous hastelloy alloy
PublikacjaW pracy przedstawiono badania korozyjne stopu Hastelloy w wysokich temperaturach.
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Porous biomaterial for orthopaedic implants based on titanium alloy
PublikacjaTytan i jego stopy są szeroko stosowane jako biomateriały dla zastosowań ortopedycznych. Badania związane z ich najlepszą odpornością na korozję i ścieranie, biozgodnością i bioaktywnością są stale prowadzone. Obecne badania koncentrują się również na projektowaniu i produkcji materiałów porowatych w oparciu o stopy np. Ti-13Nb-13Zr, które mogą być stosowane do wytwarzania implantów. Jedną z najbardziej efektywnych metod wytwarzania...
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Microstructure and corrosion properties of the laser treated SUPERSTON alloy
PublikacjaPrzedstwiono wyniki laserowego nadtapiania powierzchni stopu SUPERSTON w warunkach kriogenicznych. Zaprezentowano obraz powierzchni stopu po badaniach korozyjnych oraz wyniki pomiarów mikrotwardości i odporności korozyjnej.
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Pin Angle Thermal Effects on Friction Stir Welding of AA5058 Aluminum Alloy: CFD Simulation and Experimental Validation
PublikacjaThe friction stir welding (FSW) of tool pin geometry plays a critical role in the final properties of the produced joint. The tool pin geometry directly affects the generation of heat and the flow of internal materials during the FSW process. The effects of the FSW tool pin angle on heat generation and internal flow have not been quantitatively investigated in detail. In this manuscript, a validated Computational Fluid Dynamic...
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Fractographical quantitative analysis of EN-AW 2024 aluminum alloy after creep pre-strain and LCF loading
PublikacjaThis paper explores the applicability of a new damage parameter combining both fracture surface topography and loading features to estimate the fatigue lifetime under creep pre-strain and low-cycle fatigue loading. Fractures of EN-AW 2024 aluminum alloy caused by mixed creep and low-cycle fatigue loading are experimentally characterized and quantified via surface topography analysis. The specimens were preliminary damaged in a...